Effect of Dilution on Acoustic and Transport Properties of Reservoir Fluid Systems and Their Interplay

SPE Journal ◽  
2020 ◽  
Vol 25 (06) ◽  
pp. 2867-2880
Author(s):  
Ram R. Ratnakar ◽  
Edward J. Lewis ◽  
Birol Dindoruk

Summary Acoustic velocity is one of the key thermodynamic properties that can supplement phase behavior or pressure/volume/temperature (PVT) measurements of pure substances and mixtures. Several important fluid properties are relatively difficult to obtain through traditional measurement techniques, correlations, or equation of state (EOS) models. Acoustic measurements offer a simpler method to obtain some of these properties. In this work, we used an experimental method based on ultrasonic pulse-echo measurements in a high-pressure/high-temperature (HP/HT) cell to estimate acoustic velocity in fluid mixtures. We used this technique to estimate related key PVT parameters (such as compressibility), thereby bridging gaps in essential data. In particular, the effect of dilution with methane (CH4) and carbon dioxide (CO2) at pressures from 15 to 62 MPa and temperatures from 313 to 344 K is studied for two reservoir fluid systems to capture the effect of the gas/oil ratio (GOR) and density variations on measured viscosity and acoustic velocity. Correlative analysis of the acoustic velocity and viscosity data were then performed to develop an empirical correlation that is a function of GOR. Such a correlation can be useful for improving the interpretation of the sonic velocity response and the calibration of viscosity changes when areal fluid properties vary with GOR, especially in disequilibrium systems. In addition, under isothermal conditions, the acoustic velocity of a live oil decreases monotonically with decreasing pressure until the saturation point where the trend is reversed. This observation can also be used as a technique to estimate the saturation pressure of a live oil or as a byproduct of the target experiments. It supplements the classical pressure/volume measurements to determine the bubblepoint pressure.

2009 ◽  
Vol 12 (05) ◽  
pp. 793-802 ◽  
Author(s):  
P. David Ting ◽  
Birol Dindoruk ◽  
John Ratulowski

Summary Fluid properties descriptions are required for the design and implementation of petroleum production processes. Increasing numbers of deep water and subsea production systems and high-temperature/high-pressure (HTHP) reservoir fluids have elevated the importance of fluid properties in which well-count and initial rate estimates are quite crucial for development decisions. Similar to rock properties, fluid properties can vary significantly both aerially and vertically even within well-connected reservoirs. In this paper, we have studied the effects of gravitational fluid segregation using experimental data available for five live-oil and condensate systems (at pressures between 6,000 and 9,000 psi and temperatures from 68 to 200°F) considering the impact of fluid composition and phase behavior. Under isothermal conditions and in the absence of recharge, gravitational segregation will dominate. However, gravitational effects are not always significant for practical purposes. Since the predictive modeling of gravitational grading is sensitive to characterization methodology (i.e., how component properties are assigned and adjusted to match the available data and component grouping) for some reservoir-fluid systems, experimental data from a specially designed centrifuge system and analysis of such data are essential for calibration and quantification of these forces. Generally, we expect a higher degree of gravitational grading for volatile and/or near-saturated reservoir-fluid systems. Numerical studies were performed using a calibrated equation-of-state (EOS) description on the basis of fluid samples taken at selected points from each reservoir. Comparisons of measured data and calibrated model show that the EOS model qualitatively and, in many cases, quantitatively described the observed equilibrium fluid grading behavior of the fluids tested. First, equipment was calibrated using synthetic fluid systems as shown in Ratulowski et al. (2003). Then real reservoir fluids were used ranging from black oils to condensates [properties ranging from 27°API and 1,000 scf/stb gas/oil ratio (GOR) to 57°API and 27,000 scf/stb GOR]. Diagnostic plots on the basis of bulk fluid properties for reservoir fluid equilibrium grading tendencies have been constructed on the basis of interpreted results, and sensitivities to model parameters estimated. The use of centrifuge data was investigated as an additional fluid characterization tool (in addition to composition and bulk phase behavior properties) to construct more realistic reservoir fluid models for graded reservoirs (or reservoirs with high grading potential) have also been investigated.


2004 ◽  
Vol 44 (1) ◽  
pp. 605
Author(s):  
A.K.M. Jamaluddin ◽  
C. Dong ◽  
P. Hermans ◽  
I.A. Khan ◽  
A. Carnegie ◽  
...  

Obtaining an adequate fluid characterisation early in the life of a reservoir is becoming a key requirement for successful hydrocarbon development. This work presents and discusses a number of new fluid sampling and fluid characterisation technologies that can be deployed either down hole or at surface in the early stages of the exploration and development cycle to achieve this objective. Techniques discussed include methods to monitor and quantify oil-based mud contamination, gas-liquid-ratio (GLR) and basic fluid composition in real time during open-hole formation testing operations. In addition, we demonstrate the applicability of new surface analysis techniques that allow for rapid, accurate, and reliable measurements of key fluid properties, such as saturation pressure, gas-oil ratio, extended carbon number composition, viscosity, and density, on-site within a few hours of retrieving reservoir fluid samples at surface. Finally, prediction tools used to extend these limited measurements to a traditional PVT fluid characterisation are presented along with example measurements from all the techniques described. In conclusion, it is shown that the implementation of these techniques in a complementary program can reduce the risk associated with making key development decisions that are based on an understanding of reservoir fluid properties.


2019 ◽  
Vol 19 (1) ◽  
pp. 147-161
Author(s):  
Nguyen Manh Hung ◽  
Hoang Dinh Tien ◽  
Nguyen Viet Ky

Oil and gas have been discovered and produced from Cuu Long basin for more than 20 years however the distribution charateristics according to stratigraphy have not been studied. In this study, data from more than 200 PVT reports of more than 30 discoveries and published reports of previous studies were investigated to find out the distribution characteristics of reservoir fluid properties. The results show that oil and gas in Cuu Long basin mainly follow normal distribution, in some areas they are in redistribution (retrogradation) stage. Saturation pressure, GOR and compressibility are very high at the centre area and rapidly reduce at the margin area, whereas reservoir fluid density is in the inverse trend. Oil and gas have tendency to accumulate in NW-SE direction. Condensate discoveries in Cuu Long basin mainly result from redistribution process except some discoveries in center of basin.


2009 ◽  
Vol 43 (4) ◽  
pp. 327-331 ◽  
Author(s):  
Jeff Hargrove ◽  
Eric D. Zemper ◽  
Mary L. Jannausch

Abstract A novel technique for achieving plethysmography measurements utilizing noncontact laser displacement sensors is described. This method may have utility in measuring respiratory and pulmonary function similar to that of respiratory inductive plethysmography. The authors describe the apparatus and method and provide results of a validation study comparing respiratory excursion data obtained by (1) the laser sensor technique, (2) standard respiratory inductive plethysmography (RIP), and (3) lung volume measurements determined by pressure variations in a control volume. Six healthy volunteers (five female, one male, ages ranging from 19 to 23 years) were measured for tidal breathing excursions simultaneously via all three measurement techniques. Results: Excellent correlation between the techniques was shown. Pairwise comparisons among all three measurement techniques across all subjects showed intraclass correlation coefficients of 0.995 in each case. These results indicate the laser plethysmograph (LP) system provides results that are, at a minimum, equivalent to those of the RIP at the two sites commonly measured by RIP. Use of the LP system has the potential to provide much more extensive and precise measurements of chest wall function and the respiratory musculature.


1964 ◽  
Vol 4 (01) ◽  
pp. 56-66 ◽  
Author(s):  
L.L. Melton ◽  
W.T. Malone

Abstract Fluid mechanics research conducted with non-Newtonian fluid systems now permits prediction of the behavior of these fluid systems in both laminar and turbulent modes of flow through circular pipes. Present work concerns non-Newtonian fluid systems currently used in the hydraulic fracturing process. During fracturing treatments, an unsteady-state condition may frequently be encountered arising from' the reaction rate of a chemical additive. This condition must be evaluated in order to predict the actual behavior of a particular fluid during field application. Design and operation of the apparatus used to determine fluid-flow behavior permit obtaining data under such non-equilibrium conditions. This paper shows methods used to obtain rheology measurements, develop hydraulic relationships and evaluate chemical reactions producing unsteady-state conditions. Engineering application of this research is illustrated by employing measured rheological values and developed hydraulic relationships to produce frictional pressure loss (psi/100 ft) vs flow rate (bbl/min) charts of common tubing and casing sizes for an example fracturing fluid. How these charts and chemical reaction rate information are then combined to predict actual turbulent hydraulic behavior during unsteady-state field conditions is also discussed. Introduction Many fluids used in hydraulic fracturing contain chemical additives which impart non-Newtonian fluid properties that may drastically alter their hydraulic behavior. Equally drastic alteration in wellhead pressure, injection rate and hydraulic horsepower requirement may result from these fluid properties. Prior research conducted to relate non-Newtonian fluid properties with hydraulic behavior has not as yet produced a universal relationship, particularly for the turbulent flow region. Which of the many possible non-Newtonian fluid properties is responsible has not been conclusively established. A systematic description, suggested by Metzner, of the many possible non-Newtonian fluid properties exhibited by real - fluid behavior, and a current discussion of theoretical and applied aspects of non-Newtonian fluid technology can be found in Handbook of Fluid Dynamics. Little or no research has previously been attempted with fluids exhibiting time - dependent properties. Addition of chemicals during a fracturing treatment is often accomplished by continuously mixing and displacing the fluid. This produces a time-dependent effect or unsteady-state condition while the fluid is progressing through surface and wellbore conductors. This condition is due to solution or chemical reaction of the additive. Considerable departure from conventional methods of obtaining and interpreting data was found necessary to consider these conditions. Therefore methods were developed to obtain hydraulic behavior information under these complex, unsteady-state conditions. Relationships presented in this paper to predict hydraulic behavior of non-Newtonian fluids in circular pipes were obtained by constructing and operating a small pipeline apparatus in the manner of a pilot-plant study. These relationships are suggested as scale-up equations and are not proposed as fundamental rheological parameters. While perhaps deficient from a fundamental research viewpoint, a pilot-plant study does permit the determination and convenient evaluation of variables pertinent to a process. A pilot-plant study can result in a valid engineering application procedure even when fundamental relationships are still undefined. An excellent series of articles by Bowen has appeared in the chemical engineering literature. These give a thorough review of proposed hydraulic relationships and their limitations for non-Newtonian fluid behavior in circular pipes. A graphical method is presented to scale up data for a fluid exhibiting an anomalous hydraulic behavior in the turbulent flow region. Considerable assistance has been obtained from these articles to interpret the anomalous behavior noted during this investigation. These articles also provided assurance that a pilot plant is a practical approach to evaluate the hydraulic behavior of non-Newtonian fracturing fluids. SPEJ P. 56ˆ


2014 ◽  
Vol 17 (03) ◽  
pp. 384-395 ◽  
Author(s):  
Odd Steve Hustad ◽  
Na Jia ◽  
Karen Schou Pedersen ◽  
Afzal Memon ◽  
Sukit Leekumjorn

Summary This paper presents fluid composition, high-pressure pressure/volume/temperature (PVT) measurements, and equation-of-state (EoS) modeling results for a recombined Tahiti oil, Gulf of Mexico (GoM), and for the oil mixed with nitrogen in various concentrations. The data include: Upper and lower asphaltene onset pressures and bubblepoint pressures for the reservoir fluid swelled with nitrogen. At the reservoir conditions of 94 MPa (13,634 psia) and 94°C (201.2°F), asphaltene precipitation is seen after the addition of 27 mol% of nitrogen. Viscosity data for the swelled fluids showing that the addition of nitrogen significantly reduces the oil viscosity. Slimtube runs indicating that the minimum miscibility pressure (MMP) of the oil with nitrogen is significantly higher than estimated from published correlations. The data were modeled with the volume-corrected Soave-Redlich-Kwong (SRK) EoS and the perturbed-chain statistical association fluid theory (PC-SAFT) EoS. Although both equations provide a good match of the PVT properties of the reservoir fluid, PC-SAFT is superior to the SRK EoS for simulating the upper asphaltene onset pressures and the liquid-phase compressibility of the reservoir fluid swelled with nitrogen. Nitrogen-gas flooding is expected to have a positive impact on oil recovery because of its favorable oil-viscosity-reduction and phase behavior effects.


Sign in / Sign up

Export Citation Format

Share Document