scholarly journals Permeability Damage and Supercritical Fluid Storage in the Cauvery Basin Neyveli Lignite Bed Containing Kaolinite Deposits during Alternative Injection of Brine and CO2

2020 ◽  
Author(s):  
Perumal Rajkumar ◽  
Justine K. Antony ◽  
Selvaraj Mahalingam ◽  
Rakesh Ravi Shankar ◽  
Ramadoss Kesavakumar ◽  
...  
Keyword(s):  
Microstructural Analysis ◽  
Pressure Change ◽  
High Rate ◽  
Coal Bed ◽  
Structural Collapse ◽  
Two Phase ◽  
Test Analysis ◽  
Coal Beds ◽  
Fluid Saturation ◽  
Permeability Damage

Abstract A laboratory based investigation has been conducted on permeability damage and CO2 storage or retention in the lignite core during alternative injection of brine and supercritical carbon dioxide. Moreover, anthracite and bituminous coal beds were focused by the scientific community for effective production and reservoir formation damage study. But, now-a-days, lignite based coal bed methane reservoirs have attracted attention for productive exploitation and formation collapse investigation. Hence, for this purpose, a single component injection two phase (Brine + Supercritical CO2) coreflood test analysis under alternative injections were performed to investigate the occurrence of lignite structural collapse, permeability damage, injectivity decline and CO2 retention as well. The experimental study reveals that, due to gravity segregation there is a high rate of fluid saturation in lignite core and also, moderate level of heat transfer coefficient was also noted. Also, lignite core structural collapse under the brine and supercritical CO2 injection at different velocities resulted in huge volume of coal and kaolinite fines concentration. Kaolinite and coal fines migration resulted in pressure change and permeability decline in lignite core. The suspensions produced were passed to microstructural analysis and it revealed that kaolinite fine particle tends to possess a leaflet geometrical structure, which obstructed the cleats and restricted the fluid flow. Subsequently, hysteresis modelling (Pranesh 2018) was applied to this problem to quantify the amount of CO2 retention in lignite core. Additionally, statistical model, multiple linear regression was applied to this problem to validate the experimental model, which showed good agreement.

The Temperature-Phased Anaerobic Biofilter Process

1994 ◽  
Vol 29 (9) ◽  
pp. 213-223 ◽  
Author(s):  
Sandra K. Kaiser ◽  
Richard R. Dague
Keyword(s):  
System Performance ◽  
Anaerobic Treatment ◽  
Size Ratio ◽  
High Rate ◽  
Phase System ◽  
Optimum Size ◽  
Treatment Technology ◽  
Two Phase ◽  
In Series ◽  
Two Temperature

The “temperature-phased anaerobic biofilter” or TPAB process (U.S. Patent pending), is a new high-rate anaerobic treatment system that includes a thermophilic (56°C) biofilter connected in series with a mesophilic (35°C) biofilter providing for two-temperature, two-phase treatment. Three TPAB systems of different thermophilic:mesophilic reactor size ratios were operated at system HRTs of 24 hrs, 36 hrs, and 48 hrs to characterize performance and to determine if an optimum size ratio exists between the thermophilic and mesophilic phases. The three TPAB systems achieved SCOD reductions in excess of 97% and TCOD reductions in excess of 90% for a synthetic milk substrate over a range of system COD loadings from 2 g COD/L/day to 16 g COD/L/day. There was little difference in performance between the three TPAB systems based on COD reduction and methane production. The 1:7 ratio of thermophilic:mesophilic phase TPAB system performed as well as the 1:3 and 1:1 size ratio TPAB systems. In applications of the process, a relatively small thermophilic first-phase can be used without sacrificing overall two-phase system performance. The TPAB process is a promising new anaerobic treatment technology with the ability to achieve higher efficiencies of organic removals than is generally possible for single-stage anaerobic filter systems operated at equivalent HRTs and organic loadings.

Using HEM surveys to evaluate disposal of by-product water from CBNG development in the Powder River Basin, Wyoming

Geophysics ◽  
2008 ◽  
Vol 73 (3) ◽  
pp. B77-B84 ◽  
Author(s):  
Brian A. Lipinski ◽  
James I. Sams ◽  
Bruce D. Smith ◽  
William Harbert
Keyword(s):  
River Basin ◽  
Produced Water ◽  
Water Discharge ◽  
Geophysical Methods ◽  
Powder River Basin ◽  
Coal Bed ◽  
Coal Beds ◽  
Occam’S Inversion ◽  
Product Water ◽  
Location Strategies

Production of methane from thick, extensive coal beds in the Powder River Basin of Wyoming has created water management issues. Since development began in 1997, more than 650 billion liters of water have been produced from approximately 22,000 wells. Infiltration impoundments are used widely to dispose of by-product water from coal bed natural gas (CBNG) production, but their hydrogeologic effects are poorly understood. Helicopter electromagnetic surveys (HEM) were completed in July 2003 and July 2004 to characterize the hydrogeology of an alluvial aquifer along the Powder River. The aquifer is receiving CBNG produced water discharge from infiltration impoundments. HEM data were subjected to Occam’s inversion algorithms to determine the aquifer bulk conductivity, which was then correlated towater salinity using site-specific sampling results. The HEM data provided high-resolution images of salinity levels in the aquifer, a result not attainable using traditional sampling methods. Interpretation of these images reveals clearly the produced water influence on aquifer water quality. Potential shortfalls to this method occur where there is no significant contrast in aquifer salinity and infiltrating produced water salinity and where there might be significant changes in aquifer lithology. Despite these limitations, airborne geophysical methods can provide a broadscale (watershed-scale) tool to evaluate CBNG water disposal, especially in areas where field-based investigations are logistically prohibitive. This research has implications for design and location strategies of future CBNG water surface disposal facilities within the Powder River Basin.

Operando XRD study of LiMn1.5Ni0.5O4 high-voltage cathode under high-rate charge-discharge reaction

2019 ◽  
Vol 34 (S1) ◽  
pp. S8-S13
Author(s):  
T. Konya ◽  
Y. Shiramata ◽  
T. Nakamura
Keyword(s):  
Volume Change ◽  
Low Voltage ◽  
High Rate ◽  
Insertion Reaction ◽  
Phase Reaction ◽  
Two Phase ◽  
Voltage Range ◽  
Lattice Volume ◽  
Rate Determining Step ◽  
Spinel Cathode

Structural variation of LiMn1.5Ni0.5O4 spinel cathode during the Li+ extraction/insertion reaction was studied using operando X-ray diffraction. It was found that the reaction in the voltage range from 3.5 to 4.9 V consisted of two consecutive two-phase reactions, where three spinel phases of LiMn1.5Ni0.5O4, Li0.5Mn1.5Ni0.5O4 and Mn1.5Ni0.5O4 were identified and the lattice volume change in the whole reaction was evaluated as 6%. The reactions were symmetric and reversible under low-current conditions, but some asymmetries were detected during high current operation. Furthermore, a two-phase reaction between cubic and tetragonal phases was observed in the low-voltage reaction at 2.1–3.5 V, where the lattice volume change was approximately 4.9%. The rate-determining step was discussed based on these operando results.

scholarly journals In-situ Experiments to Capture the Evolution of Microstructure During Phase Transformation of Titanium Under Dynamic Loading

2018 ◽  
Vol 183 ◽  
pp. 03020
Author(s):  
Benjamin M. Morrow ◽  
David R. Jones ◽  
Paulo A. Rigg ◽  
George T. Gray ◽  
Ellen K. Cerreta
Keyword(s):  
Phase Transformation ◽  
Dynamic Loading ◽  
Microstructural Analysis ◽  
Alpha Phase ◽  
Material Behavior ◽  
High Rate ◽  
Omega Phase ◽  
In Situ Experiments ◽  
Consistent Picture ◽  
Underlying Mechanisms

Under sufficient stresses, such as during dynamic loading, titanium experiences a phase transformation from hcp alpha phase to hexagonal omega phase. Omega phase is often retained in the microstructure after unloading, and has a strong influence on subsequent mechanical properties. Simulations suggest there are multiple pathways and underlying mechanisms for this transformation. Due to the incredibly short timescales involved, experimental measurements for model validation have been difficult. However, new capabilities at the Advanced Photon Source have enabled diffraction measurements during plate impact experiments to study the evolution of titanium during transformation. These high-rate data allow us to probe the mechanism and kinetics of phase transformations in new ways. Recent results will be presented and compared to post-mortem characterization of soft-recovered shocked specimens. Comparisons are made with previous tests where material was shock-loaded and soft recovered for microstructural analysis. Together these techniques create a consistent picture of material behavior during the shock-induced ff–! phase transformation in titanium.

A high rate capability and long lifespan symmetric sodium-ion battery system based on a bipolar material Na2LiV2(PO4)3/C

2018 ◽  
Vol 6 (21) ◽  
pp. 9962-9970 ◽  
Author(s):  
Meng Li ◽  
Zonglin Zuo ◽  
Jianqiu Deng ◽  
Qingrong Yao ◽  
Zhongmin Wang ◽  
...  
Keyword(s):  
Anode Material ◽  
Rate Capability ◽  
Sodium Ion ◽  
High Rate ◽  
Sodium Ion Battery ◽  
High Rate Capability ◽  
Two Phase ◽  
Battery System

A rhombohedral structured two-phase Na2LiV2(PO4)3/C nanocomposite was synthesized and employed as both cathode and anode material.

scholarly journals Effect of flow rates of gases flowing through a coal bed during coal heating and cooling on concentrations of gases emitted and fire hazard assessment

2019 ◽  
Vol 7 (1) ◽  
pp. 107-121 ◽  
Author(s):  
Marek Więckowski ◽  
Natalia Howaniec ◽  
Adam Smoliński
Keyword(s):  
Fire Hazard ◽  
The Self ◽  
Coal Bed ◽  
Flow Rates ◽  
Coal Beds ◽  
Heating And Cooling ◽  
Heating Phase ◽  
Two Samples ◽  
Cooling Phase ◽  
Phase Temperature

AbstractThe flow velocity of gases in gobs directly influences the kinetics and intensity of gaseous components release during heating and cooling of coal. The assessment of fire hazard is performed on the basis of concentrations of particular gases in a mine air. These concentrations differ in coal heating and cooling phase which was proven in the study. This paper presented the results of the experimental study on temperature distribution in a simulated coal bed in heating (50–250 °C) and cooling (250–35 °C) phases as well as its correlation to variations in concentration of gases released in these phases and flow rates of gases flowing through the coal bed. The research was performed on twenty-two samples of bituminous coals acquired from various coal beds of Polish coal mines. Considerable differences were observed between heating and cooling phases in terms of the concentrations of gases taken into account in calculations of self-combustion index. In the heating phase temperature increase resulted in the decrease of concentrations ratios of ethane, ethylene, propane, propylene and acetylene, while in the cooling phase these ratios increased systemically. The effect of air (in heating phase) and nitrogen (in cooling phase) flow rate on the self-ignition index CO/CO2 was also determined.

Kraft-Mill Biosolids Treatment by Conventional and Biphasic Fermentation

1999 ◽  
Vol 40 (11-12) ◽  
pp. 169-177 ◽  
Author(s):  
S. Ghosh ◽  
D. C. Taylor
Keyword(s):  
Energy Recovery ◽  
Single Stage ◽  
High Rate ◽  
Net Energy ◽  
Municipal Sludge ◽  
Nutrient Source ◽  
Two Phase ◽  
Fuel Gas ◽  
Reduction Efficiency ◽  
Nitrogen Phosphorus

Kraft primary and mixed primary-activated sludges were gasified by thermophilic (50 °C) high-rate and mesophilic two-phase digestion. Kraft sludges were deficient in nitrogen, phosphorus, and other unidentified nutrients. Municipal sludge proved to be a much better nutrient source than inorganic salts. Performance of the mesophilic (35°C), two-phase anaerobic digestion (TPAD) system was about the same as that of thermophilic single-stage, high-rate digestion at a 10-day HRT as judged in terms of methane yield (0.17 SCM/kg VS added) and VS reduction efficiency (43%). The mesophilic TPAD process yielded a higher methane-content (65%) fuel gas; it is capable of exhibiting higher net-energy recovery efficiency than thermophilic single-stage digestion.

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