scholarly journals Effects of organic carbon content on in situ remediation time using steam–air injection

2021 ◽  
Author(s):  
W. Awandu ◽  
O. Trötschler
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Fine Sand ◽  
Coarse Sand ◽  
Air Injection ◽  
Halogenated Hydrocarbons ◽  
Organic Carbon Content ◽  
Desorption Time ◽  
Remediation Time ◽  
Time Required

Abstract Groundwater contamination by chlorinated hydrocarbons (CHC) is a common phenomenon that poses health risks to both humans and animals. These halogenated hydrocarbons infiltrate into the soil matrices and form pools at the bottoms of the aquifers thus contaminating the groundwater sources. Thermally enhanced soil vapour extraction (TSVE) using steam–air injection has gained popularity as an alternative technique to remediate the saturated and vadose source zones contaminated with CHC. This technique has been successfully applied in the remediation of contaminated sites (brownfields, industrial sites) and groundwater. However, the presence of organic carbon (OC) contents within the soil matrices has not been intensively studied. This paper, therefore, intends to contribute toward increasing the understanding of the effects of OC on the remediation time using TSVE. A 2-D flume experimental model was conducted in VEGAS laboratory using coarse sand, fine sand and silty soil with 0, 1 and 2% addition of the activated carbon as OC to investigate the desorption time of PCE and TCE as CHC during TSVE extraction using steam–air injection. 100 kg of soil mixed with the activated carbon was treated with 50 g TCE and 50 g PCE and then remediated using TSVE. The remediation times were recorded and recovered CHC was documented. It was discovered that the presence of OC enhanced the adsorption of the CHC onto the soil matrices thereby increasing the time required for the complete remediation of the contaminant from the soil. An increase of OC by 1% resulted in desorption time by a factor of 4–7.

scholarly journals Determination of soil specific surface area by water vapor adsorption: I Drying of soil samples

1987 ◽  
Vol 59 (2) ◽  
pp. 63-65
Author(s):  
Raina Niskanen ◽  
Väinö Mäntylahti
Keyword(s):  
Organic Carbon ◽  
Carbon Content ◽  
Mineral Soil ◽  
Clay Content ◽  
Fine Sand ◽  
Water Vapor Adsorption ◽  
Soil Samples ◽  
Organic Carbon Content ◽  
Clay Sample

Drying of three mineral soil samples (clay content 4—58 %, organic carbon content 1—5 %) equilibrated at 75.5 % relative humidity was studied. The soils were dried in an oven at +50°C, +70°C and + 105°C for 4 and 8 hours and in a desiccator over pure concentrated H2SO4 and P2O5. Drying over desiccants for 8 hours removed less water than drying at + 50°C. Drying over desiccants for 3—7 days was as efficient as drying at +70°C, for 14—24 days as efficient as 4 hours of drying at + 105°C. Eight hours of drying at + 105°C seemed to be too drastic, because it caused a greater weight loss in the clay sample of 5 % organic carbon content than did prolonged desiccant-drying. Drying at + 70°Cremoved as much water from fine sand which contained 4 % clay as prolonged desiccant-drying.

scholarly journals Microbial activity promoted with organic carbon accumulation in macroaggregates of paddy soils under long-term rice cultivation

2016 ◽  
Vol 13 (24) ◽  
pp. 6565-6586 ◽  
Author(s):  
Yalong Liu ◽  
Ping Wang ◽  
Yuanjun Ding ◽  
Haifei Lu ◽  
Lianqing Li ◽  
...  
Keyword(s):  
Enzyme Activity ◽  
Organic Carbon ◽  
Soil Respiration ◽  
Soil Aggregates ◽  
Fine Sand ◽  
Coarse Sand ◽  
Rice Cultivation ◽  
Rice Soils ◽  
Size Fractions ◽  
Gene Abundance

Abstract. While soil organic carbon (SOC) accumulation and stabilization has been increasingly the focus of ecosystem properties, how it could be linked to soil biological activity enhancement has been poorly assessed. In this study, topsoil samples were collected from a series of rice soils shifted from salt marshes for 0, 50, 100, 300 and 700 years from a coastal area of eastern China. Soil aggregates were fractioned into different sizes of coarse sand (200–2000 µm), fine sand (20–200 µm), silt (2–20 µm) and clay (< 2 µm), using separation with a low-energy dispersion protocol. Soil properties were determined to investigate niche specialization of different soil particle fractions in response to long-term rice cultivation, including recalcitrant and labile organic carbon, microbial diversity of bacterial, archaeal and fungal communities, soil respiration and enzyme activity. The results showed that the mass proportion both of coarse-sand (2000–200 µm) and clay (< 2 µm) fractions increased with prolonged rice cultivation, but the aggregate size fractions were dominated by fine-sand (200–20 µm) and silt (20–2 µm) fractions across the chronosequence. SOC was highly enriched in coarse-sand fractions (40–60 g kg−1) and moderately in clay fractions (20–25 g kg−1), but was depleted in silt fractions (∼ 10 g kg−1). The recalcitrant carbon pool was higher (33–40 % of SOC) in both coarse-sand and clay fractions than in fine-sand and silt fractions (20–29 % of SOC). However, the ratio of labile organic carbon (LOC) to SOC showed a weakly decreasing trend with decreasing size of aggregate fractions. Total soil DNA (deoxyribonucleic acid) content in the size fractions followed a similar trend to that of SOC. Despite the largely similar diversity between the fractions, 16S ribosomal gene abundance of bacteria and of archaeal were concentrated in both coarse-sand and clay fractions. Being the highest generally in coarse-sand fractions, 18S rRNA gene abundance of fungi decreased sharply but the diversity gently, with decreasing size of the aggregate fractions. The soil respiration quotient (ratio of respired CO2–C to SOC) was the highest in the silt fraction, followed by the fine-sand fraction, but the lowest in coarse-sand and clay fractions in the rice soils cultivated over 100 years, whereas the microbial metabolic quotient was lower in coarse-sand-sized fractions than in other fractions. Soil respiration was higher in the silt fraction than in other fractions for the rice soils. For the size fractions other than the clay fraction, enzyme activity was increased with prolonged rice cultivation, whereas soil respiration appeared to have a decreasing trend. Only in the coarse-sand fraction was both microbial gene abundance and enzyme activity well correlated to SOC and LOC content, although the chemical stability and respiratory of SOC were similar between coarse-sand and clay fractions. Thus, biological activity was generally promoted with LOC accumulation in the coarse-sand-sized macroaggregates of the rice soils, positively responding to prolonged rice cultivation management. The finding here provides a mechanistic understanding of soil organic carbon turnover and microbial community succession at fine scale of soil aggregates that have evolved along with anthropogenic activity of rice cultivation in the field.

Evaluating ozone dose for AOC removal in two-step GAC filters

1998 ◽  
Vol 37 (9) ◽  
pp. 113-120 ◽  
Author(s):  
R. Vahala ◽  
T. Ala-Peijari ◽  
J. Rintala ◽  
R. Laukkanen
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Second Step ◽  
Humic Lake ◽  
Short Term ◽  
Feasible Method ◽  
Assimilable Organic Carbon ◽  
Water Treatment Plants ◽  
Ozone Dose ◽  
Ozonated Water

Upgrading an existing post-ozonation plant with two-step granular activated carbon (GAC) filtration for assimilable organic carbon (AOC) removal was studied. The effects of ozone dose on AOC formation and its removal in the subsequent two-step GAC filtration was studied using chemically pretreated 2 to 14° C humic lake water. Two parallel pilot-plant trains with different ozone doses (0 to 1.2 mgO3/mgTOC) and a short-term ozonation study were performed. The optimum ozone dose for maximum AOC formation was 0.4–0.5 mgO3/mgTOC. The AOC-P17 of ozonated water was three-fold higher and AOC-NOX over ten-fold higher than in non-ozonated water, while the following biofiltration (first step) removed 51% and 72% of AOC-P17 and AOC-NOX, respectively. The adsorber (second step) contributed to less than 10% of the overall AOC reduction. It appeared that biofiltration is a feasible method in upgrading water treatment plants for AOC removal even when treating cold humic waters, while the subsequent adsorber seems to have less significance for AOC removal.

New Biology for Advanced Wastewater Treatment

1999 ◽  
Vol 40 (4-5) ◽  
pp. 137-144 ◽  
Author(s):  
K. Miserez ◽  
S. Philips ◽  
W. Verstraete
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Organic Carbon ◽  
Genetically Modified Organisms ◽  
New Technologies ◽  
Chemical Oxidation ◽  
Advanced Treatment ◽  
Biological Activated Carbon ◽  
Catabolic Potential ◽  
New Biology

A number of new technologies for the advanced treatment of wastewater have recently been developed. The oxidative cometabolic transformation by methanotrophs and by nitrifiers represent new approaches in relation to organic carbon. The Biological Activated Carbon Oxidative Filters characterized by thin biofilms are also promising in that respect. Moreover, implementing genetically modified organisms with improved catabolic potential in advanced water treatment comes into perspective. For very refractory effluents chemical support techniques, like e.g. strong chemical oxidation, can be lined up with advanced biology.

Space-time monitoring of soil organic carbon content across a semi-arid region of Australia

2021 ◽  
Vol 24 ◽  
pp. e00367
Author(s):  
Patrick Filippi ◽  
Stephen R. Cattle ◽  
Matthew J. Pringle ◽  
Thomas F.A. Bishop
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Carbon Content ◽  
Arid Region ◽  
Space Time ◽  
Organic Carbon Content ◽  
Soil Organic Carbon Content ◽  
Semi Arid Region ◽  
Semi Arid

scholarly journals Influence of Slope Gradient and Aspect on Soil Organic Carbon Content in the Region of Niš, Serbia

2021 ◽  
Vol 13 (15) ◽  
pp. 8332
Author(s):  
Snežana Jakšić ◽  
Jordana Ninkov ◽  
Stanko Milić ◽  
Jovica Vasin ◽  
Milorad Živanov ◽  
...  
Keyword(s):  
Land Use ◽  
Spatial Distribution ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Slope Aspect ◽  
Available Phosphorus ◽  
Organic Carbon Content ◽  
Slope Gradient ◽  
Phosphorus And Potassium ◽  
Uncultivated Land

Topography-induced microclimate differences determine the local spatial variation of soil characteristics as topographic factors may play the most essential role in changing the climatic pattern. The aim of this study was to investigate the spatial distribution of soil organic carbon (SOC) with respect to the slope gradient and aspect, and to quantify their influence on SOC within different land use/cover classes. The study area is the Region of Niš in Serbia, which is characterized by complex topography with large variability in the spatial distribution of SOC. Soil samples at 0–30 cm and 30–60 cm were collected from different slope gradients and aspects in each of the three land use/cover classes. The results showed that the slope aspect significantly influenced the spatial distribution of SOC in the forest and vineyard soils, where N- and NW-facing soils had the highest level of organic carbon in the topsoil. There were no similar patterns in the uncultivated land. No significant differences were found in the subsoil. Organic carbon content was higher in the topsoil, regardless of the slope of the terrain. The mean SOC content in forest land decreased with increasing slope, but the difference was not statistically significant. In vineyards and uncultivated land, the SOC content was not predominantly determined by the slope gradient. No significant variations across slope gradients were found for all observed soil properties, except for available phosphorus and potassium. A positive correlation was observed between SOC and total nitrogen, clay, silt, and available phosphorus and potassium, while a negative correlation with coarse sand was detected. The slope aspect in relation to different land use/cover classes could provide an important reference for land management strategies in light of sustainable development.

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