<p><strong>1. Introduction</strong></p><p>Rapid variations in species concentration at the terminator have the potential to cause asymmetries in the species distributions along the line of sight (LOS) of a solar occultation experiment. Ozone, in particular, displays steep gradients across the terminator of Mars due to photolysis [1]. Nowadays, most of the retrieval algorithms for solar and stellar occultations rely on the assumption of a spherically symmetrical atmosphere. However, photochemically induced variations near sunrise/sunset conditions need to be taken into account in the retrieval process in order to prevent inaccuracies.</p><p>Here, we investigated the impact of gradients along the LOS of the solar occultation experiment TGO/NOMAD-UVIS for the retrieval of ozone under sunrise/sunset conditions. We used the diurnal variations in the ozone concentration obtained from photochemical model calculations together with an adapted radiative transfer code.</p><p><strong>2. The NOMAD UVIS channel</strong></p><p>NOMAD is a spectrometer composed of 3 channels: 1) a solar occultation channel (SO) operating in the infrared (2.3-4.3 &#956;m); 2) a second infrared channel LNO (2.3-3.8 &#956;m) capable of doing nadir, as well as solar occultation and limb; and 3) an ultraviolet/visible channel <strong>UVIS</strong> (200-650 nm) that can work in the three observation modes [2,3].</p><p>The UVIS channel has a spectral resolution <1.5 nm. In the solar occultation mode it is mainly devoted to study the climatology of <strong>ozone</strong> and <strong>aerosols</strong> content [4].</p><p>Since the beginning of operations, on 21 April 2018, NOMAD UVIS acquired more than 3000 solar occultations with an almost complete coverage of the planet.</p><p><strong>3. Retrieval technique</strong></p><p>NOMAD-UVIS spectra are simulated using the line-by-line radiative transfer code <strong>ASIMUT-ALVL</strong> developed at IASB-BIRA [5]. In a preliminary study based on SPICAM-UV solar occultations (see [6]), ASIMUT was modified to take into account the atmospheric composition and structure at the day-night terminator. As input for ASIMUT, we used gradients predicted by the 3D GEM-Mars v4 Global Circulation Model (GCM) [7,8]. UVIS ozone profiles will also be compared to SPICAM-UV retrievals.</p><p><strong> 4. Summary and future work</strong></p><p>We will present ozone vertical profiles retrieved from the first Martian year of observations from TGO/NOMAD-UVIS. In addition, we plan to compare our retrievals to SPICAM-UV observations. As first step, we will retrieve O<sub>3</sub> profiles without taking in account gradients. Then, we will investigate the effects of ozone density gradients on the retrieval of ozone.</p><p><strong>References</strong></p><p>[1] Lef&#232;vre, F., Bertaux, J.L., Clancy, R. T., Encrenaz, T., Fast, K., Forget, F., Lebonnois, S., Montmessin, F., Perrier, S., Aug. 2008. Heterogeneous chemistry in the atmosphere of Mars. Nature 454, 971&#8211;975.</p><p>[2] Vandaele, A.C., et al., Planetary and Space Science, Vol. 119, pp. 233&#8211;249, 2015.</p><p>[3] Neefs, E., et al., Applied Optics, Vol. 54 (28), pp. 8494-8520, 2015.</p><p>[4] M.R. Patel et al., In: Appl. Opt. 56.10 (2017), pp. 2771&#8211;2782. DOI: 10.1364/AO.56.002771.</p><p>[5] Vandaele, A.C., et al., JGR, 2008. 113 doi:10.1029/2008JE003140.</p><p>[6] Piccialli, A., Icarus, 2019, </p><p>[7] Neary, L., and F. Daerden (2018), Icarus, 300, 458&#8211;476, doi:10.1016/j.icarus.2017.09.028.</p><p>[8] Daerden et al., 2019, Icarus 326, https://doi.org/10.1016/j.icarus.2019.02.030</p><!-- COMO-HTML-CONTENT-END -->
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<strong class="co_mto_htmlabstract-citationHeader-intro">How to cite:</strong>
Piccialli, A., Vandaele, A. C., Willame, Y., Aoki, S., Depiesse, C., Trompet, L., Neary, L., Viscardy, S., Daerden, F., Erwin, J., Thomas, I. R., Ristic, B., Mason, J. P., Patel, M., Bellucci, G., and Lopez-Moreno, J.-J.: Impact of gradients at the Martian terminator on the retrieval of ozone from TGO/NOMAD-UVIS, Europlanet Science Congress 2020, online, 21 September&#8211;9 Oct 2020, EPSC2020-670, 2020
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