Treatment of highly-colored surface water by a hybrid microfiltration membrane system incorporating ion-exchange

2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 369
Author(s):  
Shengji Xia ◽  
Xinran Zhang ◽  
Yuanchen Zhao ◽  
Fibor J. Tan ◽  
Pan Li ◽  
...  

The membrane separation process is being widely used in water treatment. It is very important to control membrane fouling in the process of water treatment. This study was conducted to evaluate the efficiency of a pre-oxidation-coagulation flat ceramic membrane filtration process using different oxidant types and dosages in water treatment and membrane fouling control. The results showed that under suitable concentration conditions, the effect on membrane fouling control of a NaClO pre-oxidation combined with a coagulation/ceramic membrane system was better than that of an O3 system. The oxidation process changed the structure of pollutants, reduced the pollution load and enhanced the coagulation process in a pre-oxidation-coagulation system as well. The influence of the oxidant on the filtration system was related to its oxidizability and other characteristics. NaClO and O3 performed more efficiently than KMnO4. NaClO was more conducive to the removal of DOC, and O3 was more conducive to the removal of UV254.


2003 ◽  
Vol 3 (5-6) ◽  
pp. 15-22
Author(s):  
P. Kouadio ◽  
M. Tétrault

Three colored surface water nanofiltration pilot-scale projects were conducted in the province of Quebec (eastern Canada), between November 2000 and March 2002, by the company H2O Innovation (2000) inc., for the municipalities of Lac Bouchette, Latulipe-et-Gaboury and Charlesbourg (now part of Quebec City). Results indicated that nanofiltration permeate quality has an advance on present drinking water regulation standard in Quebec, but important membrane fouling occurred. Fouling can be controlled by pretreatment and optimization of the operating conditions.


2001 ◽  
Vol 1 (5-6) ◽  
pp. 357-364 ◽  
Author(s):  
Y. Jimbo ◽  
K. Goto

The design standards of the iron and manganese removal system by membrane filtration were investigated. The membrane filtration after pre-chlorination could remove iron completely and could remove around 70% of manganese. In the case of manganese concentration being more than 0.05 mg/l, the membrane filtration could remove them completely after the deposition in the oxidation tank. The concentrations of iron and manganese were reduced more than 90% by the oxidation tank and were reduced until under the detection limit after the membrane filtration. The economic comparisons between the rapid sand filtration system and this membrane filtration system in a small capacity and a middle capacity were investigated. The 15 years total costs of the membrane filtration system were estimated to be smaller than or around equal to the rapid sand filtration system in both capacities.


Author(s):  
Aklilu T. G. Giorges ◽  
John A. Pierson

Membrane filtration is one of the methods for separating targeted material from a fluid stream. Membrane based filtration is applied in many areas of processing to separate and concentrate fluids. However, fouling and film growth at the filter surface is a major problem that causes loss in efficiency. The cake buildup during the filtration process is investigated experimentally to understand the affect of flow dynamics on the cake characteristics, shape and associated resistance. The experiments were conducted without and with shear generated using an impeller operated at various rotational speeds. The results illustrate that indeed the cake shape and character are affected by the flow dynamics that eventually influence filtration resistance. Likewise the filtrate rate and the cake shape significantly affect the flow dynamics. Furthermore, the filtration resistance is not only affected by the thickness of the cake, but also by how the cake is formed. After similar volumes of filtrate, the flux rate of 120 Lm−2hr−1 for 4.4 mm thick and 1.8 g cake is observed for dead-end filtration, while the flux rate of 600 Lm−2hr−1 for 1.1 mm thick and 0.35 g cake where observed with a shearing rate of 630 s−1. Understanding the size and characters of cake buildup is very important to designing a system to overcome the drawbacks associated with membrane fouling. Moreover, developing a technology with the cleaning process that removes or eliminates cake and maintains a reasonable flux for an extended period requires a thorough understanding of the filtration system geometry and flow dynamics.


2001 ◽  
Vol 1 (5-6) ◽  
pp. 341-348 ◽  
Author(s):  
S. Takizawa ◽  
L. Fu ◽  
N. Pradhan ◽  
T. Ike ◽  
M. Ohtaki ◽  
...  

Experimental studies on chemical and biological pretreatments in membrane filtration processes were carried out to removal manganese contained in raw water and to prevent membrane fouling due to manganese. Two types of the pretreatment reactors, i.e. the fluidised-bed and fixed-bed configurations, were compared in the biological pretreatment experiments. New synthetic media (tubular polypropylene, I.D. 3 mm, O.D. 4 mm, length 5 mm) were used in all three experiments as a manganese-oxidising catalyst. The chemical pretreatment using sodium hypochlorite was effective in manganese removal and controlling membrane fouling; more than 0.8 mg-Cl2/L of chlorine dose was necessary to bring the manganese concentration from 0.4 mg/L in raw water to less than 0.05 mg/L. The biological pretreatment for manganese removal required a long start-up period of more than 40 days. The fixed-bed biological pretreatment was superior in manganese removal and in control of membrane fouling to the fluidised-bed biological pretreatment, which showed wash-out of the attached bacteria resulting in membrane fouling. The linear velocity and the empty-bed retention time required for the treatment of 0.14 mg-Mn/L in the fixed-bed biological pretreatment was 206 m/d and 8.0 minutes, respectively.


MEMBRANE ◽  
2013 ◽  
Vol 38 (5) ◽  
pp. 207-214
Author(s):  
Yoshihisa Fujii ◽  
Sadaki Samitsu ◽  
Izumi Ichinose

2017 ◽  
Vol 76 (2) ◽  
pp. 490-500 ◽  
Author(s):  
Yufei Wang ◽  
Hui Jia ◽  
Hongwei Zhang ◽  
Jie Wang ◽  
Wenjin Liu

A recycling magnetic flocculation membrane filtration (RMFMF) process integrating circulating coagulation, magnetic enhanced flocculation and membrane filtration was investigated for the treatment of surface water micro-polluted by tetracycline, a typical pharmaceutical and personal care product. A bench-scale experiment was conducted and several water quality parameters including turbidity, ultraviolet absorbance at 254 nm (UV254), total organic carbon and tetracycline concentration were evaluated, taking coagulation membrane filtration and magnetic flocculation membrane filtration processes as reference treatments. The experimental results showed that at the optimum doses of 20 mg·L−1 ferric chloride (FeCl3), 4 mg·L−1 magnetite (Fe3O4) and 6 mg·L−1 reclaimed magnetic flocs in RMFMF processes, removal efficiencies of above evaluated parameters ranged from 55.8% to 92.9%, which performed best. Simultaneously, the largest average particle size of 484.71 μm and the highest fractal dimension of 1.37 of flocs were achieved, which did not only present the best coagulation effect helpful in enhancing the performance of removing multiple contaminants, but also lead to the generation of loose and porous cake layers favouring reduced permeate flux decline and membrane fouling.


2021 ◽  
Vol 15 (1) ◽  
pp. 37-44
Author(s):  
Szabolcs Gyula Szerencsés ◽  
Sándor Beszédes ◽  
Zsuzsanna László ◽  
Gábor Veréb ◽  
Balázs Szegedi ◽  
...  

Nowadays, several environmental challenges are present to cope with. One with outstanding importance is the protection of our water supplies, therefore examination of wastewater treatment technology is a priority, especially in the European Union. In this work, the effect of membrane module vibration amplitude on the efficiency of ultrafiltration (UF) was investigated in a vibratory shear enhanced membrane filtration system. Based on the results of model dairy effluent UF and statistical analysis, the maximum vibration level available resulted in the most efficient filtration process, due to the most significant reduction of membrane fouling. From our results it was observed that the permeate fluxes more than doubled, specific energy demand was roughly halved, with almost identical retentions for organic matter, and total filtration resistance was reduced to less than half. Results also showed that setting the optimal operating parameters, an advantageous, efficiency focused, and sustainable wastewater treatment technology can be established.


2002 ◽  
Vol 2 (2) ◽  
pp. 177-183
Author(s):  
K. Kimura ◽  
Y. Watanabe

We have developed a novel biofilm-membrane reactor (BMR) in which a nitrifying biofilm is fixed on the surface of a rotating membrane disk. With this reactor, both strict solid-liquid separation and oxidation of ammonia nitrogen can be simultaneously performed. Based on the results obtained in previous bench-scale experiments, a pilot-scale study was conducted using river water at a water purification plant. The results obtained in the pilot study can be summarized as follows. (1) By implementation of pre-treatment (coagulation and sedimentation) and simple membrane cleaning (sponge cleaning), the filter run could be continued for 17 months without any chemical washing. (2) Sufficient nitrification was observed when water temperature was high. Deterioration in nitrification efficiency during winter was reduced by the addition of phosphorus. (3) In addition to nitrification, biological oxidation of AOC and manganese can be expected with the BMR. In this study, both AOC and manganese concentration in the permeate decreased to a level less than 10 μg/L. (4) Irreversible membrane fouling, which was thought to be mainly caused by manganese, became significant as the operation period became longer.


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