The effect of clay amendment on speciation of heavy metals in sewage sludge

1996 ◽  
Vol 34 (7-8) ◽  
pp. 413-420 ◽  
Author(s):  
L. Qiao ◽  
Goen Ho
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Sewage Sludge ◽  
Red Mud ◽  
Heavy Metal Contamination ◽  
Metal Speciation ◽  
Metal Mobility ◽  
Potential Hazard ◽  
Application Rates ◽  
Physico Chemical

When sewage sludge is used as a soil conditioner, heavy metal contamination can limit its application rates. The potential hazard of heavy metals is, however, dependent on the physico-chemical forms of the metals in the sludge and soil. Bauxite refining residue (red mud) has been used to reduce the mobility and availability of heavy metals in municipal solid waste compost. In the present research a sequential step extraction was employed to investigate metal speciation (into exchangeable, bound to carbonate, to Mn & Fe oxides, to organic matter and in residue phase) and the effect of red mud on metal speciation in sewage sludge for Cd, Cr, Cu, Ni, Pb and Zn. The effect of red mud addition on metal distribution in sewage sludge compost was significant. Red mud addition can effectively reduce the metal mobility and the potential hazard of releasing metals from sludge due to the further breakdown of organic matter. Drying of sludge makes heavy metals more available. Red mud addition will be desirable in such a case. Plant available metals (determined by DTPA extraction) are, however, not as effectively reduced except for Pb and Zn.

Chromium speciation in municipal solid waste: effects of clay amendment and composting

1998 ◽  
Vol 38 (2) ◽  
pp. 17-23 ◽  
Author(s):  
Ho Goen ◽  
Qiao Liang
Keyword(s):  
Organic Matter ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Red Mud ◽  
Metal Speciation ◽  
Metal Mobility ◽  
Potential Hazard ◽  
Composting Process ◽  
Heavy Metal Mobility ◽  
Free Metal

The addition of clay in the form of bauxite refining residue (red mud) prior to composting has been suggested as a way to control heavy metal mobility in compost. Leachability and plant availability of metals in a mixture of grass clippings and sawdust spiked with metal solution was markedly reduced during the composting process. The fate of metals in municipal solid waste compost applied to land was examined by using a sequential step extraction to investigate metal speciation (into exchangeable and bound to carbonate forms, to Mn & Fe oxides, to organic matter and in residue phase) in red mud amended compost. The effects of red mud and the composting process on metal speciation in the compost for Cd, Cr, Cu, Ni, Pb and Zn were investigated, and a comparison of some effects with biosolids compost was made. Addition of red mud reduced the metal mobility and the potential hazard of releasing metals from compost through promoted precipitation, adsorption and complexation of free metal cations to red mud. Red mud however, was not able to desorb metals bound to organic matter. Since most of the metals in the municipal solid waste were not usually bound to organic matter, the addition of red mud prior to composting fixed the free metal ions before they bound to this fraction. Results for Cr speciation are reported in this paper.

Speciation of heavy metals in sewage sludge after mesophilic and thermophilic anaerobic digestion

2012 ◽  
Vol 66 (6) ◽  
Author(s):  
Lidia Dąbrowska
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Metal Ions ◽  
Metal Speciation ◽  
Speciation Analysis ◽  
Chromium Concentration ◽  
Residual Fraction ◽  
Stabilization Process

AbstractTwo types of sewage sludge anaerobic digestion were carried out: mesophilic and thermophilic. Metal speciation analysis was performed revealing some changes in the chemical form of the metals during the stabilization process of sludge. After both methane fermentation processes, a comparable level of organic matter distribution was obtained (≈ 40 %). The amount of produced methane during thermophilic and mesophilic digestion was 560 mL of CH4 and 580 mL of CH4 from 1 g of removed organic matter, respectively. Low concentration of heavy metal ions in the liquid phase of sludge was observed. Metal ions precipitated and remained bound throughout the stabilization process. No accumulation of heavy metals in the mobile fractions of sludge (exchangeable and carbonate) was observed for either digestion process. The highest increase of zinc, copper, nickel, cadmium, and chromium concentration was observed in the organic-sulfide fraction, whereas the highest increase of lead was found in the residual fraction.

scholarly journals Levels of Lead, Copper, and Zinc in Cabbage (Brassica oleracea sp.) and Lettuce (Lactuca sativa sp.) Grown on Soil Amended with Sewage Sludge

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Bernard Fei-Baffoe ◽  
Jeffery Amo-Asare ◽  
Alhassan Sulemana ◽  
Kodwo Miezah
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Sewage Sludge ◽  
Metal Uptake ◽  
Organic Matter Content ◽  
Matter Content ◽  
Yield Enhancement ◽  
Nitrogen Application ◽  
Application Rates

The study focused on levels of selected heavy metals (Pb, Zn, and Cu) in sewage sludge, soil, and in lettuce and cabbage grown on sewage sludge amended soil. Also, the effect of sewage sludge on soil properties (pH, soil organic matter, and soil conductivity) was studied. Three treatments were used based on nitrogen application rates of the sewage sludge: 100, 150, and 200 kg N/ha for lettuce while 160, 210, and 260 kg N/ha for cabbage. A pot experiment was conducted with pots arranged in a completely randomized design and under local climatic conditions. The study revealed that soil organic matter content and conductivity increased significantly with increasing nitrogen application rates. Levels of heavy metals in the soil increased significantly with increasing application rates. The controls for both plants recorded the lowest heavy metal uptake. Cabbage had an uptake of 0.48 ± 0.13, 1.36 ± 0.23, and 2.60 ± 0.29 mg/kg for Pb, Zn, and Cu, respectively, while lettuce had 0.34 ± 0.19, 1.35 ± 0.31, and 2.30 ± 0.14 mg/kg uptake for Pb, Zn, and Cu, respectively. Highest metal uptake was recorded at the highest application rate in both plants (0.66 ± 0.17, 2.66 ± 0.09, and 4.33 ± 0.14 mg/kg for Pb, Zn, and Cu, respectively, for cabbage and 0.54 ± 0.01, 2.24 ± 0.17, and 3.88 ± 0.19 mg/kg of Pb, Zn, and Cu, respectively, for lettuce). The uptake of Zn and Cu was significant, while Pb uptake was insignificant for both plants. Yields increased significantly with increasing application rates. The study provides information on yield enhancement resulting from cultivating plants on soil amended with sewage sludge and the associated health risk implication.

The change in agrochemical indicators of soil fertility under the influence of heavy metal contamination

2016 ◽  
Vol 2 (91) ◽  
pp. 17-21
Author(s):  
S. H. Korsun ◽  
N. I. Dovbash
Keyword(s):  
Heavy Metals ◽  
Forest Soil ◽  
Heavy Metal Contamination ◽  
Gray Forest Soil ◽  
Mineral Fertilizers ◽  
Background Concentration ◽  
Physico Chemical ◽  
Natural Background Concentration ◽  
Nitrogen Phosphorus ◽  
Hydrolytic Acidity

The aim of the study was to establish changes in the physico-chemical and agrochemical characteristics of gray forest large-clay loamy soil, depending on the contamination of ecotopes by heavy metals. Methods. Field, laboratory, mathematical and statistical. Results. The results of the study of the soil of areas with an over-dimensioned content of heavy metals and the transformation of agrochemical characteristics of gray forest soil in the cultivation of corn for grain. It was established that under conditions of systematic application of mineral fertilizers in agrocenoses, an increase in the lead concentration to 100 mg/kg, cadmium to 2,0, zinc to 50 mg/kg in gray forest soil did not result in a decrease in the amount available forms of nitrogen, phosphorus, potassium by plants, compared with the natural background. Concentration of lead in the amount of 1000 mg/kg, cadmium – 20, zinc – 500 mg/kg marked an increase in exchange and hydrolytic acidity and loss of humus.

scholarly journals Optimal Solutions for the Use of Sewage Sludge on Agricultural Lands

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 585
Author(s):  
Catalina Iticescu ◽  
Puiu-Lucian Georgescu ◽  
Maxim Arseni ◽  
Adrian Rosu ◽  
Mihaela Timofti ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Agricultural Production ◽  
Agricultural Land ◽  
Chemical Characteristics ◽  
Optimal Solutions ◽  
Physico Chemical ◽  
Agricultural Areas ◽  
The Impact ◽  
Made In

The use of sewage sludge in agriculture decreases the pressure on landfills. In Romania, massive investments have been made in wastewater treatment stations, which have resulted in the accumulation of important quantities of sewage sludge. The presence of these sewage sludges coincides with large areas of degraded agricultural land. The aim of the present article is to identify the best technological combinations meant to solve these problems simultaneously. Adapting the quality and parameters of the sludge to the specificity of the land solves the possible compatibility problems, thus reducing the impact on the environment. The physico-chemical characteristics of the fermented sludge were monitored and optimal solutions for their treatment were suggested so as to allow that the sludge could be used in agriculture according to the characteristics of the soils. The content of heavy metals in the sewage sludge was closely monitored because the use of sewage sludge as a fertilizer does not allow for any increases in the concentrations of these in soils. The article identifies those agricultural areas which are suitable for the use of sludge, as well as ways of correcting some parameters (e.g., pH), which allow the improvement of soil quality and obtained higher agricultural production.

Using Regional Characteristic Amendments to Modify Heavy Metal Contaminated Soil of Guangxi, South China

2014 ◽  
Vol 675-677 ◽  
pp. 654-657
Author(s):  
Qiu Jun Li ◽  
Rui Jie Zhang ◽  
Ying Hui Wang ◽  
Da Rong Li
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Matter ◽  
Soil Ph ◽  
South China ◽  
Contaminated Soil ◽  
Red Mud ◽  
Great Influence ◽  
Regional Characteristic ◽  
Coconut Husk

In this study we compared the efficiency of four kinds of amendments (silkworm excrement, coconut husk, red mud, sepiolite) and their mixtures to immobilize the heavy metals present in a contaminated acidic soil (Pb:420 mg ·kg−1; Zn :334 mg· kg−1) and to influence several enzymatic activities. The results showed that, silkworm excrement, coconut husk and their mixtures, which had high pH and/or high content of organic matter, reduced exchangeable Pb in the soil by 18% to 46%, and reduced available Zn by 24% to 35%, which was more efficacious than single sepiolite. The complex of silkworm excrement and red mud had a great influence on soil pH, while coconut husk increased the content of organic matter in soil significantly.

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