An Alternative Use of Biogas Applied at the Water Denitrification

1999 ◽  
Vol 40 (8) ◽  
pp. 115-122 ◽  
Author(s):  
Eric Houbron ◽  
Michel Torrijos ◽  
Bernard Capdeville

The urban wastewater treatment plants of the 21st century will have to consider the removal of the carbon, nitrogen and phosphorus. On one hand, the usual exogenous carbon source for tertiary treatment are generally supplied as methanol, ethanol, acetic acid, etc. On the other hand, the anaerobic wastewater treatment plant produces a biogas which contains up to 90 % of methane and which could be used as a cheap carbon source for denitrification. The first step of this work conducted in batch culture with or without copper, has shown that a consortium of methanotrophic and denitrifying bacteria are involved in this process. The methanotrophic bacteria oxidises methane under aerobic conditions via a specific enzyme (Methane Mono Oxygenase) and produces a soluble organic carbon in the liquid phase available for the denitrification. During the batch culture, when dissolved oxygen concentration decreases below 1 mg/l, a maximum denitrification rate of 3.3 mg N-NO3/l.h was obtained with 80 μg/l of copper in the medium. The consumption rate of methane was 3.5 mmol CH4/l.h. The molar ratio of the oxygen/methane consumed was 1.27, and the mass ratio of C-CH4 consumed to N-NO3 eliminated was 10.9. During chemostat culture, denitrification on synthetic and real nitrifying water was tested. The stability of the consortium has been verified under different culture conditions. The variation of the dilution rate showed that the maximum one was 0.16 h−1. The specific denitrification rate obtained with synthetic and real water were respectively 6.1 and 9.47 mg N-NO3/TSS.h, with a C/N mass ratio of 3.6 and 4.6. In chemostat, culture the efficiency of the methane oxidation and the denitrification was improved.

2012 ◽  
Vol 573-574 ◽  
pp. 659-662
Author(s):  
Hao Wang

In Tangshan area, the secondary effluent of wastewater treatment plants was used for this study. Horizontal zeolite wetland was carried out treating it. Hydraulic loading rate was the parameters for analyzing the nitrogen and phosphorus removal efficiency of pollutants from the secondary effluent of wastewater treatment plant. Zeolite constructed wetlands showed different behaviors for nitrogen and phosphorus removals.Under the optimum hydraulic loading rate, the primary pollutions were removed to a large extent.


Author(s):  
Yongkui Yang ◽  
Longfei Wang ◽  
Feng Xiang ◽  
Lin Zhao ◽  
Zhi Qiao

Controlling wastewater pollution from centralized industrial zones is important for reducing overall water pollution. Microbial community structure and diversity can adversely affect wastewater treatment plant (WWTP) performance and stability. Therefore, we studied microbial structure, diversity, and metabolic functions in WWTPs that treat industrial or municipal wastewater. Sludge microbial community diversity and richness were the lowest for the industrial WWTPs, indicating that industrial influents inhibited bacterial growth. The sludge of industrial WWTP had low Nitrospira populations, indicating that influent composition affected nitrification and denitrification. The sludge of industrial WWTPs had high metabolic functions associated with xenobiotic and amino acid metabolism. Furthermore, bacterial richness was positively correlated with conventional pollutants (e.g., carbon, nitrogen, and phosphorus), but negatively correlated with total dissolved solids. This study was expected to provide a more comprehensive understanding of activated sludge microbial communities in full-scale industrial and municipal WWTPs.


1992 ◽  
Vol 26 (5-6) ◽  
pp. 1315-1323 ◽  
Author(s):  
H. Aspegren ◽  
B. Andersson ◽  
U. Nyberg ◽  
J. la C. Jansen

Optimization of wastewater treatment plants with extensive phosphorus and nitrogen removal is complicated. The Klagshamn wastewater treatment plant in Sweden is operated with pre-precipitation of phosphorus with ferric chloride and denitrification with methanol as carbon source. An activated sludge process, operated with pre-precipitation and denitrification with external carbon source in a compartmentalized plant, requires only small tank volumes but increases the need for proper operation and optimization. On-line nitrogen, ammonia, and TOC sensors are used for a day-to-day control and optimization while mathematical modelling is used for long term strategic planning. The on-line measurements are further used as the basis for the modelling. TOC and ammonia sensors at the influent clearly identify typical and extreme loading variations and nitrate measurements in the activated sludge tanks and the effluent shows the dynamics of the processes. These measurements provide a basis for model calibration. In combination low residuals of nitrogen, phosphorus and organic matter can be achieved.


2012 ◽  
Vol 65 (8) ◽  
pp. 1496-1505 ◽  
Author(s):  
Xavier Flores-Alsina ◽  
Krist V. Gernaey ◽  
Ulf Jeppsson

This paper examines the effect of different model assumptions when describing biological nutrient removal (BNR) by the activated sludge models (ASM) 1, 2d & 3. The performance of a nitrogen removal (WWTP1) and a combined nitrogen and phosphorus removal (WWTP2) benchmark wastewater treatment plant was compared for a series of model assumptions. Three different model approaches describing BNR are considered. In the reference case, the original model implementations are used to simulate WWTP1 (ASM1 & 3) and WWTP2 (ASM2d). The second set of models includes a reactive settler, which extends the description of the non-reactive TSS sedimentation and transport in the reference case with the full set of ASM processes. Finally, the third set of models is based on including electron acceptor dependency of biomass decay rates for ASM1 (WWTP1) and ASM2d (WWTP2). The results show that incorporation of a reactive settler: (1) increases the hydrolysis of particulates; (2) increases the overall plant's denitrification efficiency by reducing the SNOx concentration at the bottom of the clarifier; (3) increases the oxidation of COD compounds; (4) increases XOHO and XANO decay; and, finally, (5) increases the growth of XPAO and formation of XPHA,Stor for ASM2d, which has a major impact on the whole P removal system. Introduction of electron acceptor dependent decay leads to a substantial increase of the concentration of XANO, XOHO and XPAO in the bottom of the clarifier. The paper ends with a critical discussion of the influence of the different model assumptions, and emphasizes the need for a model user to understand the significant differences in simulation results that are obtained when applying different combinations of ‘standard’ models.


2021 ◽  
Vol 2021 (2) ◽  
pp. 7-16
Author(s):  
Ihor Popadiuk ◽  
◽  
Ivan Matlai ◽  
Bohdan Pitsyshyn ◽  
Taras Sydor ◽  
...  

The article is devoted to the unsatisfactory operation of biological wastewater treatment plants. At present in Ukraine there are no developments of equipment and devices to ensure the operation of treatment facilities using the technology of nitridenitrification of deep wastewater treatment from nitrogen and phosphorus compounds. The analysis of the equipment of biological treatment systems - nitri treatment plant - denitrifier, clarifier tanks is carried out. At the same time, the standards of the degree of purification of both Ukraine and the European Union were taken into account. On the example of treatment facilities in Kolomyia, Ivano-Frankovsk region, modern schemes of biological wastewater treatment for the removal of nitrogen and phosphorus have been proposed, namely, the re-equipment of single-corridor aerotanks into bioreactors of nitridenitrifiers by creating zones with different oxygen conditions in their volume.


1994 ◽  
Vol 29 (12) ◽  
pp. 59-67
Author(s):  
M. Fruhen ◽  
W. Kühn ◽  
M. Dohmann

The upgrading of wastewater treatment plants with the objective of enhancing the elimination of nitrogen and phosphorus is a demanding undertaking as regards the choice of process technology, especially if the basic function of existing treatment systems is to be retained. With reference to an existing two-stage biological sewage plant with trickling filters in the second stage, the present paper illustrates how the volume of the activated sludge stage that is being enlarged can be minimized by exploiting the benefits of a primary treatment stage with high BOD5 elimination and by integrating the trickling filters in the main stream of the treatment chain. This requires that the extremely costly filtration stage that is essential for eliminating the phosphorus also fulfils other tasks, in this case residual denitrification.


Plants ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 1802
Author(s):  
Costanza Baldisserotto ◽  
Sara Demaria ◽  
Ornella Accoto ◽  
Roberta Marchesini ◽  
Marcello Zanella ◽  
...  

Microalgae are photosynthetic microorganisms and are considered excellent candidates for a wide range of biotechnological applications, including the removal of nutrients from urban wastewaters, which they can recover and convert into biomass. Microalgae-based systems can be integrated into conventional urban wastewater treatment plants (WW-TP) to improve the water depuration process. However, microalgal strain selection represents a crucial step for effective phytoremediation. In this work, a microalga isolated from the effluent derived from the thickening stage of waste sludge of an urban WW-TP was selected and tested to highlight its potential for nutrient removal. Ammonium and phosphate abatements by microalgae were evaluated using both the effluent and a synthetic medium in a comparative approach. Parallelly, the isolate was characterized in terms of growth capability, morphology, photosynthetic pigment content and photosystem II maximum quantum yield. The isolated microalga showed surprisingly high biomass yield and removal efficiency of both ammonium and phosphate ions from the effluent but not from the synthetic medium. This suggests its clear preference to grow in the effluent, linked to the overall characteristics of this matrix. Moreover, biomass from microalgae cultivated in wastewater was enriched in photosynthetic pigments, polyphosphates, proteins and starch, but not lipids, suggesting its possible use as a biofertilizer.


1998 ◽  
Vol 37 (9) ◽  
pp. 151-158
Author(s):  
Dieter Schreff ◽  
Peter A. Wilderer

Systems in which denitrification follows nitrification (post-denitrification) copy the natural sequence of nitrogen removal. The disadvantage of post-denitrification, however, is that an external carbon source must be added to the denitrification reactor. In the concept discussed in this paper, excess sludge from a high loaded activated sludge plant is used as carbon source and as source of denitrifiers in a three-stage system. The sludge is fed into a anoxic reactor placed in between the nitrification reactor (e.g., trickling filter) and the final clarifier. Two different operation methods were investigated at a pilot-scale system set up at the Ingolstadt wastewater treatment plant. Low nitrate effluent values were obtained at high sludge feeding rates, but at the expense of a significant increase in turbidity and NH4-N effluent concentrations. This problem could be solved by a reduction of the sludge feeding rate and by applying intermittent feeling. The effluent turbidity was kept at an acceptable level, but denitrification was relatively slow in progress. To achieve both low effluent turbidity and low nitrate discharge, a combination of pre- and post-denitrification is recommended.


1996 ◽  
Vol 33 (12) ◽  
pp. 117-126 ◽  
Author(s):  
I. Purtschert ◽  
H. Siegrist ◽  
W. Gujer

In coordination with the EU-guidelines the large wastewater treatment plants in Switzerland have to be extended with enhanced nitrogen removal. Due to the existing plant configuration, the low COD/N ratio and dilute wastewater, denitrification supported by an external carbon source instead of extending the plant may be an interesting and cost effective solution for municipal wastewater treatment. At the wastewater treatment plant Zürich-Werdhölzli different experiments were performed with methanol addition to predenitrification from March to July 1994. The aim of this work was to evaluate the use of methanol as an alternative to plant extension to achieve a higher nitrogen removal efficiency. Therefore, two parallel denitrifying lanes were investigated, one served for methanol addition experiments and the other as a control. The effect of oxygen input into the anoxic zone due to influent, return sludge and mixing was investigated, too. The results show that nitrogen removal efficiency can be substantially increased as compared to the reference lane. The adaptation period for methanol degradation was only a few days and the process was relatively stable. Based on total nitrogen in the inflow, the average denitrification was 55% with methanol addition and 35% without methanol. The yield coefficient YCOD was 0.4 g CODX g−1 CODMe. Due to the small net growth rate of the methanol degraders the denitrification capacity is relatively low and nitrate peak loads cannot be fully denitrified. Hence, methanol as a carbon source requires more or less constant dosing. To prevent nitrate limitation, methanol addition should be controlled by the anoxic nitrate concentrations.


1994 ◽  
Vol 30 (2) ◽  
pp. 193-203 ◽  
Author(s):  
Angela Ante ◽  
Hans Ulrich Besche ◽  
Harald Voss

The incorporation of enhanced biological phosphorus elimination in the single sludge process is a contemporary challenge in the design of biological wastewater treatment plants. The simultaneous biological removal of nitrogen and phosphorus is a process of considerable technical and biological complexity owing to the mixed substrates and the diversity of microorganism populations. In addition, an interaction takes place between the phosphorus-accumulating organisms and the nitrogen-eliminating organisms owing to the physiological demands. When designing wastewater treatment plant, it is necessary to establish anaerobic zones for producing the short fatty acids necessary for phosphorus removal, an xic zones for denitrification, and aerated zones for nitrification and phosphorus removal. We have developed a mathematical model based on IA WPRC-model No I for this process scenario. In addition to the degradation kinetics of carbonaceous components and nitrogen, the model describes the microkinetics of enhanced biological phosphorus elimination. The assumptions of the model are discussed in relation to the recent literature. The range of values found in the literature and the used default values of the model parameters are listed. The simulation program is presented, and first results of simulation are shown.


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