Heavy metal removal from wastewater and leachate co-treatment sludge by sulfur oxidizing bacteria

2001 ◽  
Vol 44 (10) ◽  
pp. 53-58 ◽  
Author(s):  
L. C. Aralp ◽  
A. Erdincler ◽  
T. T. Onay

Heavy metal concentration in sludge is one of the major obstacles for the application of sludge on land. There are various methods for the removal of heavy metals in sludge. Using sulfur oxidizing bacteria for microbiological removal of heavy metals from sludges is an outstanding option because of high metal solubilization rates and the low cost. In this study, bioleaching by indigenous sulfur oxidizing bacteria was applied to sludges generated from the co-treatment of municipal wastewater and leachate for the removal of selected heavy metals. Sulfur oxidizing bacteria were acclimated to activated sludge. The effect of the high organic content of leachate on the bioleaching process was investigated in four sets of sludges having different concentrations of leachate. Sludges in Sets A, B, C and D were obtained from co-treatment of wastewater and 3%, 5%, 7% and 10% (v/v) leachate respectively. The highest Cr, Ni and Fe solubilization was obtained from Set A. Sulfur oxidizing bacteria were totally inhibited in Set D that received the highest volume of leachate.

Water ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1121
Author(s):  
Sylwan Ida ◽  
Thorin Eva

Resource reuse has become an important aspect of wastewater management. At present, use of sludge in agriculture is one of the major reuse routes. Conventional municipal wastewater treatment does not involve any designated process for removal of heavy metals, and these distribute mainly between effluent and sludge. Enhanced removal of heavy metals during primary treatment may decrease the heavy metal concentrations in both effluent and sludge from secondary treatment and promote long-term reuse of secondary sludge. This review considers heavy metal occurrence and removal during primary settling, together with possible treatment technologies for heavy metal removal in primary settlers and their theoretical performance. The variation in total heavy metal concentrations and dissolved fraction in raw municipal wastewater points to a need for site-specific assessments of appropriate technologies for improved heavy metal removal. Studies examining the heavy metal speciation beyond dissolved/particulate are few. Missing or disparate information on process parameters such as hydraulic retention time, pH and composition of return flows makes it hard to generalize the findings from studies concerning heavy metal removal in primary settlers. Coagulation/flocculation and use of low-cost sorbents were identified as the most promising methods for enhancing heavy metal removal during primary settling. Based on the available data on heavy metal speciation and removal during primary settling, sorption technologies may be most effective for enhancing the removal of Cu and Ni, while coagulation may be efficient for Cd, Cr, Cu, Pb, Zn and Hg removal (but not as efficient for Ni removal).


2016 ◽  
Vol 7 (4) ◽  
pp. 387-419 ◽  
Author(s):  
Renu ◽  
Madhu Agarwal ◽  
K. Singh

Heavy metals are discharged into water from various industries. They can be toxic or carcinogenic in nature and can cause severe problems for humans and aquatic ecosystems. Thus, the removal of heavy metals from wastewater is a serious problem. The adsorption process is widely used for the removal of heavy metals from wastewater because of its low cost, availability and eco-friendly nature. Both commercial adsorbents and bioadsorbents are used for the removal of heavy metals from wastewater, with high removal capacity. This review article aims to compile scattered information on the different adsorbents that are used for heavy metal removal and to provide information on the commercially available and natural bioadsorbents used for removal of chromium, cadmium and copper, in particular.


RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 29885-29907 ◽  
Author(s):  
Phoebe Zito Ray ◽  
Heather J. Shipley

Schematic of inorganic adsorbents (INA) for heavy metal removal.


Author(s):  
Tehseen Yaseen ◽  
Anum Yaseen

Nanotechnology is the area of nano science that shows great potential to establish a new process for wastewater treatment. It has been applied on a nanometer scale level. Currently, limited water resources and real treatment of wastewater is a chief requirement for the growing economy. It is in great demand to introduce the progressive wastewater treatment technologies. Therefore, the modern innovative processes in nanomaterial sciences have been appealing the target of scientists. The chapter addresses the developments in nanotechnology with respect to wastewater treatment, especially the removal of heavy metals and to the environmental applications. It will discuss the application of different classes of nanomaterials for wastewater treatment in removal of heavy metals and its possible effects to the environment. Therefore, the scope is to offer an overview of how nanomaterials are causing concerns related to heavy metal removal for water and in the surrounding environment.


2020 ◽  
Author(s):  
Maribel Guzman ◽  
Maggy Romero ◽  
Michael Flores ◽  
Sebastian Bravo

Abstract One of the greatest environmental issues related to the development of the mining activity is the generation of Acid Mine Drainage (AMD). This effluent generated by active and abandoned mines in Peru produces multiple discussions about the role of the industry for a sustainable development. Many methods have been developed for AMD treatment, being wetlands a good option for heavy metal removal. In this sense, removal of heavy metal by using laboratory constructed wetlands with Phragmites Australis was studied. During a 9-day period the variation of different physicochemical parameters and heavy metals concentrations was recorded. The pH decreased to a constant value of 8.24 after the sixth day. The electrical conductivity presented a slight variation from 1 to 1.33 µS cm-1 on the ninth day. Moreover, fluctuating values of Dissolved Oxygen and Turbidity were observed. A reduction between 69% and 93% of ammonia nitrogen (NH3-N) was registered. Cu concentration was reduced in 68% and 87%; Zn concentrations dropped in 53% and 95%; and Pb was reduced in 20% and 55%. It was concluded that Phragmites Australis can be an alternative in the treatment of the contaminants produced by AMD.


2014 ◽  
Vol 25 (4) ◽  
pp. 51-54
Author(s):  
Anna Kwarciak-Kozłowska ◽  
Lucyna Sławik-Dembiczak ◽  
Bartłomiej Bańka

Abstract Phycoremediation is the use of algae for the removal or biotrans-formation of pollutants from wastewater. The study is a novel at-tempt to integrate nutrient (N and P) removal and some heavy met-als (iron, manganese and zinc) bioaccumulation from municipal wastewater using two microalgae species: Chlorella vulgaris and Scenedesmus armatus. The Chlorella vulgaris showed higher re-moval of total nitrogen (TN) both in influent and effluent waste water than Scenedesmus armatus. Nevertheless, more than 51% of total phosphorus (TP) in effluent and 36% in influent wastewaters were removed by Scenedesmus armatus. More efficient microalga in heavy metal removal in influent wastewater was Scenedesmus armatus. The results showed that Chlorella vulgaris was appropriate for TN removal and bioaccumulation of heavy metals from effluent wastewater. Nevertheless, Scenedesmus armatus was highly pref-erable for heavy metals removal from influent wastewater.


Author(s):  
Harendra Kumar Sharma ◽  
Irfan Rashid Sofi ◽  
Khursheed Ahmad Wani

Heavy metal contamination in water is a serious concern to the environment and human health. High concentrations of heavy metals in the environment can be toxic to a variety of living species. Natural bio-absorbents are abundant and inexpensive and considered a waste if not managed properly. The role of bio-absorbents has been widely studied and has been utilized for the removal of heavy metals. The objective of the chapter is to search the database for different absorbents and their efficiency for the removal of heavy metals. Key words related to the study have been used to select different papers published by the researchers all over the world. A rigorous three-tier process has been utilized by the authors to select the papers from the database for the current study. This chapter has identified a few research gaps in the field of heavy metal removal by using different low cast absorbents that need to be taken into account in future research.


2002 ◽  
Vol 57 (7-8) ◽  
pp. 629-633 ◽  
Author(s):  
Kolishka Tsekova ◽  
Galin Petrov

This study assesses the ability of mycelia of Rhizopus delemar (both free and immobilized on polyurethane foam) to remove heavy metals from single-ion solutions as well as from a mixture of them. All experiments were conducted using 0.5-5 mm solutions of CuSO4·5H2O, CoCl2·6H2O and FeSO4·7H2O. Mycelia immobilized on polyurethane foam cells showed some times increase in uptake compared with that of free cells. Metal ions accumulation from a mixed solution was decreased slightly for cobalt and iron and considerable for copper ions. Heavy metal uptake was examined in the immobilized column experiments and more than 92% heavy metal removal (mg heavy metals removed/mg heavy metals added) from a mixed solution was achieved during the 5 cycles. During these experiments, the dry weight of the immobilized cells was decreased by only 2%. These results showed that immobilized mycelia of Rhizopus delemar can be used repeatedly for removal of heavy metals from aqueous solutions.


2018 ◽  
Vol 78 (4) ◽  
pp. 982-990 ◽  
Author(s):  
Jianhong Ma ◽  
Yuanmeng Zhang ◽  
Yanhong Tang ◽  
Yuanfeng Wei ◽  
Yutang Liu ◽  
...  

Abstract It is hard to balance high water permeability and good mechanical strength of hydrogel adsorbents. In this study, an enhanced double network hydrogel adsorbent of poly (vinyl alcohol)/poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PVA/PAMPS) was prepared via simple free-radical polymerization. Hydrophilic PAMPS guaranteed high swellability of the adsorbent, which made the sufficient diffusion of metal ions towards adsorbent inside. Meanwhile, the cross-linkage between PVA and PAMPS chains ensured good mechanical strength of the adsorbent. Significantly, the introduction of multifunctional groups (-NHR, -SO3H and -OH) endowed the adsorbent with both chelation and ion exchange function for enhancing heavy metal adsorption. The maximum adsorption capacities of Pb2+ and Cd2+ reached 340 and 155.1 mg/g, respectively. The adsorbent could efficiently remove heavy metals in melting effluent, especially Pb2+ and Cd2+. The removal efficiencies reached 88.1% for Pb2+, 91.4% for Cd2+, 70.4% for Zn2+, 77.4% for Cu2+, 42.5% for Mn2+, 45.1% for Ni2+ and 95.4% for Fe3+ using 2 g/L adsorbent in 2 h. Moreover, the adsorbent showed a good reusability, and the removal efficiencies maintained 94% for Pb2+ and 93% for Cd2+ in the fifth cycle (m/V = 1 g dry gel/L). This work developed a highly practical hydrogel adsorbent for heavy metal removal from wastewater.


2012 ◽  
Vol 178-181 ◽  
pp. 507-511
Author(s):  
Zhi Min Zhang

The concentration of heavy metals in excess sludge from municipal wastewater treatment plants has restricted its convertion to soil fertilizer, so it is necessary to remove the heavy metals from sludge. In this article, the effects of heavy metal removal by some mineral acids such as HCl, H2SO4, H3PO4, HNO3 were analysed, when treating excess sludge from a second sediment tank in municipal wastewater treatment plants. To improve the treatment, a combination of H2O2 and acid was also investigated. Consequently, the difference of heavy metal removal among those acids was showed. Its removal of Hg by HNO3 was better than by other acids. Lower pH enhanced the dissolving of heavy metal, yet the removal of Cr was insensitive to the pH. Aided by H2O2, the removal by the acid was enhanced. The suitable dosage of H2O2 was specially related to the solid content of sludge, pH and the acid kind.


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