Anaerobic treatment of sludge: focusing on reduction of las concentration in sludge

2002 ◽  
Vol 46 (10) ◽  
pp. 159-165 ◽  
Author(s):  
F. Haggensen ◽  
A.S. Mogensen ◽  
I. Angelidaki ◽  
B.K. Ahring
Keyword(s):  
Organic Matter ◽  
Anaerobic Treatment ◽  
Clear Correlation ◽  
Biological Degradation ◽  
Anaerobic Conditions ◽  
Linear Alkylbenzene ◽  
Stirred Tank Reactors ◽  
Bioavailable Fraction ◽  
Solids Concentration ◽  
Linear Alkylbenzene Sulfonates

Anaerobic degradation of linear alkylbenzene sulfonates (LAS) was tested in continuous stirred tank reactors (CSTR). LAS12 was used as a model compound and was spiked on sewage sludge. The experiments clearly showed that transformation of LAS12 occurred under anaerobic conditions. The degree of transformation varied between 14% and 25%. HPLC analysis showed that disappearance of LAS12 was followed by the formation of a metabolite. The experiments indicated that there is a clear correlation between degradation of organic matter contained in sludge and transformation of LAS12. When the reduction degree of the organic matter increased from 22% to 28%, the transformation degree of LAS12 also increased, from 14% to 20%. Decreasing the total solids concentration of the influent sludge or increasing the spiked concentration of LAS12 did not alter the degree of LAS12 transformation significantly. A clear correlation between transformed and bioavailable LAS12 was found, indicating that it is merely the bioavailable fraction of LAS12 that is transformed by anaerobic digestion. The results from the present study are promising and indicate that a great potential for biological degradation of LAS is possible even at anaerobic conditions.

Comparison of linear alkylbenzene sulfonates removal in conventional activated sludge systems and membrane bioreactors

2004 ◽  
Vol 50 (5) ◽  
pp. 219-225 ◽  
Author(s):  
H. De Wever ◽  
S. Van Roy ◽  
C. Dotremont ◽  
J. Müller ◽  
T. Knepper
Keyword(s):  
Activated Sludge ◽  
Membrane Bioreactors ◽  
Operating Conditions ◽  
Biological Degradation ◽  
Linear Alkylbenzene ◽  
Conventional Activated Sludge ◽  
Operational Variables ◽  
Linear Alkylbenzene Sulfonates ◽  
Model Components ◽  
Activated Sludge Systems

The potential of a membrane bioreactor (MBR) and a conventional activated sludge (CAS) system to remove polar micropollutants was evaluated using linear alkylbenzene sulfonates (LAS) as model components. Removal efficiencies over 97% were achieved in both reactor systems. The appearance of biological breakdown metabolites and the respirometric response of the sludges to LAS addition indicated that LAS removal was due to biodegradation, rather than sorption phenomena. The effect of operational variables, such as hydraulic retention time, LAS composition and hydrophobicity of the membrane used in the MBR, was negligible in the range tested. A stepwise increase in LAS influent concentration resulted in higher residual effluent concentrations but did not change the procentual removal efficiency. Because an increase in LAS and SPC effluent concentration occurred to a larger extent in the CAS than in the MBR under similar operating conditions, MBRs may turn out to be be more robust with respect to biological degradation of micropollutants than CAS.

Acetate uptake efficiency of polyphosphate-accumulating organisms under exposure to surfactants

2009 ◽  
Vol 60 (11) ◽  
pp. 2775-2780
Author(s):  
K. Tsuji ◽  
M. Fujita ◽  
H. Furumai
Keyword(s):  
Municipal Wastewater ◽  
Batch Reactor ◽  
Alcohol Ethoxylates ◽  
Anaerobic Conditions ◽  
Linear Alkylbenzene ◽  
Acetate Uptake ◽  
Batch Tests ◽  
Linear Alkylbenzene Sulfonates ◽  
Negative Impacts ◽  
Polyphosphate Accumulating Organisms

We investigated the influence of surfactants such as linear alkylbenzene sulfonates (LAS) and alcohol ethoxylates (AE) on acetate uptake by polyphosphate-accumulating organisms (PAOs) under anaerobic conditions, using the phosphate requirement for acetate uptake (+ΔP/−ΔAc ratio). In order to estimate the +ΔP/−ΔAc ratio, anaerobic batch tests were conducted using activated sludge collected from an anaerobic/oxic sequencing batch reactor used to treat municipal wastewater continuously supplemented with a detergent containing LAS and AE. We demonstrated that LAS and AE have both positive and negative impacts on acetate uptake by PAOs. The disadvantage is that long-term exposure to the detergent inhibits acetate uptake by PAOs, thus deteriorating the efficiency, even if the surfactants are no longer present during the tests. Furthermore, the existence of LAS and/or AE with acetate further diminishes the efficiency. The advantage is that LAS and AE are potential sources of polyhydroxyalkanoate for PAOs, because acetate is produced from the surfactants under anaerobic conditions.

scholarly journals Oligomers, organosulfates, and nitroxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry

2008 ◽  
Vol 8 (5) ◽  
pp. 17439-17466 ◽  
Author(s):  
K. E. Altieri ◽  
B. J. Turpin ◽  
S. P. Seitzinger
Keyword(s):  
Mass Spectrometry ◽  
Organic Matter ◽  
High Resolution ◽  
Electrospray Ionization ◽  
Mass Range ◽  
Negative Ion ◽  
Ion Cyclotron Resonance ◽  
Linear Alkylbenzene ◽  
Linear Alkylbenzene Sulfonates ◽  
Ft Icr

Abstract. Wet deposition is an important removal mechanism for atmospheric organic matter, and a potentially important input for receiving ecosystems, yet less than 50% of rainwater organic matter is considered chemically characterized. Precipitation samples collected in New Jersey, USA, were analyzed by negative ion ultra-high resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Elemental compositions of 552 unique molecular species were determined in the mass range 50–500 Da in the rainwater. Three main groups of organic compounds were identified: compounds containing carbon, hydrogen, and oxygen (CHO) only, sulfur (S) containing CHOS compounds, and S- and nitrogen containing CHONS compounds. Organic acids commonly identified in precipitation were detected, as well as linear alkylbenzene sulfonates, which are persistent pollutants commonly measured in river water, seawater, and sediments, but to our knowledge, not previously documented in atmospheric samples. Within the three main groups of compounds detected in the rainwater, oligomers, organosulfates, and nitroxy-organosulfates were identified. The majority of the compounds identified are products of atmospheric reactions and are known contributors to secondary organic aerosol (SOA) formed from gas phase, aerosol phase, and in-cloud reactions in the atmosphere. It is suggested that the large uncharacterized component of SOA is the main contributor to the large uncharacterized component of rainwater organic matter.

Sludge minimization by disintegration at different wastewater treatment plants

2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Luchien Luning ◽  
Paul Roeleveld ◽  
Victor W.M. Claessen
Keyword(s):  
Organic Matter ◽  
Wastewater Treatment ◽  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
New Technologies ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Biological Degradation ◽  
Ongoing Research ◽  
Sludge Minimization

In recent years new technologies have been developed to improve the biological degradation of sewage sludge by anaerobic digestion. The paper describes the results of a demonstration of ultrasonic disintegration on the Dutch Wastewater Treatment Plant (WWTP) Land van Cuijk. The effect on the degradation of organic matter is presented, together with the effect on the dewatering characteristics. Recommendations are presented for establishing research conditions in which the effect of sludge disintegration can be determined in a more direct way that is less sensitive to changing conditions in the operation of the WWTP. These recommendations have been implemented in the ongoing research in the Netherlands supported by the National Institute for wastewater research (STOWA).

Anaerobic treatment of soil wash fluids from a wood preserving site

1998 ◽  
Vol 38 (7) ◽  
pp. 63-72 ◽  
Author(s):  
K. M. Miller ◽  
M. T. Suidan ◽  
G. A. Sorial ◽  
A. P. Khodadoust ◽  
C. M. Acheson ◽  
...  
Keyword(s):  
Soil Washing ◽  
Anaerobic Treatment ◽  
Integrated System ◽  
Waste Stream ◽  
Adsorptive Capacity ◽  
Anaerobic Conditions ◽  
Washing Process ◽  
Polycyclic Aromatic ◽  
Treatment Technologies ◽  
Solvent Washing

An integrated system has been developed to remediate soils contaminated with pentachlorophenol (PCP) and polycyclic aromatic hydrocarbons (PAHs). This system involves the coupling of two treatment technologies, soil solvent washing and anaerobic biotreatment of the extract. Specifically, this study evaluated the effectiveness of the granular activated carbon (GAC) fluidized-bed reactor to treat a synthetic waste stream of PCP and four PAHs (naphthalene, acenaphthene, pyrene, and benzo(b)fluoranthene) under anaerobic conditions. This waste stream was intended to simulate the wash fluids from a soil washing process treating soils from a wood preserving site. The reactor achieved a removal efficiency of greater than 99.8% for PCP with conversion to its dechlorination intermediates ranging from 47% to 77%. Effluent, carbon extraction, and isotherm data also indicate that naphthalene and acenaphthene were removed from the liquid phase with efficiencies of 86% and 93%, respectively. Effluent levels of pyrene and benzo(b)fluoranthene were extremely low due to the adsorptive capacity of GAC for these compounds. Experimental evidence does not suggest that these compounds were chemically transformed within the reactor.

Anaerobic Degradation Pathway of Linear Alkylbenzene Sulfonates (LAS) in Sulfate-Reducing Marine Sediments

2010 ◽  
Vol 44 (5) ◽  
pp. 1670-1676 ◽  
Author(s):  
Pablo A. Lara-Martín ◽  
Abelardo Gómez-Parra ◽  
José Luis Sanz ◽  
Eduardo González-Mazo
Keyword(s):  
Marine Sediments ◽  
Anaerobic Degradation ◽  
Degradation Pathway ◽  
Linear Alkylbenzene ◽  
Sulfate Reducing ◽  
Linear Alkylbenzene Sulfonates

Fate and Distribution of Linear Alkylbenzene Sulfonates in the Littoral Environment

1998 ◽  
Vol 32 (11) ◽  
pp. 1636-1641 ◽  
Author(s):  
Eduardo González-Mazo ◽  
Jesus María Forja ◽  
Abelardo Gómez-Parra
Keyword(s):  
Linear Alkylbenzene ◽  
Linear Alkylbenzene Sulfonates

Enhancement of polycyclic aromatic hydrocarbons removal during anaerobic treatment of urban sludge

2003 ◽  
Vol 48 (4) ◽  
pp. 53-60 ◽  
Author(s):  
E. Trably ◽  
D. Patureau ◽  
J.P. Delgenes
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Sewage Sludge ◽  
Aromatic Hydrocarbons ◽  
Agricultural Soils ◽  
Biogas Production ◽  
Bacterial Consortium ◽  
Anaerobic Treatment ◽  
Biological Degradation ◽  
Low Concentrations ◽  
Polycyclic Aromatic

Anaerobically stabilized sewage sludge has potential to partially substitute synthetic fertilizers. The main risk with the recycling of urban sludge on agricultural soils is the accumulation of unwanted products, such as trace metals and organic micropollutants. In this context, the polycyclic aromatic hydrocarbons (PAHs) are particularly monitored because of their toxic properties at low concentrations and their high resistance to biological degradation. The aim of the present study was to optimize PAHs removal during anaerobic digestion of contaminated sewage sludge. Thirteen PAHs were monitored in laboratory-scale anaerobic bioreactors under mesophilic (35°C) and thermophilic (55°C) methanogenic conditions. Abiotic losses were statistically significant for the lightest PAHs, such as fluorene, phenanthrene and anthracene. It was shown that PAH removal was due to a specific biological activity. Biological PAHs removal was significantly enhanced by an increase of the temperature from 35°C to 55°C, especially for the heaviest PAHs. Bioaugmentation experiment was also performed by addition of a PAH-adapted bacterial consortium to a non-acclimated reactor. Significant enhancement of PAHs removal was observed. It was finally shown that PAH removal efficiencies and methanogenic performances were closely linked. The rate of biogas production may be used as an indicator of bacterial activity on PAH removal.

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