scholarly journals Vulcânicas potássicas intemperizadas como protólitos dos filitos hematíticos da Serra do Espinhaço Meridional (Minas Gerais)

2020 ◽  
Vol 34 (2) ◽  
pp. 183-194
Author(s):  
Alexandre Chaves ◽  
Luiz Knauer
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Volcanic Rocks ◽  
Alkaline Rock ◽  
Major Elements ◽  
Volcanic Origin ◽  
Espinhaço Range ◽  
Weathering Processes ◽  
Igneous Layering ◽  
Hematitic Phyllite

The hematitic phyllite is a rock that occurs in the São João da Chapada and Sopa-Brumadinho formations of the southern Espinhaço range. Its origin is widely discussed in papers on Espinhaço, but there is no consensus on its protolith due to certain characteristics of the lithotype, such as its chemical composition and textural features. The pattern of rare earth elements strongly enriched [(La/Yb)N 6.80-17.68], with light rare earth elements [(La/Sm)N 2.54-4.83] richer than heavy ones [(Gd/Yb)N 1.28-3,32], suggests that the protolith was an alkaline volcanic rock formed during the rift that generated the Espinhaço basin. The major elements indicate that the alkaline rock met weathering processes, becoming a regolith. During the Brasiliano metamorphism, it finally became hematitic phyllite. Other characteristics of the lithotype, such as the presence of sericite-bearing rounded parts (possibly formed by alteration and deformation of leucite crystals) and the preservation of igneous layering, suggest a potassic volcanic origin for hematitic phyllite. In diagram that allows identifying altered and metamorphic volcanic rocks, the investigated samples have composition similar to a feldspathoid-rich alkali-basalt, probably a leucite tephrite, a leucitite or even a lamproite, rocks from mantle source.

Geochemistry of two metavolcanic arc suites from the Central Metasedimentary Belt of the Grenville Province, southeastern Ontario, Canada

1991 ◽  
Vol 28 (9) ◽  
pp. 1429-1443 ◽  
Author(s):  
Luc Harnois ◽  
John M. Moore
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Partial Melting ◽  
Volcanic Rocks ◽  
Parental Magma ◽  
Major Elements ◽  
Grenville Province ◽  
Element Abundances ◽  
Felsic Rocks

Samples of two subalkaline metavolcanic suites, the Tudor formation (ca. 1.28 Ga) and the overlying Kashwakamak formation, have been analysed for major elements and 27 trace elements (including rare-earth elements). The Tudor formation is tholeiitic and contains mainly basaltic flows, whereas the Kashwakamak formation is calc-alkaline and contains mainly andesitic rocks with minor felsic rocks. The succession has been regionally metamorphosed to upper greenschist – lower amphibolite facies. Trace-element abundances and ratios indicate that rocks of the Tudor and Kashwakamak formations are island-arc type. Geochemical modelling using rare-earth elements, Zr, Ti, and Y indicates that the Tudor volcanic rocks are not derived from a single parental magma through simple fractional crystallization. Equilibrium partial melting of a heterogeneous Proterozoic upper mantle can explain the trace-element abundances and ratios of Tudor formation volcanic rocks. The intermediate to felsic rocks of the Kashwakamak formation appear to have been derived from a separate partial melting event. The data are consistent with an origin of the arc either on oceanic crust or on thinned continental crust, and with accretion of the arc to a continental margin between the time of extrusion of Tudor volcanic rocks and that of Kashwakamak volcanic rocks.

scholarly journals U-Pb geochronology, Sr-Nd geochemistry, petrogenesis and tectonic setting of Gandab volcanic rocks, northeastern Iran

2017 ◽  
Vol 44 (1) ◽  
pp. 269-286 ◽  
Author(s):  
Azam Entezari Harsini ◽  
Seyed A Mazaheri ◽  
Saeed Saadat ◽  
José F Santos
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Rare Earth Element ◽  
Earth Element ◽  
Saturation Index ◽  
Tectonic Setting ◽  
Volcanic Rocks ◽  
Major Elements ◽  
Magmatic Arc ◽  
Heavy Rare Earth Elements

Abstract This paper addresses U-Pb geochronology, Sr-Nd geochemistry, petrogenesis and tectonic setting in the Gandab volcanic rocks. The Gandab volcanic rocks belong to the Sabzevar zone magmatic arc (northeastern Iran). Petrographically, all the studied volcanic rocks indicate porphyritic textures with phenocrysts of plagioclase, K-feldespar, hornblende, pyroxene, and magnetite which are embedded in a fine to medium grained groundmass. As well, amygdaloidal, and poikilitic textures are seen in some rocks. The standard chemical classifications show that the studied rocks are basaltic trachy andesite, trachy andesite, trachyte, and trachy dacite. Major elements reveal that the studied samples are metaluminous and their alumina saturation index varies from 0.71 to 1.02. The chondrite-normalized rare earth element and mantle-normalized trace element patterns show enrichment in light rare earth elements (LREE) relative to heavy rare earth elements (HREE) and in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). As well they show a slightly negative Eu anomaly (Eu/Eu* = 0.72 – 0.97). The whole-rock geochemistry of the studied rocks suggests that they are related to each other by fractional crystallization. LA-MC-ICP-MS U-Pb analyses in zircon grains from two volcanic rock samples (GCH-119 and GCH-171) gave ages ranging of 5.47 ± 0.22 Ma to 2.44 ± 0.79 Ma, which corresponds to the Pliocene period. In four samples analysed for Sr and Nd isotopes 87Sr/86Sr ratios range from 0.704082 to 0.705931 and εNd values vary between +3.34 and +5. These values could be regarded to as representing mantle derived magmas. Taking into account the comparing rare earth element (REE) patterns, an origin of the parental magmas in enriched lithospheric mantle is suggested. Finally, it is concluded that Pliocene Gandab volcanic rocks are related to the post-collision environment that followed the Neo-Tethys subduction.

Petrogenesis of the Upper Cretaceous volcanism in the Kefken region, Western Pontides, NW Turkey

2021 ◽  
Author(s):  
Turgut Duzman ◽  
Ezgi Sağlam ◽  
Aral I. Okay
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Partial Melting ◽  
Upper Cretaceous ◽  
Volcanic Rocks ◽  
Early Eocene ◽  
Heavy Rare Earth ◽  
Heavy Rare Earth Elements ◽  
Cretaceous Volcanism ◽  
Oceanic Slab

<p>The Upper Cretaceous volcanic and volcaniclastic rocks crop out along the Black Sea coastline in Turkey. They are part of a magmatic arc that formed as a result of northward subduction of the Tethys ocean beneath the southern margin of Laurasia. The lower part of the Upper Cretaceous volcanism in the Kefken region, 100 km northeast of Istanbul, is represented by basaltic andesites, andesites, agglomerates and tuffs, which have yielded Late Cretaceous (Campanian, ca. 83 Ma) U-Pb zircon ages. The volcanic and volcanoclastic rocks are stratigraphically overlain by shallow to deep marine limestones, which range in age from Late Campanian to Early Eocene.  Geochemically, basaltic andesites and andesites display negative anomalies in Nb, Ta and Ti, enrichment in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). Light rare earth elements (LREE) show slightly enrichment relative to heavy rare earth elements (La<sub>cn</sub>/Yb<sub>cn</sub> =2.51-3.63) and there are slight negative Eu anomalies (Eu/Eu* = 0.71-0.95) in basaltic andesite and andesite samples. The geochemical data indicate that Campanian volcanic rocks were derived from the partial melting of the mantle wedge induced by hydrous fluids released by dehydration of the subducted oceanic slab.</p><p>There is also a horizon of volcanic rocks, about 230 m thick, within the Late Campanian-Early Eocene limestone sequence.  This volcanic horizon, which consists of pillow basalts, porphyritic basalts,  andesites and dacites, is of Maastrichtian age based on paleontological data from the intra-pillow sediments and U-Pb zircon ages from the andesites and dacites (72-68 Ma).  The Maastrichtian andesites and dacites are geochemically distinct from the Campanian volcanic rocks. They show distinct adakite-like geochemical signatures with high ratios of Sr/Y (>85.5), high La<sub>cn</sub>/Yb<sub>cn </sub>(16.4-23.7) ratios, low content of Y (7.4-8.6 ppm) and low content of heavy rare-earth elements (HREE). The adakitic rocks most probably formed as a result of partial melting of the subducting oceanic slab under garnet and amphibole stable conditions.</p><p>The Upper Cretaceous arc sequence in the Kefken region shows a change from typical subduction-related magmas to adakitic ones, accompanied by decrease in the volcanism.</p><p> </p><p> </p>

Geochemistry and petrogenesis of the early Proterozoic Hemlock volcanic rocks and the Kiernan sills, southern Lake Superior region

1988 ◽  
Vol 25 (4) ◽  
pp. 528-546 ◽  
Author(s):  
W. C. Ueng ◽  
T. P. Fox ◽  
D. K. Larue ◽  
J. T. Wilband
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
North Atlantic ◽  
North Atlantic Ocean ◽  
Lake Superior ◽  
Volcanic Rocks ◽  
Wall Rock ◽  
Major Elements ◽  
Chemical Contamination ◽  
Early Proterozoic

During the early Proterozoic, the 2 km thick differentiated gabbroic Kiernan sills were emplaced into a thick accumulation of pillow basalt and associated deep-water strata, the Hemlock Formation, in the southern Lake Superior region. On the basis of major elements and trace elements (including rare-earth-element data), the Kiernan sills and the hosting volcanic rocks of the Hemlock Formation were determined to be comagmatic in origin, and both evolved from assimilation – crystal fractionation processes. The major assimilated components in these igneous rocks are identified as terrigenous sedimentary rocks. Assimilation affected the abundance of Nb, Ta, light rare-earth elements, and most likely P, Rb, Th, and K in the magma. The effect of chemical contamination from wall-rock assimilation accumulates with increasing differentiation.With wall-rock contamination carefully evaluated, a series of tectonic discriminating methods utilizing immobile trace elements indicates that the source magma was a high-Ti tholeiitic basalt similar to present-day mid-ocean-ridge basalts (MORB). It is suggested from this study that most of the enriched large-ion lithophile elements and LREE of the magma were not inherited from the mantle but from assimilation of supracrustal rocks. Chemical signatures of these rocks are distinctively different from those of arc-related volcanics. A rifting tectonic regime analogous to the opening of the North Atlantic Ocean and extrusion of North Atlantic Tertiary volcanics best fits the criteria revealed by this study.

Evolution of deep mantle sourced carbonated melt in the mantle lithosphere

2020 ◽  
Author(s):  
Guoliang Zhang
Keyword(s):  
Rare Earth ◽  
Field Strength ◽  
Rare Earth Elements ◽  
Lithospheric Mantle ◽  
High Field ◽  
Volcanic Rocks ◽  
Mantle Lithosphere ◽  
High Field Strength ◽  
Alkali Basalts ◽  
Deep Mantle

<p>Deep sourced magmas play a key role in distribution of carbon in the Earth’s system. Oceanic hotspots rooted in deep mantle usually produce CO<sub>2</sub>-rich magmas. However, the association of CO<sub>2</sub> with the origin of these magmas remains unclear. Here we report geochemical analyses of a suite of volcanic rocks from the Caroline Seamount Chain formed by the deep-rooted Caroline hotspot in the western Pacific. The most primitive magmas have depletion of SiO<sub>2</sub> and high field strength elements and enrichment of rare earth elements that are in concert with mantle-derived primary carbonated melts. The carbonated melts show compositional variations that indicate reactive evolution within the overlying mantle lithosphere and obtained depleted components from the lithospheric mantle. The carbonated melts were de-carbonated and modified to oceanic alkali basalts by precipitation of perovskite, apatite and ilmenite that significantly decreased the concentrations of rare earth elements and high field strength elements. These magmas experienced a stage of non-reactive fractional crystallization after the reactive evolution was completed. Thus, the carbonated melts would experience two stages, reactive and un-reactive, of evolution during their transport through in thick oceanic lithospheric mantle. We suggest that the mantle lithosphere plays a key role in de-carbonation and conversion of deep-sourced carbonated melts to alkali basalts. This work was financially supported by the National Natural Science Foundation of China (91858206, 41876040).</p>

Paleoproterozoic carbonatitic ultrabasic volcanic rocks (meimechites?) of Cape Smith Belt, Quebec

2001 ◽  
Vol 38 (9) ◽  
pp. 1313-1334 ◽  
Author(s):  
W RA Baragar ◽  
U Mader ◽  
G M LeCheminant
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Hydrothermal Alteration ◽  
Regional Metamorphism ◽  
Volcanic Rocks ◽  
Light Rare Earth ◽  
Shallow Marine ◽  
Incompatible Elements ◽  
Thick Lens ◽  
Light Rare Earth Elements

A 500 m-thick lens of carbonatitic ultrabasic lapilli tuffs and lavas interbedded with platformal Povungnituk sediments in the foreland of the Cape Smith Belt is its earliest known magmatism and may relate to its initial rifting. The sequence comprises tuffs capped in part by effusives. Accretionary and cored lapilli in the tuffs and pillows in the lavas suggest emplacement in a shallow marine environment. Its current assemblage of antigorite, chlorite, talc, and (in part primary?) carbonate, magnetite, ilmenite, minor chromite, and phlogopite results from probable concurrent hydrothermal alteration and subsequent greenschist regional metamorphism. Surviving accessory minerals: apatite, monazite, zircon, rutile, and aeschenite(?) are widespread but scarce. Carbonate (mostly dolomite) is a major and integral component of the rock and interpreted as an original, albeit recrystallized, magmatic constituent. Magnetite is conspicuous in the tuffs: as lapilli and lapilli cores, locally as giant crystals, and as stringers. Except in subhedral groundmass crystals, its negligible TiO2 is evidence of its hydrothermal reconstitution. Compositions of chromite cores and rare relicts of phlogopite crystals are consistent with mantle derivation. Rock compositions are low in SiO2 (<35%) and Al2O3 (<3%), high in MgO (>25 wt.%) and alkaline. The immobile incompatible elements (e.g., Zr, average 260 ppm; Nb, average 130 ppm) and the light rare-earth elements are enriched. The rocks are compositionally similar to type Siberian meimechites and closely resemble the "meimechite"–carbonatite eruptives of Castignon Lake, Labrador Trough. Based on experimental evidence, Lac Leclair magmas are interpreted as originating by minor partial melting of carbonated mantle at ~100 km depths and reaching the surface via conduits opened by deep rifting that initiated the Cape Smith segment of the Trans-Hudson Orogen.

scholarly journals Geochemistry of garnet megacrysts from the Mir kimberlite pipe (Yakutia) and the nature of prothokimberlite melt

2019 ◽  
Vol 486 (5) ◽  
pp. 583-587
Author(s):  
A. M. Agashev
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Negative Correlation ◽  
Kimberlite Pipe ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Incompatible Elements ◽  
Composition Study ◽  
Melt Composition

The paper presents the results of major and trace elements composition study of garnet megacrysts from Mir kimberlite pipe. On the major elements composition those garnets classified as low Cr and high Ti pyropes. Concentrations of TiO2 show a negative correlation with MgO и Cr2O3 contents in megacrysts composition. Fractional crystallization modeling indicates that the most appropriate melt to reproduce the garnet trace elements signatures is the melt of picritic composition. Composition of garnets crystallized from kimberlite melt do not correspond to observed natural garnets composition. Kimberlites contain less of Ti, Zr, Y and heavy REE (rare earth elements) but more of very incompatible elements such as light REE, Th, U, Nb, Ba then the model melt composition that necessary for garnet crystallization.

scholarly journals Rock alteration at the post-Variscan nonconformity: implications for Carboniferous–Permian surface weathering versus burial diagenesis and paleoclimate evaluation

Solid Earth ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 1165-1184
Author(s):  
Fei Liang ◽  
Jun Niu ◽  
Adrian Linsel ◽  
Matthias Hinderer ◽  
Dirk Scheuvens ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Basaltic Andesite ◽  
Inductively Coupled Plasma ◽  
Volcanic Rocks ◽  
Polarization Microscopy ◽  
Burial Diagenesis ◽  
X Ray ◽  
Physical Weathering ◽  
Geochemical Indices

Abstract. A nonconformity refers to a hiatal surface located between metamorphic or igneous rocks and overlying sedimentary or volcanic rocks. These surfaces are key features with respect to understanding the relations among climate, lithosphere and tectonic movements during ancient times. In this study, the petrological, mineralogical and geochemical characteristics of Variscan basement rock as well as its overlying Permian volcano-sedimentary succession from a drill core in the Sprendlinger Horst, Germany, are analyzed by means of polarization microscopy, and environmental scanning electron microscope, X-Ray diffraction, X-ray fluorescence and inductively coupled plasma mass spectrometry analyses. In the gabbroic diorite of the basement, the intensity of micro- and macro-fractures increases towards the top, indicating an intense physical weathering. The overlying Permian volcanic rock is a basaltic andesite that shows less intense physical weathering compared with the gabbroic diorite. In both segments, secondary minerals are dominated by illite and a mixed-layer phase of illite and smectite (I–S). The corrected chemical index of alteration (CIA) and the plagioclase index of alteration (PIA) indicate an intermediate to unweathered degree in the gabbroic diorite and an extreme to unweathered degree in the basaltic andesite. The τ values for both basaltic andesite and gabbroic diorite indicate an abnormal enrichment of K, Rb and Cs that cannot be observed in the overlying Permian sedimentary rocks. Accompanying minerals such as adularia suggest subsequent overprint by (K-rich) fluids during burial diagenesis which promoted the conversion from smectite to illite. The overall order of element depletion in both basaltic andesite and gabbroic diorite during the weathering process is as follows: large-ion lithophile elements (LILEs) > rare earth elements (REEs) > high-field-strength elements (HFSEs). Concerning the REEs, heavy rare earth elements (HREEs) are less depleted than light rare earth elements (LREEs). Our study shows that features of supergene physical and chemical paleo-weathering are well conserved at the post-Variscan nonconformity despite hypogene alteration. Both can be distinguished by characteristic minerals and geochemical indices. Based on these results, a new workflow to eliminate distractions for paleoclimate evaluation and evolution is developed.

scholarly journals The distribution of the trace element contents in lignite and ash from Drama lignite deposit, using multivariate statistical analysis

2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Rare Earth Elements ◽  
Multivariate Statistical Analysis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Inorganic Matter

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.

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