scholarly journals Pemodelan dan Simulasi Proses Adsorpsi Gas Pengotor oleh Molecular Sieve pada Pendingin Rde dengan Software Chemcad

2019 ◽  
Vol 3 ◽  
pp. 69 ◽  
Author(s):  
Sriyono Sriyono ◽  
Atiqah M. Hilda ◽  
Mia Kamayani
Keyword(s):  
Molecular Sieve ◽  
Computer Code ◽  
Absorption Capacity ◽  
Bed Height ◽  
Purification System ◽  
Pressure Swing ◽  
Air Ingress ◽  
Molecular Sieve Column ◽  
Helium Coolant ◽  
High Absorption

The purity of RDE10 helium coolant should be maintained from various impurities gas due to water/air ingress that reacts with the reflector graphite (C). These impurities are CH4, CO, CO2, H2O, H2, O2, and N2 which can initiate oxidation corrosion or carburization-decarburization so the concentration should be maintain to be a minimum. The helium coolant is purified by Helium Purification System (HPS). One of the stages in HPS is adsorption by Molecular Sieve mainly for CO2 and H2O molecules. This paper discusses the influence of pressure, known as pressure swing adsorption (PSA) on the adsorption ability of the Molecular Sieve aims to determine the most effective pressure that will be operated on Molecular Sieve column. Molecular Sieve is modeled with CHEMCAD computer code in two columns, one column for the adsorption process, and the other for the regeneration (desorption). Adsorption methods used in the analysis is the Langmuir method. Models that have been developed simulated by providing input: total flow rate of 10.5 kg/hour, 30 °C, porosity 0.7, bed height 2 m, pore diameter 5 A, and the amount of O2 and N2 impurities respective each 1 g/s. The pressure varies between 5 to 50 bars, and the Molecular Sieve adsorption capability is analyzed. Simulation results show that with the increase in pressure of 5 to 50 bar, indicating an increase in Molecular Sieve absorption capacity to CO2 is 15.90% and to H2O is 15.80%. In the SPH design, the input stream to the Molecular Sieve must be compressed until 50 bar to obtain high absorption capability of the CO2 and H2O.

Investigation of Quench-16 Experiment With MELCOR Computer Code

2014 ◽  
Author(s):  
Petya Vryashkova ◽  
Pavlin Groudev ◽  
Antoaneta Stefanova
Keyword(s):  
Experimental Data ◽  
Flow Rate ◽  
Initial Temperature ◽  
Computer Code ◽  
Air Flow Rate ◽  
Fuel Rod ◽  
Fuel Bundle ◽  
Oxygen Starvation ◽  
Air Ingress ◽  
Good Agreement

This paper presents a comparison of MELCOR calculated results with experimental data for the QUENCH-16 experiment. The analysis for the air ingress experiment QUENCH-16 has been performed by INRNE. The calculations have been performed with MELCOR code. The QUENCH-16 experiment has been performed on 27-th of July 2011 in the frame of the EC-supported LACOMECO program. The experiments have focused on air ingress investigation into an overheated core following earlier partial oxidation in steam. QUENCH-16 has been performed with limited pre-oxidation and low air flow rate. One of the main objectives of QUENCH-16 was to examine the interaction between nitrogen and oxidized cladding during a prolonged period of oxygen starvation. The bundle is made from 20 heated fuel rod simulators arranged in two concentric rings and one unheated central fuel rod simulator, each about 2.5 m long. The tungsten heaters were surrounded by annular ZrO2 pellets to simulate the UO2 fuel. The geometry and most other bundle components are prototypical for Western-type PWRs. To improve the obtained results it has been made a series of calculations to select an appropriate initial temperature of the oxidation of the fuel bundle and modified correlation oxidation of Zircaloy with MELCOR computer code. The compared results have shown good agreement of calculated hydrogen and oxygen starvation in comparison with test data.

Understanding the unique interaction of amine-containing ionic compounds with SO2 for high absorption capacity

RSC Advances ◽  
2013 ◽  
Vol 3 (48) ◽  
pp. 25944 ◽  
Author(s):  
Hyunjoo Lee ◽  
Young Mee Jung ◽  
Keun Im Lee ◽  
Hoon Sik Kim ◽  
Ho Seok Park
Keyword(s):  
Absorption Capacity ◽  
Ionic Compounds ◽  
High Absorption

scholarly journals Capture of Acidic Gases from Flue Gas by Deep Eutectic Solvents

Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1268
Author(s):  
Yan Wang ◽  
Shuhang Ren ◽  
Yucui Hou ◽  
Weize Wu
Keyword(s):  
Hydrogen Bond ◽  
Flue Gas ◽  
Deep Eutectic Solvents ◽  
Absorption Capacity ◽  
Physical Interaction ◽  
Co2 Absorption ◽  
Physicochemical Interaction ◽  
Acidic Gases ◽  
New Strategies ◽  
High Absorption

Up to now, many kinds of deep eutectic solvents (DESs) were investigated for the capture of acidic gases from flue gases. In this review, non-functionalized and functionalized DESs, including binary and ternary DESs, for SO2, CO2 and NO capture, are summarized based on the mechanism of absorption, physical interaction or chemical reaction. New strategies for improving the absorption capacity are introduced in this review. For example, a third component can be introduced to form a ternary DES to suppress the increase in viscosity and improve the CO2 absorption capacity. DESs, synthesized with halogen salt hydrogen bond acceptors (HBAs) and functionalized hydrogen bond donors (HBDs), can be used for the absorption of SO2 and NO with high absorption capacities and low viscosities after absorption, due to physicochemical interaction between gases and DESs. Emphasis is given to introducing the absorption capacities of acidic gases in these DESs, the mechanism of the absorption, and the ways to enhance the absorption capacity.

Enhanced scavenging of a minor component from mixtures of two immiscible liquids by hollow polymer microgels

2022 ◽  
Author(s):  
Mikhail V. Anakhov ◽  
Rustam A. Gumerov ◽  
Igor Potemkin
Keyword(s):  
Minor Component ◽  
Absorption Capacity ◽  
Immiscible Liquids ◽  
A Minor ◽  
Soft Nanoparticles ◽  
High Absorption

Hollow soft nanoparticles are known to be highly perspective containers with high absorption capacity of various substances. In particular, this feature can be applied in terms of solvents separation on...

Ultralight and highly compressible coal oxide-modified graphene aerogels for organic solvent absorption and light-to-heat conversion

2020 ◽  
Vol 44 (6) ◽  
pp. 2228-2235 ◽  
Author(s):  
Shengchao Hou ◽  
Yan Lv ◽  
Xueyan Wu ◽  
Jixi Guo ◽  
Qingqing Sun ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Conversion Efficiency ◽  
Low Cost ◽  
Thermal Conversion ◽  
Absorption Capacity ◽  
Solar Thermal ◽  
Graphene Aerogels ◽  
Solvent Absorption ◽  
Modified Graphene ◽  
High Absorption

Ultralight, hydrophobic, highly compressible and low-cost coal oxide-modified graphene aerogels exhibit high absorption capacity and high solar thermal conversion efficiency.

Fabrication of a porous chitosan/poly-(γ-glutamic acid) hydrogel with a high absorption capacity by electrostatic contacts

2020 ◽  
Vol 159 ◽  
pp. 986-994 ◽  
Author(s):  
Guangjun Nie ◽  
Kangjin Hong ◽  
Erwei Zhang ◽  
Ning Liu ◽  
Mengmeng Wang ◽  
...  
Keyword(s):  
Glutamic Acid ◽  
Absorption Capacity ◽  
Porous Chitosan ◽  
High Absorption

scholarly journals Macroporous Oil-Sorbents with a High Absorption Capacity and High-Temperature Tolerance Prepared through Cryo-Polymerization

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1620 ◽  
Author(s):  
Haleem ◽  
Wang ◽  
Li ◽  
Hu ◽  
Li ◽  
...  
Keyword(s):  
High Temperature ◽  
Organic Solvents ◽  
Thermo Gravimetric Analysis ◽  
Temperature Tolerance ◽  
Absorption Capacity ◽  
Synthesis Process ◽  
Gravimetric Analysis ◽  
High Temperature Tolerance ◽  
Oil Sorbents ◽  
High Absorption

The facile preparation and admirable performance of macro-porous poly(lauryl acrylate)-based oil-sorbents for organic solvents and oils are reported in this manuscript. Cryo-polymerizations of lauryl acrylate (LA) with ethylene glycol dimethacrylate (EGDMA) as the cross-linker were carried out at temperatures below the freezing point of the polymerization mixture. The polymerization medium and pore-forming agent was 1,4-dioxane. The influences of the total monomer concentration, EGDMA content and cryo-polymerization temperature on the structure of the obtained P(LA-co-EGDMA) cryogels were investigated with the techniques of Fourier transform infrared spectroscopy, scanning electron microscopy, contact angle measurement and thermo-gravimetric analysis. Through the modulation of the crosslinking density and porosity of these cryogels, the P(LA-co-EGDMA) oil-sorbents demonstrated a high absorption capacity for organic solvents and oils, recyclability and high-temperature tolerance. The absorption capacity reached 20–21 and 16–17 g/g for toluene and gasoline oil, respectively. Those fabricated sorbents survived high temperatures up to 150 °C without any change in absorption capacity as well as porosity. Considering the convenient synthesis process and absorption performance, the present work offers a remarkable opportunity to bring polymer cryogels to practical application in waste oil clean-up.

scholarly journals An Active Absorbent for Cleanup of High-Concentration Strong Acid and Base Solutions

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3389
Author(s):  
Nara Han ◽  
Sol Park ◽  
Byung Kwon Kaang ◽  
Wooree Jang ◽  
Hye Young Koo ◽  
...  
Keyword(s):  
Surface Morphology ◽  
Strong Acid ◽  
Absorption Capacity ◽  
Dust Particles ◽  
High Concentration ◽  
Strong Base ◽  
Base Solution ◽  
Acid And Base ◽  
Drop Tests ◽  
High Absorption

There is significant interest in developing novel absorbents for hazardous material cleanup. Iron oxide-coated melamine formaldehyde sponge (MFS/IO) absorbents with various IO layer thicknesses were synthesized. Various other absorbents were also synthesized and compared to evaluate the absorption capability of the MFS/IO absorbents for strong acid (15%, v/v) and base (50%, m/m) solutions. Specifically, absorbent and solution drop tests, dust tests, and droplet fragment tests were performed. Among the various absorbents, MFS/IO absorbents possessing a needlelike surface morphology showed several unique characteristics not observed in other absorbents. The MFS/IO absorbents naturally absorbed a strong base solution (absorption time: 0.71–0.5 s, absorption capacity: 10,000–34,000%) without an additional external force and immediately absorbed a strong acid solution (0.31–0.43 s, 9830–10,810%) without absorption delay/overflow during absorbent and solution drop tests, respectively. The MFS/IO absorbents were also demonstrated to be ideal absorbents that generated fewer dust particles (semiclass 1 (ISO 3) level of 280 piece/L) than the level of a clean room (class 100). Furthermore, the MFS/IO absorbents were able to prevent the formation of droplet fragments and solution overflow during the solution drop test due to their unique surface morphology and extremely high absorption speed/capacity, respectively.

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