scholarly journals Exploring the conservativeness of deuterated water as the artificial tracer for hydrogeological tests

Author(s):  
Xiaohua Huang ◽  
Guodong Liu ◽  
Jie Mei

Deuterated water has been applied in hydrogeological tracer tests in recent years. However, there is a contradiction about the conservativeness of artificial deuterium (D/2H). In this study, what circumstances HDO behaved truly conservatively were investigated through laboratory-scale experiments via comparing the widely used tracer chloride (Cl-). And reasons for the non-conservativeness of HDO were discussed comprehensively for the first time. In addition, the advection-dispersion equation (ADE) and dual-domain mass transfer (DDMT) equation were employed to describe the breakthrough curves (BTCs) of tracers. HDO behaved conservatively when it transported in the porous media with high permeability (approximately K > 1m/d), and ADE could describe BTCs successfully. While hysteresis effect of HDO expressed in the media with low permeability. And the lower the permeability of the porous media, the stronger the hysteresis effect. DDMT was more suitable for demonstrating BTCs in low permeability media. Hydrogen bonds between HDO and H2O, the isotopic exchange effect, and the dual-domain model of the media all could lead to the hysteresis effect. The retardation factor (R = 1.712) was used to describe transporting behaviors of HDO in clay firstly. And the threshold hydraulic conductivity (Kcr) and the proportion of immobile regions of HDO were greater than that of Cl-, while dispersion coefficients of HDO were smaller. These could provide further considerations for using deuterium in hydrogeological tracer tests.

Author(s):  
Gennadiy Sandrakov ◽  
Andrii Hulianytskyi ◽  
Vladimir Semenov

Modeling of dynamic processes of diffusion and filtration of liquids in porous media are discussed. The media are formed by a large number of blocks with low permeability, and separated by a connected system of faults with high permeability. The modeling is based on solving initial boundary value problems for parabolic equations of diffusion and filtration in porous media. The structure of the media leads to the dependence of the equations on a small parameter. Assertions on the solvability and regularity of such problems and the corresponding homogenized convolution problems are considered. The statements are actual for the numerical solution of this problem with guaranteed accuracy that is necessary to model the considered processes.


Ground Water ◽  
2012 ◽  
Vol 50 (6) ◽  
pp. 927-934 ◽  
Author(s):  
Yuan Liu ◽  
Peter K. Kitanidis

2021 ◽  
Vol 11 (10) ◽  
pp. 4411
Author(s):  
Yulong Yang ◽  
Tongjing Liu ◽  
Yanyue Li ◽  
Yuqi Li ◽  
Zhenjiang You ◽  
...  

During micro-scale tracer flow in porous media, the permeability and fluid velocity significantly affect the fluid dispersion properties of the media. However, the relationships between the dispersion coefficient, permeability, and fluid velocity in core samples are still not clearly understood. Two sets of experiments were designed to study the effects of tracer fluid flow velocity and porous medium permeability on the dispersion phenomenon in a core environment, using natural and sand-filled cores, respectively. From experimental data-fitting by a mathematical model, the relationship between the dispersion coefficient, flow velocity, and permeability was identified, allowing the analysis of the underlying mechanism behind this phenomenon. The results show that a higher volumetric flow rate and lower permeability cause a delay in the tracer breakthrough time and an increase in the dispersion coefficient. The core experimental results show that the dispersion coefficient is negatively correlated with the permeability and positively correlated with the superficial velocity. The corresponding regression equations indicate linear relations between the dispersion coefficient, core permeability, and fluid velocity, resulting from the micron scale of grain diameters in cores. The combination of high velocity and low permeability yields a large dispersion coefficient. The effects of latitudinal dispersion in porous media cannot be ignored in low-permeability cores or formations. These findings can help to improve the understanding of tracer flow in porous media, the design of injection parameters, and the interpretation of tracer concentration distribution in inter-well tracer tests.


2013 ◽  
Vol 136 (1) ◽  
Author(s):  
Navid Shahangian ◽  
Damon Honnery ◽  
Jamil Ghojel

Interest is growing in the benefits of homogeneous charge compression ignition engines. In this paper, we investigate a novel approach to the development of a homogenous charge-like environment through the use of porous media. The primary purpose of the media is to enhance the spread as well as the evaporation process of the high pressure fuel spray to achieve charge homogenization. In this paper, we show through high speed visualizations of both cold and hot spray events, how porous media interactions can give rise to greater fuel air mixing and what role system pressure and temperature plays in further enhancing this process.


2021 ◽  
Author(s):  
Imane Guetni ◽  
Claire Marlière ◽  
David Rousseau

Abstract Application of chemical enhanced oil recovery (C-EOR) processes to low-permeability sandstone reservoirs (in the 10-100 mD range) can be very challenging as strong retention and difficult in-depth propagation of polymer and surfactant can occur. Transport properties of C-EOR chemicals are particularly related to porous media mineralogy (clay content). The present experimental study aimed at identifying base mechanisms and providing general recommendations to design economically viable C-EOR injection strategies in low permeability clayey reservoirs. Polymer and surfactant injection corefloods were conducted using granular packs (quartz and clay mixtures) with similar petrophysical characteristics (permeability 70-130 mD) but having various mineralogical compositions (pure quartz sand, sand with 8 wt-% kaolinite and sand with 8 wt-% smectite). The granular packs were carefully characterized in terms of structure (SEM) and specific surface area (BET). The main observables from the coreflood tests were the resistance and residual resistance factors generated during the chemical injections, the irreversible polymer retention and the surfactant retention in various injection scenarios (polymer alone, surfactant alone, polymer and surfactant). A first, the impact of the clay contents on the retention of polymer and surfactant considered independently was examined. Coreflood results have shown that retention per unit mass of rock strongly increased in presence of both kaolinite and smectite, but not in the same way for both chemicals. For polymer, retention was about twice higher with kaolinite than with smectite, despite the fact that the measured specific surface area of the kaolinite was about 5 times less than that of the smectite. Conversely, for surfactant, retention was much higher with smectite than with kaolinite. Secondly, the impact of the presence of surfactant on the polymer in-depth propagation and retention was investigated in pure quartz and kaolinite-bearing porous media. In both mineralogies, the resistance factor quickly stabilized when polymer was injected alone whereas injection of larger solution volumes was required to reach stabilization when surfactant was present. In pure quartz, polymer retention was shown, surprisingly, to be one order of magnitude higher in presence of surfactant whereas with kaolinite, surfactant did not impact polymer retention. The results can be interpreted by considering adsorption-governed retention. The mechanistic pictures being that (a) large polymer macromolecules are not able to penetrate the porosity of smectite aggregates, whereas surfactant molecules can, and (b) that surfactant and polymer mixed adsorbed layers can be formed on surfaces with limited affinity for polymer. Overall, this study shows that C-EOR can be applied in low permeability reservoirs but that successful injection strategies will strongly depend on mineralogy.


2019 ◽  
Author(s):  
Imane Guetni ◽  
Claire Marliere ◽  
David Rousseau ◽  
Isabelle Bihannic ◽  
Manuel Pelletier ◽  
...  

Symmetry ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 364 ◽  
Author(s):  
Huimin Wang ◽  
Jianguo Wang ◽  
Xiaolin Wang ◽  
Andrew Chan

Low-permeability porous medium usually has asymmetric distributions of pore sizes and pore-throat tortuosity, thus has a non-linear flow behavior with an initial pressure gradient observed in experiments. A threshold pressure gradient (TPG) has been proposed as a crucial parameter to describe this non-linear flow behavior. However, the determination of this TPG is still unclear. This study provides multi-scale insights on the TPG in low-permeability porous media. First, a semi-empirical formula of TPG was proposed based on a macroscopic relationship with permeability, water saturation, and pore pressure, and verified by three sets of experimental data. Second, a fractal model of capillary tubes was developed to link this TPG formula with structural parameters of porous media (pore-size distribution fractal dimension and tortuosity fractal dimension), residual water saturation, and capillary pressure. The effect of pore structure complexity on the TPG is explicitly derived. It is found that the effects of water saturation and pore pressure on the TPG follow an exponential function and the TPG is a linear function of yield stress. These effects are also spatially asymmetric. Complex pore structures significantly affect the TPG only in the range of low porosity, but water saturation and yield stress have effects on a wider range of porosity. These results are meaningful to the understanding of non-linear flow mechanism in low-permeability reservoirs.


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