Cure Process Impact on Cure Time and Properties of Low Temperature Polyimide for 3D Stacking Applications

Author(s):  
Zia Karim ◽  
Kenneth Sautter ◽  
Kay Song ◽  
Charudatta Galande ◽  
Kaushal Singh
2012 ◽  
Vol 2012 (DPC) ◽  
pp. 1-24
Author(s):  
Michael Gallagher ◽  
Jong-Uk Kim ◽  
Eric Huenger ◽  
Kai Zoschke ◽  
Christina Lopper ◽  
...  

3D stacking, one of the 3D integration technologies using through silicon vias (TSVs), is considered as a desirable 3D solution due to its cost effectiveness and matured technical background. For successful 3D stacking, precisely controlled bonding of the two substrates is necessary, so that various methods and materials have been developed over the last decade. Wafer bonding using polymeric adhesives has advantages. Surface roughness, which is critical in direct bonding and metal-to-metal bonding, is not a significant issue, as the organic adhesive can smooth out the unevenness during bonding process. Moreover, bonding of good quality can be obtained using relatively low bonding pressure and low bonding temperature. Benzocyclobutene (BCB) polymers have been commonly used as bonding adhesives due to their relatively low curing temperature (~250 °C), very low water uptake (<0.2%), excellent planarizing capability, and good affinity to Cu metal lines. In this study, we present wafer bonding with BCB at various conditions. In particular, bonding experiments are performed at low temperature range (180 °C ~ 210 °C), which results in partially cured state. In order to examine the effectiveness of the low temperature process, the mechanical (adhesion) strength and dimensional changes are measured after bonding, and compared with the values of the fully cured state. Two different BCB polymers, dry-etch type and photo type, are examined. Dry etch BCB is proper for full-area bonding, as it has low degree of cure and therefore less viscosity. Photo-BCB has advantages when a pattern (frame or via open) is to be structured on the film, since it is photoimageable (negative tone), and its moderate viscosity enables the film to sustain the patterns during the wafer bonding process. The effect of edge beads at the wafer rim area and the soft cure (before bonding) conditions on the bonding quality are also studied. Alan/Rey ok move from Flip Chip and Wafer Level Packaging 1-6-12.


1949 ◽  
Vol 22 (3) ◽  
pp. 735-755
Author(s):  
D. W. Young ◽  
D. J. Buckley ◽  
R. G. Newberg ◽  
L. B. Turner

Abstract 1. 1,3-Butadiene-acrylonitrile copolymers were mill-mixed with benzothiazoyl disulfide, sulfur, litharge, and vinyl resins, such as Vinylite (VYNW), and Saran and cured to compounds with good tensile strength, modulus, hardness, solvent resistance, and blocking temperature. 2. Results show that higher acrylonitrile type of copolymers give cured Vinylite-rubber blends with higher tensile strength, higher 100 per cent modulus, and greater ultimate elongation to break than low acrylonitrile copolymers. 3. The low temperature properties of the cured blends improve as the acrylonitrile content of the synthetic rubber is reduced. 4. An effective cure at 287° F is obtained in 15 to 30 minutes by using 2 parts of accelerator and 2 parts of sulfur per hundred parts of 1,3-butadieneacrylonitrile type copolymer-Vinylite blends. Added amounts of sulfur, and accelerator did not improve the properties or decrease the cure time at 287° F. 5. Some of the cured blends studied are free of tackiness at temperatures as high as 230° F. 6. Some stabilizers for vinyls tested as well as sodium acetate can be used to activate sulfur cures in 1,3-butadiene-acrylonitrile copolymer-Vinylite blends to formulate light-colored transparent products.


2013 ◽  
Vol 58 (9) ◽  
pp. 17-28 ◽  
Author(s):  
L. Di Cioccio ◽  
I. Radu ◽  
G. Gaudin ◽  
T. Lacave ◽  
F. Baudin ◽  
...  

Author(s):  
Paing Myo ◽  
Ser Choong Chong ◽  
Ling Xie ◽  
Soon Wee Ho ◽  
Wai Hong See Toh ◽  
...  
Keyword(s):  

1999 ◽  
Vol 122 (1) ◽  
pp. 124-131 ◽  
Author(s):  
B. Ramakrishnan ◽  
L. Zhu ◽  
R. Pitchumani

Curing of fiber-resin mixtures is often the critical and productivity controlling step in the fabrication of thermosetting-matrix composites. The long processing times (and costs) have remained the fundamental impediment to widespread commercialization of composites. Shortening the cure cycle time, while ensuring a complete and uniform cure in the product, is imperative for realizing the goal of affordable materials processing, and forms the focus of this investigation. Toward addressing the affordability challenge, this paper explores the use of conductive carbon mats embedded inside the composite as a means of providing internal volumetric resistance heating during the cure process. The supplemental heating results in temperature and cure uniformity through the cross section, as well as speeds up the cure process. In the context of application to resin transfer molding, systematic experimental and theoretical studies on various resistive heating configurations are presented. Optimum processing strategies are derived based on the cure time and microstructural product quality considerations. [S1087-1357(00)01101-1]


Author(s):  
Su-Seng Pang ◽  
Liangfeng Sun ◽  
Arthur M. Sterling ◽  
Randy A. Jones

Preliminary study of a composite pipe Tee-joint using heat coupling technology was conducted in this paper. The cutting process of the pipes for the Tee-joint was developed. Because the cutting edges of the pipes were coarse, it is necessary to smooth them. Both epoxy resin and prepreg were applied to the joined areas of the pipes. Shrink tape was also applied to the outside of the prepreg to add pressure and compression force. An optimized cure cycle for the epoxy prepreg used as the bonding materials was determined from the thermal cure analysis. The cure process of the joined pipes by epoxy prepreg was conducted in a specially designed oven. The total cure time was about 138 minutes. Several factors, including the thickness and length of the prepreg applied and the adhesive applied to the joints, have been considered in designing Teejoints. The hydrostatic pressure test results showed that the thickness of the wrapped epoxy prepreg had a very important effect on the quality of the joined pipes in terms of pressure.


Author(s):  
Fumihiro Inoue ◽  
Kimoon Park ◽  
Jaber Derakhshandeh ◽  
Bongyoung Yoo
Keyword(s):  

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