A thin-section holder for selected area X-ray diffraction.

1986 ◽  
Vol 13 (4) ◽  
pp. 187-194
Author(s):  
Yasuo KANAZAWA ◽  
Hiromoto NAKAZAWA
Keyword(s):  
X Ray ◽  
1987 ◽  
Vol 31 ◽  
pp. 77-85
Author(s):  
Thomas L. Nunes ◽  
Charles C. Goldsmith

AbstractThe semiconductor industry is continually striving'for smaller, denser devices. Microdiffractometry is an analytical technique which endeavors to apply x-ray diffraction techniques for measuring strain and phase information to areas approaching 50 micrometers diameter or less.This study extends the work of Goldsmith and Walker in the measurement of strain using the lattice distortion or sin2(ψ) plot method.The systematic errors arising from both sample and beam displacement relative to the center of rotation of the cample ie examined. A relationship is derived which predicts the influence of these displacements upon the slope of a stress plot. The predictions are compared to experiment.The influence of random errors arising from particle size and photon counting statistics will also be discussed. Guidelines will be presented which will minimize both systematic and random errors.


1972 ◽  
Vol 2 (02) ◽  
pp. 244-252 ◽  
Author(s):  
John Chappell ◽  
Henry A. Polach

The issue of sea level during the last interstadial revolves largely around the problem of achieving reliable 14C dates for shell carbonate from Late Pleistocene shallow marine and littoral deposits. A set of 27 samples were collected from Late Pleistocene reefs in New Guinea, and measurements made of 13C, 14C, plus the degree of recrystallisation (determined by X-ray diffraction). The original fibrous aragonite structure of the samples (corals and clams) is seen in thin section to recrystallise in two quite different modes. The carbon isotope results strongly suggest that one mode, the sparry calcite recrystallisation, represents an open geochemical system which allows contamination by more recent 14C, while the subtle coarsening mode of recrystallisation represents a closed system, often yielding reliable results. The reliability of the latter can be validated if a similarly recrystallised sample, known to be outside the range of 14C dating, shows a background 14C count.


1977 ◽  
Vol 41 (319) ◽  
pp. 313-322
Author(s):  
P. G. Moeskops

SummaryInvestigation of serpentine minerals from metaserpentinized ultramafic rocks in two Archaean green-stone belts, east of Kalgoorlie, has indicated that antigorite, exhibiting a very wide range of textures in thin section, is the dominant serpentine species; however, it is locally accompanied by relict lizardite. Chrysotile occurs both in late tectonic veins and as a present-day weathering product of relict olivine. Analytical data and structural formulae on seven serpentines, characterized independently by X-ray diffraction analysis, support the chemical differences between antigorite and chrysotile postulated by earlier workers.


1983 ◽  
Vol 27 ◽  
pp. 229-238
Author(s):  
C.C. Goldsmith ◽  
G.A. Walker

AbstractThe trend towards smaller devices and packages in the semiconductor industry makes it increasingly important and increasingly difficult to obtain useful X-ray diffraction information from the small areas employed. This study covers applications of a Rigaku micro-diffractometer to measure strain and obtain phase information from areas less than 100μm in diameter. Examples of residual stress mappings between electrical vias only 100μm apart and phase determination on a single electrical via 120μm diameter will be shown.


2012 ◽  
Vol 15 (3) ◽  
pp. 157-163 ◽  
Author(s):  
J.L. Contreras ◽  
M.A. Ortiz ◽  
G.A. Fuentes ◽  
M. Ortega ◽  
R. Luna ◽  
...  

The effect of WOx over Ni-hydrotalcite catalysts to produce H2 by ethanol steam reforming was studied. The catalysts were characterized by N2 physisorption (BET area), X-ray diffraction, Infrared and UV-vis spectroscopies. The W concentration ranged from 0.5 to 3 wt%. As W concentration increased, the intensity of XRD reflections of the Ni catalysts decreased. The porous structure of the materials consisted of parallel layers with a monomodal mesoporous distribution. The surface groups detected by IR were: -OH, Al-OH, Mg-OH, W=O and CO32-. UV-vis results suggested that Ni2+ ions were substituted by W ions. The catalytic evaluations were made in a fixed bed reactor using a water/ethanol mol ratio of 4 at 450°C. Catalysts with low loadings of W (0.5 and 1%) showed the highest H2 production and stability. W promoted the conversion of ethanol towards hydrogen in the case of the Ni-hydrotalcite catalysts. The reaction products were; H2, CO2, CH3CHO, CH4 and C2H4. The catalysts did not produce CO.


2002 ◽  
Vol 41 (Part 2, No. 9A/B) ◽  
pp. L1013-L1015 ◽  
Author(s):  
Shigeru Kimura ◽  
Yasushi Kagoshima ◽  
Kenji Kobayashi ◽  
Koichi Izumi ◽  
Yasutaka Sakata ◽  
...  

Clay Minerals ◽  
1982 ◽  
Vol 17 (2) ◽  
pp. 259-262 ◽  
Author(s):  
A. Meunier ◽  
B. Velde

Precise identification of clay minerals found in granular rocks has always posed a great problem to the clay petrographer. Even if it is possible to locate the position of authigenic clay mineral formation in a thin section, subsequent identification of this same material by X-ray diffractometry is usually very difficult. Attempts have been made using selected-area radiation of thin sections (Pawluck & Dumanski, 1973; Wicks & Zussman, 1975; Wilson & Clark, 1978) but the area analysed remains relatively large, i.e. of the order of several mm2. The other solution is micro-picking of material from a thin section and subsequent identification by Debye-Scherrer camera methods (Wallace, 1955; Rickwood, 1977). This method, however, does not allow preferred orientation, and thus precise identification, of many clay species. The ideal method is to combine micro-picking from thin sections from areas of several hundreds of square microns with an oriented sample preparation, which can then be treated in the traditional way (glycolation, heating, etc.) for characterization by X-ray diffractometry.


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