scholarly journals Plotting of the solubility isotherm for the NH4NO3 + NaVO3 + H2O system

2008 ◽  
Vol 10 (4) ◽  
pp. 11-14 ◽  
Author(s):  
Mieczysław Trypuć ◽  
Sebastian Drużyński ◽  
Krzysztof Mazurek

Plotting of the solubility isotherm for the NH4NO3 + NaVO3 + H2O system The equilibrium research was performed for the NH4NO3 + NaVO3 + NH4VO3 + NaNO3 + H2O system at 293 and 303 K. The location of the P1 and P2 triple points was determined on the equilibrium plots with the planar projection according to Jänecke method. The maximum yield of the conversion of ammonium nitrate(V) to ammonium vanadate(V) was calculated at P1 points. The results constitute the basis to design further equilibrium experiments aimed to precisely determine the lines separating the areas of the co-crystallization of salts in the investigated system on the equilibrium plots in the oblique projection on a plane according to Jänecke method.

2021 ◽  
pp. 20-24
Author(s):  
Artem Vladimirovich Ermilov ◽  
Roman Aleksandrovich Kamenev ◽  
Anatoly Petrovich Solodovnikov ◽  
Vladimir Nikolaevich Maksimchuk

The article presents an analysis of the determination of the effectiveness of mineral and organic fertilizers on the yield of winter wheat grain. The studies were carried out in 2017–2020 in the Rostov region on the southern chernozem. The object of research was the Doneko winter wheat variety. The predecessor is corn for grain. Ammonium nitrate, ANP fertilizer (16-16-16) and urea were used as mineral fertilizers, which were applied in the fertilization system of winter wheat and acted as a background option in the experimental scheme. ANP fertilizer (16-16-16) was introduced when sowing winter wheat, ammonium nitrate - scattered over thawed-frozen soil and carbamide in the heading phase by foliar method. Organomineral fertilizers were represented by the following types: Ruther, Leili 2000, Siamino Pro, Gumiful Pro, Soft Guard and Double Wine MKR (monocaliphosphate) produced by Biokepharm (Switzerland). The raw material for the production of organomineral fertilizers was the algae of the warm seas Laminaria. In the field experiment, the options for the joint application of foliar application and pre-sowing seed treatment with organomineral fertilizers were also studied. The control was the option without mineral fertilizers and the option with the background of the use of mineral fertilizers (farm fertilization system). It was found out that the use of organic fertilizers Ruter (0.5 or 0.25 l / t) and Leyli (0.25 l / t) for seed treatment before sowing, the use of Soft Guard (0.2 l / ha) and Gumiful Pro ( 0.2 l / ha) in the spring tillering phase and in the flag leaf phase against the background of sowing nitroammophoska at a dose of N32P32K32, random fertilizing on thawed-frozen soil with ammonium nitrate at a dose of N40 and the use of carbamide in the heading phase at a dose of N20 increased grain yield on average for 2018–2020 compared with the control (fertilization system of the farm) by 0.73 t / ha, or 23.0%. The maximum yield increase from the root-forming agent Ruther, used for pre-sowing seed treatment, reached 0.36 t / g, or 11.3%.  


1968 ◽  
Vol 71 (2) ◽  
pp. 195-203 ◽  
Author(s):  
D. R. Hodgson ◽  
A. P. Draycott

SUMMARYField experiments with Italian ryegrass cut four times a year compared aqueous ammonia with ammonium sulphate and with a mixture of ammonium nitrate and urea (equal parts by weight). In 1963 four rates of nitrogen, 224, 448, 672 and 896 lb/acre, were applied as single and split dressings of injected aqueous ammonia, as solid ammonium sulphate and as injected solution of ammonium sulphate. There was little difference in total dry-matter yield between a single injection of aqueous ammonia and the split dressing of solid. Injecting ammonium sulphate solution eliminated scorch caused by single applications of solid supplying 448 lb N/acre or more and gave significantly greater dry-matter yields. A single application of 448 lb N/acre provided enough nitrogen to sustain the response of the grass to the end of the season.In 1964 a single injection of aqueous ammonia was compared with ammonium nitrate/urea applied as solid or solution at 280, 560 and 840 lb N/acre. There was no difference in total dry-matter yield between aqueous ammonia and ammonium nitrate/urea at rates of 560 and 840 lb/acre. At 280 lb/acre a split dressing of solid produced most dry matter. More than 280 lb N/acre was required, therefore, as a single application in spring to last the whole season, but this rate of nitrogen applied as a split dressing was almost sufficient to give maximum yield.In both experiments the seasonal distribution of dry matter was similar for single and split applications except in 1963 when large single injections of ammonium sulphate produced greater yields at the third cut than the split applications. The percentage of nitrogen recovered in the harvested grass decreased as nitrogen rate was increased and was greater from single than split applications. Recovery of nitrogen from aqueous ammonia was less efficient from four injections than one, and was greater in 1964 than 1963 due to better penetration of the sward by injector tines. Least nitrogen was recovered from surface-applied solutions of ammonium nitrate/urea. Regressions of dry-matter yield on nitrogen yield showed that single injections of aqueous ammonia were as efficient as other fertilizers tested.


2012 ◽  
Vol 18 (1) ◽  
Author(s):  
A. B. Kovács ◽  
R. Kremper ◽  
A. Jakab ◽  
A. Szabó

A greenhouse pot experiment was conducted to investigate the effects of ammonium-nitrate, food waste compost, bacterial fertilizer (EM-1) and their combinations on production and nutrient contents of carrot. The study was conducted on a calcareous chernozem and acidic sandy soils in a randomized complete block design with 8 treatments and four replications. NH4NO3 in chernozem soil increased the weight of carrot leaves only, while in sandy soil resulted in reduced yield and highly increased NO3-N content of roots. Sandy soil showed higher response of biomass production to food waste compost application than chernozem soil. The highest carotenoid content of roots was measured with compost treatment. Combined application of compost and NH4NO3 in chernozem proved to be good combination but in sandy soil have turn out to be less favourable than sole compost treatment. Bacterial fertilizer (EM-1) did not cause marked effect on the yield parameters, but caused increased phosphorus content of plant. In chernozem soil the maximum yield parameters were achieved with the combined treatment of ammonium-nitrate+compost+EM-1. In sandy soil the most favourable treatment proved to be the compost treatment. Results suggest that application of food waste compost as a nutrient source could be a promising agrochemical practice especially in soils having low organic material and low nutrient supply.


Author(s):  
Y.I. Ilchenko ◽  
◽  
O.A. Biryukova ◽  
A.V. Kucherenko ◽  
A.M. Medvedeva

The article presents the results of a three-year study of the effect of mineral fertilizers on the yield of winter wheat in the No-till system in the soil and climatic conditions of the southern zone of the Rostov region. The combined introduction of ammophos and kalimagnesia before sowing with two fertilizing with ammonium nitrate in the tillering and outlet phases of the tube helps to improve the nutritional regime of the soil and ensures maximum yield of winter wheat.


2020 ◽  
Vol 4 (2) ◽  
pp. 257-262
Author(s):  
I. I. Gasanova ◽  
M. V. Yerashova ◽  
T. M. Pedash

The influence of nitrogen top dressing on the yielding capacity and grain quality of modern varieties of soft winter wheat in the Northern Steppe were discovered. The field trial was placed on the bare fallow. The rate of application of mineral fertilizers under presowing cultivation was N30P60K30. Three varieties of winter wheat was sown: Kokhanka (SI The Institute of Grain Crops), Pylypivka and Misiia Odeska (Selection and Genetic Institute). The sowing time of the winter wheat is September 20, the sowing rate is 5 million germinable seeds per 1 ha. The following nitrogenous fertilizers were used for the top dressings: ammonium nitrate and carbamide. Ammonium nitrate was applied at the end of the spring tillering stage by means of a seeder locally (30 and 60 kg/ha of active substance) end carbamide (30 kg/ha of active substance) and a tank mixture of carbamide (30 kg/ha of active substance) and fungicide Falcon (600 ml/ha) – in the earing phase foliar. It is established that top dressing of the winter wheat crops at the end of the tillering stage locally with ammonium nitrate contributed to an increase in yield of varieties by 0,34–0,64 t/ha, moreover the maximum yield gains were for the application of fertilizers in the rate of 60 kg/ha of nitrogen. A significant increase in yielding capacity was provided by the treatment of crops in the earing stage with the tank mixture of carbamide and fungicide. Nitrogen top dressings, as a rule, had a positive effect on both the physical indicators of the winter wheat grain (grain weight per hectoliter and vitreousness) and biochemical indicators (protein content, gluten content, sedimentation rate). It is found, that the varieties Kokhanka and Pylypivka in all variants of the experiment formed the grain weight per hectoliter over 800 g/l. In these varieties the content of protein and gluten were higher. In the strong grain quality varieties Misiia Odeska and Pylypivka in comparison with the variety Kokhanka (valuable) were noted higher values of sedimentation. According to the set of indicators, food grain of the second class was obtained in Kokhanka variety in the variant where the tank mixture of carbamide with fungicide was used for crop treatment, and in Pylypivka variety – for top dressings of crops at the end of tillering stage locally (N30–60) or N30 foliar. Keywords: winter wheat, variety, bare fallow, nitrogen fertilization, yielding capacity, protein, gluten.


Author(s):  
H.-J. Kleebe ◽  
J.S. Vetrano ◽  
J. Bruley ◽  
M. Rühle

It is expected that silicon nitride based ceramics will be used as high-temperature structural components. Though much progress has been made in both processing techniques and microstructural control, the mechanical properties required have not yet been achieved. It is thought that the high-temperature mechanical properties of Si3N4 are limited largely by the secondary glassy phases present at triple points. These are due to various oxide additives used to promote liquid-phase sintering. Therefore, many attempts have been performed to crystallize these second phase glassy pockets in order to improve high temperature properties. In addition to the glassy or crystallized second phases at triple points a thin amorphous film exists at two-grain junctions. This thin film is found even in silicon nitride formed by hot isostatic pressing (HIPing) without additives. It has been proposed by Clarke that an amorphous film can exist at two-grain junctions with an equilibrium thickness.


1960 ◽  
Vol 04 (02) ◽  
pp. 253-260 ◽  
Author(s):  
Franco Gobbi

SummaryThe fractionation properties of human Factor VIII (antihaemophilic factor, AHF, antihaemophilic globulin) have been studied using a plasma of congenital afibrinogenaemia as a starting material.From a fibrinogen-free plasma, Factor VIII does not precipitate with ethanol at a final concentration of 8%; on the contrary the maximum yield is reached at an ethanol concentration of 25%.With a precipitation method carried out by a one to ten dilution of plasma with distilled water and acidification by N/10 hydrochloric acid to a pFI 5.2, Factor VIII does not precipitate with the euglobulin fraction; when normal plasma is used, such a precipitation is almost complete.With the salting-out fractionation method by ammonium sulphate, Factor VIII precipitates at a concentration between 25 and 33% of saturation either from fibrinogen-free and from normal human plasma.A non-specific thromboplastic activity appears in the fractions prepared by every method. This activity, which is probably due to the activation of seric accelerators, is easily removed by Al(OH)s adsorption. Thus, in order to insure the specificity of Factor VIII assays, the preliminary adsorption of the fractions is indispensable before testing their antihaemophilic activity.Fibrinogen and Factor VIII have different and definite precipitation patterns. When these two factors are associated the fractionation properties of AHF appear quite modified, showing a close similarity to those of fibrinogen. This fact can explain the technical difficulties encountered in the attempt to purify the antihaemophilic factor, and the lack of reproducible procedures for removing fibrinogen without affecting Factor VII.


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