scholarly journals Geochemistry, petrology and tectonomagmatic significance of basaltic rocks from the ophiolite mélange at the NW External-Internal Dinarides junction (Croatia)

2010 ◽  
Vol 61 (4) ◽  
pp. 273-292 ◽  
Author(s):  
Damir Slovenec ◽  
Boško Lugović ◽  
Irena Vlahović

Geochemistry, petrology and tectonomagmatic significance of basaltic rocks from the ophiolite mélange at the NW External-Internal Dinarides junction (Croatia)At the NW inflexion of the Sava-Vardar Suture Zone ophiolite mélanges, known as the Kalnik Unit, form the surface of the slopes of several Pannonian inselbergs in the SW Zagorje-Mid-Transdanubian Zone. The Mt Samoborska Gora ophiolite mélange, thought to be a part of the Kalnik Unit, forms a separate sector obducted directly onto Dinaric Triassic carbonate sediments. Basaltic rocks, the only magmatic rocks incorporated in the mélange, include Middle-Triassic (Illyrian-Fassanian) alkali within-plate basalts and Middle Jurassic (uppermost Bathonian-Lower Callovian) tholeiitic basalts. The latter sporadically constitute composite olistoliths, and are geochemically divided into N-MORB-like (high-Ti basalts) and transitional MORB/IAT (medium-Ti basalts). These geochemically different rocks suggest crystallization at various tectonomagmatic settings, which is also indicated by the rock paragenesis and host clinopyroxene compositions. Alkali basalts reflect melts derived from an OIB-type enriched mantle source [Ti/V= 62.2-82.4; (La/Lu)cn= 6.4-12.8] with Nd-Sr isotope signatures close resembling the Bulk Earth [εNd(T=235 Ma)= + 1.6 to + 2.5]. They are recognized as preophiolite continental rift basin volcanic rocks that closely predate the opening of the Repno oceanic domain (ROD) of the Meliata-Maliac ocean system. The high-Ti and medium-Ti basalts from composite blocks derived from a similar depleted mantle source (εNd(T=165 Ma) = + 6.01 vs. + 6.35) succesively metasomatized by expulsion of fluids from a subducting slab leading to a more pronounced subduction signature in the latter [Ti/V=31.6-44.8 and (Nb/La)n=0.67-0.90 vs. Ti/V=21.5-33.9 and (Nb/La)n=0.32-0.49]. These composite blocks indicate crust formation in an extensional basin spreading over the still active subducting ridge. The majority of high-Ti basalts may represent the fragments of older crust formed at a spreading ridge and incorporated in the mélange of the accretionary wedge formed in the proto-arc-fore-arc region. The Mt Samoborska Gora ophiolite mélange represents the trailing edge of the Kalnik Unit as a discrete sector that records the shortest stage of tectonomagmatic evolution related to intraoceanic subduction in the ROD.

Geology ◽  
2020 ◽  
Author(s):  
Ingo Grevemeyer ◽  
Shuichi Kodaira ◽  
Gou Fujie ◽  
Narumi Takahashi

Subduction zones may develop submarine spreading centers that occur on the overriding plate behind the volcanic arc. In these back-arc settings, the subducting slab controls the pattern of mantle advection and may entrain hydrous melts from the volcanic arc or slab into the melting region of the spreading ridge. We recorded seismic data across the Western Mariana Ridge (WMR, northwestern Pacific Ocean), a remnant island arc with back-arc basins on either side. Its margins and both basins show distinctly different crustal structure. Crust to the west of the WMR, in the Parece Vela Basin, is 4–5 km thick, and the lower crust indicates seismic P-wave velocities of 6.5–6.8 km/s. To the east of the WMR, in the Mariana Trough Basin, the crust is ~7 km thick, and the lower crust supports seismic velocities of 7.2–7.4 km/s. This structural diversity is corroborated by seismic data from other back-arc basins, arguing that a chemically diverse and heterogeneous mantle, which may differ from a normal mid-ocean-ridge–type mantle source, controls the amount of melting in back-arc basins. Mantle heterogeneity might not be solely controlled by entrainment of hydrous melt, but also by cold or depleted mantle invading the back-arc while a subduction zone reconfigures. Crust formed in back-arc basins may therefore differ in thickness and velocity structure from normal oceanic crust.


Lithosphere ◽  
2020 ◽  
Vol 2020 (1) ◽  
pp. 1-22
Author(s):  
Jialin Wang ◽  
Chaodong Wu ◽  
Zhuang Li ◽  
Tianqi Zhou ◽  
Yanxi Zhou ◽  
...  

Abstract In this paper, we present new petrological, zircon U–Pb–Hf isotopic, bulk-rock geochemical, and Sr–Nd isotopic data for the rocks from the Pennsylvanian Liushugou and Qijiagou Formations, Bogda Mountains (BMs), northwest China. The new data help in understanding the petrogenesis and geodynamic background of the two formations, further constraining the evolution of BMs during the Pennsylvanian. The eastern Liushugou Formation is composed mainly of bimodal volcanic rocks, while the western Liushugou Formation is dominated by pillow basalts with interstitial limestones, peperites, and pyroclastic rocks. The Qijiagou Formation consists principally of bioclastic limestones, peperites, and volcanic and volcaniclastic rocks with turbidites. Depositional environment analyses of the Liushugou and Qijiagou Formations reveal subaqueous volcanism and a progressively deepening shallow marine environment with times. Zircon LA-ICP-MS U–Pb dating of felsic volcanic rocks from the Liushugou Formation indicates that the subaqueous volcanism occurred at ca. 310–302 Ma, viz., the Pennsylvanian era. The basaltic rocks from the Liushugou and Qijiagou Formations are high-K calc-alkaline, enriched in light rare earth elements and large-ion lithophile elements, and depleted in high-field-strength elements (Nb, Ta, and Ti). The above characteristics, together with their depleted isotopic signature (εNdt=3.0-8.1, εHft=8.0-15.6, and ISr=0.703-0.707), suggest the derivation from a depleted mantle source metasomatized by slab-derived fluids and sediment-derived melts. Most felsic volcanic rocks of the high-K calc-alkaline to shoshonite series from the Liushugou and Qijiagou Formations show features of the A2-type granites and have similar trace and isotopic composition to the basaltic rocks, which were probably generated from the partial melting of juvenile continental crust. Combining the newly acquired data with the regional geology, we propose that the Pennsylvanian volcanic and sedimentary rocks in the BMs were formed in a series of postcollisional rift basins which were related to local strike-slip faulting. Moreover, the volcanic rocks in the east were derived from a relatively deeper mantle source (thick lithosphere) due to their smaller rifting.


2016 ◽  
Author(s):  
Cody L. MacCabe ◽  
◽  
Greg L. Melton ◽  
Richard Wendlandt

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.


2010 ◽  
Vol 58 ◽  
pp. 35-65
Author(s):  
Paul Martin Holm ◽  
L.E. Pedersen, ◽  
B Højsteen

More than 250 dykes cut the mid Proterozoic basement gneisses and granites of Bornholm. Most trend between NNW and NNE, whereas a few trend NE and NW. Field, geochemical and petrological evidence suggest that the dyke intrusions occurred as four distinct events at around 1326 Ma (Kelseaa dyke), 1220 Ma (narrow dykes), 950 Ma (Kaas and Listed dykes), and 300 Ma (NW-trending dykes), respectively. The largest dyke at Kelseaa (60 m wide) and some related dykes are primitive olivine tholeiites, one of which has N-type MORB geochemical features; all are crustally contaminated. The Kelseaa type magmas were derived at shallow depth from a fluid-enriched, relatively depleted, mantle source,but some have a component derived from mantle with residual garnet. They are suggested to have formed in a back-arc environment. The more than 200 narrow dykes are olivine tholeiites (some picritic), alkali basalts, trachybasalts, basanites and a few phonotephrites. The magmas evolved by olivine and olivine + clinopyroxene fractionation. They have trace element characteristics which can be described mainly by mixing of two components: one is a typical OIB-magma (La/Nb < 1, Zr/Nb = 4, Sr/Nd = 16) and rather shallowly derived from spinel peridotite; the other is enriched in Sr and has La/Nb = 1.0 - 1.5, Zr/Nb = 9, Sr/Nd = 30 and was derived at greater depth, probably from a pyroxenitic source. Both sources were probably recycled material in a mantle plume. A few of these dykes are much more enriched in incompatible elements and were derived from garnet peridotite by a small degree of partial melting. The Kaas and Listed dykes (20-40 m) and related dykes are evolved trachybasalts to basaltic trachyandesites. They are most likely related to the Blekinge Dalarne Dolerite Group. The few NW-trending dykes are quartz tholeiites, which were generated by large degrees of rather shallow melting of an enriched mantle source more enriched than the source of the older Bornholm dykes. The source of the NW-trending dykes was probably a very hot mantle plume.


Lithosphere ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 834-854 ◽  
Author(s):  
Yan Zhao ◽  
Wenhao Ao ◽  
Hong Zhang ◽  
Qian Wang ◽  
Mingguo Zhai ◽  
...  

Abstract Latest Paleoproterozoic (ca. 1.8–1.6 Ga) magmatic rocks outcrop in the Dunhuang terrane, represented by A-type granites and mafic (basaltic) rocks that have metamorphosed into amphibolites. The A-type granites, emplaced at ca. 1.79–1.77 Ga, are geochemically characterized by high Na2O + K2O, Fe2O3T, Zr, Nb, and Ce contents, as well as high Fe2O3T/(Fe2O3T + MgO) and Ga/Al ratios. Furthermore, they have Nb/Ta, Y/Nb, Rb/Nb, and Sc/Nb ratios of 12.10–15.56, 1.45–1.79, 3.52–6.51, and 0.11–0.19, respectively, showing affinity to A2-type granite. The A-type granites have negative εNd(t) values (−5.4 to −4.8) with Neoarchean depleted mantle (TDM2) ages (2591–2494 Ma), corresponding to coupling between εHf(t) values (−4.85 to -0.92) and TDM2 ages (2817–2556 Ma) of zircons. Therefore, the A-type granite pluton was mostly generated by partial melting of Neoarchean tonalitic to granodioritic basement rocks of the Dunhuang Complex in a postcollisional tectonic setting following a late Paleoproterozoic continent-continent collisional event. The metamafic rocks have a protolith age of 1605 ± 45 Ma and metamorphic age of 317 ± 20 Ma, indicating a Paleozoic tectonic event. The metamafic rock samples are geochemically characterized by relatively high alkali (Na2O + K2O = 4.39–4.81 wt%) contents and low Nb/Y (0.63–0.66) ratios, and they show steep rare earth element (REE) patterns with light REE enrichment and insignificant Eu anomalies and Nb-Ta, Zr-Hf, and Ti anomalies, resembling subalkaline oceanic-island basalt affinity. They have positive εNd(t) values (+0.8 to +1.8) close to the chondrite evolutionary line and variable εHf(t) values (-1.09 to +9.06) of zircons. Hence, the protolith of the metamafic rocks may have been produced by magma mixing processes between a depleted mantle source and a metasomatized lithospheric mantle source during the initial rifting stage in an extensional setting, completing the formation of the Precambrian Dunhuang Complex. Considering the ca. 1.85–1.80 Ga regional metamorphism in the Dunhuang terrane, the latest Paleoproterozoic (ca. 1.8–1.6 Ga) A2-type granitic magmatism and mafic magmatism documented the postorogenic to initial rifting processes following the global-scale late Paleoproterozoic collisional event, which is comparable with ca. 1.80–1.67 Ga postcollisional and ca. 1.60–1.53 Ga anorogenic magmatism in the North China craton, but different from that of the Tarim craton.


Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 410 ◽  
Author(s):  
Wei Wang ◽  
Fengyou Chu ◽  
Xichang Wu ◽  
Zhenggang Li ◽  
Ling Chen ◽  
...  

The nature of upper mantle is important to understand the evolution of the South China Sea (SCS); thus, we need better constrains on its mantle heterogeneity. Magma water concentration is a good indicator, but few data have been reported. However, the rarity of glass and melt inclusions and the special genesis for phenocrysts in SCS basalts present challenges to analyzing magmatic water content. Therefore, it is possible to estimate the water variations through the characteristics of partial melting and magma crystallization. We evaluated variations in Fe depletion, degree of melt fractions, and mantle source composition along the fossil spreading ridge (FSR) using SCS basalt data from published papers. We found that lava from the FSR 116.2° E, FSR 117.7° E, and non-FSR regions can be considered normal lava with normal water content; in contrast, lava from the FSR 117° E-carbonatite and 114.9–115.0° E basalts have higher water content and show evidence of strong Fe depletion during the fractional crystallization after elimination of the effects of plagioclase oversaturation. The enriched water in the 117° E-carbonatite basalts is contained in carbonated silicate melts, and that in the 114.9–115.0° E basalts results from mantle contamination with the lower continental crust. The lava from the 117° E-normal basalt has much lower water content because of the lesser influence of the Hainan plume. Therefore, there must be a mantle source compositional transition area between the southwestern and eastern sub-basins of the SCS, which have different mantle evolution histories. The mantle in the west is more affected by contamination with continental materials, while that in the east is more affected by the Hainan mantle plume.


2020 ◽  
Vol 105 (12) ◽  
pp. 1778-1801
Author(s):  
Takafumi Kimura ◽  
Kazuhito Ozawa ◽  
Takeshi Kuritani ◽  
Tsuyoshi Iizuka ◽  
Mitsuhiro Nakagawa

Abstract Ophiolite pulses, which are periods of enhanced ophiolite generation and emplacement, are thought to have a relevance to highly active superplumes (superplume model). However, the Cambrian-Ordovician pulse has two critical geological features that cannot be explained by such a superplume model: predominance of subduction-related ophiolites and scarcity of plume-related magma activities. We addressed this issue by estimating the mechanism and condition of magma generation, including mantle potential temperature (MPT), from a ~500 Ma subduction-related ophiolite, the Hayachine-Miyamori ophiolite. We developed a novel method to overcome difficulties in global MPT estimation from an arc environment by using porphyritic ultramafic dikes showing flow differentiation, which have records of the chemical composition of the primitive magma, including its water content, because of their high pressure (~0.6 GPa) intrusion and rapid solidification. The solidus conditions for the primary magmas are estimated to be ~1450 °C, ~5.3 GPa. Geochemical data of the dikes show passive upwelling of a depleted mantle source in the garnet stability field without a strong influence of slab-derived fluids. These results, combined with the extensive fluxed melting of the mantle wedge prior to the dike formation, indicate sudden changes of the melting environment, its mechanism, and the mantle source from extensive fluxed melting of the mantle wedge to decompressional melting of the sub-slab mantle, which has been most plausibly triggered by a slab breakoff. The estimated MPT of the sub-slab mantle is ~1350 °C, which is very close to that of the current upper mantle and may reflect the global value of the upper mantle at ~500 Ma if small-scale convection maintained the shallow sub-slab mantle at a steady thermal state. We, therefore, conclude that the Cambrian-Ordovician ophiolite pulse is not attributable to the high temperature of the upper mantle. Frequent occurrence of slab breakoff, which is suggested by our geochemical compilation of Cambrian-Ordovician ophiolites, and subduction termination, which is probably related to the assembly of the Gondwana supercontinent, may be responsible for the ophiolite pulse.


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