scholarly journals Milk Thistle Leaves Aqueous Extract as a New Corrosion Inhibitor for Aluminum Alloys in Alkaline Medium

2021 ◽  
pp. 363-372
Author(s):  
Khudhair Abbas Kareem Al-Rudaini ◽  
Khulood Abid Saleh Al-Saadie
Keyword(s):  
Aluminum Alloy ◽  
Corrosion Inhibitor ◽  
Aqueous Extract ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Sodium Hydroxide Solution ◽  
Milk Thistle ◽  
Silybum Marianum ◽  
Green Corrosion Inhibitor ◽  
Mixed Type Inhibitor

The aqueous extract of milk thistle (Silybum marianum) leaves as a green corrosion inhibitor for AA7051 aluminum alloy in sodium hydroxide solution was investigated at a range of temperatures. Potentiodynamic polarization findings exhibit a mixed–type inhibitor with directly increased inhibition efficiency with the concentration of inhibitor. The adsorption of the inhibitor on aluminum alloy obeys Langmuir isotherm and the kinetic as well as thermodynamic parameters were measured and discussed.

Electrochemical Investigation of Myclobutanil as Corrosion Inhibitor for Copper in Acid Medium

2014 ◽  
Vol 960-961 ◽  
pp. 229-233 ◽  
Author(s):  
Li Zheng ◽  
Ji Liu ◽  
Zhi Hua Tao ◽  
Wei He ◽  
Ding Jun Xiao ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Investigation ◽  
Eis Measurements ◽  
Good Agreement ◽  
Mixed Type Inhibitor

This paper is mainly to discuss that myclobutanil as corrosion inhibitor and its corrosion efficiency were evaluated via electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The potentiodynamic polarization measurements showed that the inhibition efficiency increases sharply with the increasing of concentration of myclobutanil, and the highest inhibition efficiency of the myclobutanil reached 84.3% at 3.2×10-4 mol/L in 1 mol/L HCl. The result also indicated that myclobutanil belongs to the mixed type inhibitor. The results obtained from EIS measurements are in good agreement with that obtained from potentiodynamic polarization.

The corrosion inhibition of carbon steel in 5 per cent HCl by Momordica charantia extract

2014 ◽  
Vol 61 (4) ◽  
pp. 255-260 ◽  
Author(s):  
Xie Xuejun* ◽  
Xiao Peng* ◽  
He Jie ◽  
Xiao Wen ◽  
Fu Qiang ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Xps Analysis ◽  
Content Type ◽  
Isotherm Equation ◽  
Inhibition Effect ◽  
Langmuir Isotherm Equation ◽  
Ir Analysis ◽  
Mixed Type Inhibitor

Purpose – To study the inhibition effect and mechanism of the Momordica charantia extract (BM) to 20 A carbon steel in 5 per cent HCl. Design/methodology/approach – The weight loss, polarization curve, infrared spectrum (IR) analysis and X-ray photoelectron spectrum (XPS) analysis were carefully investigated to indicate the inhibition effect and mechanism of the BM to 20 A carbon steel in 5 per cent HCl. Findings – BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. The inhibition efficiency increased with the increasing concentration of BM. BM behaved as a mixed-type inhibitor, and the inhibition of BM to 20 A carbon steel might be its adsorption through the coordinate covalent bonding among the lone pair electrons of N and O and the empty 3d orbits of Fe, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation. Research limitations/implications – The inhibition of the BM to 20 A carbon steel in 5 per cent HCl. Practical implications – BM could be used in 5 per cent HCl to prevent 20 A carbon steel from corrosion. Social implications – BM could be used in the chemical cleaning of the boilers to prevent the thermal equipments from corrosion. Originality/value – The inhibition effect and mechanism of the BM to 20 A carbon steel were studied by the weight loss, polarization curve, IR analysis and XPS analysis. BM was composed of C, N and O. Functional groups such as N–H and C=O were found in BM. BM behaved as a mixed-type inhibitor. The inhibition efficiency increased with the increasing concentration of BM, and the adsorption on the surface of 20 A carbon steel obeyed the Langmuir isotherm equation.

Adsorption Behavior and Corrosion Inhibition of 2-Benzothiazolethiol for Q235 Steel in Hydrochloric Acid Solution

2012 ◽  
Vol 212-213 ◽  
pp. 947-950
Author(s):  
Tao Wang ◽  
Xi Yang He ◽  
Xue Yang
Keyword(s):  
Hydrochloric Acid ◽  
Acid Solution ◽  
Hydrochloric Acid Solution ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Hydrochloric Acid Concentration ◽  
Adsorption Behaviour ◽  
Q235 Steel ◽  
Increase With Increase ◽  
Mixed Type Inhibitor

The weight loss measurements and potentiodynamic polarization techniques are used to assess the inhibitive and adsorption behaviour of 2-Benzothiazolethiol (BTT) for Q235 steel in hydrochloric acid solution. The inhibition efficiency is found to increase with increase in BTT concentration but decrease with rise in temperature and hydrochloric acid concentration. The results show that BTT acts as a good corrosion inhibitor in hydrochloric acid solution. Adsorption of BTT is found to obey Langmuir isotherm. Polarization curves indicate BTT is a mixed-type inhibitor.

Inhibition Effect of N-Octyl-2-Pyrrolidonium Chloride on the Corrosion of Mild Steel in Acidic Medium

2013 ◽  
Vol 634-638 ◽  
pp. 651-654
Author(s):  
Zi Chong Zhuang ◽  
Bao Hua Huang ◽  
Jun Liu ◽  
Yu Jing Lu ◽  
Zhan Chang Pan ◽  
...  
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Acidic Medium ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Electrochemical Techniques ◽  
Inhibition Mechanism ◽  
Inhibition Effect ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new ionic liquid, N-octyl-2-pyrrolidonium chloride (NOPC), were synthesized and evaluated as inhibitors for mild steel (Q235) corrosion in 1 mol/L HCl. The adsorption behavior and corrosion inhibition mechanism of NOPC for mild steel in HCl solution were investigated by using weight loss measurements, electrochemical techniques, and SEM. The inhibition efficiency increases with the increasing concentration of NOPC in 1 mol/L HCl and decreases as the temperature increases. The results indicate that NOPC is able to function as a mixed type inhibitor.

scholarly journals Electrochemical and quantum chemical parameters of (-)-(S)-9-flu¬oro-2,3-dihydro-3-methyl-10-(4-methyl-1-pipera-zinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acidas anti-corrosive agent for API 5L X-52 steel

2020 ◽  
Vol 10 (3) ◽  
pp. 234-244
Author(s):  
Fidelis Ebunta Abeng ◽  
Magdalene Edet Ikpi ◽  
Victor E. Okpashi ◽  
Onumashi A. Ushie ◽  
Mbang E. Obeten
Keyword(s):  
Quantum Chemical ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Quantum Chemical Study ◽  
Chemical Study ◽  
Chemical Parameters ◽  
Polarization Method ◽  
Quantum Chemical Parameters ◽  
Inhibitive Action ◽  
Mixed Type Inhibitor

The inhibitive action of (-)-(S)-9-fluoro-2,3-dihydro-3-methyl-10-(4-methyl-1-piperazinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acid (Levaquin) on API 5L X-52 steel in 2 M HCl solution was investigated using potentiodynamic polarization method and quantum chemical study. Levaquin drug showed good inhibition efficiency of 88 and 95 % at 303 and 323 K, respectively. The results of experimental measurements revealed that Levaquin drug works as a mixed type inhibitor. Langmuir thermodynamic model was tested to describe the mode of inhibitor adsorption on the steel surface. The quantum chemical calculations confirmed the efficacy of Levaquin drug as a corrosion inhibitor.

scholarly journals Water-soluble chitosan from shrimp and mussel shells as corrosion inhibitor on tinplate in 2% NaCl

2019 ◽  
Vol 15 (2) ◽  
pp. 212-217
Author(s):  
Harmami Harmami ◽  
Ita Ulfin ◽  
Arina Hidayatus Sakinah ◽  
Yatim Lailun Ni’mah
Keyword(s):  
Corrosion Inhibitor ◽  
Polymer Chain ◽  
Potentiodynamic Polarization ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Water Soluble ◽  
Polarization Method ◽  
Shrimp Shells ◽  
Maximum Inhibition ◽  
Mussel Shells

Water-Soluble Chitosan (WSC) was synthesized form shrimp and mussel shells wastes and used as corrosion inhibitor on tinplate in 2% NaCl. Chitin was extracted from shrimp and mussel shells wastes by demineralization and deproteinization reactions.Chitin was deacetylated to crude chitosan. WSC was obtained by shortening the crude chitosan polymer chain using H2O2. WSC was characterized by FTIR. WSC performance as corrosion inhibitor on tinplate in 2% NaCl was studied by weightloss and potentiodynamic polarization methods. WSC inhibition efficiency was studied in various concentrations from 10-1500 mg/L. Maximum inhibition efficiencies of WSC from shrimp shells waste were 72,73% (weightloss method) and 91,41% (potentiodynamic polarization method), while maximum inhibition efficiency of WSC from mussel shells waste was 54,55% (weightloss method) with the addition of 1300 mg/L WSC concentration. Weightloss studies revealed that WSC acted as mixed type of inhibitor and obeyed Freundlich adsorption isoterm.

APPLICATION OF ESSENTIAL OIL OF ARTEMISIA HERBA ALBA AS GREEN CORROSION INHIBITOR FOR STEEL IN 0.5 M H2SO4

2009 ◽  
Vol 16 (01) ◽  
pp. 49-54 ◽  
Author(s):  
O. OUACHIKH ◽  
A. BOUYANZER ◽  
M. BOUKLAH ◽  
J.-M. DESJOBERT ◽  
J. COSTA ◽  
...  
Keyword(s):  
Weight Loss ◽  
Chemical Composition ◽  
Adsorption Isotherm ◽  
Essential Oil ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Electrochemical Polarization ◽  
Capillary Gc ◽  
Green Corrosion Inhibitor ◽  
Natural Oil

Essential oil from Artemisia herba alba (Art) was hydrodistilled and tested as corrosion inhibitor of steel in 0.5 M H 2 SO 4 using weight loss measurements and electrochemical polarization methods. Results gathered show that this natural oil reduced the corrosion rate by the cathodic action. Its inhibition efficiency attains the maximum (74%) at 1 g/L. The inhibition efficiency of Arm oil increases with the rise of temperature. The adsorption isotherm of natural product on the steel has been determined. A. herba alba essential oil was obtained by hydrodistillation and its chemical composition oil was investigated by capillary GC and GC/MS. The major components were chrysanthenone (30.6%) and camphor (24.4%).

scholarly journals Pyrite Passivation by Triethylenetetramine: An Electrochemical Study

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Yun Liu ◽  
Zhi Dang ◽  
Yin Xu ◽  
Tianyuan Xu
Keyword(s):  
Cyclic Voltammetry ◽  
Potentiodynamic Polarization ◽  
Mixed Type ◽  
Open Circuit Potential ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Experimental Results ◽  
Coating Agent ◽  
Mixed Type Inhibitor

The potential of triethylenetetramine (TETA) to inhibit the oxidation of pyrite in H2SO4solution had been investigated by using the open-circuit potential (OCP), cyclic voltammetry (CV), potentiodynamic polarization, and electrochemical impedance (EIS), respectively. Experimental results indicate that TETA is an efficient coating agent in preventing the oxidation of pyrite and that the inhibition efficiency is more pronounced with the increase of TETA. The data from potentiodynamic polarization show that the inhibition efficiency (η%) increases from 42.08% to 80.98% with the concentration of TETA increasing from 1% to 5%. These results are consistent with the measurement of EIS (43.09% to 82.55%). The information obtained from potentiodynamic polarization also displays that the TETA is a kind of mixed type inhibitor.

scholarly journals Investigation ofCitrus aurantiifoliaLeaves Extract as Corrosion Inhibitor for Mild Steel in 1 M HCL

2009 ◽  
Vol 6 (3) ◽  
pp. 785-795 ◽  
Author(s):  
R. Saratha ◽  
S. V. Priya ◽  
P. Thilagavathy
Keyword(s):  
Mild Steel ◽  
Plant Extract ◽  
Mixed Type ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Stable Complex ◽  
Electrochemical Studies ◽  
Inhibitive Action ◽  
Citrus Aurantiifolia ◽  
Mixed Type Inhibitor

The inhibition efficiency of acid extract of leaves ofCitrus aurantiifolia[CAL] plant on the corrosion of mild steel in 1 M HCl was investigated by weight loss measurements and electrochemical studies. The corrosion rate of mild steel and the inhibition efficiencies of the extract were calculated. The results obtained show that the extract could serve as an effective inhibitor for the corrosion of mild steel in HCl media. Inhibition was found to increase with increasing concentration of the plant extract. The inhibitive action of plant extract is discussed on the basis of adsorption of stable complex at the mild steel surface. Theoretical fitting of different isotherms, Langmuir, Temkin, Freundlich, Frumkin, Flory-Huggins and the kinetic thermodynamic model, were tested to clarify the nature of adsorption. Polarisation curves revealed that this inhibitor act as a mixed type inhibitor and the inhibition efficiency of up to 97.91% can be obtained. The surface analysis study confirms the corrosion of mild steel and its inhibition by the inhibitor CAL.

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