scholarly journals Soil quality assessment and phytoaccumulation potentials of selected edible vegetables around Ntigha solid waste dump, Abia State, Nigeria

2018 ◽  
Vol 2 ◽  
pp. 14
Author(s):  
U. Kelechi Osuocha ◽  
C. Ezinne Chukwu ◽  
S. Ahamefula Ezekwe

The present study evaluated the impact of open solid waste dumping on soil physicochemical characteristics, enzyme activities, soil heavy metals and bioavailability of these metals in selected edible vegetables. Twenty-six soil samples were collected from 13 different points. The considered points were center of the dumpsite (DC), 4 meters away east (E1), west (W1), north (N1), and south (S1) from the center of the dumpsite; and 8 meters away east (E2), west (W2), north (N2) and south (S2) from the center of the dumpsite. The controls were taken 100 meters away from the dumpsite center east (E3), west (W3), north (N3), and south (S3). Soil samples were collected at the depth of 0-45cm and 46-90cm at each point. Results obtained showed the physicochemical and enzyme activities of the center of the dumpsite (DC) were affected when compared to other points considered in this study. Significant differences between soil depths were also observed. Soil heavy metals also showed significant increase in dumpsite compared to control soils (P<0.05). Phytoavailability of the heavy metals studied showed that vegetables grown around Ntigha dumpsite accumulated significant level of the metals compared to their control counterparts (P<0.05). This study has revealed that open pit disposal of solid waste increased the phytoaccumulation potentials of edible vegetables grown around the dumpsite. Hence proper waste disposal method is advocated so as to prevent bioaccumulation of these heavy metals in human food chain.

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Besufekad Mekonnen ◽  
Alemayehu Haddis ◽  
Wuhib Zeine

An increase in urban population and the rising demand for food and other essentials perpetuate a rise in the amount of waste being generated daily by each household. In Ethiopia, this waste is eventually thrown into open dump sites. It can cause severe impact on soil and surface water quality. As a result, it becomes the probable source of human health risk through food chain. Therefore, this study was aimed at assessing the effect of a solid waste dump site on surrounding soil and river water quality in Tepi town, Southwest Ethiopia. Three surface water, one leachate, and four soil samples were collected and analyzed. Six heavy metals for surface water and leachate samples and four heavy metals for soil samples were measured by flame atomic absorption spectroscopy. In addition, physiochemical parameters were analyzed using standard methods. The data were analyzed statistically using Origin pro version 8.0 computer software packages. The pH of soil was slightly basic ranging from 8 ± 0.1 to 8.7 ± 0.21. Electrical conductivity was lower at 60 meters (1800 ± 0.5 μs/cm) and higher in the other sample sites (3490 ± 0.66–4920 ± 1.04 μs/cm). The concentration of heavy metals in soil samples revealed cadmium (0.53 ± 0.01–2.26 ± 0.02 mg/kg), zinc (623.93 ± 0.29–859.41 ± 0.02 mg/kg), lead (3.26 ± 0.25–57.560.26 mg/kg), and copper (204.06 ± 0.06–337.11 ± 0.01 mg/kg). Lead, cadmium, manganese, nickel, copper, and zinc were found in the leachate water; nickel and manganese were found in the nearby river water; BOD5 and COD for both leachate and stream water samples were found to be higher than standard guideline values. The finding suggested that solid waste open dump site adversely affects soil and water quality in the study area and becomes a probable source of risk for human health via the food chain.


Author(s):  
M. N. Okeke ◽  
Paul Chukwuka Eze ◽  
C. N. Eze

<strong>Aims:</strong> The purpose of this project is to find the concentration of heavy metals (Cu, Zn, Pb, As, Cr, Ni, Cd, Fe and Mn) in the top soil and the plant around the waste dumpsite from Enugu municipal solid waste disposal sites. <strong>Methodology and results: </strong>This was done through collection of soil samples from four designated public municipal solid waste dump sites (Ngwo Umueze, Presidential, New-market and Emene) in Enugu metropolis. The soil samples were collected at 10 metres intervals away from the centre location point of each dump site at constant depth (0 - 15 cm were mixed together and sample picked from it). The samples collection design are as follows: centre (0m) of the dump sites, 10 metres, 20 metres, 30 metres and the control sample which measured 65 metres away from the centre of dumpsites at the same depth. Plant samples were taken just at the centre (0m) and control measures which is at 65 meters distance away from each dump sites. The Goat grasses harvested were taken to the lab to check and analyse its heavy metals intake from the soil. These samples were analysed using atomic absorption spectrophotometer (AA320N) model. On the average, high concentrations of Zn, Fe, Mn, Cu, and Pb were found in the soil samples collected at the centre of the dump sites as 141.70, 121.5, 75.53, 70.33 and 64.53mg/kg respectively. The lower concentrations were obtained in the soil samples taken at the control site which 65 metres distance away from the centre of the four dump sites as 12.00, 81.55, 8.70, 9.56 and 6.51mg/kg for Zn, Fe, Mn, Cu, and Pb respectively. In the plant sample, concentration of Fe (98.00 mg/kg) was found to be the highest in the root at New market dumpsites, while Nil concentration of as (Nil mg/kg) was the least value at Emene from the control distance. <strong>Conclusion, significance and impact study:</strong> SPSS statistical package was used to find out the significant differences between the treatments mean (heavy metals). The result shows that the heavy metals analyses were within the acceptable or permissible limit by WHO/FAO.


2016 ◽  
Vol 18 (1) ◽  
pp. 51-57 ◽  
Author(s):  
Piotr Grzesiak ◽  
Joanna Łukaszyk ◽  
Elżbieta Gabała ◽  
Joanna Kurczewska ◽  
Grzegorz Schroeder

Abstract 3-Mercaptopropyl-trimethoxysilane and [3-(2-aminoethylamino)propyl]trimethoxysilane were used to functionalize the surface of silica from Piotrowice in Poland to stabilize heavy metals (HMs) and arsenic in soil. The soil for the study was sampled from the impact zone of Głogów Copper Smelter and Refinery. The soil samples were exposed to five-step Tessier sequential extraction. The speciation studies were limited to five sequentially defined fractions in which metal content was determined. The addition of unmodified silica did not affect significantly the concentration of metals in individual fractions. Significant changes were noted upon introduction of functionalized silica in the soil. The hybrid formulations obtained significantly reduce the release of heavy metals and arsenic from soil sorption complex. The results indicate the potential use of functional formulations for reduction of metal migration in soil in the areas of exceeded concentration of heavy metals and arsenic in the soil, caused by industrial activity.


2019 ◽  
Author(s):  
Besufekad Asres Mekonnen ◽  
Alemayehu Haddis ◽  
Wuhib Zeine

Abstract Background An increase in the urban population and the rising demand for food and other essentials perpetuate a rise in the amount of waste being generated daily by each household. In low-income countries, this waste is eventually thrown into open dump sites. It can cause severe impacts on human health and the surrounding environment. This study was aimed at assessing the effect of a solid waste dump site of Teppi town on surrounding soil and river water quality. Methods A total of three surface water, one leachate water samples, and four soil samples were collected and were analyzed. Six heavy metals for surface water and leachate samples and four heavy metals for soil samples were measured by flame atomic absorption spectroscopy. Additionally, physical and chemical parameters were analyzed using standard methods. The soil and water data were analyzed statistically using Origin pro version 8.0 computer software packages. Analysis of variance (ANOVA) was used to assess whether the mean values of heavy metals and physicochemical parameters in soil and water samples varied significantly between distances and location from the dump site, possibilities less than 0.05 (p< 0.05) was considered statistically significant. Results pH of soil was slightly basic (pH 8±0.1 up to 8.7±0.21. Similarly, EC was lower in 60 meters (1800±0.5μs/cm) and higher in the other sample sites (3490±0.66-4920±1.04μs/cm). The concentration of heavy metals such as cadmium (0.53±0.01-2.26±0.02 mg/kg), zinc (623.93±0.29-859.41±0.02mg/kg), lead (3.26±0.25-57.560.26mg/kg), and copper (204.06±0.06 337.11±0.01mg/kg) in the sample soils has been found to be higher than Ethiopian EPA and USEPA guideline values. Lead, cadmium, manganese, nickel, copper, and zinc in the leachate water and nickel and manganese in nearby river water, total dissolved solid, BOD5, chemical oxygen demand, and turbidity for both leachate and stream water samples were found to be higher than the Ethiopian EPA and WHO standard guideline values. Conclusions The finding suggested that solid waste open dump site adversely affects soil and water quality in the study area and probable source of human health risks via the food chain. The soil in the area requires Phytoremediation technologies. In addition, sanitary landfill is recommended.


2021 ◽  
Vol 6 (1) ◽  
pp. 146-152
Author(s):  
M. Z. Karkana ◽  
◽  
Mujahid Ajah Matazu

The research was conducted to assess the level of heavy metals contamination using single and integrated pollution indices in soils around municipal solid waste dumpsites of Kano Metropolis, Kano State, Nigeria. Forty two soil samples were collected from seven municipal solid waste dumpsites of Kano metropolis using circular plot method. A stainless hand auger at a depth of (0 to 15) top soils and sub-surface soils (15-30cm) depth were collected and analyzed with Flame atomic absorption spectrophotometer to determine the heavy metal concentration. The mean concentration (mg/kg) of heavy metals from the depth of (15-30 cm) were observed to follow a decreasing order Pb (7.71)>Zn (0.50) > Ni (0.45) > Cr (0.31) > Cd (0.025) while for surface soils (0- 15cm) the mean concentration were in the following order: Pb (1.77) > Ni (0.49) > Zn (0.30) > Cr (0.27) > Cd (0.012).The results showed that calculated CF and Er recorded that investigated soil samples are uncontaminated with Zn, Pb, Cd, Cr and Pb and Ni. The pollution load index (PLI) was less than unity showing that there was minimum pollution in the studied dumpsite. The potential ecological risk showed that soil samples were in the class of low contaminated with the studied heavy metals. The results showed that concentrations of heavy metals of soil samples from dumpsites location at waste dumpsites of Kano Metropolis were within limits of European Union (2002) standards. Keywords: Heavy metals, single and integrated pollution indices Kano, Municipal dumpsites


Author(s):  
N. P. Udeh ◽  
A. C. Ikegwuonu ◽  
O. A. Okeke ◽  
C. Obudulu ◽  
K. P. Okafor ◽  
...  

Soil samples and cassava tubers collected from farmlands within Nnamdi Azikiwe University, Awka vicinity were analyzed for their heavy metal levels using Atomic Absorption Spectrophotometer (AAS) in order to assess their levels of contamination on the environment as a result of excessive fertilizers and automobile emission. Physiochemical properties of the soil samples were determined using standard methods. The soil pH had a mean value of 6.27 ± 0.07, 6.10 ± 0.06 and 6.57 ± 0.03 respectively indicating that the soils were slightly acidic to neutrality. Total organic carbon and nitrate mean values were 105.20 ± 6.20, 95.75 ± 9.57 and 94.6 ± 2.27 and 138.07 ± 12.09, 149.35 ± 14.25 and 149.20 ± 1.17 respectively showing presence of some organic matters. The mean levels of heavy metals in the soil samples were 0.01 ± 0.01, 0.05 ± 0.03 and 0.05 ± 0.03 for lead (Pb), 0.24 ± 0.16, 0.001 ± 0.001 and 0.001 ± 0.000 for cadmium (Cd) and 0.00 ± 0.00, 0.010 ± 0.006 and 0.001 ± 0.001 for chromium (Cr). These metals levels were in the abundance trend of Pb>Cd> Cr. The mean metal concentrations obtained in the cassava tubers respectively were 0.001 ± 0.001, 0.001 ± 0.001 and 0.005 ± 0.005 for lead (Pb), 0.000 ± 0.000, 0.0003 ± 0.0003 and 0.000 ± 0.000 for cadmium (Cd) and 0.002 ± 0.002, 0.000 ± 0.000 and 0.002 ± 0.002 for chromium (Cr). These metals levels were in the abundance trend of Pb> Cr > Cd. For both the soil and cassava samples, there were no significant variations in the heavy metal concentrations and also in physicochemical parameter except for pH; this showed that there is low heavy metal enrichment in the soils studied. Based on the study, the following heavy metals (Pb, Cd, and Cr) falls within the Codex maximum permissible limits 0.1mg/l or ppm expect soil cadmium in science village which is above the Codex limit. The overall results showed that the farmlands (on soils and cassava tuber) appear to be free from poisoning or some metal enrichment and safe for agricultural purposes and also safe for human health and consumption.


2021 ◽  
Vol 82 (3) ◽  
pp. 115-120
Author(s):  
SINTSOV ALEXANDER V. ◽  
◽  
BARMIN ALEXANDER N. ◽  
ZIMOVETS PETR A. ◽  
VALOV MICHAIL V. ◽  
...  

Anthropogenic and technogenic processes in the urban environment significantly change the chemical composition of the soil cover. One of such processes influencing the state of the urban soil is the process of soil cover pollution with heavy metals. Heavy metals are biochemically active and highly toxic; they are found in various components of the natural environment, as well as in systems of anthropogenic and technogenic origin. They have the property of accumulation in the body of living beings and have a negative effect on their condition. This group of chemical elements includes lead, zinc, chromium, mercury, copper, iron and other metals. Exceeding the permissible concentration of heavy metals in the soil of an urbanized area and their toxic effects pose a significant danger to humans. Contamination of the soil cover of an urbanized area with heavy metals is associated with the impact of a large number of sources of anthropogenic and technogenic origin, namely, energy and industrial facilities, city infrastructure support systems, zones of construction activities and storage of materials or waste. One of the main highly toxic chemical pollutants of the soil cover of the urbanized territory belonging to the group of heavy metals is zinc «Zincum-Zn». The article describes the results of a 2020 study of the current zinc content in the soil cover of the city of Astrakhan. The relevance of the work lies in the geochemical analysis of the content of heavy metals in the soil of the city of Astrakhan. The aim of the work was to study the modern process of soil contamination of the city of Astrakhan with zinc. The work was based on the task of determining the degree of exceeding the hygienic standards of the maximum permissible concentration of zinc in soil samples. Methods of geographical and ecological research were used in the work, soil samples were collected, followed by determination of the concentration of a substance in each of the soil samples in a certified laboratory. In the course of the work, the indicators of exceeding the maximum permissible concentration of zinc in the soil of the city of Astrakhan were determined and the presumptive sources of pollution were identified.


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