scholarly journals Characterization of a Modular Flow Cell System for Electrocatalytic Experiments and Comparison to a Commercial RRDE System

2020 ◽  
Author(s):  
Frederik J. Stender ◽  
Keisuke Obata ◽  
Max Baumung ◽  
Fatwa F. Abdi ◽  
Marcel Risch
Keyword(s):  
Analytical Solutions ◽  
Electrode Materials ◽  
Collection Efficiency ◽  
Flow Cell ◽  
Cell System ◽  
Attractive Alternative ◽  
Pt Electrodes ◽  
Double Electrode ◽  
The Cost

Generator-collector experiments offer insights into the mechanisms of electrochemical reactions by correlating the product and generator currents. Most commonly, these experiments are performed using a rotating ring-disk electrode (RRDE). We developed a double electrode flow cell (DEFC) with exchangeable generator and detector electrodes where the electrode width equals the channel width. Commonalities and differences between the RRDE and DEFC are discussed based on analytical solutions, numerical simulations and measurements of the ferri-/ferrocyanide redox couple on Pt electrodes in a potassium chloride electrolyte. The analytical solutions agree with the measurements using electrode widths of 5 and 2 mm. Yet, we find an unexpected dependence on the exponent of the width so that wider electrodes cannot be analysed using the conventional analytical solution. In contrast, all the investigated electrodes show a collection efficiency of close to 35.4% above a minimum rotation speed or flow rate, where the narrowest electrode is most accurate at the cost of precision and the widest electrode the least accurate but most precise. Our DEFC with exchangeable electrodes is an attractive alternative to commercial RRDEs due to the flexibility to optimize the electrode materials and geometry for the desired reaction.

scholarly journals Characterization of a Modular Flow Cell System for Electrocatalytic Experiments and Comparison to a Commercial RRDE System

2020 ◽  
Author(s):  
Frederik J. Stender ◽  
Keisuke Obata ◽  
Max Baumung ◽  
Fatwa F. Abdi ◽  
Marcel Risch
Keyword(s):  
Analytical Solutions ◽  
Electrode Materials ◽  
Collection Efficiency ◽  
Flow Cell ◽  
Cell System ◽  
Attractive Alternative ◽  
Pt Electrodes ◽  
Double Electrode ◽  
The Cost

Generator-collector experiments offer insights into the mechanisms of electrochemical reactions by correlating the product and generator currents. Most commonly, these experiments are performed using a rotating ring-disk electrode (RRDE). We developed a double electrode flow cell (DEFC) with exchangeable generator and detector electrodes where the electrode width equals the channel width. Commonalities and differences between the RRDE and DEFC are discussed based on analytical solutions, numerical simulations and measurements of the ferri-/ferrocyanide redox couple on Pt electrodes in a potassium chloride electrolyte. The analytical solutions agree with the measurements using electrode widths of 5 and 2 mm. Yet, we find an unexpected dependence on the exponent of the width so that wider electrodes cannot be analysed using the conventional analytical solution. In contrast, all the investigated electrodes show a collection efficiency of close to 35.4% above a minimum rotation speed or flow rate, where the narrowest electrode is most accurate at the cost of precision and the widest electrode the least accurate but most precise. Our DEFC with exchangeable electrodes is an attractive alternative to commercial RRDEs due to the flexibility to optimize the electrode materials and geometry for the desired reaction.

scholarly journals AB1062 LIPODERMATOSCLEROSIS AS A TYPE OF LOBULAR PANNICULITIS: THE EFFECTIVENESS OF NON-PHARMACOLOGICAL TREATMENT METHODS

2020 ◽  
Vol 79 (Suppl 1) ◽  
pp. 1821.1-1821
Author(s):  
M. Sukhareva ◽  
O. Egorova ◽  
B. Belov
Keyword(s):  
Subcutaneous Fat ◽  
Lymphatic Drainage ◽  
Normal Body Mass Index ◽  
Positive Trend ◽  
Group I ◽  
Positive Clinical Effect ◽  
Group Ii ◽  
The Cost ◽  
Lobular Panniculitis

Background:In medical practice lobular panniculitis-lipodermatosclerosis (LDS) is becoming more and more common. It is manifested by degenerative-dystrophic changes in subcutaneous fat (SCF) and occurs more often in middle-aged women affected by chronic venous insufficiency.Objectives:to evaluate the effectiveness of mesotherapy (MT) and shockwave ultrasound therapy (UST) for LDSMethods:among 539 patients referred to the V.A. Nasonova Research Institute of Rheumatology with the referral diagnoses of erythema nodosum or panniculitis 8.5% (46) of patients (44 women, 2 men) aged 18 to 82 with overweight (32) LDS with the disease duration of 11,8±6.4 months was verified. Patients were randomized into two groups of 23 patients each: group I received daily MT (10 sessions) therapy with drugs that have antioxidant, anti-inflammatory, lymphatic drainage and lipolytic effects, and 3 MHz UST of the node area twice a week (5 sessions). In group II MT was performed daily with 9% Natrii chloridum solution at a dose comparable to group I. The control methods included general clinical examination (characterization of induration on the lower legs with an assessment of the effect of pain pressing according to visual analogue scale (VAS pain), general blood and urine tests and ultrasound with elastography (USE) of the compaction. The main stages of control: initial (T0), after 14 days (T1), 1 month (T2) and 3 months (T3).Results:before treatment 38 patients with LDS demonstrated asymmetric (83%) inflammation of SCF of the lower legs (100%) on its medial surface (91%). LDS regressed faster with normal body mass index (p = 0,04). In all patients of group I, after a course of physiotherapy a positive trend was registered, that is a decrease in VAS pain intensity (T0 50±18 mm; T1 35±11 mm), decrease in diameter (T0 6±2.2 cm; T1 4.5±1, 7 mm) and color intensity of the node (p<0.002), SCF thickening which results in “lumping” with macrovascularization according to USE, and decrease in ESR and CRP. In 44% of cases the treatment effect increased to T2 (p <0.05). After 3 months of observation, 15 patients required a second course of physiotherapy. In group II a positive clinical effect was registered for T2 in 14 patients (60.8%) and for T3 in 19 patients (83%) (p<0.05). Over the entire observation period LDS recurrence was registered in 19 patients (41%), the median of recurrence was 3 [1; 6] months, mainly in patients of group I. Recurrence was associated with node fusion into conglomerates (OR 4.33, 95% CI 1.05-17.8; p = 0.037). MT and UST were tolerated well, no side effects were detected.Conclusion:the use of MT with 9% Natrii chloridum solution allowed us to achieve positive dynamics in patients with LDS, which significantly reduced the cost of treatment. Further studies are needed to evaluate the significance of these techniques.Disclosure of Interests:None declared

scholarly journals A New Breeding Strategy towards Introgression and Characterization of Stay-Green QTL for Drought Tolerance in Sorghum

Agriculture ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 598
Author(s):  
Nasrein Mohamed Kamal ◽  
Yasir Serag Alnor Gorafi ◽  
Hanan Abdeltwab ◽  
Ishtiag Abdalla ◽  
Hisashi Tsujimoto ◽  
...  
Keyword(s):  
Phenotypic Expression ◽  
Phenotypic Selection ◽  
Breeding Strategy ◽  
Stay Green ◽  
Breeding Programs ◽  
The Public ◽  
Drought Tolerant ◽  
Selection Step ◽  
The Cost

Several marker-assisted selection (MAS) or backcrossing (MAB) approaches exist for polygenic trait improvement. However, the implementation of MAB remains a challenge in many breeding programs, especially in the public sector. In MAB introgression programs, which usually do not include phenotypic selection, undesired donor traits may unexpectedly turn up regardless of how expensive and theoretically powerful a backcross scheme may be. Therefore, combining genotyping and phenotyping during selection will improve understanding of QTL interactions with the environment, especially for minor alleles that maximize the phenotypic expression of the traits. Here, we describe the introgression of stay-green QTL (Stg1–Stg4) from B35 into two sorghum backgrounds through an MAB that combines genotypic and phenotypic (C-MAB) selection during early backcross cycles. The background selection step is excluded. Since it is necessary to decrease further the cost associated with molecular marker assays, the costs of C-MAB were estimated. Lines with stay-green trait and good performance were identified at an early backcross generation, backcross two (BC2). Developed BC2F4 lines were evaluated under irrigated and drought as well as three rainfed environments varied in drought timing and severity. Under drought conditions, the mean grain yield of the most C-MAB-introgression lines was consistently higher than that of the recurrent parents. This study is one of the real applications of the successful use of C-MAB for the development of drought-tolerant sorghum lines for drought-prone areas.

scholarly journals A Theoretical Study on Reversible Solid Oxide Cells as Key Enablers of Cyclic Conversion between Electrical Energy and Fuel

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4517
Author(s):  
Saheli Biswas ◽  
Shambhu Singh Rathore ◽  
Aniruddha Pramod Kulkarni ◽  
Sarbjit Giddey ◽  
Sankar Bhattacharya
Keyword(s):  
Energy Demand ◽  
Electrode Materials ◽  
Scale Up ◽  
High Capacity ◽  
Electrical Energy ◽  
Solid Oxide ◽  
Lower Efficiency ◽  
Internal Reforming ◽  
Fuels And Chemicals ◽  
The Cost

Reversible solid oxide cells (rSOC) enable the efficient cyclic conversion between electrical and chemical energy in the form of fuels and chemicals, thereby providing a pathway for long-term and high-capacity energy storage. Amongst the different fuels under investigation, hydrogen, methane, and ammonia have gained immense attention as carbon-neutral energy vectors. Here we have compared the energy efficiency and the energy demand of rSOC based on these three fuels. In the fuel cell mode of operation (energy generation), two different routes have been considered for both methane and ammonia; Routes 1 and 2 involve internal reforming (in the case of methane) or cracking (in the case of ammonia) and external reforming or cracking, respectively. The use of hydrogen as fuel provides the highest round-trip efficiency (62.1%) followed by methane by Route 1 (43.4%), ammonia by Route 2 (41.1%), methane by Route 2 (40.4%), and ammonia by Route 1 (39.2%). The lower efficiency of internal ammonia cracking as opposed to its external counterpart can be attributed to the insufficient catalytic activity and stability of the state-of-the-art fuel electrode materials, which is a major hindrance to the scale-up of this technology. A preliminary cost estimate showed that the price of hydrogen, methane and ammonia produced in SOEC mode would be ~1.91, 3.63, and 0.48 $/kg, respectively. In SOFC mode, the cost of electricity generation using hydrogen, internally reformed methane, and internally cracked ammonia would be ~52.34, 46.30, and 47.11 $/MWh, respectively.

Growth and characterization of Ba0.6Sr0.4TiO3 thin films on Si with Pt electrodes

1999 ◽  
Vol 17 (4) ◽  
pp. 2148-2150 ◽  
Author(s):  
L. Kinder ◽  
X. F. Zhang ◽  
I. L. Grigorov ◽  
C. Kwon ◽  
Q. X. Jia ◽  
...  
Keyword(s):  
Thin Films ◽  
Pt Electrodes

Electrochemical characterization of titanium biomaterials using the Mini-cell System

2006 ◽  
Vol 41 (11) ◽  
pp. 3323-3327 ◽  
Author(s):  
M. L. Nascimento ◽  
W. D. Mueller ◽  
A. C. Carvalho ◽  
H. M. Tomás
Keyword(s):  
Cell System ◽  
Electrochemical Characterization

scholarly journals Characterization of Spent Ni-MH Batteries

2012 ◽  
Vol 730-732 ◽  
pp. 569-574
Author(s):  
Marta Cabral ◽  
Fernanda Margarido ◽  
Carlos A. Nogueira
Keyword(s):  
Quantitative Analysis ◽  
Electrode Materials ◽  
Phase Identification ◽  
Recycling Process ◽  
X Ray ◽  
Leaching Experiments ◽  
Plastic Components ◽  
Definition Of ◽  
Physical And Chemical

Spent Ni-MH batteries are not considered too dangerous for the environment, but they have a considerable economical value due to the chemical composition of electrodes which are highly concentrated in metals. The present work aimed at the physical and chemical characterisation of spent cylindrical and thin prismatic Ni-MH batteries, contributing for a better definition of the recycling process of these spent products. The electrode materials correspond to more than 50% of the batteries weight and contain essentially nickel and rare earths (RE), and other secondary elements (Co, Mn, Al). The remaining components are the steel parts from the external case and supporting grids (near 30%) containing Fe and Ni, and the plastic components (<10%). Elemental quantitative analysis showed that the electrodes are highly concentrated in metals. Phase identification by X-ray powder diffraction combined with chemical analysis and leaching experiments allowed advancing the electrode materials composition. The cathode is essentially constituted by 6% metallic Ni, 66% Ni(OH)2, 4.3% Co(OH)2 and the anode consists mainly in 62% RENi5 and 17% of substitutes and/or additives such as Co, Mn and Al.

scholarly journals Demonstration of an integrated nanophotonic chip-scale alkali vapor magnetometer using inverse design

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Yoel Sebbag ◽  
Eliran Talker ◽  
Alex Naiman ◽  
Yefim Barash ◽  
Uriel Levy
Keyword(s):  
Spatial Resolution ◽  
Near Field ◽  
Computer Assisted ◽  
Experimental Characterization ◽  
Optical Isolation ◽  
New Concepts ◽  
On Chip ◽  
The Cost ◽  
Micrometer Scale

AbstractRecently, there has been growing interest in the miniaturization and integration of atomic-based quantum technologies. In addition to the obvious advantages brought by such integration in facilitating mass production, reducing the footprint, and reducing the cost, the flexibility offered by on-chip integration enables the development of new concepts and capabilities. In particular, recent advanced techniques based on computer-assisted optimization algorithms enable the development of newly engineered photonic structures with unconventional functionalities. Taking this concept further, we hereby demonstrate the design, fabrication, and experimental characterization of an integrated nanophotonic-atomic chip magnetometer based on alkali vapor with a micrometer-scale spatial resolution and a magnetic sensitivity of 700 pT/√Hz. The presented platform paves the way for future applications using integrated photonic–atomic chips, including high-spatial-resolution magnetometry, near-field vectorial imaging, magnetically induced switching, and optical isolation.

scholarly journals Automated Testing and Characterization of Additive Manufacturing (ATCAM)

2021 ◽  
Author(s):  
Arash Alex Mazhari ◽  
Randall Ticknor ◽  
Sean Swei ◽  
Stanley Krzesniak ◽  
Mircea Teodorescu
Keyword(s):  
Additive Manufacturing ◽  
Fused Deposition Modeling ◽  
Cell System ◽  
Automated Testing ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Machine Calibration

AbstractThe sensitivity of additive manufacturing (AM) to the variability of feedstock quality, machine calibration, and accuracy drives the need for frequent characterization of fabricated objects for a robust material process. The constant testing is fiscally and logistically intensive, often requiring coupons that are manufactured and tested in independent facilities. As a step toward integrating testing and characterization into the AM process while reducing cost, we propose the automated testing and characterization of AM (ATCAM). ATCAM is configured for fused deposition modeling (FDM) and introduces the concept of dynamic coupons to generate large quantities of basic AM samples. An in situ actuator is printed on the build surface to deploy coupons through impact, which is sensed by a load cell system utilizing machine learning (ML) to correlate AM data. We test ATCAM’s ability to distinguish the quality of three PLA feedstock at differing price points by generating and comparing 3000 dynamic coupons in 10 repetitions of 100 coupon cycles per material. ATCAM correlated the quality of each feedstock and visualized fatigue of in situ actuators over each testing cycle. Three ML algorithms were then compared, with Gradient Boost regression demonstrating a 71% correlation of dynamic coupons to their parent feedstock and provided confidence for the quality of AM data ATCAM generates.

Sign in / Sign up

Export Citation Format

Share Document