scholarly journals The Effects of Biodiesel on NOx Emissions for Automotive Transport

Author(s):  
Ruslana Kolodnytska ◽  
Oleksandr Kravchenko ◽  
Juraj Gerlici ◽  
Kateryna Kravchenko

Automobiles with internal combustion engine using diesel fuel have large harmful emissions of nitrogen oxides and soot, which affect the health of the population and especially children and carbon dioxide, which is dangerous for the planet as a whole. Biodiesel is used in Europe as an additive to diesel fuel to reduce soot emissions (including carcinogens), as well as to improve the balance of carbon dioxide on the planet. Using the biodiesel in internal combustion engines tends to show higher nitrogen oxides emissions compared to diesel. In this paper, the impact of flame temperature, ignition delay and density on NOx formation of biodiesel and its component for both stationary engine and automotive engine were analysed. Emissions of nitrogen oxides increase with increasing load. In no-load modes, biodiesel shows lower emissions of nitrogen oxides than diesel.

2019 ◽  
Vol 11 (23) ◽  
pp. 6585 ◽  
Author(s):  
Markiewicz ◽  
Muślewski

The application of fuels from renewable energy sources for combustion engine powering involves a great demand for this kind of energy while its production infrastructure remains underdeveloped. The use of this kind of fuel is supposed to reduce the emission of greenhouse gases and the depletion of natural resources and to increase the share of renewable energy sources in total energy consumption and thus support sustainable development in Europe. This study presents the results of research on selected performance parameters of transport by internal combustion engines including: power, torque, the emission of sound generated by the engine, the content of exhaust components (oxygen O2, carbon monoxide CO, carbon dioxide CO2, nitrogen dioxide NO2), and the content of particulate matter (PM) in exhaust emission. Three self-ignition engines were tested. The fuel injection controllers of the tested internal combustion engines were additionally adjusted by increasing the fuel dose and the load of air. The material used in the tests were mixtures of diesel oil and fatty acid methyl esters of different concentration. A statistical analysis was performed based of the results. The purpose of the work was to develop a resulting model for assessing the operation of engines fueled with biofuel and diesel mixtures while changing the vehicle's computer software. A computer simulation algorithm was also developed for the needs of the tests which was used to prognose the state of the test results for variable input parameters.


2021 ◽  
Vol 1 (2) ◽  
pp. 101-112
Author(s):  
A.V. Shabanov ◽  
◽  
D.V. Kondratiev ◽  
V.K. Vanin ◽  
A.Yu. Dunin ◽  
...  

The most effective method of reducing nitrogen oxides in diesel exhaust gas is selective purifica-tion by the SCR-NH3 method. The method uses ammonia released during thermolysis and hydroly-sis of a urea solution when it is injected through a nozzle into a neutralizer. This method has a rela-tively low efficiency of cleaning the exhaust gas from nitrogen oxides. The main factor hindering the achievement of high efficiency of the NOx neutralization system is the insufficiently high tem-perature during the implementation of this process. The article analyzes various ways to increase the efficiency of the neutralization process and proposes a new method for neutralizing NOx by using urea injection into the cylinders of the inter-nal combustion engine at the expansion stroke in a diesel internal combustion engine. Efficiency can be achieved due to a higher exhaust gas temperature in the cylinder of the internal combustion engine and an increase in the time of the process of thermolysis and hydrolysis of urea. The kinetics of the decomposition of nitrogen oxides, the process of NH3 oxidation, and the cal-culation of temperature conditions in the cylinder of a diesel internal combustion engine at the ex-haust cycle are considered. The experience of neutralization of NOx contained in the flue gases of thermal power plants, where NOx purification takes place at high temperatures without the use of a catalyst, is analyzed. It is shown that the modernization of the SCR-NH3 process, due to the injection of urea at the exhaust stroke in a diesel internal combustion engine, will simplify the existing method of NOx neutralization and at the same time obtain additional advantages for a modern high-speed engine


An account was given in a paper entitled “Proknocks and Hydrocarbon Combustion” (Ubbelohde, Drinkwater and Egerton 1935) of some experiments made to trace the source of the nitrogen peroxide which had been found by sampling the products from the cylinder of a petrol engine at various stages of the stroke. Those experiments indicated that it was not simply a matter of nitric oxide formed by the flame giving rise to the nitrogen peroxide, for different results were obtained using different exhaust-valve surfaces. Nevertheless it seemed probable that the flame should be mainly responsible for the formation of nitric oxide, and so further experiments have been made. In order to make progress it was essential to determine the amount of nitric oxide as well as the amount of nitrogen peroxide, and analytical methods had to be devised to do this. The first part of this note deals with the methods of determining small quantities (of the order of 10 -4 mol. fraction) of total nitrogen oxides and of nitrogen peroxide, and the second part with the results of analyses of the gases sampled from the cylinder of internal combustion engines by the methods described by Egerton, Smith and Ubbelohde (1935) and by Drinkwater and Egerton for the C. I. engine in a paper shortly to be published.


2018 ◽  
Vol 234 ◽  
pp. 03001 ◽  
Author(s):  
Evgeni Dimitrov ◽  
Boyko Gigov ◽  
Spas Pantchev ◽  
Philip Michaylov ◽  
Mihail Peychev

In this paper, a dual-fuel compression ignition engine test bench is presented. In hydrogen-diesel fuel co-combustion conditions, the engine parameters are determined – performance: effective torque, effective power and mean effective pressure; fuel economy: fuel consumption and specific fuel consumption; toxicity: carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and smoke emissions (opacity). The impact of hydrogen-diesel fuel mass ratio on the performance, toxicity and economy of the engine is studied by obtaining a series of hydrogen-diesel fuel ratio variation characteristics at constant engine speed and load. Improvement of the economical parameters of the engine and reduction of carbon dioxide concentration in exhaust gases is detected under operation with hydrogen gas fuel. Significant reduction of the exhaust gases opacity is observed. It is not clear what the impact of the quantity of hydrogen, injected in the engine, on the concentration of nitrogen oxides in the exhaust gases is.


2014 ◽  
Vol 2014 ◽  
pp. 1-12
Author(s):  
Shunsen Wang ◽  
Kunlun Bai ◽  
Yonghui Xie ◽  
Juan Di ◽  
Shangfang Cheng

A novel thermodynamic system is proposed to recover the waste heat of an internal combustion engine (ICE) by integrating the transcritical carbon dioxide (CO2) refrigeration cycle with the supercritical CO2power cycle, and eight kinds of integration schemes are developed. The key parameters of the system are optimized through a genetic algorithm to achieve optimum matching with different variables and schemes, as well as the maximum net power output (Wnet). The results indicate that replacing a single-turbine scheme with a double-turbine scheme can significantly enhance the net power output (Wnet) and lower the inlet pressure of the power turbine (P4). With the same exhaust parameters of ICE, the maximumWnetof the double-turbines scheme is 40%–50% higher than that of the single-turbine scheme. Replacing a single-stage compression scheme with a double-stage compression scheme can also lower the value ofP4, while it could not always significantly enhance the value ofWnet. Except for the power consumption of air conditioning, the net power output of this thermodynamic system can reach up to 13%–35% of the engine power when it is used to recover the exhaust heat of internal combustion engines.


2021 ◽  
Author(s):  
Marek Idzior

New designs of internal combustion engines require the use of engine oils that can cope with more demanding conditions, primarily with greater loads and higher temperatures. The requirements of recent years have led to a wider use of modern base oils and specially designed additive packages. This avoids the formation of impurities and changes in viscosity as a result of shearing of the viscosity additives under high loads. The article discusses the important problem of oil aging during operation and the impact of this phenomenon on the operation of internal combustion engines. The influence of oil service life and its replacement on the emission of toxic exhaust gas components was discussed, and the results of research on the effect of oil service life on changes in their viscosity were presented.


Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6360
Author(s):  
Alberto Benato ◽  
Alarico Macor

The anaerobic digestion of biodegradable substrates and waste is a well-known process that can be used worldwide to produce a renewable fuel called biogas. At the time of writing, the most widespread way of using biogas is its direct usage in combined heat and power internal combustion engines (CHP-ICEs) to generate electricity and heat. However, the combustion process generates emissions, which in turn have an impact on human health. Therefore, there is a need to: (i) measure the ICE emissions (both regulated and unregulated), (ii) compute the impact on human health, (iii) identify the substances with the highest impact and (iv) calculate the avoided damage to human health per Euro of investment in technology able to abate the specific type of pollutant. To this end, the authors conducted an experimental campaign and selected as a test case a 999 kWel biogas internal combustion engine. Then, the collected data, which included both regulated and unregulated emissions, were used to calculate the harmfulness to human health and identify the more impactful compounds. Thus, combining the results of the impact analysis on human health and the outcomes of a market analysis, the avoided damage to human health per Euro of investment in an abatement technology was computed. In this manner, a single parameter, expressed in DALY -1, provided clear information on the costs to reduce each disability-adjusted life year (DALY). The impact analysis on human health, which was performed using the Health Impact Assessment, showed that NOx was the main contributor to damage to human health (approximately 91% of the total), followed by SOx (6.5%), volatile organic compounds (1.4%) and CO (0.7%). Starting from these outcomes, the performed investigation showed that the technology that guarantees the maximum damage reduction per unit of cost is the denitrification system or the oxidizing converter, depending on whether the considered plant is already in-operation or newly built. This is an unexpected conclusion considering that the most impacting emission is the NOx.


2021 ◽  
Vol 2094 (5) ◽  
pp. 052017
Author(s):  
A V Egorov ◽  
Yu F Kaizer ◽  
A V Lysyannikov ◽  
R B Zhelukevich ◽  
A V Kuznetsov ◽  
...  

Abstract Reducing carbon dioxide emissions by passenger vehicles allows you to achieve the use of electric power plants and hybrid power plants made on the basis of thermal internal combustion engines and electric machines. However, the application of the above-mentioned approach for trucks is associated with significant difficulties due to the low specific capacity of the chemical current sources currently used. The recovery of braking energy of cargo vehicles in the pneumatic form is constrained by the need to achieve a high speed of switching on the pneumatic recuperator. In order to minimize the energy losses of the pneumatic recuperator during acceleration and steady-state. Without changing the design and reducing the reliability of the internal combustion engine, it is possible to supply air to its inlet at pressures not exceeding 350 kPa. When air is supplied to the internal combustion engine inlet at pressures of 200 and 300 kPa, it is possible to reduce specific carbon dioxide emissions by 16 and 37 % per unit of generated mechanical energy, respectively, compared to air supply under normal atmospheric conditions.


2016 ◽  
Vol 23 (4) ◽  
pp. 67-72
Author(s):  
Marek Dzida ◽  
Jerzy Girtler

Abstract An evaluation proposal (quantitative determination) of any combustion turbine engine operation has been presented, wherein the impact energy occurs at a given time due to Energy conversion. The fact has been taken into account that in this type of internal combustion engines the energy conversion occurs first in the combustion chambers and in the spaces between the blade of the turbine engine. It was assumed that in the combustion chambers occurs a conversion of chemical energy contained in the fuel-air mixture to the internal energy of the produced exhaust gases. This form of energy conversion has been called heat. It was also assumed that in the spaces between the blades of the rotor turbine, a replacement occurs of part of the internal energy of the exhaust gas, which is their thermal energy into kinetic energy conversion of its rotation. This form of energy conversion has been called the work. Operation of the combustion engine has been thus interpreted as a transmission of power receivers in a predetermined time when there the processing and transfer in the form (means) of work and heat occurs. Valuing the operation of this type of internal combustion engines, proposed by the authors of this article, is to determine their operation using physical size, which has a numerical value and a unit of measurement called joule-second [joule x second]. Operation of the combustion turbine engine resulting in the performance of the turbine rotor work has been presented, taking into account the fact that the impeller shaft is connected to the receiver, which may be a generator (in the case of one-shaft engine) or a propeller of the ship (in the case of two or three shaft engine).


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 996
Author(s):  
Venera Giurcan ◽  
Codina Movileanu ◽  
Adina Magdalena Musuc ◽  
Maria Mitu

Currently, the use of fossil fuels is very high and existing nature reserves are rapidly depleted. Therefore, researchers are turning their attention to find renewable fuels that have a low impact on the environment, to replace these fossil fuels. Biogas is a low-cost alternative, sustainable, renewable fuel existing worldwide. It can be produced by decomposition of vegetation or waste products of human and animal biological activity. This process is performed by microorganisms (such as methanogens and sulfate-reducing bacteria) by anaerobic digestion. Biogas can serve as a basis for heat and electricity production used for domestic heating and cooking. It can be also used to feed internal combustion engines, gas turbines, fuel cells, or cogeneration systems. In this paper, a comprehensive literature study regarding the laminar burning velocity of biogas-containing mixtures is presented. This study aims to characterize the use of biogas as IC (internal combustion) engine fuel, and to develop efficient safety recommendations and to predict and reduce the risk of fires and accidental explosions caused by biogas.


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