scholarly journals Regularities of hydrogen accumulation and distribution in titanium coatings formed on a steel substrate by the cathode-arc method

2021 ◽  
Vol 77 (2) ◽  
Author(s):  
A.V. Kopyrina ◽  
A.S. Abdyr
Keyword(s):  
Steel Substrate ◽  
Titanium Coatings ◽  
Hydrogen Accumulation ◽  
Cathode Arc

scholarly journals On the Mechanism of Formation of Conversion Titanium-Containing Coatings

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 328 ◽  
Author(s):  
Aleksey Abrashov ◽  
Nelya Grigoryan ◽  
Tigran Vagramyan ◽  
Naum Asnis
Keyword(s):  
Steel Substrate ◽  
Titanium Oxides ◽  
Active Centers ◽  
Continuous Film ◽  
Solution Flow ◽  
Linear Rate ◽  
Titanium Coatings ◽  
First Time ◽  
Aluminum Surfaces ◽  
Hydrolysis Of

The present work is devoted to the study of the mechanism of the process of formation of adhesive oxide-titanium coatings on steel, zinc, and aluminum surfaces. For the first time, the following hypothesis has been confirmed experimentally, namely, that nickel, being the first metal to be deposited on a steel substrate, creates active centers on which titanium oxides are formed, because the hydrolysis of hexafluorotitanic acid is adsorbed, which then form a continuous film. The data obtained, regarding the dependence of the coating thickness on the linear rate of the solution flow along the treated surface, indirectly confirm that the formation of insoluble titanium oxides occurs because of the alkalization of the solution adjacent to the surface. It has been established that in the presence of hexavalent molybdenum compounds in the solution as oxidizers, molybdenum is included in the coating in the form of oxides. It has been revealed that in the lower layers of the coating, molybdenum is contained in the form of compounds of molybdenum (V) and (VI), while in the upper layers, it is contained only in the form of the compound of molybdenum (VI).

Vibration based Energy Harvester Employing ZnO Film on the Stainless Steel Substrate

2013 ◽  
Vol 133 (4) ◽  
pp. 126-127 ◽  
Author(s):  
Shota Hosokawa ◽  
Motoaki Hara ◽  
Hiroyuki Oguchi ◽  
Hiroki Kuwano
Keyword(s):  
Stainless Steel ◽  
Energy Harvester ◽  
Stainless Steel Substrate ◽  
Steel Substrate ◽  
Zno Film

Wear behavior of laser cladded WC-FeAl coating on 321 stainless steel substrate

2020 ◽  
Vol 32 (4) ◽  
pp. 042015
Author(s):  
Alireza Mostajeran ◽  
Reza Shoja-Razavi ◽  
Morteza Hadi ◽  
Mohammad Erfanmanesh ◽  
Hadi Karimi
Keyword(s):  
Stainless Steel ◽  
Stainless Steel Substrate ◽  
Wear Behavior ◽  
Steel Substrate

A Practical Ultrasonic Inspection Method for Detecting and Characterising Defects Found Within Composite Repairs

2018 ◽  
Author(s):  
J Downing ◽  
A Hook
Keyword(s):  
Wall Thickness ◽  
Steel Substrate ◽  
Ultrasonic Method ◽  
Ultrasonic Inspection ◽  
Heat Exposure ◽  
Matrix Cracking ◽  
Ultrasonic Technique ◽  
Inspection Method ◽  
Composite Repairs ◽  
Layered Matrix

Two steel substrate test panels were developed to represent common plate thicknesses found on naval vessels and scanned using the Babcock developed ultrasonic technique. One sample comprised of a series of slotted surface breaking flaws of varying widths and through thicknesses to represent fracturing/cracking. The inspection method detected simulated cracking to a depth of 2mm and 0.5mm in width. The second sample included numerous loss of wall thickness areas of varying diameters and through thicknesses, with the smallest detectable loss of wall thickness being 0.1mm at a 15mm diameter. After proving confidence in detection, there was a need to characterise flaws to provide support and ascertain a repair action. Samples were produced that were subjected to either impact or heat exposure to induce realistic representative damage. The practical ultrasonic method was successfully used to independently characterise between the samples, with induced de-laminations caused by blisters, and multi layered matrix cracking caused by varying levels of projectile impacts, due to their unique morphology.

The study of the electrochemical properties of zinc-rich coating on the base of water sodium silicate

2019 ◽  
Vol 24 (4) ◽  
pp. 51-58
Author(s):  
Le Hong Quan ◽  
Nguyen Van Chi ◽  
Mai Van Minh ◽  
Nong Quoc Quang ◽  
Dong Van Kien
Keyword(s):  
Carbon Steel ◽  
Electrochemical Properties ◽  
Sodium Silicate ◽  
Cathodic Protection ◽  
Electrochemical Impedance ◽  
Steel Substrate ◽  
Electrical Contact ◽  
Electrochemical Impedance Spectra ◽  
Pure Zinc ◽  
Electric Circuits

The study examines the electrochemical properties of a coating based on water sodium silicate and pure zinc dust (ZSC, working title - TTL-VN) using the Electrochemical Impedance Spectra (EIS) with AutoLAB PGSTAT204N. The system consists of three electrodes: Ag/AgCl (SCE) reference electrode in 3 M solution of KCl, auxiliary electrode Pt (8x8 mm) and working electrodes (carbon steel with surface treatment up to Sa 2.5) for determination of corrosion potential (Ecorr) and calculation of equivalent electric circuits used for explanation of impedance measurement results. It was shown that electrochemical method is effective for study of corrosion characteristics of ZSC on steel. We proposed an interpretation of the deterioration over time of the ability of zinc particles in paint to provide cathodic protection for carbon steel. The results show that the value of Ecorr is between -0,9 and -1,1 V / SCE for ten days of diving. This means that there is an electrical contact between the zinc particles, which provides good cathodic protection for the steel substrate and most of the zinc particles were involved in the osmosis process. The good characteristics of the TTL-VN coating during immersion in a 3,5% NaCl solution can also be explained by the preservation of corrosive zinc products in the coating, which allows the creation of random barrier properties.

scholarly journals Investigation of Multiparameter Laser Stripping of AlTiN and DLC C Coatings

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 951
Author(s):  
Tomáš Primus ◽  
Josef Hlavinka ◽  
Pavel Zeman ◽  
Jan Brajer ◽  
Martin Šorm ◽  
...  
Keyword(s):  
Surface Roughness ◽  
High Efficiency ◽  
Steel Substrate ◽  
Cutting Tools ◽  
High Hardness ◽  
Working Time ◽  
Nanosecond Laser ◽  
Altin Coating ◽  
Successful Removal ◽  
Frequency Laser

The lifetime and properties of cutting tools and forming moulds can be prolonged and enhanced by the deposition of hard, thin coatings. After a certain period of usage, the coating will deteriorate. Any remaining coating must be removed prior to successful recoating. Laser stripping is a fast and environmentally friendly coating removal method. In this paper, we present laser removal of two types of coatings deposited on a 1.2379 tool steel substrate, namely, an AlTiN coating with high hardness and a DLC C coating with a small coefficient of friction (COF). A powerful nanosecond laser was employed to remove the coating from the substrate with high efficiency, along with suitable residual surface roughness. Measurements were taken of surface roughness, removed depth, and working time on a stripped area of 1 cm2. The samples were evaluated under a microscope, with a 3D profilometer, and by EDS chemical analysis. Successful removal of the coating was confirmed by optical analysis, but detailed chemical characterisation showed that about 30% of the coating element may remain on the surface. Moreover, a working time of less than 7.5 s per cm2 was obtained in this study. In addition, it was shown that the application of a second low energy, high frequency laser beam pass leads to remelting of the peaks of the material and reduced surface roughness.

scholarly journals Semi-Hybrid CO2 Laser Metal Deposition Method with Inter Substrate Buffer Zone

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 720
Author(s):  
Bogdan Antoszewski ◽  
Hubert Danielewski ◽  
Jan Dutkiewicz ◽  
Łukasz Rogal ◽  
Marek St. Węglowski ◽  
...  
Keyword(s):  
Structural Steel ◽  
Co2 Laser ◽  
Hybrid Method ◽  
Steel Substrate ◽  
Metal Deposition ◽  
Inconel 625 ◽  
Metallographic Analysis ◽  
Deposition Method ◽  
High Alloy ◽  
Powder Deposition

This article presents the results of the metal deposition process using additive materials in the form of filler wire and metal powder. An important problem in wire deposition using a CO2 laser was overcome by using a combination of the abovementioned methods. The deposition of a multicomponent alloy—Inconel 625—on a basic substrate such as structural steel is presented. The authors propose a new approach for stopping carbon and iron diffusion from the substrate, by using the Semi-Hybrid Deposition Method (S-HDM) developed by team members. The proposed semi-hybrid method was compared with alternative wire and powder deposition using laser beam. Differences of S-HDM and classic wire deposition and powder deposition methods are presented using metallographic analysis, within optic and electron microscopy. Significant differences in the obtained results reveal advantages of the developed method compared to traditional deposition methods. A comparison of the aforementioned methods performed using nickel based super alloy Inconel 625 deposited on low carbon steel substrate is presented. An alternative prototyping approach for an advanced high alloy materials deposition using CO2 laser, without the requirement of using the same substrate was presented in this article. This study confirmed the established assumption of reducing selected components diffusion from a substrate via buffer layer. Results of metallographic analysis confirm the advantages and application potential of using the new semi-hybrid method for prototyping high alloy materials on low alloy structural steel substrate.

Processing strategy for high strength Ni-based hybrid composite clad on SS 316L steel through microwave heating

2021 ◽  
pp. 095440542110213
Author(s):  
Sarbjeet Kaushal ◽  
Satnam Singh ◽  
Dheeraj Gupta
Keyword(s):  
Sliding Wear ◽  
Steel Surface ◽  
Steel Substrate ◽  
Microstructural Analysis ◽  
High Strength ◽  
Phase Changes ◽  
Microwave Exposure ◽  
Pull Out ◽  
316L Steel ◽  
Microwave Applicator

Processing of nickel-based high strength composites and alloys is a difficult and thought-provoking task. In this work, a strategy of heating through microwaves radiation is utilized to process the high strength hybrid Ni-based composite clad on SS 316L steel surface containing 15% (WC-8Co) and 5% Mo. The premixed composite powder was placed on the steel surface and irradiated with domestic microwave applicator having 2.45 GHz fixed frequency and 900 W power. The hybrid clad was successfully developed within 12–15 min of microwave exposure. The processed clad was subjected to various metallurgical and mechanical characterizations to understand the microstructures and phase changes. Microstructural analysis study revealed that the clad of ∼0.85 mm thickness was obtained and presence of dispersed reinforced particles of WC-8Co and Mo in nickel matrix were observed. Some inter-metallic phases of W2C, Ni2Mo4C, Ni4W and NiSi2 were observed in the clad. The average microhardness of the composite clad was712 ± 58 HV. The microwave processed clad exhibited a flexural strength of 852 ± 6 MPa with deformation index of 35 × 10−5 mm/N. Further, the sliding wear study revealed that the sliding velocity of 1.0 m/s favoured the formation of oxide tribo layers. The various mechanisms of wear revealed by the analysis of worn-out surfaces were abrasion, adhesion, surface pull-out and deformation of surfaces. The microwave processed clad revealed significant improvement in wear resistance in comparison to the steel substrate.

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