scholarly journals Mathematical modelling of formation process for multi-layer 3D structure produced by additive method using arc heat sources

2019 ◽  
Vol 91 (7) ◽  
pp. 45-54
Author(s):  
Walery A. Kostin ◽  
Georgy M. Grigorenko ◽  
Viktor A. Shapovalov ◽  
Alexandr N. Pikulin
Keyword(s):  
Computer Modelling ◽  
Layer Structure ◽  
3D Structure ◽  
Structural Transformations ◽  
Temperature Fields ◽  
Effect Of Temperature ◽  
Maximum Temperature ◽  
Physical Parameters ◽  
Heat Sources ◽  
Kinetics Of

The results of modelling of temperature fields, kinetics of deposition of layers of dissimilar metals and nature of structural transformations in formation of multi-layer structure of 17G1S and 30KhGS steels are presented. Computer modelling was performed using COMSOL Multiphysics software package. The work takes into account effect of temperature on thermal and physical parameters of steels. To increase productivity of additive process the work has studied simultaneous effect of 3 arcs on process of deposit formation, kinetics of structural transformations and diffusion processes of alloying elements redistribution. The calculations show that preheating of the substrate by arc in the beginning of the process before application of deposited material is necessary in order to decrease a stress level between additive deposit and substrate to 50 MPa. It is shown that the time of passing between neighbor arc heat sources shall be kept in 5- 30 s range. It is determined that low power of arc (1 kW) mainly provokes formation of ferrite-bainite structure in the deposit, portion of bainite in which makes 71 %, ferrite 28% and martensite ~ 1%. Application of larger power arc (5 kW) forms in the deposit bainite-martensite structure, portion of bainite in which makes ~  50%, portion of martensite rises up to 40% and that of ferrite to 10%. Increase of arc power results in rise of maximum temperature of liquid pool to 1750-1850 °C, growth of cooling rate to 15 – 25 °C/s , and, as a consequence, increase of martensite portion in the structure of deposited layers. 

Visualizing 3D Molecular Structures Using an Augmented Reality App

2019 ◽  
Author(s):  
Kristina Eriksen ◽  
Bjarne Nielsen ◽  
Michael Pittelkow
Keyword(s):  
Augmented Reality ◽  
Small Molecules ◽  
Computer Modelling ◽  
Simple Procedure ◽  
3D Structure ◽  
Molecular Structures ◽  
Free Software ◽  
Programming Skills ◽  
2D Space ◽  
Made In

<p>We present a simple procedure to make an augmented reality app to visualize any 3D chemical model. The molecular structure may be based on data from crystallographic data or from computer modelling. This guide is made in such a way, that no programming skills are needed and the procedure uses free software and is a way to visualize 3D structures that are normally difficult to comprehend in the 2D space of paper. The process can be applied to make 3D representation of any 2D object, and we envisage the app to be useful when visualizing simple stereochemical problems, when presenting a complex 3D structure on a poster presentation or even in audio-visual presentations. The method works for all molecules including small molecules, supramolecular structures, MOFs and biomacromolecules.</p>

Temperature Effect on the Two-Dimensional Phase Transition Kinetics of Adenine Adsorbed at the Hg Electrode/Aqueous Solution Interface

2003 ◽  
Vol 68 (8) ◽  
pp. 1407-1419 ◽  
Author(s):  
Claudio Fontanesi ◽  
Roberto Andreoli ◽  
Luca Benedetti ◽  
Roberto Giovanardi ◽  
Paolo Ferrarini
Keyword(s):  
Phase Transition ◽  
Aqueous Solution ◽  
Phase Change ◽  
Temperature Effect ◽  
Transition Rate ◽  
Effect Of Temperature ◽  
Two Dimensional ◽  
Solution Interface ◽  
Phase Transition Kinetics ◽  
Kinetics Of

The kinetics of the liquid-like → solid-like 2D phase transition of adenine adsorbed at the Hg/aqueous solution interface is studied. Attention is focused on the effect of temperature on the rate of phase change; an increase in temperature is found to cause a decrease of transition rate.

scholarly journals A Novel Pseudomonas geniculata AGE Family Epimerase/Isomerase and Its Application in d-Mannose Synthesis

Foods ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 1809
Author(s):  
Zhanzhi Liu ◽  
Ying Li ◽  
Jing Wu ◽  
Sheng Chen
Keyword(s):  
3D Structure ◽  
Three Dimensional ◽  
Optimal Temperature ◽  
Reaction Conditions ◽  
Enzymatic Production ◽  
Physiological Properties ◽  
Potential Applications ◽  
Kinetics Of ◽  
Optimal Reaction ◽  
Gene Age

d-mannose has exhibited excellent physiological properties in the food, pharmaceutical, and feed industries. Therefore, emerging attention has been applied to enzymatic production of d-mannose due to its advantage over chemical synthesis. The gene age of N-acetyl-d-glucosamine 2-epimerase family epimerase/isomerase (AGEase) derived from Pseudomonas geniculata was amplified, and the recombinant P. geniculata AGEase was characterized. The optimal temperature and pH of P. geniculata AGEase were 60 °C and 7.5, respectively. The Km, kcat, and kcat/Km of P. geniculata AGEase for d-mannose were 49.2 ± 8.5 mM, 476.3 ± 4.0 s−1, and 9.7 ± 0.5 s−1·mM−1, respectively. The recombinant P. geniculata AGEase was classified into the YihS enzyme subfamily in the AGE enzyme family by analyzing its substrate specificity and active center of the three-dimensional (3D) structure. Further studies on the kinetics of different substrates showed that the P. geniculata AGEase belongs to the d-mannose isomerase of the YihS enzyme. The P. geniculata AGEase catalyzed the synthesis of d-mannose with d-fructose as a substrate, and the conversion rate was as high as 39.3% with the d-mannose yield of 78.6 g·L−1 under optimal reaction conditions of 200 g·L−1d-fructose and 2.5 U·mL−1P. geniculata AGEase. This novel P. geniculata AGEase has potential applications in the industrial production of d-mannose.

A STUDY OF THE MECHANISM AND KINETICS OF THE SULPHITE PROCESS

1939 ◽  
Vol 17b (4) ◽  
pp. 121-132 ◽  
Author(s):  
J. M. Calhoun ◽  
F. H. Yorston ◽  
O. Maass
Keyword(s):  
Temperature Coefficient ◽  
Arrhenius Equation ◽  
Practical Interest ◽  
Effect Of Temperature ◽  
Wood Meal ◽  
Spruce Wood ◽  
Mechanism And Kinetics ◽  
Kinetics Of

The rate of delignification of resin extracted spruce wood-meal has been determined in calcium-base sulphite liquor at temperatures from 130 °C. down to 50 °C. No break was found in the temperature coefficient curve at the lower temperatures, the reaction following the Arrhenius equation closely. Possible mechanisms of the reaction are discussed in the light of existing theories, and the effect of temperature on the yield of pulp is pointed out for its practical interest.

Development of Convective Heat Transfer Near Suddenly Heated, Vertically Aligned Horizontal Wires

1987 ◽  
Vol 109 (4) ◽  
pp. 912-918 ◽  
Author(s):  
J. R. Parsons ◽  
M. L. Arey
Keyword(s):  
Heat Transfer ◽  
Heat Source ◽  
Fluid Layer ◽  
Convective Motion ◽  
Transient Behavior ◽  
Temperature Fields ◽  
Heat Sources ◽  
Transfer Coefficients ◽  
Vertically Aligned ◽  
The Wire

Experiments have been performed which describe the transient development of natural convective flow from both a single and two vertically aligned horizontal cylindrical heat sources. The temperature of the wire heat sources was monitored with a resistance bridge arrangement while the development of the flow field was observed optically with a Mach–Zehnder interferometer. Results for the single wire show that after an initial regime where the wire temperature follows pure conductive response to a motionless fluid, two types of fluid motion will begin. The first is characterized as a local buoyancy, wherein the heated fluid adjacent to the wire begins to rise. The second is the onset of global convective motion, this being governed by the thermal stability of the fluid layer immediately above the cylinder. The interaction of these two motions is dependent on the heating rate and relative heat capacities of the cylinder and fluid, and governs whether the temperature response will exceed the steady value during the transient (overshoot). The two heat source experiments show that the merging of the two developing temperature fields is hydrodynamically stabilizing and thermally insulating. For small spacing-to-diameter ratios, the development of convective motion is delayed and the heat transfer coefficients degraded by the proximity of another heat source. For larger spacings, the transient behavior approaches that of a single isolated cylinder.

Thermo-Solutal Convection of a Nanofluid Utilizing Fourier’s-Type Compass Conditions

2020 ◽  
Vol 9 (4) ◽  
pp. 362-374
Author(s):  
J. C. Umavathi ◽  
Ali J. Chamkha
Keyword(s):  
Brownian Motion ◽  
Prandtl Number ◽  
Boundary Conditions ◽  
Volume Fraction ◽  
Temperature Fields ◽  
Physical Parameters ◽  
Surface Boundary ◽  
Perturbation Scheme ◽  
Runge Kutta ◽  
The Impact

Nanotechnology has infiltrated into duct design in parallel with many other fields of mechanical, medical and energy engineering. Motivated by the excellent potential of nanofluids, a subset of materials engineered at the nanoscale, in the present work, a new mathematical model is developed for natural convection in a vertical duct containing nanofluid. Numerical scrutiny for the double-diffusive free and forced convection within a duct encumbered with nanofluid is performed. Buongiorno’s model is deployed to define the nanofluid. Robin boundary conditions are used to define the surface boundary conditions. Thermal and concentration equations envisage the viscous, Brownian motion, thermosphores of the nanofluid, Soret and Dufour effects. Using the Boussi-nesq approximation the solutal buoyancy effect as a result of gradients in concentration are incorporated. The conservation equations which are nonlinear are numerically estimated using fourth order Runge-Kutta methodology and analytically ratifying regular perturbation scheme. The mass, heat, nanoparticle concentration and species concentration fields on eight dimensionless physical parameters such as thermal and mass Grashof numbers, Brownian motion parameter, thermal parameter, Prandtl number, Eckert number, Schmidt parameter, and Soret parameter are calculated. The impact of these parameters are outlined pictorially. The velocity and temperature fields are boosted with the thermal Grashof number. The Soret and the Schemidt parameters reduces the nanoparticle volume fraction but it heightens the momentum, temperature and concentration. At the cold wall thermal and concentration Grashof numbers reduces the Nusselt values but they increase the Nusselt values at the hot wall. The reversal consequence was attained at the hot plate. The perturbation and Runge-Kutta solutions are equal in the nonappearance of Prandtl number. The (E. Zanchini, Int. J. Heat Mass Transfer 41, 3949 (1998)). results are restored for the regular fluid. The heat transfer rate is high for nanofluid when matched with regular fluid.

Effect of temperature and pH on the production, activity, and stability of α-amylase from Bacillus subtilis V37

2021 ◽  
Vol 66 (1) ◽  
pp. 72-79
Author(s):  
Thuoc Doan Van ◽  
Hung Nguyen Phuc
Keyword(s):  
Enzyme Activity ◽  
Bacillus Subtilis ◽  
Animal Feed ◽  
Culture Conditions ◽  
Effect Of Temperature ◽  
Physical Parameters ◽  
Original Activity ◽  
Optimum Ph ◽  
Production Activity ◽  
Ph Range

The effect of physical parameters such as temperature and pH on the production, activity, and stability of α-amylase from Bacillus subtilis V37 was investigated. The results indicated that the optimum culture conditions for enzyme activity were pH 7.0 and 35 oC. The optimum pH and temperature for enzyme activity were 6.0 and 70 oC. The crude enzyme was found to be stable in the pH range of 5.0 to 7.0. The enzyme was stable for 1 h at a temperature from 30 to 80 oC; nearly 100% of enzyme activity remained at temperatures of 30 - 40 oC, and about 34% of original activity remained at a temperature of 80 oC. These features demonstrated that α-amylase from B. subtilis V37 can be applied in many areas such as the food, fermentation, and animal feed industries.

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