scholarly journals The influence of uncontrolled technological impurities on the temperature dependence of the gain coefficient of a bipolar n-p-n-transistor

Author(s):  
V. B. Odzaev ◽  
A. N. Pyatlitski ◽  
V. A. Pilipenko ◽  
U. S. Prosolovich ◽  
V. A. Filipenia ◽  
...  

Herein, the temperature dependences of the static current gain (β) of bipolar n-p-n-transistors, formed by similar process flows (series A and B), in the temperature range 20–125 °С was investigated. The content of uncontrolled technological impurities in the A series devices was below the detection limit by the TXRF method (for Fe < 4.0 · 109 at/cm2). In series B devices, the entire surface of the wafers was covered with a layer of Fe with an average concentration of 3.4 ∙ 1011 at/cm2; Cl, K, Ca, Ti, Cr, Cu, Zn spots were also observed. It was found that in B series devices at an average collector current level (1.0 ∙ 10–6 < Ic <1.0 ∙ 10–3 A) the static current gain was greater than the corresponding value in A series devices. This was due to the higher efficiency of the emitter due to the high concentration of the main dopant. This circumstance also determined a stronger temperature dependence of β in series B devices due to a significant contribution to its value from the temperature change in the silicon band gap. At Ic < 1.0 ∙ 10–6 A β for B series devices became significantly less than the corresponding values for A series devices and practically ceases to depend on temperature. In series B devices, the recombination-generation current prevailed over the useful diffusion current of minority charge carriers in the base due to the presence of a high concentration of uncontrolled technological impurities. For A series devices at Ic < 10–6 A, the temperature dependence of β practically did not differ from the analogous dependence for the average injection level.

2010 ◽  
Vol 645-648 ◽  
pp. 1061-1064
Author(s):  
Benedetto Buono ◽  
Reza Ghandi ◽  
Martin Domeij ◽  
Bengt Gunnar Malm ◽  
Carl Mikael Zetterling ◽  
...  

The current gain of 4H-SiC BJTs has been modeled using interface traps between SiC and SiO2 to describe surface recombination, by a positive temperature dependence of the carrier lifetime in the base region and by bandgap narrowing in the emitter region. The interface traps have been modeled by one single level at 1 eV above the valence band, with capture cross section of 1 × 10-15 cm2 and concentration of 2 × 1012 cm-2. The temperature behavior of SiC BJTs has been simulated and the results have been compared with measurements. An analysis of the carrier concentration has been performed in order to describe the mechanisms for fall-off of the current gain at high collector current. At room temperature high injection in the base and forward biasing of the base-collector junction occur simultaneously causing an abrupt drop of the current gain. At higher temperatures high injection in the base is alleviated by the higher ionization degree of the aluminum dopants, and then forward biasing of the base-collector junction is the only acting mechanism for the current gain fall-off at high collector current. This mechanism and the negative temperature dependence of the carrier mobility can also explain the reduction of the knee current for gain fall-off with increasing temperature. Simulations with different emitter widths have been also performed and analyzed to characterize the emitter size effect. Higher current density caused by reducing the emitter width introduces higher carrier recombination in the emitter region, leading to a reduction of the current gain.


1993 ◽  
Vol 58 (2) ◽  
pp. 234-243 ◽  
Author(s):  
Viliam Klimo ◽  
Martina Bittererová ◽  
Stanislav Biskupič ◽  
Ján Urban ◽  
Miroslav Micov

The reaction O + OH → O2 + H in conditions of combustion of hydrocarbons and polymers was modelled by using the method of quasiclassical trajectories. The potential energy surface was determined by the multiconfiguration interaction method and fitted with the analytical form of the extended LEPS function. Attention was paid to the mean values of the vibrational and rotational quantum numbers of O2 molecules and their temperature dependence. The temperature dependence of the mean lifetime of the OOH collision complex was also examined. The calculated rate constants were analyzed and compared with the experimental data over the temperature region of the combustion processes.


1974 ◽  
Vol 29 (1) ◽  
pp. 145-157 ◽  
Author(s):  
Tetsuhiko Tomiki ◽  
Takeo Miyata ◽  
Hirokazu Tsukamoto

Phenomenological and physical aspects of the intrinsic tail spectra of the alkalihalides are studied referring to the new results on the intrinsic tail spectra of KBr and KI and to the temperature dependences of the lowest-energy Γ-exciton peak of the sodium- and potassium-halides. Systematically analysing the temperature dependence of the steepness parameter σs (T) of the Urbach rule for these halides, it is found that the frequency factor has the value nearly equal to the acoustic phonon energy at X or L of each host lattice and the steepness constant σs0 becomes larger in passing from fluoride to iodide. This halogen dependence of σs0 is discussed in terms of the hole band-mass of the Γ8-level.


2006 ◽  
Vol 53 (5) ◽  
pp. 1245-1249 ◽  
Author(s):  
P.A. Ivanov ◽  
M.E. Levinshtein ◽  
A.K. Agarwal ◽  
S. Krishnaswami ◽  
J.W. Palmour

2005 ◽  
Vol 483-485 ◽  
pp. 889-892 ◽  
Author(s):  
Martin Domeij ◽  
Erik Danielsson ◽  
Hyung Seok Lee ◽  
Carl Mikael Zetterling ◽  
Mikael Östling

The current gain (b) of 4H-SiC BJTs as function of collector current (IC) has been investigated by DC and pulsed measurements and by device simulations. A measured monotonic increase of b with IC agrees well with simulations using a constant distribution of interface states at the 4H-SiC/SiO2 interface along the etched side-wall of the base-emitter junction. Simulations using only bulk recombination, on the other hand, are in poor agreement with the measurements. The interface states degrade the simulated current gain by combined effects of localized recombination and trapped charge that influence the surface potential. Additionally, bandgap narrowing has a significant impact by reducing the peak current gain by about 50 % in simulations.


2004 ◽  
Vol 808 ◽  
Author(s):  
Yue Kuo ◽  
Yu Lei ◽  
Helinda Nominanda

ABSTRACTThe conventional a-Si:H thin film transistor (TFT) is a field effect transistor (FET), which has disadvantages of a low operation speed and a small current driving capability. To achieve a higher speed and larger current driving capability, a potential solution is to fabricate the a-Si:H-based bipolar thin film transistor (B-TFT). In this study, a-Si:H p-i-n junctions were prepared and studied in order to determine the proper layer thickness for good junction behaviors. B-TFTs composed of a stacked structure of n+/i/p/i/n+ were then fabricated. The complete B-TFT was made using plasma enhanced chemical vapor deposition (PECVD) to deposit all doped and undoped a-Si:H layers and SiNx dielectrics at 250°C. Reactive ion etching (RIE) and wet etching methods were used to define base and emitter regions and contacts. The I-V characteristics of the complete B-TFT were investigated. The common-emitter current gain is 3∼6, which is larger than the literature report of 2∼3. In addition, a collector current larger than the literature value was obtained. A significant current noise was observed, which may be contributed to the high series resistance of the base layer and defective junction interfaces. In this paper, process and structure influences on the a-Si:H junction and B-TFT performances are discussed.


2006 ◽  
Vol 361 (1472) ◽  
pp. 1307-1315 ◽  
Author(s):  
Lin Wang ◽  
Nina M Goodey ◽  
Stephen J Benkovic ◽  
Amnon Kohen

Residues M42 and G121 of Escherichia coli dihydrofolate reductase ( ec DHFR) are on opposite sides of the catalytic centre (15 and 19 Å away from it, respectively). Theoretical studies have suggested that these distal residues might be part of a dynamics network coupled to the reaction catalysed at the active site. The ec DHFR mutant G121V has been extensively studied and appeared to have a significant effect on rate, but only a mild effect on the nature of H-transfer. The present work examines the effect of M42W on the physical nature of the catalysed hydride transfer step. Intrinsic kinetic isotope effects (KIEs), their temperature dependence and activation parameters were studied. The findings presented here are in accordance with the environmentally coupled hydrogen tunnelling. In contrast to the wild-type (WT), fluctuations of the donor–acceptor distance were required, leading to a significant temperature dependence of KIEs and deflated intercepts. A comparison of M42W and G121V to the WT enzyme revealed that the reduced rates, the inflated primary KIEs and their temperature dependences resulted from an imperfect potential surface pre-arrangement relative to the WT enzyme. Apparently, the coupling of the enzyme's dynamics to the reaction coordinate was altered by the mutation, supporting the models in which dynamics of the whole protein is coupled to its catalysed chemistry.


2010 ◽  
Vol 645-648 ◽  
pp. 1025-1028 ◽  
Author(s):  
Qing Chun Jon Zhang ◽  
Robert Callanan ◽  
Anant K. Agarwal ◽  
Albert A. Burk ◽  
Michael J. O'Loughlin ◽  
...  

4H-SiC Bipolar Junction Transistors (BJTs) and hybrid Darlington Transistors with 10 kV/10 A capability have been demonstrated for the first time. The SiC BJT (chip size: 0.75 cm2 with an active area of 0.336 cm2) conducts a collector current of 10 A (~ 30 A/cm2) with a forward voltage drop of 4.0 V (forced current gain βforced: 20) corresponding to a specific on-resistance of ~ 130 mΩ•cm2 at 25°C. The DC current gain, β, at a collector voltage of 15 V is measured to be 28 at a base current of 1 A. Both open emitter breakdown voltage (BVCBO) and open base breakdown voltage (BVCEO) of ~10 kV have been achieved. The 10 kV SiC Darlington transistor pair consists of a 10 A SiC BJT as the output device and a 1 A SiC BJT as the driver. The forward voltage drop of 4.5 V is measured at 10 A of collector current. The DC forced current gain at the collector voltage of 5.0 V was measured to be 440 at room temperature.


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