scholarly journals Distinctive IR-Spectroscopic Features of Functional Groups of Low-Grade Phosphorites After Microbiological and Acid Processing

Land Science ◽  
2020 ◽  
Vol 2 (1) ◽  
pp. p43
Author(s):  
Ilkhom Tagaev ◽  
Nodirjon Doniyarov ◽  
Anvar Asrorov ◽  
Islom Murodov ◽  
N.KH. Usanbaev ◽  
...  

The article discusses the current problems of enrichment of low-grade phosphorites by the thermal method as well as the production of mineral fertilizers using various acids. An alternative biotechnological method for producing organomineral fertilizers using neutrophilic, heterotrophic microorganisms of activated sludge at a biochemical treatment station for municipal wastewater for the processing of low-grade phosphorites and the production of phosphorus-containing organomineral fertilizers is proposed.In this case, a natural acceleration of the processes of the phosphorus cycle in nature occurs, which does not pollute the environment. A comparative description of IR spectroscopic descriptions of the results of microbiological treatment and treatment with sulfuric and nitric acids showed distinctive characteristics of the appearance of functional groups, which showed the transfer of valuable phosphorus components during acid treatment to sediment and their irrevocable loss in the form of waste.The studies will serve the utilization of low-grade phosphorites unused in the production, the production of a new type of organomineral fertilizer using and recycling of human waste (in most countries, incinerated), will lead to a gradual improvement in the structural composition of soils.Human vital activity waste and low-grade phosphorites have zero cost, the applied technology of biochemical treatment of domestic wastewater is available in all major cities that can be used to enrich phosphorites with organic matter.

2020 ◽  
pp. 34-44
Author(s):  
Gergana Peeva ◽  
Ralitza Koleva ◽  
Maya Stancheva ◽  
Husein Yemendzhiev ◽  
Valentin Nenov

The paper gives information on the depletion of phosphorus (P) as an important element for all forms of life and its pollution impact on the environment in case of intensive discharge of phosphorus compounds into water bodies. Two secondary waste sources of Phosphorus are under consideration, namely the domestic wastewater and sludge and animal manure. The characteristics of these two fluids regarding organic matter and nutrient content are summarized. Discussing the techniques for P extraction mostly attention is given to phosphorus precipitation as ammonium magnesium phosphate (struvite). Examples of effectiveness of P precipitation as struvite in Municipal Wastewater Treatment Plants (MWWTPs) with chemical and biological P removal are presented. The examples of struvite production from sewage and manure waste show evidently the great potential of utilization of such a waste as a source of phosphorus. The recovered product is valuable both as it is a slow release fertilizer and with its low content of heavy metals compared to the mineral fertilizers. In respect of the diminishing amount of natural P rocks, the sewagec wastewater and sludge and the animal manure can be regarded as an important secondary source of Phosphorus.


Author(s):  
Ю.А. Егорова ◽  
В.И. Кичигин ◽  
О.И. Нестеренко ◽  
А.А. Юдин

Осадки городских очистных канализационных сооружений являются самым массовым технологическим отходом, создающим проблемы утилизации для любого города. Рассмотрены возможные методы обработки осадков сточных вод на городских очистных канализационных сооружениях городского округа Самара с целью их последующей утилизации. Обозначены причины и приведены документальные подтверждениянекорректности возложения ответственности за обращение с такими отходами только на организации водопроводно-канализационного хозяйства. Рассмотрен способ захоронения обезвоженного осадка сточных вод в обвалованном полигоне. Установлено, что обработанные на очистных сооружениях осадки относятся к V классу опасности для окружающей среды. Обработанные, стабилизированные, подсушенные, обезвреженные отходы осадков сточных вод (малоопасный осадок с песколовок при очистке хозяйственно-бытовых и смешанных сточных вод, практически не опасный осадок с песколовок при очистке хозяйственно-бытовых и смешанных сточных вод и избыточный ил биологических очистных сооружений в смеси с сырым осадком) могут быть использованы в качестве наполнителей бетонно-цементных смесей и органоминеральных удобрений или переданы для утилизации сторонним организациям. Sludge from the municipal wastewater treatment facilities is the most massive technological waste that causes trouble for any city. Possible methods of wastewater sludge treatment at the municipal wastewater treatment facilities of the Samara Urban District with the purpose of its further utilization are considered. The reasons are indicated and documentary evidence of the incorrectness of assigning the responsibility for processing such wastes only to the water and wastewater utilities is provided. The method of landfilling dewatered wastewater sludge in a ridged landfill is considered. It has been established that the sludge processed at the wastewater treatment facilities is referred to the V class of environmental hazard. Sludge subjected to the treatment, stabilization, drying and neutralization (low hazardous sludge from grit chambers for domestic and mixed wastewater treatment; almost non-hazardous sludge from grit chambers for domestic and mixed wastewater treatment and excess sludge from biological treatment facilities mixed with raw sludge) can be used as fillers for concrete-cement mixtures and organo-mineral fertilizers or transferred for disposal to outside companies.


Author(s):  
R. Edgecock ◽  
V. V. Bratishko ◽  
I. V. Zinchenko ◽  
S. H. Karpus ◽  
D. O. Milko ◽  
...  

Annotation Purpose. Summarize the regulatory and technological requirements for the production of organic (organo-mineral) fertilizers on the base of sewage sludge. Methods. Analysis and generalization of the requirements of regulatory documents on the management of organic waste and their use as raw materials for the production of organic fertilizers and soil improvers. Results. The current legislative, departmental and regulatory documentary base in Ukraine concerning the treatment of sediment resulting from biological sewage treatment at municipal wastewater treatment plants for its further use in agriculture as fertilizers is analysed. Indicators are identified and analysed to determine the possibility, feasibility, efficiency and scope of organic fertilizers produced using sewage sludge. The analysis of changes in the content of organic matter and total nitrogen in the sewage sludge during its storage at the sewage treatment plant sites is presented. The technological feasibility of using sludge of different shelf life in composting production has been determined. Conclusions 1. The regulatory framework of Ukraine contains a sufficiently complete list of indicators that should be met by organic raw materials (sewage sludge) for further use as organic fertilizers. Some of these indicators – bio security and heavy metals content – can be improved in the composting process of fertilizers. 2. Fresh sediment, as well as sediment accumulated in the last late autumn and winter periods, is of main value for use as a raw material in the production of organic fertilizers. 3. The use in the production of compost sludge stored on sludge sites for a period of half a year or more requires special control of the process of decontamination. In this case, it is advisable to use additional means of wastewater decontamination. Keywords: heavy metals, manure, humus, decontamination, composting, organic fertilizers, sewage sludge.


Author(s):  
R. VIJAYARAGAVAN ◽  
S. MULLAINATHAN ◽  
M. BALACHANDRAMOHAN ◽  
N. KRISHNAMOORTHY ◽  
S. NITHIYANANTHAM ◽  
...  

The usability of waste rock (rock residue) powder as an additive material in ceramic samples was investigated. Qualitative analysis was carried out to determine the major and minor constituent minerals present in ceramic bodies made from rock residue powder by using FT-IR spectroscopic technique. Further, the representative ceramic bodies are analyzed by FT-IR technique to yield more information about the functional groups and also to estimate the order or disorder of kaolinite structure.


2003 ◽  
Vol 47 (11) ◽  
pp. 153-156 ◽  
Author(s):  
J.-S. Kim ◽  
Y.-W. Hwang ◽  
C.-G. Kim ◽  
J.-H. Bae

This study was performed to develop a granular sulfur packed nitrification/denitrification process employing a uniquely designed single biofilter, which treated a relatively low carbon loaded domestic wastewater taken from a primary clarifier at a municipal wastewater treatment facility. The system was tested on varying experimental conditions, e.g. inflow flow, organic load and nitrogen load. Regardless of flow rate being increased, SS and COD was unvaryingly removed up to 90 and 80%, respectively. Moreover, TKN was also decomposed up to 90%. Increase in COD load gradually led to escalating level of non-biodegradable compounds observed in effluent. Nitrification was accomplished as high as 92%, whereas denitrification was achieved up to approximately 87%. For a while, nitrification and denitrification were observed at 0.65 and 0.55 kg/m3áday, respectively. Eventually, T-N was decomposed as high as 46%. It was concluded that granular sulfur can be used for not only electron donor, but also for a media to properly treat low carbon loaded wastewater and to filter SS efficiently.


2011 ◽  
Vol 356-360 ◽  
pp. 1331-1334
Author(s):  
Tao Lv ◽  
Wu Long Zhang ◽  
Xie Zhang ◽  
Feng Xue

This paper studies through project cases the treatment effect of integrated technique of anaerobic filter and constructed wetland on domestic wastewater in military camps, and the method for preventing the blocking of anaerobic filter and constructed wetland packing. The results show that its average removal rate of COD, NH4+-N, TP and SS is 83.1%, 37.5%, 49.8% and 91.5% respectively, with effluent meeting the standard of Grade II in Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB18918-2002); as planned, two anaerobic filters, one for operation and the other laying fallow at a alternate period of 6 months, in combination of the design of spoil disposal, can effectively prevent the packing layer from being blocked; being preprocessed, anaerobic filter can effectively prevent the packing layer of constructed wetland from being blocked; in case of a certain difference in elevation, the integrated technique can achieve unpowered operation. Besides, it is easy to implement and manage at a low operational cost without professional technician, and can treat decentralized domestic wastewater, therefore, is suitable for camps.


2014 ◽  
Vol 1030-1032 ◽  
pp. 387-390
Author(s):  
Chun Di Gao ◽  
Shi Xin Fan ◽  
Er Long Jiao ◽  
Hao Li ◽  
Wei Xiao Wang

A novel alternating oxic-anoxic operation mode of shortcut nitrification-denitrification was developed in a sequencing batch reactor at ambient temperature. Operational parameters favorable for maintaining the shortcut nitrification-denitrification were investigated and optimized. The experiments showed that alternating oxic-anoxic shortcut nitrification-denitrification system was able to be an independent treatment process in domestic wastewater treatment. And the optimization approach was so efficient that the main pollutant discharge targets achieved Standard A of the first class in "Discharge standard of pollutants for municipal wastewater treatment plant". Moreover, the reliability of the operation strategy in this experimentation was proved, which indicated the excellent nitrogen removal performances.


2009 ◽  
Vol 60 (12) ◽  
pp. 3121-3127 ◽  
Author(s):  
Halil Hasar ◽  
Ubeyde Ipek ◽  
Cumali Kinaci

Young leachate was a high strength wastewater with regard to carbon and nitrogen matter, and up to now many researchers have focused on a number of treatment methods to treat the leachate. By using various treatment processes, joint treatment of leachate with domestic wastewater, resulted from same community, is one of the most significant methods because domestic wastewater has either larger mass or lower strength than leachate. In this study, a submerged membrane bioreactor (sMBR) was used for treatment of blending wastewater, including differential mixture ratios of domestic wastewater and leachate. In raw leachate, BOD5/COD was between 0.40 and 0.67 and total phosphorus was between 17 and 24 mg/l. After the leachate was blended with domestic wastewater in the ratios of 1/5–1/20, the influent COD decreased from 8,500–14,200 mg/l to 750–2,400 mg/l as ammonium decreased from 1,100–2,150 mg/l to 30–180 mg/l. The sMBR, which was aerated intermittently, accomplished both COD oxidation and nutrient removal at optimal conditions without adding the external phosphorus source, providing < 15 mg COD/l, <1.3 mg NH4+-N/l, and <2.0 mg P/l on average at solid retention times (SRT) higher than 10 days. Consequently, the results showed the mixture of leachate and domestic wastewater could be an acceptable alternative by means of membrane bioreactor technology.


2009 ◽  
Vol 59 (6) ◽  
pp. 1077-1083 ◽  
Author(s):  
J. O. Pereira ◽  
J. S. S. Celani ◽  
C. A. L. Chernicharo

This paper presents an innovative reactor concept which is based on a double-stage biogas collection (DSBC) device aimed at controlling scum formation and accumulation in UASB reactors treating municipal wastewater. Scum production inside a control reactor and a DSBC-UASB reactor was compared and much lower scum yield coefficients were observed for the DSBC-UASB reactor. However, the mass balance indicated that the dominant control mechanism was scum disaggregation and exit to settler zone rather than scum degradation.


2018 ◽  
Vol 6 (2) ◽  
Author(s):  
Satmoko Yudo ◽  
Taty Hernaningsih

The increasing variety of industrial activities in Indonesia resulted in ground water reserves in some areas experiencing drought. Exploitation of ground water by industry and the community in some big cities like Jakarta, resulting in the decrease of ground water and ground water quality reduced caused sea water instrusion. While the potential of wastewater produced by industrial and household waste high today. Based on the matters mentioned above and see the use of ground water that will be even greater in the future, then one of alternative that a lot of attention in many countries around the world are using wastewater reuse, particularly urban domestic wastewater (municipal wastewater) as a source of raw water for water supply. BPPT as a government office has made use of wastewater reuse technology, however, when the performance of the appliance is not working properly for it is necessary for re-evaluation and selection of wastewater reuse technology for better and sustainable. Keywords : Wastewater Reuse Technology, Domestic Wastewater, Water Consumption Survey


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