REMOVAL OF SOME ENVIRONMENTALLY RELEVANT HEAVY METALS USING LOW-COST NATURAL SORBENTS

2009 ◽  
Vol 8 (2) ◽  
pp. 353-372 ◽  
Author(s):  
Raluca Maria Hlihor ◽  
Maria Gavrilescu
Author(s):  
Seroor Atalah Khaleefa Alia ◽  
Dr. Mohammed Ibrahimb ◽  
Hussein Ali Hussein

Adsorption is most commonly applied process for the removal of pollutants such as dyes and heavy metals ions from wastewater. The present work talks about preparing graphenic material attached sand grains called graphene sand composite (GSC) by using ordinary sugar as a carbon source. Physical morphology and chemical composition of GSC was examined by using (FTIR, SEM, EDAX and XRD). Efficiency of GSC in the adsorption of organic dyes from water was investigated using reactive green dye with different parameters such as (ph, temperature, contact time and dose). Adsorption isotherm was also studied and the results showed that the maximum adsorption capacity of dye is 28.98 mg/g. This fast, low-cost process can be used to manufacture commercial filters to treat contaminated water using appropriate engineering designs.


2013 ◽  
Vol 12 (3) ◽  
pp. 239-247

The removal of heavy metals from wastewaters is a matter of paramount importance due to the fact that their high toxicity causes major environmental pollution problems. One of the most efficient, applicable and low cost methods for the removal of toxic metals from aqueous solutions is that of their adsorption on an inorganic adsorbent. In order to achieve high efficiency, it is important to understand the influence of the solution parameters on the extent of the adsorption, as well as the kinetics of the adsorption. In the present work, the adsorption of Cu(II) species onto TiO2 surface was studied. It was found that the adsorption is a rapid process and it is not affected by the value of ionic strength. In addition, it was found that by increasing the pH, the adsorbed amount of Cu2+ ions and the value of the adsorption constant increase, whereas the value of the lateral interaction energy decreases.


The Analyst ◽  
2015 ◽  
Vol 140 (15) ◽  
pp. 5184-5189 ◽  
Author(s):  
Rudy J. Wojtecki ◽  
Alexander Y. Yuen ◽  
Thomas G. Zimmerman ◽  
Gavin O. Jones ◽  
Hans W. Horn ◽  
...  

The detection of trace amounts (<10 ppb) of heavy metals in aqueous solutions is described using hexahydrotriazines as a chemical indicator and a low cost fluorimeter-based detection system.


2010 ◽  
Vol 18 (5) ◽  
pp. 28-31
Author(s):  
R.B. Simmons

In recent years there has been a virtual explosion in the world of art glass. New glass formulations have brought a host of new colors into the marketplace, and the availability of low-cost, high-quality torches and other tools has brought art glass to the hobbyist. In addition to burn risks and possible cutting injury, there are a number of less obvious hazards that should be known to novice glass workers. One of these is the presence of heavy metals in or on glass surfaces and possibly in the atmosphere immediately surrounding the work area, presenting both potential skin contact and inhalation hazards. This study examines the metallic surfaces generated on five glass colors commonly used in art glass jewelry.


Sensor Review ◽  
2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mulayam Singh Gaur ◽  
Rajni Yadav ◽  
Mamta Kushwah ◽  
Anna Nikolaevna Berlina

Purpose This information will be useful in the selection of materials and technology for the detection and removal of mercury ions at a low cost and with high sensitivity and selectivity. The purpose of this study is to provide the useful information for selection of materials and technology to detect and remove the mercury ions from water with high sensitivity and selectivity. The purpose of this study is to provide the useful information for selection of materials and technology to detect and remove the mercury ions from water with high sensitivity and selectivity. Design/methodology/approach Different nano- and bio-materials allowed for the development of a variety of biosensors – colorimetric, chemiluminescent, electrochemical, whole-cell and aptasensors – are described. The materials used for their development also make it possible to use them in removing heavy metals, which are toxic contaminants, from environmental water samples. Findings This review focuses on different technologies, tools and materials for mercury (heavy metals) detection and remediation to environmental samples. Originality/value This review gives up-to-date and systemic information on modern nanotechnology methods for heavy metal detection. Different recognition molecules and nanomaterials have been discussed for remediation to water samples. The present review may provide valuable information to researchers regarding novel mercury ions detection sensors and encourage them for further research/development.


2016 ◽  
Vol 78 (8-3) ◽  
Author(s):  
Nurrulhidayah Salamun ◽  
Sugeng Triwahyono ◽  
Aishah Abdul Jalil

Mercury is one of the most toxic pollutants which pose a great threat to both human health and organism security. A great deal of research over recent decades has been motivated by the requirement to lower the concentration of these heavy metals in water and the need to develop low cost techniques which can be widely applied for heavy metals remediation. Adsorption is by far the most reliable technologies for removing mercury from water. In this study, banana stem fibers, a natural biomass was loaded with zirconium (IV) to investigate its feasibility for mercury removal from an aquatic environment. The XRD pattern for both BSF-HCl and Zr/BSF-HCl exhibited mainly the cellulose I structure which consists of two distinct crystal phases. The FESEM images illustrated the presence of relatively well organized, pronounced and uniform cavities distributed around the surface, indicated a good possibility for the metal ions to be adsorbed. The result shows that Hg (II) adsorption capacity increased from 45 to 72 mg/g after the immobilization of Zr due to increase in the active sites on the adsorbent. 


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Mulu Berhe Desta

Adsorption of heavy metals (Cr, Cd, Pb, Ni, and Cu) onto Activated Teff Straw (ATS) has been studied using batch-adsorption techniques. This study was carried out to examine the adsorption capacity of the low-cost adsorbent ATS for the removal of heavy metals from textile effluents. The influence of contact time, pH, Temperature, and adsorbent dose on the adsorption process was also studied. Results revealed that adsorption rate initially increased rapidly, and the optimal removal efficiency was reached within about 1 hour. Further increase in contact time did not show significant change in equilibrium concentration; that is, the adsorption phase reached equilibrium. The adsorption isotherms could be fitted well by the Langmuir model. The value in the present investigation was less than one, indicating that the adsorption of the metal ion onto ATS is favorable. After treatment with ATS the levels of heavy metals were observed to decrease by 88% (Ni), 82.9% (Cd), 81.5% (Cu), 74.5% (Cr), and 68.9% (Pb). Results indicate that the freely abundant, locally available, low-cost adsorbent, Teff straw can be treated as economically viable for the removal of metal ions from textile effluents.


Author(s):  
Siew-Teng. Ong ◽  
Sie-Tiong Ha ◽  
Pei-Sin Keng ◽  
Siew-Ling Lee ◽  
Yung-Tse Hung

2015 ◽  
Vol 3 (3) ◽  
pp. 35-39
Author(s):  
Sannasi Palsan ◽  
Chai Swee Fern ◽  
Stephanie Bernardine ◽  
Lim Fan Shiang

Saraca thaipingensis or ‘Gapis’ tree, classified under the Fabaceae family is a native of Taiping; copious over Peninsular Malaysia and Southeast Asia. The withered and fallen dead leaves were collected from INTI International University’s garden walkway. To date, literature has yet to capture the use of S. thaipingensis tree parts or refuse as potential biosorbent material for the removal of heavy metals thus verifying the novelty of this study. Batch experiments were carried out with the leaf powder to study the effects of dosage, particle size and contact time towards Cr(VI) removal (%) at 1-100 mg/L. Results showed that Cr(VI) removal increased from 52.22% to 99.31% (p < 0.05) with increase in biosorbent dosage (0.005, 0.010, 0.015, 0.020, 0.025 and 0.050 g). The different particle size ranges tested were: 107-125, 126-150, 151-250, 251-500, and 501- 1000 ?m. Highest Cr(VI) removal of 99.53% was obtained with the 151-250 ?m particle size; further size decrease did not yield more removal (p > 0.05). The optimal Cr(VI) removal was recorded after 45 min (99.62%) and 90 min (99.76%) contact time (p > 0.05). Further characterization and optimization studies are being carried out to develop a novel, sustainable, low cost yet effective leaf powder based biosorbent material.


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