Production and Optimization of Bio-Based Silica Nanoparticle from Teff Straw (Eragrostis tef) Using RSM-Based Modeling, Characterization Aspects, and Adsorption Efficacy of Methyl Orange Dye

The brown teff straw was utilized in this study to produce silica using the sol-gel technique. After pretreatment, the raw material of brown teff straw was characterized. The data were analyzed using the central composite design and response surface technique, and four independent parameters, namely, temperature, NaOH concentration, rotational speed, and extraction time, were evaluated for process optimization. Before extracting silica with an alkaline solution, the silica content in the ash was determined using an AAS spectrometer. The silica content of teff straw ash is around 92.89%. The ash was treated with NaOH solution in the concentrations range of 1 M to 3 M (0.5 M interval). The extraction time varied at intervals of 55, 70, 85, 100, and 115 minutes. Temperatures were changed using magnetic stirrer equipment in the range of 80°C to 100°C (5°C interval). At 350 rpm, 400 rpm, 450 rpm, 500 rpm, and 550 rpm, the rotating speed was adjusted. The best extraction conditions for amorphous silica were 1.50 M NaOH, 109.99 min, 94.98°C, and a rotating speed of 499.57 rpm, with a maximum yield of 85.85%. XRD and FTIR analyses were used to assess the physicochemical characteristics of the extracted silica. The aqueous solutions of methyl orange were used to test the adsorption efficiency of silica. The percent of removal efficiency for methyl orange was 90.48%.

A Statistical Modeling and Optimization for Cr(VI) Adsorption from Aqueous Media via Teff Straw-Based Activated Carbon: Isotherm, Kinetics, and Thermodynamic Studies

Currently, the growth of tannery industries causes a significant volume of waste disposal to the environment due to harmful Cr(VI). Long-time exposure to Cr(VI) imposes serious hazards on all living organisms. Hence, the treatment of tannery waste to remove Cr(VI) is not a choice but mandatory. Therefore, this study focused on the removal of Cr(VI) from the aqueous solutions via a teff (Eragrostis tef) straw based-activated carbon (TSAC) which was derived from locally available agricultural solid waste, teff straw (TS). The prepared TSAC was characterized using BET, FTIR, SEM, and XRD. A central composite approach-based RSM analysis was undertaken for statistical modeling and optimization for maximized Cr(VI) removal with respect to four important factors, namely, initial concentration of Cr(VI), the dosage of TSAC, pH, and adsorption time. Optimized values for maximizing adsorption of Cr(VI) (95% of removal) were acquired to be initial Cr(VI) concentration: 87.57 mg/L, TSAC dosage: 2.742 g/100 mL, pH: 2.2, and contact time:109 min. The results from the design of the experiment were also analyzed for the significance of the interaction between the selected process parameters. In addition, the pseudo-second-order kinetic and Langmuir isotherm models were found suitable for describing the adsorption data. The adsorption capacity of Cr(VI) on TSAC was 19.48 mg/g. The observed thermodynamic characteristics reveal that Cr(VI) adsorption on TASC is endothermic in nature. From the results, TSAC had shown a potential Cr(VI) efficiency on optimized process conditions that can be exploited effectively as adsorbent for removal of Cr(VI)-contaminated wastes.

Versatile Native Grasses and a Turf-Alternative Groundcover for the Arid Southwest United States

Water use limitations offers new opportunities for utilization of low-input native grasses and groundcovers for the landscapes of southwest USA. Two field studies were conducted with eleven plant species for two years in Scottsdale and Sun City West, AZ to evaluate rate of emergence, ground surface coverage, plant height, and overall plant quality. In the laboratory, Eragrostis tef at 86% and Eragrostis intermedia at 85% were showing higher percentage of germination compared to other species. Within eight weeks, ten species exhibited an average of 81% emergence at Scottsdale while nine species showed only 58% emergence at Sun City West. Sporobolus cryptandrus grew to greater than 76 cm (30 in) in height while kurapia (Lippia nodiflora) grew to about 5 cm (2 in). The performances of the groundcover kurapia and the native grasses tested demonstrated excellent potential in the low desert southwest U.S., with low rates of water use, applying fertilizer only at planting, and less frequent mowing requirements. Lippia nodiflora, Sporobolus airoides, Bouteloua gracilis, Eragrostis intermedia, and Muhlenbergia asperifolia remained green throughout the year when mowed twice a year. Lippia nodiflora, Hilaria rigida, and Bouteloua gracilis exhibited the highest ground surface coverage and uniformity in growth. Index words: groundcover, landscape, low input, native grasses, plant species. Species used in this study: Blue grama, Bouteloua gracilis (Kunth) Lag. ex Griffiths; bufflograss, Buchloe dactyloides (Nutt.) Engelm.; plains lovegrass, Eragrostis intermedia A.S. Hitchc.; teff, Eragrostis tef (Zucc) Trotter; big galleta, Hilaria rigida (Thurb); Kurapia, Lippia nodiflora (L.) Greene; alkali muhly, Muhlenbergia asperifolia (Nees & Meyen ex Trin.) Parodi; alkali sacaton, Sporobolus airoides (Torr.) Torr.; spike dropseed, Sporobolus contractus A.S. Hitchc.; sand dropseed, Sporobolus cryptandrus (Torr.) A. Gray; and desert zinnia, Zinnia acerosa (DC.) A. Gray.

Untargeted Metabolomic Profiling Reveals Variation in Metabolites Associated with Nutritional Values in Tef Accessions

Tef (Eragrostis tef), is a gluten-free orphan cereal, crop of nutritional and economical significance. Here we used untargeted metabolomics to survey metabolite variation in 14 diverse tef accessions at 15-days post germination. Tef genotypes were classified into four metabolomic groups where variation was linked to flavones and flavonols. Further analysis on white seeded accessions shows variation related to sucrose and important vitamins, nicotinamides (vitamin B3) riboflavin (vitamin B2) and folate (vitamin B9). Coloured seeded accessions showed variation in metabolism related to amino acid and sugars. This study highlights the potential of metabolomics in exploring the nutritional traits in tef.

Review on Effects of Sowing Methods and Types of Inorganic Fertilizers on Growth Yield and Yield Component of TEFF [Eragrostis TEF (ZUCC.)

Most farmers’ practices broadcast sowing methods and productivity is less. Soil fertility maintenance is a major concern in tropical Africa which needs to tackle soil fertility depletion as a fundamental constraint. Similarly, the traditional way of planting tef reduces the amount of grain production, promotes competition for inputs, and causes severe lodging. This paper aimed to review the interaction effects between seed sowing methods and different types of inorganic fertilizers on the growth and yield of teff. In Ethiopia, recent research indicates planting method (row planting and broadcasting) affects the yield and yield components of teff. The review indicates the yield components include heading and maturity, plant height, first growth rate, number of tiller and panicle, thousand seed weight, grain, straw, and total biomass yields and harvest index high in Method of Row sowing compared to broadcast in Ethiopia but Days to emergence and panicle length were more affected by broadcasting. In economical acceptance, Row sowing was found to be economically acceptable with more income from grain yield than broadcasting.