scholarly journals Influence of Sn doping ratio on the structural and optical properties of CdO films prepared by laser induced plasma

2020 ◽  
Vol 18 (45) ◽  
pp. 1-8
Author(s):  
Kadhim A. Aadim ◽  
Baida M. Ahmed ◽  
Madyan A. Khalaf
Keyword(s):  
Optical Properties ◽  
Energy Gap ◽  
Cadmium Oxide ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
Average Roughness ◽  
Optical Energy ◽  
Sn Doping ◽  
Laser Induced Plasma

In this work, we study the effect of doping Sn on the structural and optical properties of pure cadmium oxide films at different concentrations of Tin (Sn) (X=0.1,0.3 and 0.5) .The films prepared by using the laser-induced plasma at wavelength of laser 1064 nm and duration 9 ns under pressure reached to 2.5×10-2 mbar. The results of X-ray diffraction tests showed that the all prepared films  are polycrystalline. As for the topography of the films surface, it was measured using AFM , where the results showed that the grain size increases with an increase in the percentage of doping  in addition to an increase in the average roughness. The optical properties of all films have also been studied through the absorbance spectrum of the range  of  the wavelength (350-1100) nm, where the optical energy gap was direct transitions it was found that the value of the optical energy gap increased with increasing the doping.

scholarly journals Laser induced plasma of cadmium oxide: structural, morphological and optical properties

2021 ◽  
Vol 2114 (1) ◽  
pp. 012012
Author(s):  
Tamara S. Hussein ◽  
Ala F. Ahmed
Keyword(s):  
Optical Properties ◽  
Energy Gap ◽  
Cadmium Oxide ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
X Ray ◽  
Laser Induced Plasma ◽  
Atomic Force ◽  
Doping Ratio

Abstract In this study, the effect of grafting with Iron (Fe) ratios (0.1, 0.3 and 0.5) on the structural and optical properties of cadmium oxide films (CdO) was studied, as these films were prepared on glass bases using the method of pulse laser deposition (PLD). The crystallization nature of the prepared films was examined by X-ray diffraction technique (XRD), which showed that the synthesis of the prepared films is polycrystalline, and Atomic Force Microscope (AFM) images also showed that the increased vaccination with Iron led to an increase in the crustal size ratio and a decrease in surface roughness, The absorption coefficient was calculated and the optical energy gap for the prepared thin films. It was found the absorption decreases and the energy gap decreases with the increase of doping ratio.

scholarly journals A Study of the Structural and Optical Properties of SnS:F prepared by chemical spray pyrolysis technique

2014 ◽  
Vol 11 (2) ◽  
pp. 518-526
Author(s):  
Baghdad Science Journal
Keyword(s):  
Optical Properties ◽  
Spray Pyrolysis ◽  
Energy Gap ◽  
Spray Pyrolysis Technique ◽  
Chemical Spray Pyrolysis ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
Optical Energy ◽  
Chemical Spray Pyrolysis Technique ◽  
Chemical Spray

Thin films of pure tin mono-sulfide SnS and tin mono-sulfide for (1,2,3,4)% fluorine SnS:F with Thicknesses of (0.85 ±0.05) ?m and (0.45±0.05) ?m respectively were prepared by chemical spray pyrolysis technique. the effect of doping of F on structural and optical properties has been studied. X-Ray diffraction analysis showed that the prepared films were polycrystalline with orthorhombic structure. It was found that doping increased the intensity of diffraction peaks. Optical properties of all samples were studied by recording the absorption and transmission spectrum in range of wave lengths (300-900) nm. The optical energy gap for direct forbidden transition and indirect allowed transition were evaluated It is found that for doping less than 2% the optical energy gap increases as the percentage of doping increases in the samples while for doping more than 2% the values of the optical energy gap decreases as the percentage of doping increases.

Structural and Optical Properties of Er3+- Doped Zinc-Titania Tellurite Glasses

2019 ◽  
Vol 290 ◽  
pp. 9-15 ◽  
Author(s):  
S.O. Baki ◽  
Mohamed Kamari Halimah
Keyword(s):  
Optical Properties ◽  
Near Infrared ◽  
Energy Gap ◽  
Optical Transition ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
Absorption Bands ◽  
Transition Mechanism ◽  
Infrared Luminescence

In the present work, we studied the structural and optical properties of zinc-titania tellurite glass (75-x)TeO2-20ZnO-5TiO2-xEr2O3 doped with erbium ion Er3+ (where mol % : x= 0 (host), 0.5, 1, 1.5). The reported glasses were synthesized using tradition melt quench method. The X-ray diffraction and thermal profile were utilized to study the amorphous nature of the mentioned glass. Optical absorption UV-Visible-NIR spectra were measured for optical energy gap and Er3+ absorption bands analysis. Both visible and near infrared luminescence were performed at room temperature using 980 nm laser diode excitation where the optical transition mechanism of the Er3+ in the glass is finally proposed. Broad luminescence in the present glass suggests its potential for broadband optical application.

scholarly journals Synthesis and Characterization of 〖(CdO)〗_(1-x) 〖Mg〗_x films by pulsed laser deposition

2020 ◽  
Vol 18 (45) ◽  
pp. 59-67
Author(s):  
Jasim Mohamad Hussain ◽  
Awatif S Jasim ◽  
Kadhim Abdulwahid Aadim
Keyword(s):  
Absorption Coefficient ◽  
Energy Gap ◽  
Cadmium Oxide ◽  
Pulsed Laser ◽  
Laser Deposition ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
X Ray

In this study, the effect of grafting with magnesium (Mg) ratios (0.1, 0.3, 0.5) on the structural and optical properties of cadmium oxide films (CdO) was studied, as these films were prepared on glass bases using the method of pulse laser deposition (PLD). The crystallization nature of the prepared membranes was examined by X-ray diffraction technique (XRD), which showed that the synthesis of the prepared membranes is polycrystalline, and (AFM) images also showed that the increased deformation with magnesium led to an increase in the grain size ratio and a decrease in surface roughness, as well as the absorption coefficient was calculated. And the optical energy gap for the prepared membranes, where it was found that the absorption coefficient increases with the increase in the proportion of vaccination and that the energy gap decreases with increasing rates of vaccination.

scholarly journals The Structural and Optical Properties of Cobalt dioxide (CoO2 )Thin Films deposited via (SCSP) Technique for photovoltaic applications

2021 ◽  
Vol 13 (01) ◽  
pp. 33-42
Author(s):  
Mushtaq Talib Al-Helaly ◽  
◽  
Nathera A .Al-Tememee ◽  
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Energy Gap ◽  
Spray Pyrolysis Technique ◽  
Film Surface ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
Optical Energy ◽  
X Ray ◽  
Photovoltaic Applications

The research included the preparation and then studying the structural and optical properties of the cobalt dioxide (CoO2)films. The latter films were prepared using a semi-computerized spray pyrolysis technique (SCSPT),. The X-ray diffraction gave polycrystalline nature with crystal system trigonal (hexagonal axes), and the Energy Dispersive X-ray spectroscopy (EDX) showed that all films contain the elements (Co and O) indicating formation of (CoO2) films with high purity. FTIR measurements showed of chemical bonds of CoO2 clearly. Scanning Electron Microscopy (SEM ) Showed clearly that the formed thin films under the optimum conditions were homogeneous, dense and compact, and Atomic Force Microscopy(AFM) results showed that the topography of the film surface where surface roughness was found to be 7.91 nm, root mean square was 9.69 nm., and the average granularity diameter was 78.00 nm. The optical properties (absorbance, absorption coefficient, extinction coefficient, refractive index, optical Conductivity, the real ε_(1 ) and imaginary ε_2 part of the dielectric constant )were decreased with increasing the wavelength, while the transmittance increases with increasing wavelength. The optical energy gap was (1.98eV) and this is a good optical energy gap values for photovoltaic applications.

scholarly journals Structural and Optical Properties of ZnO-CdO Nanocomposite Using Electrodeposition Method

2016 ◽  
Vol 63 ◽  
pp. 127-133 ◽  
Author(s):  
Zehraa N. Abdul-Ameer ◽  
Ibrahim R. Agool
Keyword(s):  
Grain Size ◽  
Optical Properties ◽  
Surface Morphology ◽  
Electrochemical Deposition ◽  
Energy Gap ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Optical Energy Gap ◽  
X Ray ◽  
Shift Behavior

ZnO,CdO,ZnO-CdO nanocomposite were prepared using electrochemical deposition the prepared samples were characterized using X-ray diffraction and the photoluminenscence spectroscopy (PL) to get the surface morphology leading to calculation of optical energy gap .the grain size determined by Scherrer's equation (22-25) nm .through the calculation of Eg ,it was noticed a red shift behavior in ZnO manner due to addition of CdO content

Structural and Optical Properties of BiFeO3 via Polymer-Assisted Hydrothermal Synthesis under Different Weight of Chitosan

2021 ◽  
Vol 317 ◽  
pp. 53-59
Author(s):  
Muhammad Safwan Sazali ◽  
Muhamad Kamil Yaakob ◽  
Mohamad Hafiz Mamat ◽  
Oskar Hasdinor Hassan ◽  
Muhd Zu Azhan Yahya
Keyword(s):  
Optical Properties ◽  
Single Phase ◽  
Energy Gap ◽  
Bismuth Ferrite ◽  
Secondary Phase ◽  
Synthesis Process ◽  
Rhombohedral Structure ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Diffraction Angle

In this work, single phase Bismuth Ferrite, BiFeO3 was successfully synthesized by using hydrothermal method assisted with different weight (0.24 g, 0.36 g and 0.48 g) of Chitosan. Potassium hydroxide (KOH) were used as a mineralizer during the synthesis process for the precipitation. The samples were characterized for different properties such as structural and optical properties, and were then compared with previous works. The X-ray diffraction data for all the samples showed that the samples had a single phase belonging to R3c space group with perovskite rhombohedral structure at diffraction angle 32.0° to 32.5° even though the slight presence of secondary phase at diffraction angle 28° was detected. Scanning electron microscope revealed a decrement in particle size as the weight of Chitosan increased indicating effective used of Chitosan in controlling the agglomeration of the particles. All samples BiFeO3 assisted with and without Chitosan showed significant enhancement in energy gap where the obtained results showed a small energy gap values ranging from ~1.22 eV to ~1.88 eV determined from UV-vis absorbance characterization. Therefore, by the addition of Chitosan, the properties of BiFeO3 such as structural and optical have changed as well as preventing from the particle to agglomerate.

scholarly journals Structural, Thermal and Optical Properties of Rare Earth Doped Lead-Tellurite Oxide Glasses

2021 ◽  
Vol 81 (2) ◽  
pp. 52-58
Author(s):  
Fong W. L. ◽  
Sharudin Omar Baki ◽  
N. M. Arifin ◽  
Yaakob Mansor ◽  
Ahmad Nazri ◽  
...  
Keyword(s):  
Optical Properties ◽  
Rare Earth ◽  
Energy Gap ◽  
Structural Deformation ◽  
Oxide Glasses ◽  
X Ray Diffraction ◽  
Optical Energy Gap ◽  
Erbium Ions ◽  
Glass Transformation

Structural, thermal and optical properties of lead-tellurite oxide glasses consisting TeO2 – PbO – Bi2O3 – Er2O3, synthesized by high temperature melt-quenching-thermal annealing method were investigated in this study. The role of rare-earth element, erbium ion as dopant into the host glass has affected physically, thermally and optically of the glasses. The amorphous nature of the glasses was confirmed by XRD (x-ray diffraction). Thermal exo-endothermic event profiles clarify its glass transformation temperature Tg, crystallization temperature Tx, and melting temperature Tm are exist. Both UV-Vis-NIR optical absorption and Raman spectroscopy have revealed optical energy gap changes due to the structural deformation by the erbium ions. Related obtained glass parameters such as polarizability, refractive indices and metallization criterion were also explained further in this study.

scholarly journals EFFECT OF THICKNESS ON THE STRUCTURE AND OPTICAL PROPERTIES OF LASER-INDUCED PLASMA CDO THIN FILMS

2021 ◽  
Vol 03 (03) ◽  
pp. 41-50
Author(s):  
Hiyam Ch. MAJED
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Energy Gap ◽  
Plasma Deposition ◽  
Cadmium Oxide ◽  
Laser Wavelength ◽  
Dielectric Constants ◽  
Laser Induced Plasma ◽  
Glass Substrates ◽  
Cdo Thin Films

Thin films of cadmium oxide (CdO) deposited on glass substrates using Nd-YAG laser wavelength (alpha= 532 nm) and period time (10ns) via laser-induced plasma deposition technique (PLD). The structural properties of these films have been described as a change in thickness (200 , 400 ,and 1000) nm) at substrate temperature of (400 ° C) and energy flounce of (0.4 J / cm2). The X-ray diffraction results show that he mean size of crystallite measured using Scherer formula to adjust the thickness of 200 nm, 400 nm and 1000 nm of CdO thin films is 47 nm, 64 nm and 78 nm respectively .Also the optical properties which included transmittance, absorbance , energy gap and optical constant such as the Refractive index, extinction coefficient real and imaginary parts of dielectric constants were determined .

Absorption Spectra of Neodymium Doped Tellurite Glass

2014 ◽  
Vol 895 ◽  
pp. 395-399 ◽  
Author(s):  
Nur Amanina Mat Jan ◽  
M.R. Sahar ◽  
Sib Krishna Ghoshal ◽  
R. Ariffin ◽  
M.S. Rohani ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Urbach Energy ◽  
Energy Gap ◽  
Rare Earth Doping ◽  
Tellurite Glasses ◽  
X Ray Diffraction ◽  
Optical Energy Gap ◽  
Xrd Pattern ◽  
Optical Energy ◽  
Forbidden Transition

Modifying the optical and structural properties of tellurite glasses by controlling rare earth doping is an important issue. Neodymium doped magnesium-tellurite glasses of composition TeO2-MgO-Na2O with concentration from 0.5 to 2.5 mol% were synthesized by conventional melt-quenching technique. The amorphous natures of the glass were confirmed from x-ray diffraction (XRD) pattern. The absorption spectra (exhibits five bands) were recorded to determine the optical energy gap and Urbach energy. The values of the optical band gap are found to lie between 3.04-3.20 eV, while the Urbach energy values varies are between 0.21-0.12 eV. The optical energy gap for indirect forbidden transition has increased whereas the values of Urbach energy have decreased with the increasing of Nd2O3content. The structural and optical properties were found to be strongly affected by the varying concentration of Nd3+ions.

Sign in / Sign up

Export Citation Format

Share Document