scholarly journals Effect of viscosity on electrical conductivity in liquid foods

2021 ◽  
Author(s):  
Balaji Subbiah ◽  
Ken R. Morison

The electrical conductivities of foods affect their heating with ohmic heating and microwaves, and are required for electrical tomography studies. A range of model foods consisting of solutions of sodium carboxymethyl cellulose (NaCMC), NaCMC + sugars, concentrated skim milk, whey protein and viscous sugar solutions, with various amounts of electrolytes were prepared. The electrical conductivity was measured using a parallel plate sensor connected to an RCL meter using an a.c. voltage. The conductivity was found to increase with concentration, but was reduced by the effects of viscosity on ion mobility. The conductivity was closely related to bulk viscosity for sugar solutions following the modified Walden equation, but was unrelated to the viscosity of NaCMC solutions. Instead an “ion-diffusion” viscosity was defined and calculated from the electrical conductivity data, and this was found to relate well to the expected viscosity of the solution to which ions are exposed at a molecular scale.

2020 ◽  
Vol 36 (2) ◽  
pp. 205-219
Author(s):  
Krittiya - Khuenpet ◽  
Weerachet - Jittanit

HighlightsThis research proved that Madan juice should be filtered before pasteurization in order to be more palatable for consumer.Madan juices and its concentrates can be efficiently heated by ohmic method due to their high electrical conductivities.Mathematical models developed in this study can accurately predict the electrical conductivity of the Madan juice during ohmic heating.This research proved that the quality of pasteurized Madan juice concentrates was rather steady during 60 days of storage.Abstract.Madan is a native fruit of the Southeast Asian region. The objectives of this research were: 1) to investigate the effect of pasteurization methods on the qualities of Madan juices and 2) to examine the influence of ohmic heating on the qualities and storage stability of pasteurized and concentrated juice compared to conventional heating method. It appeared that Madan juices (5-27.2 °Brix) can be heated by ohmic method due to high electrical conductivities (1.37-4.74 S.m-1). Mathematical models developed in this study can precisely predict the electrical conductivity of Madan juice. Filtration step and pasteurization condition of 95°C for 15 s should be applied in Madan juice processing because they provided the highest sensorial scores and the lowest color change. The continuous-mode machine provided the lightest color with low redness and yellowness values. Quality changes of Madan juice concentrate samples pasteurized using double jacket kettle and ohmic heating method were diminutive during 60 days of storage. Keywords: Concentration, Juice, Madan, Ohmic heating, Pasteurization.


1984 ◽  
Vol 39 (2) ◽  
pp. 265-268 ◽  
Author(s):  
Michael Hanack ◽  
Otto Schneider

The preparation of cyanide containing phthalocyaninatoiron(II) or -iron(III) derivatives either with terminal or bridging cyanide is described. With help of the C≡N valence frequency (IR) and the magnetism of the compounds the oxidation state of the iron is determined. Thermoanalytical and electrical conductivity data are reported


2019 ◽  
Vol 104 (12) ◽  
pp. 1800-1805
Author(s):  
George M. Amulele ◽  
Anthony W. Lanati ◽  
Simon M. Clark

Abstract Starting with the same sample, the electrical conductivities of quartz and coesite have been measured at pressures of 1, 6, and 8.7 GPa, respectively, over a temperature range of 373–1273 K in a multi-anvil high-pressure system. Results indicate that the electrical conductivity in quartz increases with pressure as well as when the phase change from quartz to coesite occurs, while the activation enthalpy decreases with increasing pressure. Activation enthalpies of 0.89, 0.56, and 0.46 eV, were determined at 1, 6, and 8.7 GPa, respectively, giving an activation volume of –0.052 ± 0.006 cm3/mol. FTIR and composition analysis indicate that the electrical conductivities in silica polymorphs is controlled by substitution of silicon by aluminum with hydrogen charge compensation. Comparing with electrical conductivity measurements in stishovite, reported by Yoshino et al. (2014), our results fall within the aluminum and water content extremes measured in stishovite at 12 GPa. The resulting electrical conductivity model is mapped over the magnetotelluric profile obtained through the tectonically stable Northern Australian Craton. Given their relative abundances, these results imply potentially high electrical conductivities in the crust and mantle from contributions of silica polymorphs. The main results of this paper are as follows:The electrical conductivity of silica polymorphs is determined by impedance spectroscopy up to 8.7 GPa.The activation enthalpy decreases with increasing pressure indicating a negative activation volume across the silica polymorphs.The electrical conductivity results are consistent with measurements observed in stishovite at 12 GPa.


2018 ◽  
Vol 22 (2) ◽  
pp. 1629-1648 ◽  
Author(s):  
Etienne Bresciani ◽  
Roger H. Cranswick ◽  
Eddie W. Banks ◽  
Jordi Batlle-Aguilar ◽  
Peter G. Cook ◽  
...  

Abstract. Numerous basin aquifers in arid and semi-arid regions of the world derive a significant portion of their recharge from adjacent mountains. Such recharge can effectively occur through either stream infiltration in the mountain-front zone (mountain-front recharge, MFR) or subsurface flow from the mountain (mountain-block recharge, MBR). While a thorough understanding of recharge mechanisms is critical for conceptualizing and managing groundwater systems, distinguishing between MFR and MBR is difficult. We present an approach that uses hydraulic head, chloride and electrical conductivity (EC) data to distinguish between MFR and MBR. These variables are inexpensive to measure, and may be readily available from hydrogeological databases in many cases. Hydraulic heads can provide information on groundwater flow directions and stream–aquifer interactions, while chloride concentrations and EC values can be used to distinguish between different water sources if these have a distinct signature. Such information can provide evidence for the occurrence or absence of MFR and MBR. This approach is tested through application to the Adelaide Plains basin, South Australia. The recharge mechanisms of this basin have long been debated, in part due to difficulties in understanding the hydraulic role of faults. Both hydraulic head and chloride (equivalently, EC) data consistently suggest that streams are gaining in the adjacent Mount Lofty Ranges and losing when entering the basin. Moreover, the data indicate that not only the Quaternary aquifers but also the deeper Tertiary aquifers are recharged through MFR and not MBR. It is expected that this finding will have a significant impact on the management of water resources in the region. This study demonstrates the relevance of using hydraulic head, chloride and EC data to distinguish between MFR and MBR.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1034
Author(s):  
Oladipo Folorunso ◽  
Yskandar Hamam ◽  
Rotimi Sadiku ◽  
Suprakas Sinha Ray ◽  
Neeraj Kumar

In this study, a hybrid of graphene nanoplatelets with a polypyrrole having 20 wt.% loading of carbon-black (HGPPy.CB20%), has been fabricated. The thermal stability, structural changes, morphology, and the electrical conductivity of the hybrids were investigated using thermogravimetric analyzer, differential scanning calorimeter, X-ray diffraction analyzer, scanning electron microscope, and laboratory electrical conductivity device. The morphology of the hybrid shows well dispersion of graphene nanoplatelets on the surface of the PPy.CB20% and the transformation of the gravel-like PPy.CB20% shape to compact spherical shape. Moreover, the hybrid’s electrical conductivity measurements showed percolation threshold at 0.15 wt.% of the graphene nanoplatelets content and the curve is non-linear. The electrical conductivity data were analyzed by comparing different existing models (Weber, Clingerman and Taherian). The results show that Taherian and Clingerman models, which consider the aspect ratio, roundness, wettability, filler electrical conductivity, surface interaction, and volume fractions, closely described the experimental data. From these results, it is evident that Taherian and Clingerman models can be modified for better prediction of the hybrids electrical conductivity measurements. In addition, this study shows that graphene nanoplatelets are essential and have a significant influence on the modification of PPy.CB20% for energy storage applications.


Soil Research ◽  
2001 ◽  
Vol 39 (6) ◽  
pp. 1359 ◽  
Author(s):  
I. Vogeler ◽  
S. Green ◽  
A. Nadler ◽  
C. Duwig

Time domain reflectometry (TDR) was used to monitor the transport of conservative tracers in the field under transient water flow in a controlled experiment under a kiwifruit vine. A mixed pulse of chloride and bromide was applied to the soil surface of a 16 m2 plot that had been isolated from the surrounding orchard soil. The movement of this solute pulse was monitored by TDR. A total of 63 TDR probes were installed into the plot for daily measurements of both the volumetric water content (θ) and the bulk soil electrical conductivity (σa). These TDR-measured σa were converted into pore water electrical conductivities (σw) and solute concentrations using various θ–σa–σw relationships that were established in the laboratory on repacked soil. The depth-wise field TDR measurements were compared with destructive measurement of the solute concentrations at the end of the experiment. These results were also compared with predictions using a deterministic model of water and solute transport based on Richards’ equation, and the convection–dispersion equation. TDR was found to give a good indication of the shape of the solute profile with depth, but the concentration of solute was under- or over-estimated by up to 50%, depending on the θ–σa–σw relationships used. Thus TDR can be used to monitor in situ transport of contaminants. However, only rough estimates of the electrical conductivity of the soil solution can so far be obtained by TDR.


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