scholarly journals Study on the fluorination of dysprosium oxide by ammonium bifluoride for the preparation of dysprosium fluoride

2021 ◽  
Vol 63 (8) ◽  
pp. 9-13
Author(s):  
Trong Hung Nguyen ◽  
◽  
Ba Thuan Le ◽  
Thanh Thuy Nguyen ◽  
◽  
...  
Keyword(s):  
Reaction Time ◽  
Composition Analysis ◽  
Fluoride Salt ◽  
X Ray Diffraction ◽  
Metallothermic Reduction ◽  
Dysprosium Oxide ◽  
X Ray ◽  
Analysis Techniques ◽  
Ammonium Bifluoride ◽  
Thermal Analysis Techniques

In this report, dysprosium fluoride (DyF3) - a material for the preparation of dysprosium (Dy) metal was prepared by the fluorination of dysprosium oxide (Dy2O3) by ammonium bifluoride (NH4HF2) reagent. The effect of reaction time and temperature on the formation of dysprosium fluoride salt has been studied. The phase composition and crystal structure of the obtained products were analysed by X-ray diffraction (XRD). Thermal analysis techniques were applied to determine the temperature range of the fluorination. Scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS) was used for external morphology observation and chemical elemental composition analysis. The results showed that the high purity phase of DyF3 was formed at the conditions: reaction time and temperature of >1 h and >350oC, respectively. The product is available for the preparation of Dy metal by metallothermic reduction.

scholarly journals Structural Formation of UHMWPE Film Tracked by Real-Time Retardation Measurements during Uniaxial/Biaxial Stretching

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2292 ◽  
Author(s):  
Yoshinori Hashimoto ◽  
Shotaro Nishitsuji ◽  
Takashi Kurose ◽  
Hiroshi Ito
Keyword(s):  
Tensile Testing ◽  
X Ray Diffraction ◽  
Structural Formation ◽  
X Ray ◽  
Amorphous Phases ◽  
Analysis Techniques ◽  
Biaxial Stretching ◽  
Thermal Analysis Techniques ◽  
Ultra High Molecular Weight ◽  
Order Structures

This work reports on an experimental study of the stretching of ultra-high molecular weight polyethylene (UHMWPE) film in various uniaxial/biaxial stretching modes at various temperatures and stretching speeds. We examined the stress-birefringence relationship as a stress-optical rule (SOR) under uniaxial stretching and evaluated the stress-optical coefficient (SOC). Wide-angle X-ray diffraction (WAXD) measurements were applied to evaluate the contribution to birefringence of the crystalline and amorphous phases and to characterize stretching modes. In simultaneous biaxial stretching, the melting temperature (Tm) proved critical to structural formation. We applied thermal analysis techniques and tensile testing to evaluate higher order structures after each stretching mode.

Rotational Polymorphism of Methyl-Substituted Ammonium Perchlorates

1965 ◽  
Vol 9 ◽  
pp. 170-189 ◽  
Author(s):  
M. Stammler ◽  
R. Bruenner ◽  
W. Schmidt ◽  
D. Orcutt
Keyword(s):  
Phase Transition ◽  
Ammonium Perchlorate ◽  
Room Temperature ◽  
Decomposition Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
Cell Dimensions ◽  
Thermal Analysis Techniques ◽  
Space Requirements

AbstractThe thermal transformations which take place in solid methyl-substituted ammonium perchlorates have been studied using high-temperature X-ray diffraction and differential thermal analysis techniques. In the temperature range from 20°C to their decomposition temperature (above 300°C), ammonium perchlorate and tetramethyl ammonium perchlorate undergo only one enantiomorphic phase transition, namely at 240 and 340°C (with decomposition), respectively. This I—II transition is ascribed to the beginning of the free rotation of the ClO4− ions. The rotation of the cations, however, begins below room temperature. If the symmetry of the cation is lowered by having both methyl groups and hydrogens arranged around the nitrogen (as in monomethyl, dimethyl, and trimethyl ammonium perchlorates), there is an additional enantiomorphic phase transition. This I—II transformation is ascribed to the rotation of the cations which have, in the partially substituted ions, two sets of non-equivalent symmetry axes (different moments of inertia). The temperatures of transformation are discussed in terms of the space requirements for rotation. Symmetries and cell dimensions of some modifications were determined.

Laser Ablation Synthesis of Ceramic Powders

1990 ◽  
Vol 201 ◽  
Author(s):  
W. G. Fahrenholtz ◽  
S. R. Foltyn ◽  
K. C. Ott ◽  
M. Chadwick ◽  
D. M. Smith
Keyword(s):  
Thermal Analysis ◽  
Laser Ablation ◽  
Aluminum Oxide ◽  
Fine Powder ◽  
X Ray Diffraction ◽  
Ceramic Powders ◽  
X Ray ◽  
Analysis Techniques ◽  
Aluminum Metal ◽  
Thermal Analysis Techniques

AbstractA pulsed excimer laser was used to ablate aluminum metal into an oxygen-containing atmosphere. The resulting fine powder was collected on a 0.1 μm filter and analyzed to determine structure and composition. Using a combination of TEM, EELS, and thermal analysis techniques, the product was found to be amorphous aluminum oxide, Al2O3. The morphology of the powders was investigated using SEM, TEM, and surface area measurements. The resulting powder was crystallized and examined by x-ray diffraction.

Kinetic Study on the Formation of the Aragonite-Like Phase Ba(CuOx)1-Y(CO3)y

1995 ◽  
Vol 398 ◽  
Author(s):  
A. Tomasi ◽  
E. Galvanetto ◽  
F.C. Matacotta ◽  
P. Nozar ◽  
P. Scardi ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
High Resolution Electron Microscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
Formation Kinetics ◽  
Resolution Electron ◽  
Thermal Analysis Techniques ◽  
Kinetics Of

ABSTRACTA systematic study on phase formation and stabilisation in the Ba-Cu-C-O system in the temperature range 20-500°C, under various atmospheres, by traditional thermal analysis techniques, high temperature X-ray diffraction and high resolution electron microscopy, has permitted to identify and characterise the formation kinetics of a new copper containing phase isomorphic to γ-BaCO3.

Leakage Failure Analysis of 80SS Tubing in Gas Field

2020 ◽  
Vol 993 ◽  
pp. 1160-1167
Author(s):  
Cai Hong Lu ◽  
Li Hong Han ◽  
Chun Feng ◽  
Xin Xu ◽  
Shang Yu Yang ◽  
...  
Keyword(s):  
Ph Value ◽  
Mechanical Test ◽  
Acid Corrosion ◽  
Energy Dispersive Spectrometer ◽  
Composition Analysis ◽  
X Ray Diffraction ◽  
Gas Field ◽  
X Ray ◽  
Analysis Techniques ◽  
Leakage Failure

During acidizing process in a gas field, leakage of 80SS anti-sulfur tubing occurred.The main reasons for failure of the tubing have been investigated based on analysis techniques of chemical composition analysis,Optical Microscopy (OM), Scanning Electron Microscope (SEM), Energy Dispersive Spectrometer (EDS) , X-ray Diffraction (XRD) and mechanical test. The results show that composition and mechanical properties of the tubing were all in accordance with the corresponding requirements of API Spec 5CT standards. Furthermore,leakage of tubing from inner wall was caused by combined impacts of acid corrosion, H2S corrosion, low PH value, high temperature and a certain pressure. Meanwhile, Low concentration of corrosion inhibitor was also one of the factors of corrosion perforation.

Quasicrystalline Phase Formation in High Frequency Induction Melted Al80Cu14Fe6 Alloy

2013 ◽  
Vol 344 ◽  
pp. 37-41 ◽  
Author(s):  
H. Boularas ◽  
M.Y. Debili
Keyword(s):  
Thermal Analysis ◽  
High Frequency ◽  
Structural Characteristics ◽  
Quasicrystalline Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
Thermal Analysis Techniques ◽  
Short Time ◽  
High Frequency Induction

Structural characteristics and thermal behavior of the conventionally solidified Al80Cu14Fe6, was investigated by X-ray diffraction, optical microscopy, and differential thermal analysis techniques. It was found that the formation of quasi crystalline phase occurs after annealing for relatively low temperature (500°C) during a short time.

BETTER UNDERSTANDING THE GEOLOGY OF CENTRAL CUBA THROUGH STREAM SEDIMENT COMPOSITION ANALYSIS USING X-RAY DIFFRACTION

2019 ◽  
Author(s):  
Landon Williamson ◽  
◽  
Nicolas Perdrial ◽  
John M. Hughes ◽  
Mae Kate Campbell ◽  
...  
Keyword(s):  
Stream Sediment ◽  
Composition Analysis ◽  
X Ray Diffraction ◽  
Sediment Composition ◽  
X Ray

scholarly journals Struvite Grown in Gel, Its Crystal Structure at 90 K and Thermoanalytical Study

Crystals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 89 ◽  
Author(s):  
Jolanta Prywer ◽  
Lesław Sieroń ◽  
Agnieszka Czylkowska
Keyword(s):  
Thermal Analysis ◽  
Sodium Metasilicate ◽  
X Ray Diffraction ◽  
Gel Growth ◽  
Growth Technique ◽  
Thermoanalytical Study ◽  
X Ray ◽  
Cell Parameters ◽  
Thermal Analysis Techniques ◽  
Derivative Thermogravimetry

In this article, we report the crystallization of struvite in sodium metasilicate gel by single diffusion gel growth technique. The obtained crystals have a very rich morphology displaying 18 faces. In this study, the habit and morphology of the obtained struvite crystals are analyzed. The crystals were examined and identified as pure struvite by single X-ray diffraction (XRD). The orthorhombic polar noncentrosymmetric space group Pmn21 was identified. The structure of the crystal was determined at a temperature of 90 K. Our research indicates a lack of polymorphism, resulting from the temperature lowering to 90 K, which has not been previously reported. The determined unit cell parameters are as follows a = 6.9650(2) Å, b = 6.1165(2) Å, c = 11.2056(3) Å. The structure of struvite is presented here with a residual factor R1 = 1.2% at 0.80 Å resolution. We also present thermoanalytical study of struvite using thermal analysis techniques such as thermogravimetry (TG), derivative thermogravimetry (DTG) and differential thermal analysis (DTA).

Selective catalytic reduction of NO by Co-Mn based nanocatalysts

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Vahid Zabihi ◽  
Mohammad Hasan Eikani ◽  
Mehdi Ardjmand ◽  
Seyed Mahdi Latifi ◽  
Alireza Salehirad
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Energy Dispersive ◽  
Diffraction Field ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
Acidic Sites ◽  
Temperature Window ◽  
Temperature Programmed

Abstract One of the most significant aspects in selective catalytic reduction (SCR) of nitrogen oxides (NOx) is developing suitable catalysts by which the process occurs in a favorable way. At the present work SCR reaction by ammonia (NH3-SCR) was conducted using Co-Mn spinel and its composite with Fe-Mn spinel, as nanocatalysts. The nanocatalysts were fabricated through liquid routes and then their physicochemical properties such as phase composition, degree of agglomeration, particle size distribution, specific surface area and also surface acidic sites have been investigated by X-ray diffraction, Field Emission Scanning Electron Microscope, Energy-dispersive X-ray spectroscopy, energy dispersive spectroscopy mapping, Brunauer–Emmett–Teller, temperature-programmed reduction (H2-TPR) and temperature-programmed desorption of ammonia (NH3-TPD) analysis techniques. The catalytic activity tests in a temperature window of 150–400 °C and gas hourly space velocities of 10,000, 18,000 and 30,000 h−1 revealed that almost in all studied conditions, CoMn2O4/FeMn2O4 nanocomposite exhibited better performance in SCR reaction than CoMn2O4 spinel.

Problems Associated with Kα Doublet in Residual Stress Measurements

1979 ◽  
Vol 23 ◽  
pp. 333-339
Author(s):  
S. K. Gupta ◽  
B. D. Cullity
Keyword(s):  
Residual Stress ◽  
Silicon Powder ◽  
Lattice Parameter ◽  
Diffraction Peak ◽  
Parameter Determination ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
The Difference ◽  
Similar Accuracy

Since the measurement of residual stress by X-ray diffraction techniques is dependent on the difference in angle of a diffraction peak maximum when the sample is examined consecutively with its surface at two different angles to the diffracting planes, it is important that these diffraction angles be obtained precisely, preferably with an accuracy of ± 0.01 deg. 2θ. Similar accuracy is desired in precise lattice parameter determination. In such measurements, it is imperative that the diffractometer be well-aligned. It is in the context of diffractometer alignment with the aid of a silicon powder standard free of residual stress that the diffraction peak analysis techniques described here have been developed, preparatory to residual stress determinations.

Sign in / Sign up

Export Citation Format

Share Document