scholarly journals Lithium in Greenland ice cores measured by ion chromatography

2002 ◽  
Vol 35 ◽  
pp. 243-249 ◽  
Author(s):  
Marie-Louise Siggaard-Andersen ◽  
Jørgen Peder Steffensen ◽  
Hubertus Fischer
Keyword(s):  
Ion Chromatography ◽  
Ice Core ◽  
Ice Cores ◽  
Lithium Content ◽  
Seasonal Cycles ◽  
Ionic Component ◽  
Polar Ice ◽  
Cold Event ◽  
The North ◽  
Sample Preconcentration

AbstractIon chromatography (IC) is a widely used technique for analyzing ice cores for ions like Na+, NH4+, K+, Mg2+, Ca2+, F–, MSA–, Cl–, NO2– and SO42– that are present in polar ice cores at ppb level. By using sample preconcentration and an optimized separation technique, we have been able to detect Li+ in ice-core samples in concentrations as low as 0.0001 μeq kg–1 or 0.7 ppt by IC. During routine analysis of ions in ice cores, the lithium content has been evaluated and recorded. the IC technique used in these measurements and some exemplary IC data from the Greenland Icecore Project (GRIP) and the North Greenland Icecore Project (NorthGRIP) ice cores are presented. By these data we introduce Li+ concentration as a new parameter in the analysis of ice cores. Like other ions, Li+ reflects climatic changes and shows seasonal cycles. on the basis of the geochemistry of lithium, we suggest that Li+ measured in the Greenland ice cores is derived from mineral dust. However, data from the NorthGRIP ice core representing the 8.2 kyr BPHolocene cold event show a strong Li+ signal that does not correlate with any other ionic component measured. This means that the lithium content in ice cores is a signal with its own pattern, which is not yet understood.

scholarly journals A Synoptic Scale Perspective on Greenland Ice Core δ18O Variability and Related Teleconnection Patterns

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 294
Author(s):  
Norel Rimbu ◽  
Monica Ionita ◽  
Gerrit Lohmann
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Synoptic Scale ◽  
Local Climate ◽  
Rossby Wave Breaking ◽  
Weather Patterns ◽  
Teleconnection Patterns ◽  
Climate Anomalies ◽  
The North ◽  
Oxygen Isotope Ratios

The variability of stable oxygen isotope ratios (δ18O) from Greenland ice cores is commonly linked to changes in local climate and associated teleconnection patterns. In this respect, in this study we investigate ice core δ18O variability from a synoptic scale perspective to assess the potential of such records as proxies for extreme climate variability and associated weather patterns. We show that positive (negative) δ18O anomalies in three southern and central Greenland ice cores are associated with relatively high (low) Rossby Wave Breaking (RWB) activity in the North Atlantic region. Both cyclonic and anticyclonic RWB patterns associated with high δ18O show filaments of strong moisture transport from the Atlantic Ocean towards Greenland. During such events, warm and wet conditions are recorded over southern, western and central part of Greenland. In the same time the cyclonic and anticyclonic RWB patterns show enhanced southward advection of cold polar air masses on their eastern side, leading to extreme cold conditions over Europe. The association between high δ18O winters in Greenland ice cores and extremely cold winters over Europe is partly explained by the modulation of the RWB frequency by the tropical Atlantic sea surface temperature forcing, as shown in recent modeling studies. We argue that δ18O from Greenland ice cores can be used as a proxy for RWB activity in the Atlantic European region and associated extreme weather and climate anomalies.

scholarly journals Impact of precipitation intermittency on NAO-temperature signals in proxy records

2013 ◽  
Vol 9 (2) ◽  
pp. 871-886 ◽  
Author(s):  
M. Casado ◽  
P. Ortega ◽  
V. Masson-Delmotte ◽  
C. Risi ◽  
D. Swingedouw ◽  
...  
Keyword(s):  
General Circulation ◽  
Ice Core ◽  
Circulation Model ◽  
Ice Cores ◽  
Stable Isotope Ratio ◽  
Global Network ◽  
Temporal Correlations ◽  
The North ◽  
The North Atlantic Oscillation ◽  
The Impact

Abstract. In mid and high latitudes, the stable isotope ratio in precipitation is driven by changes in temperature, which control atmospheric distillation. This relationship forms the basis for many continental paleoclimatic reconstructions using direct (e.g. ice cores) or indirect (e.g. tree ring cellulose, speleothem calcite) archives of past precipitation. However, the archiving process is inherently biased by intermittency of precipitation. Here, we use two sets of atmospheric reanalyses (NCEP (National Centers for Environmental Prediction) and ERA-interim) to quantify this precipitation intermittency bias, by comparing seasonal (winter and summer) temperatures estimated with and without precipitation weighting. We show that this bias reaches up to 10 °C and has large interannual variability. We then assess the impact of precipitation intermittency on the strength and stability of temporal correlations between seasonal temperatures and the North Atlantic Oscillation (NAO). Precipitation weighting reduces the correlation between winter NAO and temperature in some areas (e.g. Québec, South-East USA, East Greenland, East Siberia, Mediterranean sector) but does not alter the main patterns of correlation. The correlations between NAO, δ18O in precipitation, temperature and precipitation weighted temperature are investigated using outputs of an atmospheric general circulation model enabled with stable isotopes and nudged using reanalyses (LMDZiso (Laboratoire de Météorologie Dynamique Zoom)). In winter, LMDZiso shows similar correlation values between the NAO and both the precipitation weighted temperature and δ18O in precipitation, thus suggesting limited impacts of moisture origin. Correlations of comparable magnitude are obtained for the available observational evidence (GNIP (Global Network of Isotopes in Precipitation) and Greenland ice core data). Our findings support the use of archives of past δ18O for NAO reconstructions.

scholarly journals A 60 000 year Greenland stratigraphic ice core chronology

2008 ◽  
Vol 4 (1) ◽  
pp. 47-57 ◽  
Author(s):  
A. Svensson ◽  
K. K. Andersen ◽  
M. Bigler ◽  
H. B. Clausen ◽  
D. Dahl-Jensen ◽  
...  
Keyword(s):  
North Atlantic ◽  
Time Scale ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Annual Layer ◽  
Zone Ii ◽  
Absolute Age ◽  
Age Estimates ◽  
New Time

Abstract. The Greenland Ice Core Chronology 2005 (GICC05) is a time scale based on annual layer counting of high-resolution records from Greenland ice cores. Whereas the Holocene part of the time scale is based on various records from the DYE-3, the GRIP, and the NorthGRIP ice cores, the glacial part is solely based on NorthGRIP records. Here we present an 18 ka extension of the time scale such that GICC05 continuously covers the past 60 ka. The new section of the time scale places the onset of Greenland Interstadial 12 (GI-12) at 46.9±1.0 ka b2k (before year AD 2000), the North Atlantic Ash Zone II layer in GI-15 at 55.4±1.2 ka b2k, and the onset of GI-17 at 59.4±1.3 ka b2k. The error estimates are derived from the accumulated number of uncertain annual layers. In the 40–60 ka interval, the new time scale has a discrepancy with the Meese-Sowers GISP2 time scale of up to 2.4 ka. Assuming that the Greenland climatic events are synchronous with those seen in the Chinese Hulu Cave speleothem record, GICC05 compares well to the time scale of that record with absolute age differences of less than 800 years throughout the 60 ka period. The new time scale is generally in close agreement with other independently dated records and reference horizons, such as the Laschamp geomagnetic excursion, the French Villars Cave and the Austrian Kleegruben Cave speleothem records, suggesting high accuracy of both event durations and absolute age estimates.

scholarly journals Polar ice stratigraphy from laser-light scattering: scattering from meltwater

1994 ◽  
Vol 40 (136) ◽  
pp. 504-508 ◽  
Author(s):  
Michael Ram ◽  
Matthias Illing
Keyword(s):  
Light Scattering ◽  
Sample Size ◽  
Tree Ring ◽  
Laser Light ◽  
Ice Core ◽  
Ice Cores ◽  
Laser Light Scattering ◽  
Polar Ice ◽  
The Core ◽  
Considerable Success

Abstract We describe a new laser-light-scattering instrument for measuring variations in dust concentration along polar ice cores. We have used this instrument with considerable success on the GISP2 ice core from central Greenland. Reproducibility is excellent and the required ice-sample size is relatively small. When combined with visual stratigraphy and ECM, the distinct annual spring/ summer dust peaks we observe can be used to date the core with tree-ring-like precision.

scholarly journals Towards radiocarbon dating of ice cores

2009 ◽  
Vol 55 (194) ◽  
pp. 985-996 ◽  
Author(s):  
M. Sigl ◽  
T.M. Jenk ◽  
T. Kellerhals ◽  
S. Szidat ◽  
H.W. Gäggeler ◽  
...  
Keyword(s):  
Aerosol Particles ◽  
Ice Core ◽  
Ice Cores ◽  
Swiss Alps ◽  
Carbonaceous Aerosol ◽  
Polar Ice ◽  
Low Latitude ◽  
Bolivian Andes ◽  
Glacier Ice ◽  
Dating Method

AbstractA recently developed dating method for glacier ice, based on the analysis of radiocarbon in carbonaceous aerosol particles, is thoroughly investigated. We discuss the potential of this method to achieve a reliable dating using examples from a mid- and a low-latitude ice core. Two series of samples from Colle Gnifetti (4450 m a.s.l., Swiss Alps) and Nevado Illimani (6300 m a.s.l., Bolivian Andes) demonstrate that the 14C ages deduced from the water-insoluble organic carbon fraction represent the age of the ice. Sample sizes ranged between 7 and 100 μg carbon. For validation we compare our results with those from independent dating. This new method is thought to have major implications for dating non-polar ice cores in the future, as it provides complementary age information for time periods not accessible with common dating techniques.

scholarly journals Precipitation record since AD 1600 from ice cores on the central Tibetan Plateau

2008 ◽  
Vol 4 (3) ◽  
pp. 175-180 ◽  
Author(s):  
T. Yao ◽  
K. Duan ◽  
B. Xu ◽  
N. Wang ◽  
X. Guo ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Northern Tibetan Plateau ◽  
Central Tibetan Plateau ◽  
Precipitation Record ◽  
Ice Field ◽  
The 19Th Century

Abstract. Lack of reliable long-term precipitation record from the northern Tibetan Plateau has constrained our understanding of precipitation variations in this region. We drilled an ice core on the Puruogangri Ice Field in the central Tibetan Plateau in 2000 to reveal the precipitation variations. The well dated part of the core extends back to AD 1600, allowing us to construct a 400-year annual accumulation record. This record shows that the central Tibetan plateau experienced a drier period with an average annual precipitation of ~300 mm in the 19th century, compared to ~450 mm in the wetter periods during 1700–1780 and the 20th century. This pattern agrees with precipitation reconstructions from the Dunde and Guliya ice cores on the northern Plateau but differs from that found in the Dasuopu ice cores from the southern Plateau The north-south contrasts in precipitation reconstruction reveals difference in moisture origin between the south Tibetan Plateau dominated by the Asian monsoon and the north Tibetan Plateau dominated by the continental recycling and the westerlies.

Environmental records from polar ice cores

1990 ◽  
Vol 330 (1615) ◽  
pp. 459-462 ◽  
Keyword(s):  
Solar Activity ◽  
Ice Core ◽  
Ice Cores ◽  
Polar Ice ◽  
Cosmogenic Isotope ◽  
Wide Range ◽  
Recent Part ◽  
Ice Core Records

Polar ice cores provide a wide range of information on past atmospheric climate (temperature, precipitation) and environment (gas and aerosol concentrations). The dating can be very accurate for the more recent part of the records but accuracy decreases with depth and time. Measurements of cosmogenic isotope concentrations (such as 10 Be) provide information on palaeo-precipitation rates and particular events can be used to correlate ice core records. Besides these climatic applications, 10 Be concentration records in ice cores also contain information on solar activity changes.

Timing and duration of North American glacial lake discharges and the Younger Dryas climate reversal

2011 ◽  
Vol 75 (3) ◽  
pp. 541-551 ◽  
Author(s):  
John A. Rayburn ◽  
Thomas M. Cronin ◽  
David A. Franzi ◽  
Peter L.K. Knuepfer ◽  
Debra A. Willard
Keyword(s):  
Ocean Circulation ◽  
North Atlantic ◽  
North American ◽  
Younger Dryas ◽  
Ice Cores ◽  
Cold Event ◽  
Lawrence Estuary ◽  
The North ◽  
The North Atlantic ◽  
Proglacial Lake

AbstractRadiocarbon-dated sediment cores from the Champlain Valley (northeastern USA) contain stratigraphic and micropaleontologic evidence for multiple, high-magnitude, freshwater discharges from North American proglacial lakes to the North Atlantic. Of particular interest are two large, closely spaced outflows that entered the North Atlantic Ocean via the St. Lawrence estuary about 13,200–12,900 cal yr BP, near the beginning of the Younger Dryas cold event. We estimate from varve chronology, sedimentation rates and proglacial lake volumes that the duration of the first outflow was less than 1 yr and its discharge was approximately 0.1 Sv (1 Sverdrup = 106 m3 s−1). The second outflow lasted about a century with a sustained discharge sufficient to keep the Champlain Sea relatively fresh for its duration. According to climate models, both outflows may have had sufficient discharge, duration and timing to affect meridional ocean circulation and climate. In this report we compare the proglacial lake discharge record in the Champlain and St. Lawrence valleys to paleoclimate records from Greenland Ice cores and Cariaco Basin and discuss the two-step nature of the inception of the Younger Dryas.

scholarly journals Grain Growth in Polar Ice: II. Application

1986 ◽  
Vol 32 (112) ◽  
pp. 425-433 ◽  
Author(s):  
R.B. Alley ◽  
J.H. Perepezko ◽  
C.R. Bentley
Keyword(s):  
Grain Boundaries ◽  
Grain Growth ◽  
Growth Rates ◽  
Boundary Migration ◽  
Ice Core ◽  
Ice Cores ◽  
Geometric Constraints ◽  
Polar Ice ◽  
High Concentration ◽  
Micro Particles

AbstractGrain growth observed in polar ice that is not deforming rapidly can be accounted for if concentrations and distributions of extrinsic materials (microparticles, bubbles, and dissolved impurities) are characterized fully. Dissolved impurities segregate to grain boundaries and slow grain growth in all cold glacial ice. The high concentration of soluble impurities in Wisconsinan ice from the Dome C (Antarctica) ice core (and perhaps other ice cores) probably causes the small grain-sizes observed in that ice. Microparticles have little effect on grain growth in ordinary ice. In ice layers that appear dirty owing to concentrations of volcanic tephra (such as in the Byrd Station (Antarctica) ice core) or of morainal material, micro particles reduce grain-growth rates significantly. The relatively high vapor pressure of ice allows rapid growth and high mobility of intergranular necks, so grain growth in firn is limited by boundary migration rather than by neck growth. Bubbles formed by pore close-off at the firn-ice transition are less mobile than grain boundaries, causing bubble-boundary separation whenever geometric constraints are satisfied; however, such separation reduces grain-growth rates by only about 10%. The observed linear increase of grain area with time is thus predicted by theory, but the growth rate depends on soluble-impurity concentrations as well as on temperature.

scholarly journals An optimized multi-proxy, multi-site Antarctic ice and gas orbital chronology (AICC2012): 120–800 ka

2013 ◽  
Vol 9 (4) ◽  
pp. 1715-1731 ◽  
Author(s):  
L. Bazin ◽  
A. Landais ◽  
B. Lemieux-Dudon ◽  
H. Toyé Mahamadou Kele ◽  
D. Veres ◽  
...  
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Companion Paper ◽  
Polar Ice ◽  
Uncertainty Range ◽  
Air Content ◽  
Dating Method ◽  
Long Timescales ◽  
Age Constraints ◽  
Mis 5

Abstract. An accurate and coherent chronological framework is essential for the interpretation of climatic and environmental records obtained from deep polar ice cores. Until now, one common ice core age scale had been developed based on an inverse dating method (Datice), combining glaciological modelling with absolute and stratigraphic markers between 4 ice cores covering the last 50 ka (thousands of years before present) (Lemieux-Dudon et al., 2010). In this paper, together with the companion paper of Veres et al. (2013), we present an extension of this work back to 800 ka for the NGRIP, TALDICE, EDML, Vostok and EDC ice cores using an improved version of the Datice tool. The AICC2012 (Antarctic Ice Core Chronology 2012) chronology includes numerous new gas and ice stratigraphic links as well as improved evaluation of background and associated variance scenarios. This paper concentrates on the long timescales between 120–800 ka. In this framework, new measurements of δ18Oatm over Marine Isotope Stage (MIS) 11–12 on EDC and a complete δ18Oatm record of the TALDICE ice cores permit us to derive additional orbital gas age constraints. The coherency of the different orbitally deduced ages (from δ18Oatm, δO2/N2 and air content) has been verified before implementation in AICC2012. The new chronology is now independent of other archives and shows only small differences, most of the time within the original uncertainty range calculated by Datice, when compared with the previous ice core reference age scale EDC3, the Dome F chronology, or using a comparison between speleothems and methane. For instance, the largest deviation between AICC2012 and EDC3 (5.4 ka) is obtained around MIS 12. Despite significant modifications of the chronological constraints around MIS 5, now independent of speleothem records in AICC2012, the date of Termination II is very close to the EDC3 one.

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