Elaboration of weatherproof steel 06гн3мд for structures of bridges exploited in coastal zone

Author(s):  
G. A. Kunitsin ◽  
А. А. Pridein ◽  
O. V. Samokhina ◽  
D. V. Nizhel’skii ◽  
E. M. Gitman

At present decreasing of costs and increasing of efficiency are the most priority directions in any industry. Developing in this way, JSC “Ural steel” together with FGUP “CNIIchermet after I.P. Barding” had mastered production of sheet metal product with increased resistivity against atmosphere corrosion made of steel 14ХГНДЦ for construction of bridges. Because of specific chemical composition of the steel, in the process of metal structures running in the open air, a solid strong oxide film is formed on the metal of the structures which prevents further corrosion without painting. For bridge builders elimination of costly operation of painting of span structures will enable to decrease considerably the costs of bridges construction and running. Having many advantages, steel 14ХГНДЦ has some restrictions in applications for steel structures without painting, as follows: - in sea zone according to domestic norms no close than 500 m from coastline; - in case of disorderly conditions of protective film formation and/or application of salt solutions for surface cleaning (as a rule the restrictions refer to traffic area of bridge span). In view of that for JSC “Ural Steel”, as the leading producer of bridge steel in Russia, an actual task erose: to elaborate and create a weatherproof steel, which could not only operate the whole period of a bridge running without additional protection at bridges con­struction through sea areas or close to coastline, but also withstand severe climate conditions of our country, including areas of High North with temperature lower -50°С. To solve the task together with OJSC “Institute Giprostroymost” and JSC BNIIZhT, a research work was accomplished to elaborate a system of alloying new steel 06ГН3МД with nickel content ~3.0 %, as well as production modes ensuring required corrosion resistance for operation in sea zone. Results of laboratory studies of the new weatherproof steel 06ГН3МД for application in bridge  structures for coastal conditions and sea areas presented. Results of mechanical, technological, corrosion as well as fatigue tests of rolling products of the elaborated steel presented. It was established by laboratory studies that the new steel is weatherproofed and ensures lower corrosion losses, higher impact toughness at negative temperatures and plasticity comparing with steels used at present. It was shown that the strength class, technology and modes of factory welding of steel 06ГН3МД meet the  requirements to steel span structures of bridges. Base on the results of the studies, the chemical composition of the steel 06ГН3МД was specified, as well as modes of heat treatment, ensuring the required characteristics with significant acceding. It was established that samples of the new steel 06ГН3МД showed considerably higher corrosion resistance - in average by 20% comparing with steel 14ХГНДЦ. At that corrosion resistance tests of welded joints of the new steel showed even higher resistance of the seam comparing with the basic metal, which speaks about quality selection of welding modes and welding materials.

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4074
Author(s):  
Felix Großwendt ◽  
Louis Becker ◽  
Arne Röttger ◽  
Abootorab Baqerzadeh Chehreh ◽  
Anna Luise Strauch ◽  
...  

This work aims to show the impact of the allowed chemical composition range of AISI 316L stainless steel on its processability in additive manufacturing and on the resulting part properties. ASTM A276 allows the chromium and nickel contents in 316L stainless steel to be set between 16 and 18 mass%, respectively, 10 and 14 mass%. Nevertheless, the allowed compositional range impacts the microstructure formation in additive manufacturing and thus the properties of the manufactured components. Therefore, this influence is analyzed using three different starting powders. Two starting powders are laboratory alloys, one containing the maximum allowed chromium content and the other one containing the maximum nickel content. The third material is a commercial powder with the chemical composition set in the middle ground of the allowed compositional range. The materials were processed by laser-based powder bed fusion (PBF-LB/M). The powder characteristics, the microstructure and defect formation, the corrosion resistance, and the mechanical properties were investigated as a function of the chemical composition of the powders used. As a main result, solid-state cracking could be observed in samples additively manufactured from the starting powder containing the maximum nickel content. This is related to a fully austenitic solidification, which occurs because of the low chromium to nickel equivalent ratio. These cracks reduce the corrosion resistance as well as the elongation at fracture of the additively manufactured material that possesses a low chromium to nickel equivalent ratio of 1.0. A limitation of the nickel equivalent of the 316L type steel is suggested for PBF-LB/M production. Based on the knowledge obtained, a more detailed specification of the chemical composition of the type 316L stainless steel is recommended so that this steel can be PBF-LB/M processed to defect-free components with the desired mechanical and chemical properties.


Alloy Digest ◽  
2001 ◽  
Vol 50 (11) ◽  

Abstract Magnifer 8105 and 8105 So are soft magnetic alloys with a high nickel content. Typical applications for 8105 are recording heads, while 8105 So has additional applications. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-575. Producer or source: Krupp VDM GmbH.


Alloy Digest ◽  
1982 ◽  
Vol 31 (6) ◽  

Abstract Type HN is an iron-chromium-nickel alloy containing sufficient chromium for good high-temperature corrosion resistance and with nickel content in excess of the chromium. This alloy has properties somewhat similar to the more widely used ACI Type HT alloy but with better ductility. Type HN is used for highly stressed components in the 1800-2000 F temperature range. It is used in the aircraft, automotive, petroleum, petrochemical and power industries for a wide range of components and parts. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: SS-410. Producer or source: Various stainless steel casting companies.


Resources ◽  
2019 ◽  
Vol 8 (2) ◽  
pp. 108 ◽  
Author(s):  
Alberto Mannu ◽  
Gina Vlahopoulou ◽  
Paolo Urgeghe ◽  
Monica Ferro ◽  
Alessandra Del Caro ◽  
...  

The chemical composition and the color of samples of waste cooking oils (WCOs) were determined prior to and after filtration on two different pads of bentonite differing in particle size. The volatile fraction was monitored by headspace solid-phase microextraction (HS-SPME) coupled with gas-chromatography, while the variation of the composition of the main components was analyzed by 1H NMR. Both techniques allowed the detection of some decomposition products, such as polymers, terpenes, and derivatives of the Maillard process. The analysis of the chemical composition prior to and after bentonite treatment revealed a tendency for the clays to retain specific chemical groups (such as carboxylic acids or double bonds), independent of their particle size. A pair comparison test was conducted in order to detect the sensory differences of the intensity of aroma between the WCO treated with the two different bentonites. In addition, characterization of the bentonite by means of powder X-ray diffraction (XRD) and thermogravimetric measurements (TG) was performed.


1986 ◽  
Vol 28 (4) ◽  
pp. 536-539 ◽  
Author(s):  
Axel J. J. Dietrich

It is well known that there is a strong influence of fixation, i.e., acetic methanol versus formaldehyde, on the chromosome morphology at stages of the first meiotic division. In this study the influence of both these types of fixation on the morphology of mitotic chromosomes was examined in human lymphocytes. After methanol – acetic acid (3:1) fixation, the chromosomes show the "classical" condensed shape in which it is not always possible to recognize the two sister chromatids. These chromosomes are accessible to the conventional G-, R-, and C-banding techniques. After formaldehyde fixation at a relatively high pH, the chromosomes are thinner and longer (two to six times) when compared with chromosomes following methanol – acetic acid fixation. They show a scaffold-like morphology, sometimes with a halo of thin material around it. In all cases the two sister chromatids could be recognized. This chromosome structure could be easily stained with silver, Giemsa, 4,6-diamino-2-phenyl-indole (DAPI), and fluorescein isocyanate isomere 1 (FITC). The results obtained following these stainings gave no indication to any specific chemical composition of a probable central scaffold. The scaffold-like structures were not accessible to G-, R-, or C-banding techniques. The only effect observed following these banding techniques was the disappearance of the halo of thin material around the central scaffold-like structure.Key words: chromosome structure, fixation influence, human lymphocytes.


2021 ◽  
Author(s):  
Dmitry Gospodarev ◽  
Igor Lymar ◽  
Aleksandra Rakutko ◽  
Anastasia Antuseva ◽  
Dmitry Tkachev

Abstract Nowadays, chemical EOR methods are becoming more and more relevant, among which the alkali-surfactant-polymer flooding is of particular interest. The efficiency of this technology largely depends on the correct choice of the components of chemical formulation, which should be based on a set of laboratory experiments carried out in a given sequence. This paper presents a methodological approach to laboratory studies in order to develop an optimal surfactant-polymer formulation, taking into account the geological and physical characteristics of the target field and the properties of reservoir fluids. The experimental part of the research work was carried out in several stages, involving the analysis of the physicochemical characteristics of reservoir oil, the screening studies of surfactant and polymer samples, as well as a series of coreflood tests with a selected chemical formulation on the terrigenous reservoir models. During screening studies, the solubility and compatibility of the chemical components, the phase behavior of surfactant solutions with oil at different salinity values and water-oil ratios, static adsorption of chemicals on the rock and their thermal stability at reservoir temperature were investigated. Optimization of the chemical formulation was based on the results of IFT measurements of the surfactant solutions and rheological studies of the polymer solutions. At the stage of coreflood tests, physical simulation of the surfactant-polymer flooding was carried out on reservoir models using natural core material in order to optimize the composition and slug size of the developed chemical formulation. The obtained results of the displacement experiment were matched by numerical 1D simulation. Based on the results of the studies performed, an effective surfactant-polymer formulation has been designed, which provides the ultra-low IFT (2.8·10−4 mN/m) values and the ability to form stable middle-phase microemulsions when interacting with oil. The findings of thermal stability and static adsorption experiments confirmed a feasibility of selected chemicals for practical application. Within the framework of the study, the key technical parameters of proposed formulation were determined, which are required for up-scaled simulation study of the chemical flooding process at pilot site.


2017 ◽  
Vol 8 (5) ◽  
pp. 544-564
Author(s):  
Argyro Drakakaki ◽  
Charis Apostolopoulos ◽  
Alexandros Katsaounis ◽  
Hasa Bjorn

Purpose Corrosive agent constitutes a major problem for constructions located in coastal areas, since it keeps affecting their durability. This phenomenon, in synergy with moisture and high temperatures, leads to premature deterioration of the structures. Under these conditions, the need for management of the problem of resistance of steel against corrosion is an issue of paramount importance and a challenge to the structural integrity and reliability. The paper aims to discuss these issues. Design/methodology/approach The need for management of the problem of resistance of steel against corrosion is an issue of paramount importance and a challenge to the structural integrity and reliability. In the present study, an effort was made to increase the corrosion resistance of the high strength and ductility dual-phase steel B500c category, with the use of different shot blasting processes, without any interference in the chemical composition or in the production mode. In particular, shot blasting treatment was used for both cleaning and creating compressive stresses on the surface of steel bars, according to the pertinent protocols. The modified samples were studied via both conventional characterization methods and electrochemical techniques. Findings Through the whole surface treatment process of B500c steel, a positive impact came about not only the corrosion resistance, but also the mechanical performance. Originality/value Shot blasting process aims to increase the corrosion resistance of high ductility dual-phase steel (B500c), without any interference in the chemical composition or in the production mode.


2016 ◽  
Vol 844 ◽  
pp. 38-45 ◽  
Author(s):  
Tatiana Liptáková ◽  
Martin Lovíšek ◽  
Branislav Hadzima

The Al-brasses are considered corrosion resistant construction materials often used to pipe systems in energy industry, where they are exposed to flowing liquids environments. In that system the brasses are loaded chemically and mechanically. The aim of our research work is to compare corrosion properties of four Al-brasses produced by different manufactures because in operation conditions they have dissimilar reliability and durability. The examined Al-brasses have similar chemical composition but differ in microstructure, surface state what affects their corrosion and mechanical properties. The effect of the mentioned parameters on corrosion and mechanical susceptibility to degradation are investigated by chosen experimental methods.


Author(s):  
R. Subasri

Surface cleaning and activation of substrates are two critical processes that affect the mechanical and corrosion resistance properties of protective coatings when deposited on the substrates. Surface cleaning removes the contaminants, for example, grease on the substrate, and surface activation introduces active bonds on the substrate thereby increasing the surface free energy. Conventionally, surface cleaning and activation of aluminum and its alloys are carried out by a wet chemical technique. A convenient and safe alternate to the wet chemical cleaning/activation would be to use plasma for the same purpose. Plasma surface pre-treatment greatly improves adhesion of coatings deposited, which is very vital for good corrosion protection and mechanical properties such as scratch and abrasion resistance. Cold and atmospheric air plasma treatments have been the most widely studied pre-treatments for Al alloys. This article will discuss the advancements in the use of plasma treatment on Al/Al alloys and its effect on corrosion resistance and mechanical properties of coatings deposited after the surface treatment.


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