scholarly journals The Removal of Heavy Metals from the Leachate of Aged Landfill: The Application of the Fenton Process and Nanosilica Absorbent

2021 ◽  
Vol 19 (6) ◽  
pp. 1-8
Author(s):  
Kamran Taghavi ◽  
◽  
Dariush Naghipour ◽  
Seyed Davoud Ashrafi ◽  
Malihe Salehi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Retention Time ◽  
Fenton Process ◽  
Leachate Treatment ◽  
Removal Rates ◽  
Anaerobic Process ◽  
Anaerobic Reactor ◽  
Anaerobic Reactors ◽  
Removal Of Heavy Metals ◽  
And Control

Since leachate is typically composed of numerous constituents, its management requires special attention. After the raw leachate of Saravan in Rasht (Guilan Province, Iran) was transferred to a laboratory and its specifications were determined, it was subjected to experiments by the bench-scale method. The analyses of pH and heavy metals were performed in the main and control anaerobic reactors at time zero, before precipitation, and two hours after precipitation. After the anaerobic process was over and the optimal retention time was identified in the anaerobic reactor, the removal of heavy metals was analyzed by the Fenton process and nanosilica absorbent in leachate treatment. In the primary anaerobic reactor, the highest and lowest removal rates were 59 and 39% for Ni and Cu, respectively. In the Fenton process with optimal H2O2/Fe+2 ratio, Cu and Hg showed the lowest and highest removal rates of 22.4 and 54.54%, respectively. At the optimal rate of nanosilica absorbent and the retention time of 15 min, As was removed maximally with an efficiency of 38% and Cu was removed minimally. The results revealed that the integration of the anaerobic process with the Fenton process and nanosilica absorbent was very effective in removing heavy metals from the aged landfill leachate.

scholarly journals Application of Electrocoagulation with a New Steel-Swarf-Based Electrode for the Removal of Heavy Metals and Total Coliforms from Sanitary Landfill Leachate

2021 ◽  
Vol 11 (11) ◽  
pp. 5009
Author(s):  
Mayk Teles de Oliveira ◽  
Ieda Maria Sapateiro Torres ◽  
Humberto Ruggeri ◽  
Paulo Scalize ◽  
Antonio Albuquerque ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Landfill Leachate ◽  
Lower Cost ◽  
Sanitary Landfill ◽  
Leachate Treatment ◽  
Removal Of Heavy Metals ◽  
Waste Characteristics ◽  
Electrode Passivation ◽  
Steel Swarf ◽  
Sanitary Landfill Leachate

Sanitary landfill leachate (LL) composition varies according to climate variables variation, solid waste characteristics and composition, and landfill age. Leachate treatment is essentially carried out trough biological and physicochemical processes, which have showed variability in efficiency and appear a costly solution for the management authorities. Electrocoagulation (EC) seems a suitable solution for leachate treatment taking into account the characteristics of the liquor. One of the problems of EC is the electrode passivation, which affects the longevity of the process. One solution to this problem could be the replacement of the electrode by one made of recyclable material, which would make it possible to change it frequently and at a lower cost. The objective of the present work was to evaluate the removal of heavy metals (As, Ba, Cd, Cr, Cu, Fe, Pb, Mn, Ni, Se and Zn) and coliforms from a LL by EC using electrodes made from steel swarf (SfE) up to 8 h. Removal efficiencies of detected heavy metals were 51%(Cr), 59%(As), 71%(Cd), 72%(Zn), 92%(Ba), 95%(Ni) and >99%(Pb). The microbial load of coliforms in leachate was reduced from 10.76 × 104 CFU/mL (raw leachate) to less than 1 CFU/mL (after treatment with SfE) (i.e., approximately 100% reduction). The use of SfE in EC of LL is very effective in removing heavy metals and coliforms and can be used as alternative treatment solution for such effluents.

scholarly journals Sawdust for the Removal of Heavy Metals from Water: A Review

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4318
Author(s):  
Elie Meez ◽  
Abbas Rahdar ◽  
George Z. Kyzas
Keyword(s):  
Heavy Metals ◽  
Adsorption Mechanism ◽  
Freundlich Isotherm ◽  
Order Kinetic ◽  
Suitable Material ◽  
Removal Of Heavy Metals ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
And Control ◽  
Environmental Agencies

The threat of the accumulation of heavy metals in wastewater is increasing, due to their abilities to inflict damage to human health, especially in the past decade. The world’s environmental agencies are trying to issue several regulations that allow the management and control of random disposals of heavy metals. Scientific studies have heavily focused on finding suitable materials and techniques for the purification of wastewaters, but most solutions have been rejected due to cost-related issues. Several potential materials for this objective have been found and have been compared to determine the most suitable material for the purification process. Sawdust, among all the materials investigated, shows high potential and very promising results. Sawdust has been shown to have a good structure suitable for water purification processes. Parameters affecting the adsorption mechanism of heavy metals into sawdust have been studied and it has been shown that pH, contact time and several other parameters could play a major role in improving the adsorption process. The adsorption was found to follow the Langmuir or Freundlich isotherm and a pseudo second-order kinetic model, meaning that the type of adsorption was a chemisorption. Sawdust has major advantages to be considered and is one of the most promising materials to solve the wastewater problem.

scholarly journals Evaluation of Different Treatment Processes for Landfill Leachate Using Low-Cost Agro-Industrial Materials

Processes ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 111 ◽  
Author(s):  
Tawfiq J. H. Banch ◽  
Marlia M. Hanafiah ◽  
Abbas F. M. Alkarkhi ◽  
Salem S. A. Amr ◽  
Nurul U. M. Nizam
Keyword(s):  
Heavy Metals ◽  
Physicochemical Parameters ◽  
Low Cost ◽  
Hazardous Substances ◽  
Leachate Treatment ◽  
Treatment Processes ◽  
Removal Of Heavy Metals ◽  
Industrial Materials ◽  
Palm Oil Mill ◽  
Complex Liquid

Leachate is a complex liquid that is often produced from landfills, and it contains hazardous substances that may endanger the surrounding environment if ineffectively treated. In this work, four leachate treatment applications were examined: combined leachate/palm oil mill effluent (POME) (LP), leachate/tannin (LT), pre-(leachate/tannin) followed by post-(leachate/POME) (LT/LP), and pre-(leachate/POME) followed by post-(leachate/tannin) (LP/LT). The aim of this work is to evaluate and compare the performance of these treatment applications in terms of optimizing the physicochemical parameters and removing heavy metals from the leachate. The highest efficiency for the optimization of the most targeted physicochemical parameters and the removal of heavy metals was with the LP/LT process. The results are indicative of three clusters. The first cluster involves raw leachate (cluster 1), the second contains LP and LP/LT (cluster 2), and the third also consists of two treatment applications, namely, LT and LT/LP (cluster 3). The results demonstrate that LP/LT is the most appropriate method for leachate treatment using low-cost agro-industrial materials.

scholarly journals Plant-Based Tacca leontopetaloides Biopolymer Flocculant (TBPF) Produced High Removal of Heavy Metal Ions at Low Dosage

Processes ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 37
Author(s):  
Nurul Shuhada Mohd Makhtar ◽  
Juferi Idris ◽  
Mohibah Musa ◽  
Yoshito Andou ◽  
Ku Halim Ku Hamid ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Ions ◽  
Metal Ion ◽  
Metal Removal ◽  
Test Procedure ◽  
Synthetic Wastewater ◽  
Leachate Treatment ◽  
Low Concentration ◽  
Removal Of Heavy Metals

High removal of heavy metals using plant-based bioflocculant under low concentration is required due to its low cost, abundant source, and nontoxicity for improved wastewater management and utilization in the water industry. This paper presents a treatment of synthetic wastewater using plant-based Tacca leontopetaloides biopolymer flocculant (TBPF) without modification on its structural polymer chains. It produced a high removal of heavy metals (Zn, Pb, Ni, and Cd) at a low concentration of TBPF dosage. In our previous report, TBPF was characterized and successfully reduced the turbidity, total suspended solids, and color for leachate treatment; however, its effectiveness for heavy metal removal has not been reported. The removal of these heavy metals was performed using a standard jar test procedure at different pH values of synthetic wastewater and TBPF dosages. The effects of hydroxide ion, pH, initial TBPF concentration, initial metal ion concentration, and TBPF dosage were examined using one factorial at the time (OFAT). The results show that the highest removal for Zn, Pb, Ni, and Cd metal ions were 98.4–98.5%, 79–80%, 97–98%, and 92–93%, respectively, using 120 mg/L dosage from the initial concentration of 10% TBPF at pH 10. The final concentrations for Zn, Pb, Ni, and Cd metal ions were 0.043–0.044, 0.41–0.43, 0.037–0.054, and 0.11–0.13 mg/L, respectively, which are below the Standard B discharge limit set by the Department of Environment (DOE), Malaysia. The results show that TBPF has a high potential for the removal of heavy metals, particularly Zn, Pb, Ni, and Cd, in real wastewater treatment.

The Bioaccumulation Performance of Reeds and Cattails in a Constructed Treatment Wetland for Removal of Heavy Metals in Landfill Leachate Treatment (Etueffont, France)

2011 ◽  
Vol 223 (4) ◽  
pp. 1723-1741 ◽  
Author(s):  
Elise Grisey ◽  
Xavier Laffray ◽  
Océane Contoz ◽  
Eric Cavalli ◽  
Jacque Mudry ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Landfill Leachate ◽  
Treatment Wetland ◽  
Leachate Treatment ◽  
Removal Of Heavy Metals ◽  
Constructed Treatment Wetland

scholarly journals Modified Ziziphus spina-christi stones as green route for the removal of heavy metals

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Eman A. Assirey ◽  
Shadia M. Sirry ◽  
Hayfaa A. Burkani ◽  
Medhat A. Ibrahim
Keyword(s):  
Heavy Metals ◽  
Maximum Adsorption Capacity ◽  
Characteristic Functional ◽  
Chemically Modified ◽  
Green Route ◽  
Removal Of Heavy Metals ◽  
Ternary Metal ◽  
Uptake Process ◽  
And Control ◽  
By Products

AbstractGreen routes for remediation of heavy metals are worldwide challenges to overcome pollution problems on one hand and control the adverse impact of chemicals on the other hand. Biosorption is one of the most effective methods for removing lower level of heavy metals. The idea to apply natural resources as a green method for removal of heavy metals, this route has no adverse impacts on the environment. This study investigated the ability of chemically modified Ziziphus spina-christi stones (ZSCs) as agriculture by-products to perform the biosorption of Pb(II), Zn(II) and Cd(II) ions from wastewater in a single and ternary metal system. The characteristic functional groups of chemically modified ZSCs were analyzed by Fourier transform infrared. In comparison with acidic ZSCs, alkali-modified ZSCs by KOH was more effective and enhanced the removal efficiency of ZSCs. Using Langmuir isotherm, the maximum adsorption capacity on the modified ZSCs for Pb(II) was 9.06 mg/g, for Zn(II) obtained by using ZSC–citric acid was 4.19 mg/g and 5.38 mg/g for Cd(II) as obtained by using ZSC–H2O2. The molecular electrostatic potential, which was calculated at B3LYP/6-31G(d,p), indicated that each metal is di-hydrated, forming a complex with two units of amino acids. This mechanism demonstrated the uptake process by ZSCs.

Application of Iron Powder Reduction Method to Remove Heavy Metals in Waste Pickling Acid

2020 ◽  
Vol 980 ◽  
pp. 377-386
Author(s):  
Jing Liang Xie ◽  
Fei Fei Chi ◽  
Fan Li Meng ◽  
An Ran Peng
Keyword(s):  
Heavy Metals ◽  
Iron Powder ◽  
Removal Efficiency ◽  
Reduction Method ◽  
Free Acid ◽  
Removal Rate ◽  
Practical Application ◽  
Removal Rates ◽  
Magnetic Stirring ◽  
Removal Of Heavy Metals

The removal of heavy metals in waste pickling acid by iron powder reduction was studied. The effects of reaction time, reaction temperature and dosage of iron powder on the removal efficiency of Zn, Cr, Ni and Pb in waste pickling acid were investigated. The results showed that, the removal rate of Cr tended to be stable after 2 h of reaction under magnetic stirring. After 4 hours, the removal rate of Zn,Ni and Pb tended to be stable. The temperature was increased from 20°C to 90 °C, the removal rates of Ni and Pb could be increased by 9.09% and 11.6%, while the removal rates of Zn and Cr were only increased by 1.15% and 2.85%; Increasing the dosage of iron powder was beneficial to the removal of heavy metals in waste pickling acid, and the combined amount of free acid in the waste acid would affect the removal efficiency of heavy metals. The research results had important guiding significance for the practical application of iron powder reduction method in the heavy metal purification project of waste pickling acid.

Biosorption: An Eco-Friendly Technique for the Removal of Heavy Metals

2011 ◽  
Vol 2 (3) ◽  
pp. 1-8 ◽  
Author(s):  
Sasmita Sabat ◽  
◽  
R V Kavitha R V Kavitha ◽  
Shantha S L Shantha S L ◽  
Gopika Nair ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Removal Of Heavy Metals
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