scholarly journals Synthetic Process of Bio-Based Phenol Formaldehyde Adhesive Derived from Demethylated Wheat Straw Alkali Lignin and Its Curing Behavior

2021 ◽  
Vol 9 (5) ◽  
pp. 943-957
Author(s):  
Yan Song ◽  
Zhixin Wang ◽  
Xin Zhang ◽  
Rong Zhang ◽  
Jinchun Li
Polymers ◽  
2016 ◽  
Vol 8 (6) ◽  
pp. 209 ◽  
Author(s):  
Yan Song ◽  
Zhixin Wang ◽  
Ning Yan ◽  
Rong Zhang ◽  
Jinchun Li

2012 ◽  
Vol 550-553 ◽  
pp. 1293-1298 ◽  
Author(s):  
Lin Huo Gan ◽  
Ming Song Zhou ◽  
Xue Qing Qiu

Water-soluble carboxymethylated lignin (CML) was synthesized using wheat straw alkali lignin (WAL) in aqueous medium. The process of carboxymethylation was optimized with respect to the NaOH concentration, monochloroacetic acid concentration, reaction temperature and time. The optimized product has a yield of 80.47% and a carboxyl group content of 2.8231 mmol•g-1, respectively. The optimum conditions for carboxymethylation are NaOH concentration of 20.0% (wt%), monochloroacetic acid concentration of 37.5% (wt%), temperature of 70 °C and time of 90 min. The optimized CML was characterized by FTIR spectroscopy, 1H NMR spectroscopy and interfacial tension apparatus. The result shows that the substitution reaction of carboxymethylation occurs simultaneously in the phenolic hydroxyl group and aliphatic hydroxyl group in WAL. CML has the surface activity in water for industrial application as dispersant.


2018 ◽  
Vol 87 ◽  
pp. 105-108 ◽  
Author(s):  
William G. Hand ◽  
W. Robert Ashurst ◽  
Brian Via ◽  
Sujit Banerjee

RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 89599-89608 ◽  
Author(s):  
Shu Hong ◽  
Hailan Lian ◽  
Xiang Sun ◽  
Dong Pan ◽  
Arturo Carranza ◽  
...  

Choline chloride–ZnCl2 deep-eutectic solvent (ChCl–ZnCl2 DES), mole ratio 1 : 2, was used to improve the chemical reactivity of wheat straw alkali lignin under different temperatures and times of pretreatment.


2015 ◽  
Vol 24 (1) ◽  
pp. 72-76 ◽  
Author(s):  
Xinping Ouyang ◽  
Guodian Zhu ◽  
Xiangzhen Huang ◽  
Xueqing Qiu

2013 ◽  
Vol 834-836 ◽  
pp. 199-202 ◽  
Author(s):  
Ji Lei Chao ◽  
Fu Qiang Chu ◽  
Chang Li Xu ◽  
Hui Wang ◽  
Yu Xin Liu

To improve the added value of lignin, the modified alkali lignin of wheat straw was used to prepare waterborne UV-curable polyurethane. The purpose of this paper is to discuss the properties of the cured films made from the above lignin-based polyurethane. The mechanical and optical properties of the cured films were investigated. Results showed that the tensile storage modulus, tensile loss modulus, and tensile loss factor of the cured film were influenced by the addition of the lignin, which indicated that proper dosage of the lignin could change the micro-phase separation structure and improve the mechanical properties of the product. The addition of the lignin also influenced the gloss and light transmittance of the cured film. On the whole, the lignin-based polyurethane exhibits good mechanical and optical performance if proper proportion of the lignin was added to the product. The study was beneficial for utilizing the lignin in high value products.


2011 ◽  
Vol 295-297 ◽  
pp. 1639-1642 ◽  
Author(s):  
Hai Yan Mao ◽  
Ding Guo Zhou ◽  
Sun Guo Wang ◽  
Rui Yang

The waxy wheat straw surface and high SiO2content of wheat straw agrifibres make wheat straw-based panel production much more difficult than traditional wood-based panel manufacture. Plasma surface modification is regarded as one of the cost effective surface treatment techniques for many materials including natural fibers. In this study, plasma technique was employed to treat the surface of wheat straw. After the plasma treatment, the surface properties were then evaluated by determining the contact angles of 3 liquids on the wheat straw surface and by analysis using Fourier Transform Infrared Spectroscopy (FTIR).The results showed that the contact angles of water, glycerol, and UF resin after the plasma treatment decreased by 44.1%, 18.6%, and 24.9%, respectively. In the meantime, –OH, and -C=O groups increased according to the FTIR analysis. The FTIR analysis also indicated a significant SiO2reduction in the plasma treated wheat straw. Obviously, the plasma treatment improved the wettability of wheat straw, increased the numbers of oxygen-containing functional groups, and also removed the weak interface of wheat straw remarkably. By means of the plasma treatment, the internal bond property between modified wheat straw fibers was expected to enhance, and thus some cheaper traditional adhesives such as urea formaldehyde (UF) and phenol formaldehyde (PF) can be used for the wheat straw-based panel production instead of using expensive Diphenylmethane Diisocyanate (MDI).


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