Desilication of bamboo for pulp production

TAPPI Journal ◽  
2015 ◽  
Vol 14 (11) ◽  
pp. 743-749 ◽  
Author(s):  
TROY M. RUNGE ◽  
SCOTT PAUL
Keyword(s):  
Mechanical Treatment ◽  
Paper Industry ◽  
Black Liquor ◽  
Pulp Mill ◽  
Common Species ◽  
Silica Content ◽  
Kraft Pulping ◽  
High Silica ◽  
Pulp Properties ◽  
Dermis Layer

Bamboo is one of the world’s fastest growing feedstocks. It is a promising nonwood resource that can be used in the pulp and paper industry. Among more than 1200 species of bamboo, the timber varieties can be processed much like trees, allowing current pulp mill logistical systems to be used. Bamboo can be difficult to pulp because of its high silica content, which creates issues for black liquor recovery. This study compares two methods of reducing the silica content of a common species of timber bamboo. Specifically, the dermis layer of Moso bamboo (Phyllostachys edulis) was removed through mechanical treatment and then chipped. The same species was also chipped without treatment. The two chipped materials were then alkali extracted and subjected to kraft pulping experiments. The pulps were bleached with an OD0(EP)D1 sequence. The material was then refined and formed into handsheets. The results indicate that 80% of the silica could be removed from the bamboo material through a combination of dermal mechanical treatment and caustic chip extraction. Caustic chip extraction removed a significant portion of hemicellulose materials, which in turn lowered cooking yields but had minimal effect on pulp properties.

Role of Wood Extractives in Black Liquor Corrosiveness

CORROSION ◽  
2006 ◽  
Vol 62 (10) ◽  
pp. 911-917 ◽  
Author(s):  
P. E. Hazlewood ◽  
P. M. Singh ◽  
J. S. Hsieh
Keyword(s):  
Carbon Steel ◽  
Wood Species ◽  
Paper Industry ◽  
Black Liquor ◽  
Wood Chip ◽  
Pulp Mill ◽  
Kraft Pulping ◽  
Extractive Content ◽  
Operational Parameters ◽  
Black Liquors

Abstract In the pulp and paper industry, variability in the process and wood source may result in highly corrosive waste liquors, called black liquors, from the Kraft pulping process. Prior research has demonstrated corrosion rates of carbon steel in pulp mill equipment ranging from <0.03 mm/y to >2.54 mm/y, depending on the wood species pulped. In this study wood species-dependent corrosion is confirmed and age-dependent corrosion is investigated as a function of organic extractive content. The composition of the organic portion of black liquor depends largely on the wood species used. Organic components come from extractives in the wood chips or are generated from the degradation of lignin and other wood constituents during the pulping process. Depending upon the wood species used, some black liquor constituents have been identified to increase the corrosiveness of black liquors whereas others may act as corrosion inhibitors. Our research demonstrates the importance of operational parameters for wood species and wood chip usage and delivery to downstream process corrosion. Further, results show the importance of water-extracted organics in wood, such as long chain fatty acids, using a novel methodology for the separation of extractives and lignin breakdown products in the testing of black liquor corrosiveness with carbon steel A516-Grade 70 (UNS K02700).

scholarly journals The novel method to reduce the silica content in lignin recovered from black liquor originating from rice straw

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Nghi H. Do ◽  
Hieu H. Pham ◽  
Tan M. Le ◽  
Jeroen Lauwaert ◽  
Ludo Diels ◽  
...  
Keyword(s):  
Rice Straw ◽  
Black Liquor ◽  
Chemical Properties ◽  
Alkaline Treatment ◽  
Pilot Scale ◽  
Silica Content ◽  
Silica Removal ◽  
High Silica ◽  
Novel Method ◽  
Physical And Chemical

AbstractDifficulties in the production of lignin from rice straw because of high silica content in the recovered lignin reduce its recovery yield and applications as bio-fuel and aromatic chemicals. Therefore, the objective of this study is to develop a novel method to reduce the silica content in lignin from rice straw more effectively and selectively. The method is established by monitoring the precipitation behavior as well as the chemical structure of precipitate by single-stage acidification at different pH values of black liquor collected from the alkaline treatment of rice straw. The result illustrates the significant influence of pH on the physical and chemical properties of the precipitate and the supernatant. The simple two-step acidification of the black liquor at pilot-scale by sulfuric acid 20w/v% is applied to recover lignin at pH 9 and pH 3 and gives a percentage of silica removal as high as 94.38%. Following the developed process, the high-quality lignin could be produced from abundant rice straw at the industrial-scale.

scholarly journals Bioremediation of Agro-Based Pulp Mill Effluent by Microbial Consortium Comprising Autochthonous Bacteria

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Virendra Kumar ◽  
Purnima Dhall ◽  
Rita Kumar ◽  
Yogendra Prakash Singh ◽  
Anil Kumar
Keyword(s):  
Black Liquor ◽  
Oxygen Demand ◽  
Pulp Mill ◽  
Paper Mill ◽  
Kraft Pulping ◽  
Pulp And Paper ◽  
Small Scale ◽  
Pulp And Paper Mill ◽  
Nitrogen And Phosphorus ◽  
Paper Mills

Small-scale agro-based pulp and paper mills are characterized as highly polluting industries. These mills use Kraft pulping process for paper manufacturing due to which toxic lignified chemicals are released into the environment. Lack of infrastructure, technical manpower, and research and development facilities restricts these mills to recover these chemicals. Therefore, the chemical oxygen demand (COD) of the emanating stream is quite high. For solving the above problem, four bacteria were isolated from the premises of agro-based pulp and paper mill which were identified as species ofPseudomonas, Bacillus, Pannonibacter, andOchrobacterum. These bacteria were found capable of reducing COD up to 85%–86.5% in case of back water and 65-66% in case of back water : black liquor (60 : 40), respectively, after acclimatization under optimized conditions (pH 6.8, temperature 35°C, and shaking 200 rpm) when the wastewater was supplemented with nitrogen and phosphorus as trace elements.

scholarly journals Degradation and polymerization of black liquor lignin using Bacillus sp. isolated from a pulp mill

BioResources ◽  
2018 ◽  
Vol 14 (1) ◽  
pp. 1049-1076 ◽  
Author(s):  
Nipatcharaporn Sapapporn ◽  
Sirilux Chaijamrus ◽  
Wassana Chatdumrong ◽  
Tochampa
Keyword(s):  
Paper Industry ◽  
Black Liquor ◽  
Waste Product ◽  
Pulp Mill ◽  
Growth Conditions ◽  
Toxic Waste ◽  
Bacterial Strains ◽  
Industrial Utilization ◽  
Growing Conditions ◽  
First Time

A strain of Bacillus bacteria, which was able to increase the molecular weight (M) of black liquor (BL) lignin through polymerization, enabling the subsequent industrial use of lignin, was isolated and characterized. This study is believed to be the first time that actual bacteria cells, rather than pure laccase, have been used to polymerize BL lignin. Black liquor is a toxic waste product from the pulp and paper industry that contains lignin. However, the M of lignin is too low for commercial use. The bacteria performed two processes. First, the bacteria produced laccase, which degraded lignin into low M aromatic compounds (LMWACs). Second, the laccase transformed the LMWACs into quinone intermediates, which polymerized and became high M lignin. Five bacterial strains were isolated from a pulp mill, and the best strain was selected. The optimum growing conditions and BL concentration were determined. The optimum growth conditions when using pure lignin were 1 g/L lignin, 5 g/L urea, and 35 °C. When using BL instead of pure lignin, the optimum concentration was 2% BL (v/v). This information could help develop effective industrial utilization of BL lignin.

Biomass-Gasifier/Gas Turbine Cogeneration in the Pulp and Paper Industry

1992 ◽  
Vol 114 (4) ◽  
pp. 665-675 ◽  
Author(s):  
E. D. Larson
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Kraft Pulp ◽  
Paper Industry ◽  
Black Liquor ◽  
Pulp Mill ◽  
Electricity Production ◽  
Forest Residues ◽  
Commercial Development ◽  
Capital Costs

Increasing atmospheric carbon dioxide from fossil fuel combustion is raising new interest in using renewable biomass for energy. Modest-scale cogeneration systems using air-blown gasifiers coupled to aeroderivative gas turbines are expected to have high efficiencies and low unit capital costs, making them well-suited for use with biomass. Biomass-gasifier/gas turbine (BIG/GT) technology is not commercial, but efforts aimed at near-term commercialization are ongoing worldwide. Estimated performance and cost and prospects for commercial development of two BIG/GT systems are described, one using solid biomass fuel (e.g., wood chips), the other using kraft black liquor. At an energy-efficient kraft pulp mill, a BIG/GT cogeneration system could produce over three times as much electricity as is typically produced today. The mill’s on-site energy needs could be met and a large surplus of electricity would be available for export. Using in addition currently unutilized forest residues for fuel, electricity production would be nearly five times today’s level. The total cost to produce the electricity in excess of on-site needs is estimated to be below 4 cents per kWh in most cases. At projected growth rates for kraft pulp production, the associated biomass residue fuels could support up to 100 GW of BIG/GT capacity at kraft pulp mills worldwide in 2020 (30 GW in the US). The excess electricity production worldwide in 2020 would be equivalent to 10 percent of today’s electricity production from fossil fuels.

Nitrogen in the effluent of the pulp and paper industry

1997 ◽  
Vol 35 (2-3) ◽  
pp. 139-145 ◽  
Author(s):  
Risto Järvinen
Keyword(s):  
Inorganic Nitrogen ◽  
Paper Industry ◽  
Treatment Plant ◽  
Pulp Mill ◽  
Kraft Pulping ◽  
Bleached Kraft Pulp ◽  
Treated Effluent ◽  
Before And After ◽  
Nitrogen Concentrations ◽  
Biological Nitrogen

Nitrogen concentrations of effluent before and after treatment plant in two mills have been measured during five days time in a bleached kraft pulp mill and in a newsprint mill. In effluents before treatment the concentration of inorganic nitrogen was low but in the effluent of kraft pulping process, the main part is inorganic nitrogen. In effluent after treatment the concentration of inorganic nitrogen is low. After activated sludge treatment plant the concentration of dissolved organic nitrogen is about 0.6 mg/l and nitrogen in suspended solids determines fluctuation of nitrogen content in treated effluent. There is no need for biological nitrogen removal processes if the addition of nitrogen in the treatment is correct.

Biomass-Gasifier/Gas-Turbine Cogeneration in the Pulp and Paper Industry

1991 ◽  
Author(s):  
Eric D. Larson
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Kraft Pulp ◽  
Paper Industry ◽  
Black Liquor ◽  
Pulp Mill ◽  
Electricity Production ◽  
Forest Residues ◽  
Commercial Development ◽  
Capital Costs

Increasing atmospheric carbon dioxide from fossil fuel combustion is raising new interest in using renewable biomass for energy. Modest-scale cogeneration systems using air-blown gasifiers coupled to aeroderivative gas turbines are expected to have high efficiencies and low unit capital costs, making them well-suited for use with biomass. Biomass-gasifier/gas-turbine (BIG/GT) technology is not commercial, but efforts aimed at near-term commercialization are ongoing worldwide. Estimated performance and cost and prospects for commercial development of two BIG/GT systems are described, one using solid biomass fuel (e.g. wood chips), the other using kraft black liquor. At an energy-efficient kraft pulp mill, a BIG/GT cogeneration system could produce over three times as much electricity as is typically produced today. The mill’s on-site energy needs could be met and a large surplus of electricity would be available for export. Using in addition currently unutilized forest residues for fuel, electricity production would be nearly five times today’s level. The total cost to produce the electricity in excess of on-site needs is estimated to be below 4 cents per kWh in most cases. At projected growth rates for kraft pulp production, the associated biomass residue fuels could support up to 100 GW of BIG/GT capacity at kraft pulp mills worldwide in 2020 (30 GW in the US). The excess electricity production worldwide in 2020 would be equivalent to 10% of today’s electricity production from fossil fuels.

Brownstock washing: A review of the literature

TAPPI Journal ◽  
2014 ◽  
Vol 13 (1) ◽  
pp. 9-19 ◽  
Author(s):  
RICARDO B. SANTOS ◽  
PETER W. HART
Keyword(s):  
High Efficiency ◽  
Black Liquor ◽  
Material Balance ◽  
Kraft Pulping ◽  
Wash Water ◽  
Pulp Fibers ◽  
Kraft Process ◽  
Cooking Process ◽  
Materials Used ◽  
Entrapped Air

Brownstock washing is a complex, dynamic process in which dirty wash water or weak black liquor (dissolved organic and inorganic material obtained from the pulp cooking process) is separated from pulp fibers. The use of material balance techniques is of great importance to identify potential problems and determine how well the system is operating. The kraft pulping industry was the first known to combine pulp washing with the recovery of materials used and produced in the wood cooking process. The motivation behind materials recovery is economic, and more recently, environmentally driven. The chemicals used in the kraft process are expensive as compared to those used in the sulfite process. For the kraft process to be economically viable, it is imperative that a very high percentage of the cooking chemicals be recovered. To reach such high efficiency, a variety of washing systems and monitoring parameters have been developed. Antifoam additives and processing aids have also played an important role in increasing washing effectiveness. Antifoam materials help attain washing effectiveness by preventing entrapped air from forming in the system, which allows for an easier, unimpeded flow of filtrate through the screens and washers.

Co-cooking nonwoods with hardwoods

TAPPI Journal ◽  
2014 ◽  
Vol 13 (6) ◽  
pp. 19-24
Author(s):  
TROY RUNGE ◽  
CHUNHUI ZHANG
Keyword(s):  
High Performance Liquid Chromatography ◽  
High Performance ◽  
Paper Industry ◽  
Pulp And Paper Industry ◽  
Strength Properties ◽  
Agricultural Residues ◽  
Kraft Pulping ◽  
Pulp And Paper ◽  
Strength Increase ◽  
Xylan Content

Agricultural residues and energy crops are promising resources that can be utilized in the pulp and paper industry. This study examines the potential of co-cooking nonwood materials with hardwoods as means to incorporate nonwood material into a paper furnish. Specifically, miscanthus, switchgrass, and corn stover were substituted for poplar hardwood chips in the amounts of 10 wt %, 20 wt %, and 30 wt %, and the blends were subjected to kraft pulping experiments. The pulps were then bleached with an OD(EP)D sequence and then refined and formed into handsheets to characterize their physical properties. Surprisingly, all three co-cooked pulps showed improved strength properties (up to 35%). Sugar measurement of the pulps by high-performance liquid chromatography suggested that the strength increase correlated with enriched xylan content.

Biorefinery implementation for recovery debottlenecking at existing pulp mills- Part II: Techno-economic evaluation

TAPPI Journal ◽  
2012 ◽  
Vol 11 (8) ◽  
pp. 17-24 ◽  
Author(s):  
HAKIM GHEZZAZ ◽  
LUC PELLETIER ◽  
PAUL R. STUART
Keyword(s):  
Cost Estimation ◽  
Process Model ◽  
Black Liquor ◽  
Pulp Mill ◽  
Value Added ◽  
Economic Assessment ◽  
Extraction Process ◽  
Estimation Methods ◽  
Precipitation Process

The evaluation and process risk assessment of (a) lignin precipitation from black liquor, and (b) the near-neutral hemicellulose pre-extraction for recovery boiler debottlenecking in an existing pulp mill is presented in Part I of this paper, which was published in the July 2012 issue of TAPPI Journal. In Part II, the economic assessment of the two biorefinery process options is presented and interpreted. A mill process model was developed using WinGEMS software and used for calculating the mass and energy balances. Investment costs, operating costs, and profitability of the two biorefinery options have been calculated using standard cost estimation methods. The results show that the two biorefinery options are profitable for the case study mill and effective at process debottlenecking. The after-tax internal rate of return (IRR) of the lignin precipitation process option was estimated to be 95%, while that of the hemicellulose pre-extraction process option was 28%. Sensitivity analysis showed that the after tax-IRR of the lignin precipitation process remains higher than that of the hemicellulose pre-extraction process option, for all changes in the selected sensitivity parameters. If we consider the after-tax IRR, as well as capital cost, as selection criteria, the results show that for the case study mill, the lignin precipitation process is more promising than the near-neutral hemicellulose pre-extraction process. However, the comparison between the two biorefinery options should include long-term evaluation criteria. The potential of high value-added products that could be produced from lignin in the case of the lignin precipitation process, or from ethanol and acetic acid in the case of the hemicellulose pre-extraction process, should also be considered in the selection of the most promising process option.

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