scholarly journals Synthesis of TiO2 Photoelectrode Nanostructures for Sensing and Removing Textile Compounds Rhodamine B

2021 ◽  
Vol 12 (4) ◽  
pp. 5479-5485
Keyword(s):  
Rhodamine B ◽  
Oxidation Process ◽  
Diffusion Rate ◽  
Removal Rate ◽  
Ir Absorption ◽  
Potential Bias ◽  
Oh Groups ◽  
Titanium Electrode ◽  
A Value ◽  
Tio2 Photoelectrode

The study of the sensing and removal of Rhodamine B (RhB) textile compounds is the photoelectrocatalytic system applications development. RhB was used as a model to study the performance of TiO2 (NTiO2) photoelectrode nanostructures as environmentally friendly sensors. The synthesis of NTiO2 was carried out on the surface of the Titanium electrode by applying a potential bias of 25.0 V. The NTiO2 formed on the surface of the Titanium electrode (NTiO2/Ti) was characterized using SEM, XRD, FTIR, and Cyclic Voltammetry (CV). The formation of NTiO2 is characterized by the formation of a honeycomb-like tube on the Ti electrode surface. In addition, it is strengthened by diffractogram peaks at 2ϴ = 25 o and 48 o and IR absorption at wavenumbers of 3441.01 cm-1 (-OH groups) and 1629.85 cm-1 (Ti-O group). As for the results of sensing RhB using CV, it is known that RhB is oxidized on the surface of NTiO2/Ti with a value of Ea = 1.54 V. The oxidation process that occurs is controlled by the diffusion rate. Based on the results of photoelectrocatalytic RhB removal for 60 minutes, it was shown that using 0.10 M NaCl support electrolyte effectively increased the RhB removal rate. The decrease in RhB concentration during the photoelectrocatalytic removal process was 74.21%.

Rapid Mineralization of Rhodamine B Wastewater by Microwave Synergistic Fenton-Like Oxidation Process

2013 ◽  
Vol 807-809 ◽  
pp. 1384-1387 ◽  
Author(s):  
Peng Yan ◽  
Dong Bai
Keyword(s):  
Rhodamine B ◽  
Degradation Rate ◽  
Treatment Process ◽  
Oxidation Process ◽  
Removal Rate ◽  
Magnetic Nanomaterials ◽  
Factors Affecting ◽  
Initial Concentration ◽  
Microwave Assisted ◽  
The Given

The coulpling method of microwave irradiation and Fenton-like reaction with magnetic nanomaterials of CuFe2O4 as the catalyst was used for degradation of Rhodamine B wastewater. Factors affecting the degradation rate of Rhodamine B such as H2O2 dosage, CuFe2O4 dosage, Rhodamine B initial concentration, reaction temperature and so on were investigated systematically. The experimental results showed that the microwave-assisted Fenton-like process using H2O2/CuFe2O4 was the most effective treatment process compared with other methods. Unlike the conventional Fenton reactions, which are catalyzed by homogeneous catalysts/promoters, the nanopowder CuFe2O4 catalyst is easily collected by an external magnetic field and remains efficient in reuse. The results showed that under the given conditions (80°C, pH = 4, Rhodamine B initial concentration = 100mg/L, CuFe2O4 dose = 0.375g/L, H2O2 dose = 2.5mL/L, Reaction time = 2min), the removal rate of Rhodamine B could reach nearly 100%. Moreover, the COD determination results showed that under above conditions, the COD value could reach zero.

Novel CO2-Thermic Oxidation Process with Mg-Based Intermetallic Compounds and Its Application to Energy Storage Materials

2018 ◽  
Author(s):  
Younghwan Cha ◽  
Jung-In Lee ◽  
Panpan Dong ◽  
Xiahui Zhang ◽  
Min-Kyu Song
Keyword(s):  
Intermetallic Compounds ◽  
Oxidation Process ◽  
Value Added ◽  
Energy Storage Materials ◽  
Reaction Products ◽  
Materials Synthesis ◽  
Energy Materials ◽  
A Value ◽  
Carbon Coated ◽  
Novel Strategy

A novel strategy for the oxidation of Mg-based intermetallic compounds using CO<sub>2</sub> as an oxidizing agent was realized via simple thermal treatment, called ‘CO2-thermic Oxidation Process (CO-OP)’. Furthermore, as a value-added application, electrochemical properties of one of the reaction products (carbon-coated macroporous silicon) was evaluated. Considering the facile tunability of the chemical/physical properties of Mg-based intermetallics, we believe that this route can provide a simple and versatile platform for functional energy materials synthesis as well as CO<sub>2</sub> chemical utilization in an environment-friendly and sustainable way.

Study on Pretreatment of Dye Wastewater by Fenton Oxidation Process

2012 ◽  
Vol 627 ◽  
pp. 378-381
Author(s):  
Bi Rong Wang
Keyword(s):  
Reaction Time ◽  
Oxidation Process ◽  
Removal Rate ◽  
Fenton Oxidation ◽  
Dye Wastewater ◽  
Dyeing Wastewater ◽  
Reaction Conditions ◽  
Fenton Oxidation Process

Fenton pretreatment has been used for treating dye wastewater. The effects of the dos of H2O2 and FeSO4, reaction time and pH on the removal COD were investigated. It was found that, when the reaction conditions are as follows: COD 2850 mg/L dyeing wastewater, the dosage of H2O2 is 140mmol/L, FeSO4 17.02 mmol/L, pH 7.6, and reaction time 1.0 h, the CODcr of dye wastewater removal rate of up to 70%. Fenton pretreatment process of dye wastewater has a broad prospect.

scholarly journals Study on the effect of electrocatalytic oxidation treatment of 2,4,6-Trinitrophenol wastewater

2018 ◽  
Vol 238 ◽  
pp. 03003
Author(s):  
Yaling Li ◽  
Wenqiang Jiang ◽  
Ruyu Li
Keyword(s):  
Current Density ◽  
Electrocatalytic Oxidation ◽  
Electrolyte Concentration ◽  
Removal Rate ◽  
Pharmaceutical Chemical ◽  
Oxidation Treatment ◽  
Titanium Electrode ◽  
First Order Kinetics ◽  
Oxidation Technology ◽  
Aromatic Nitro

2,4,6-Trinitrophenol is a toxic aromatic nitro-compounds that widely used in pharmaceutical, chemical and pesticide production. Due to its stable structure and poor biodegradability, advanced electrocatalytic oxidation technology was selected to treat simulated wastewater. The goal of the present work is to optimize the electrolysis conditions such as current density, electrolysis pH, and electrolyte concentration. A Pt modified TiO2 electrode was chosen as the anode accompanied with a titanium electrode of the same size as the cathode The results showed that the removal efficiency of 2,4,6-Trinitrophenol was the highest when the current density was 20mA/cm2, electrolyte pH=5, electrolyte concentration was 2 g/L. Under the optimal condition, the removal rate of 2,4,6-Trinitrophenol reached 99.76% after 120 minutes electrolysis. The decay of TNP could also be described by the pseudo-first-order kinetics formula with respect to TNP concentration. Therefore, electrocatalytic oxidation technology might provide an effective method for the degradation of nitroaromatic organic compounds.

scholarly journals Removal of the Rhodamine B Dye at Ti/Ru0.3Ti0.7O2 Anode Using Flow Cell System

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Ali Baddouh ◽  
Brahim El Ibrahimi ◽  
Elhassan Amaterz ◽  
M. Mohamed Rguiti ◽  
Lahcen Bazzi ◽  
...  
Keyword(s):  
Current Density ◽  
Rhodamine B ◽  
Removal Rate ◽  
Flow Cell ◽  
Cell System ◽  
Cod Removal ◽  
Color Removal ◽  
Ion Concentration ◽  
Applied Current ◽  
Rhodamine B Dye

The electrochemical oxidation of the Rhodamine B dye (Rh-B) was carried out using dimensionally stable type anode (DSA, Ti/Ru0.3Ti0.7O2). The work was performed using the electrochemical flow cell system. The effect of several operating factors, such as supporting electrolytes, current density, electrolysis time, temperature, and initial concentration of Rh-B dye, were investigated. The UV-visible spectroscopy and chemical oxygen demand (COD) measurements were conducted to monitor the removal and degradation of Rh-B. The best color removal achieved was found to be 98.3% after 10 min applying 3.9 mA·cm−2 as a current density using 0.07 mol·L−1 of NaCl. Meanwhile, the highest COD removal rate (93.0%) was obtained for an applied current density of 3.9 mA·cm−2 as the optimal operating condition after 180 min reaction time, with 2.98 kW h·m−3 as energy consumption. This shows that the best conditions for color removal are not certainly the same as those for the COD removal. The rises in the concentration of NaCl, and applied current increased the Rh-B color removal rate. The decline in Rh-B dye concentration followed pseudo-first-order kinetics. The obtained values of apparent rate constant were increased by increasing chloride ion concentration. It is concluded that the electro-oxidation on DSA electrode using a flow cell is a suitable process for the removal of Rh-B dye in aqueous solutions.

Study on the Alage Removal by Microwave Irradiation

2010 ◽  
Vol 113-116 ◽  
pp. 87-90
Author(s):  
Qing Jie Xie
Keyword(s):  
Activated Carbon ◽  
Microwave Irradiation ◽  
Removal Efficiency ◽  
Oxidation Process ◽  
Removal Rate ◽  
Treatment Efficiency ◽  
Dynamic Reaction ◽  
Initial Concentration ◽  
First Order ◽  
Pollutants Removal

The microwave irradiation (MI) was found that it had significantly treatment efficiency for pollutants removal. It was developed to treat the alage in this paper. The granular activated carbon (GAC) was used as catalyst. The effect of the acting time, MI power, GAC amount and the initial concentration on alage removal were studied. The results showed: with the increasing of the acting time, MI power, GAC amount the alage removal rate were increased, but the effect of the initial concentration to alage removal was opposite; the optimum value of acting time, MI power and GAC amount were 5min, 450W and 3g respectively with the alage removal efficiency reached up to 100%. It also showed that with the alage removed under the MI the COD, SS were removed too. It was discovered that the oxidation process was basically in conformity with the first-order dynamic reaction(ln(C/C0)＝-0.9371t+0.6744（R2=0.9472）).

scholarly journals The removal of Rhodamine B by H2O2 or ClO2 combined with hydrodynamic cavitation

2019 ◽  
Vol 80 (8) ◽  
pp. 1571-1580
Author(s):  
Kun Wang ◽  
Ri-ya Jin ◽  
Yi-na Qiao ◽  
Zeng-di He ◽  
Ying Wang ◽  
...  
Keyword(s):  
Water Pollution ◽  
Human Health ◽  
Rhodamine B ◽  
Removal Rate ◽  
Hydrodynamic Cavitation ◽  
Operating Parameters ◽  
Initial Ph ◽  
The Individual ◽  
Better Than ◽  
Maximum Removal

Abstract Rhodamine B (RhB), widely used as an industrial dye, is a toxic organic that is hazardous to human health and can cause water pollution. In this study, the removal rate of RhB was investigated by the following methods: hydrodynamic cavitation (HC) operated individually, and HC combined with oxidants H2O2 or ClO2. The effect of different operating parameters including pressure (2–6 bar) and initial pH (2–8) on the extent of degradation was investigated using an orifice plate as the cavitation device to achieve maximum removal of RhB. Under the parameters of HC, the effect of different loadings was investigated: H2O2 (n(RhB):n(H2O2) was varied from 1:17.60 to 1:211.28) and ClO2 (n(RhB):n(ClO2) was varied from 1:8.87 to 1:177.53). A combination of cavitation and H2O2 or ClO2 resulted in degradations of 80.6% and 95.3%. The results indicated that the combination of HC and oxidants was better than the individual HC process for the degradation of RhB. When combining HC with H2O2 or ClO2, the synergistic coefficients of 62.54 and 74.79 were obtained. The combination of HC and ClO2 was proven to be more effective for the removal of RhB compared to HC alone and the hybrid process of HC and H2O2.

scholarly journals Optimization of isopropyl alcohol degradation by microwave-induced catalytic oxidation process

2019 ◽  
Vol 9 (3) ◽  
pp. 213-224
Author(s):  
Quynh Thi Phuong Tran ◽  
Chi-Hsu Hsieh ◽  
Tung-Yu Yang ◽  
Hsin-hsin Tung
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Oxidation ◽  
Working Conditions ◽  
Isopropyl Alcohol ◽  
Oxidation Process ◽  
Removal Rate ◽  
Response Variability ◽  
Manufacturing Industries ◽  
Independent Variables ◽  
Central Composite

Abstract Isopropyl alcohol (IPA) is a common waste solvent from the semiconductor and optoelectronic manufacturing industries. The current study assesses the feasibility of microwave-induced catalytic oxidation process for synthetic IPA wastewater. The effect of three independent variables, including oxidant (hydrogen peroxide), initial IPA concentration, and dosage of catalyst (granular activated carbon, GAC) on the IPA removal efficiency, were investigated and optimized by response surface methodology based on central composite design. The estimated optimal working conditions were as follows: [H2O2] &lt;0.132 M, GAC dosage = 108–123 g/L, and initial [IPA] = 0.038–0.10 M. The findings indicated that the dosage of GAC and the initial IPA concentration strongly affected the overall IPA removal. The values of R2 = 0.9948 and adjusted R2 = 0.9901 demonstrated that the response variability could be explained by the model expressing a satisfactory quadratic fit. Finally, the H2O2/GAC/MW process showed a faster and higher IPA removal rate than other processes tested.

Effect of 3C-SiC Irradiation with 8 MeV Protons

2017 ◽  
Vol 897 ◽  
pp. 311-314 ◽  
Author(s):  
Alexander A. Lebedev ◽  
Boris Ya. Ber ◽  
Gagik A. Oganesyan ◽  
Sergey V. Belov ◽  
Natalia. V. Seredova ◽  
...  
Keyword(s):  
Silicon Carbide ◽  
Hall Effect ◽  
Proton Irradiation ◽  
Removal Rate ◽  
Initial Concentration ◽  
A Value ◽  
Full Compensation ◽  
Mev Protons

Effects of proton irradiation in n-3C-SiC grown by sublimation on a 4H-SiC substrate have been studied by the Hall effect and photoluminescence methods. It was found that the carrier removal rate (Vd) reaches a value of ~110 cm-1. The full compensation of samples with an initial concentration of (1-2) x 1018 cm -3 was estimated to occur at doses of about 6 x 1015 cm -2. Compared with 4H and 6H silicon carbide, no significant increase in the intensity of so-called "defective" photoluminescence was observed in 3C-SiC.

Advanced Treatment of Ship Sewage by Fenton-Oxidation Process

2014 ◽  
Vol 1010-1012 ◽  
pp. 595-598
Author(s):  
Gui Fang Liu ◽  
Hong Mei Yan ◽  
Yuan Gao ◽  
Ya Quan Sun ◽  
Yu Ping Zhang
Keyword(s):  
Water Quality ◽  
Reaction Time ◽  
Optimum Condition ◽  
Oxidation Process ◽  
Removal Rate ◽  
Quality Standard ◽  
Fenton Oxidation ◽  
Domestic Water ◽  
Cod Removal Rate ◽  
Fenton Oxidation Process

Fenton-oxidation process was used to treat the simulation ship sewage that had met the requirement of IMO discharge standard. The effects of reaction time, doses of H2O2 and FeSO4, pH and temperature on COD removal rate were investigated. The results showed that the optimum condition for treating simulation ship sewage was as follows: pH=3.0, concentration of H2O2=9 mmol/L, concentration of FeSO4=3 mmol/L, and reaction time=30 min. Under the optimum condition, the removal rate of COD was to 62.7%. The water quality of the effluent could meet Miscellaneous Domestic Water Quality Standard.

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