Quality evaluation and determination of heavy metal contents in palm oil

2020 ◽  
Vol 55 (4) ◽  
pp. 301-310
Author(s):  
MSH Khan ◽  
KMYK Sikdar ◽  
N Saqueeb ◽  
MH Hossain ◽  
F Ahmed ◽  
...  
Keyword(s):  
Palm Oil ◽  
Elaeis Guineensis ◽  
Acid Value ◽  
Cadmium Content ◽  
Saponification Value ◽  
Metal Contents ◽  
Standard Value ◽  
Day By Day

Palm oil is an edible vegetable oil, extracted from the fruit of the Elaeis guineensis which is used for frying foods in most of the restaurants and confectionaries as well as for cosmetic preparations in industries. As the quality of palm oil in Bangladesh is deteriorating day by day, ten brands (S-1 to S-10) of commercially available palm oils were collected from different local markets, their physicochemical properties were tested and compared with the standard parameters stated by Bangladesh Standards and Testing Institution (BSTI). Results revealed that the acid value, free fatty acid value and relative density of all the palm oils (S-1 to S-10) were within the range of BSTI standard. However, the saponification value, peroxide value, iodine value, insoluble impurities and moisture content were much higher than the ranges of BSTI standard in all the samples. Moreover, lead content was higher than the standard value (>0.1 ppm) in brands S-1, S-4 and S-10. In addition, Copper and Iron contents were higher than the BSTI standards (0.1 and 1.5 ppm) in all the tested samples, whereas Cadmium content was below than the standard level (1.0 ppm). Bangladesh J. Sci. Ind. Res.55(4), 301-310, 2020

scholarly journals A Review on the Quality of Palm Oil (Elaeis guineensis) Produced Locally in Imo State, Nigeria

2018 ◽  
Vol 4 ◽  
pp. 40-50 ◽  
Author(s):  
Enyoh Christian Ebere ◽  
Verla Andrew Wirnkor ◽  
Enyoh Emmanuel Chinedu ◽  
Verla Evelyn Ngozi
Keyword(s):  
Palm Oil ◽  
Elaeis Guineensis ◽  
Meta Analysis ◽  
Oil Quality ◽  
Acid Value ◽  
Poor Quality ◽  
Smoke Point ◽  
Imo State ◽  
Open Access Journals

Over 70 % inhabitants of Imo state pend on palm oil for their cooking, frying etc. The study reviews available data on palm oil quality produced locally in Imo state with a view of providing up-to-date information and identify research gaps that could have health consequences on consumers. Peer reviewed scientific articles were reviewed and a meta-analysis of four different scientific research databases, PubMed, Web of Science, Google Scholar and Directory for Open-Access Journals was conducted. The result showed that palm oil produced locally in Imo state has average of pH (4.73), acid value (28.3 mg/KOH), FFA (14.15 mg/KOH), smoke point (115°C), iodine value (1.68 wijj’s), saponification value (197.07 mgKOH/g), ester value (168.77), moisture content (0.44 %), density (0.89 g/ml), SG (0.91), peroxide value (17.75 mEq./kg), refractive index (1.46oBx) and viscocity (60.04 cps). Overall palm oil is highly degraded and of poor quality since major quality indicators are not within Nigerian Industrial Standard and Standard Organization of Nigeria. Also, there is a dearth of information/data available on quality of palm oil produced locally in Imo state especially on its microbial status. Food scientist should look in that direction to enhance proper understanding of the quality of palm oil.

scholarly journals Effects of thermal treatment on the characteristics quality of some Ghanaian vegetable oils (palm, coconut and groundnut)

2022 ◽  
Author(s):  
Robert A Ngala ◽  
Evans Owusu Ameyaw ◽  
Dorice Berkoh ◽  
John Barimah ◽  
Simon Koffie
Keyword(s):  
Thermal Treatment ◽  
Vegetable Oils ◽  
Palm Oil ◽  
Room Temperature ◽  
Phenolic Content ◽  
Coconut Oil ◽  
Acid Value ◽  
Saponification Value ◽  
Total Antioxidant

Abstract Introduction: Vegetable oils contain natural antioxidants and other properties reported to impart anti-diabetic properties when consumed, in animal study. In humans however, these oils are subjected to high temperatures during cooking before consumption. High temperature tends to affect the characteristic quality and potential to impart on health benefits such as antidiabetic properties. The objective of this work was to determine the characteristics quality of vegetable oils after thermal treatment that equates to temperatures oils are subjected to during food processing/cooking.Methodology: Three portions of 200g of each fresh unrefined red palm oil, coconut oil and groundnut oils in three conical flasks T1, T2 and T3 were heated to room temperature 28oC (T1) to 100o C in boiling water (T2) and to 200o C in electric cooker oven (T3) for 10 minutes. Acid, iodine, peroxide, saponification, unsaponification values of the oils, Phytoconstituents (Flavanoids, polyphenols saponins etc) and antioxidant (Vitamin A&C) and DPPH (1,1-Diphenyl-2-Picrylhydrazyl) Radical Scavenging Activity were then determined after cooling to room temperature. Results: Coconut oil heated to 200˚C had the least Acid value of 2.89±0.135 whiles Palm oil heated to 100 ˚C had the highest value of 19.57±0.165. There were no peroxides formed in Coconut and Palm oils at 28 ˚C as well as Palm oil at 100 ˚C. However, peroxides were highest in Coconut oil at 200˚C with value of 15.28±2.315. Saponification value of groundnut oil at 28 ˚C was the least at 89.52 ± 2.18 and 296.57±1.045 the highest in coconut oil at 200 ˚C. Heating however increased the unsaponifiable matter in all the vegetable oils used. Total antioxidant capacity was not significantly changed across the temperature treatment. Total phenolic content was not significantly changed for palm oil but was significantly increased at 100C for coconut and groundnut oilsConclusion: The quality of the oils in terms of acid value, iodine vale, peroxide value and saponification value, total antioxidant and phenolic content were retained after one heat treatment. This implies the quality of the oils are maintained after a single heating. The oils may still retain antidiabetic property when consumed after processing.

scholarly journals Determination of functional compounds in blue shark (Prionace glauca) liver oil obtained by green technology

2020 ◽  
Vol 71 (2) ◽  
pp. 354
Author(s):  
D. N. Santos ◽  
F. S. Silva ◽  
A. B. Verde ◽  
G. M. Bittencourt ◽  
A. L. De Oliveira
Keyword(s):  
Vitamin A ◽  
Unsaturated Fatty Acids ◽  
Acid Value ◽  
Green Technology ◽  
Blue Shark ◽  
Prionace Glauca ◽  
Shark Liver Oil ◽  
Saponification Value

The objectives of this research were to obtain blue shark liver oil using supercritical CO2 and to characterize the physicochemical parameters of the oil, and the contents of squalene and vitamin A. Supercritical extractions were performed at 50 and 60 °C and pressures from 100 to 300 bar. The oil yield obtained was up to 60% and presented a profile equivalent to that of refined oils for density (0.920 – 0.922 g/mL); viscosity (52.55 – 56.47 Pas.s); refractive index (1.4760 – 1.4785); acid value (1.13 – 2.22% oleic acid); peroxides (10.47 – 24.04 meq of active O2 /kg of oil); saponification value (171.37 – 556.03 mg KOH/g oil), and iodine value (120.05 – 149.21g I2 /100g oil). The fatty acid profile indicated a majority of unsaturated fatty acids. High levels of squalene and vitamin A corroborate the high nutritional quality of this oil from an underexploited by-product with great processing potential.

Effects of Thermal Treatment on The Characteristics Quality of Some Ghanaian Vegetable Oils (Palm, Coconut and Groundnut)

2021 ◽  
Author(s):  
Evans Owusu ◽  
Dorice A Berkoh ◽  
Simone Koffie ◽  
John Barimah ◽  
Robert A Ngala
Keyword(s):  
Thermal Treatment ◽  
Vegetable Oils ◽  
Palm Oil ◽  
Food Processing ◽  
Room Temperature ◽  
Coconut Oil ◽  
Acid Value ◽  
Groundnut Oil ◽  
Saponification Value

Abstract Introduction: Vegetable oils contain natural antioxidants and other properties reported to impart anti-diabetic properties when consumed, in animal study. In humans however, these oils are subjected to high temperatures during cooking before consumption. High temperature tends to affect the characteristic quality and potential to impart on health benefits such as antidiabetic properties. The objective of this work was to determine the characteristics quality of vegetable oils after thermal treatment that equates to temperatures oils are subjected to during food processing/cooking. Methodology: Three portions of 200g of each fresh unrefined red palm oil, coconut oil and groundnut oils in three conical flasks T1, T2 and T3 were heated to room temperature 28oC (T1) to 100o C in boiling water (T2) and to 200o C in electric cooker oven (T3) for 10 minutes. Acid, iodine, peroxide, saponification, unsaponification values of the oils were then determined after cooling to room temperature. Results; Coconut oil heated to 200˚C had the least Acid value of 2.89±0.135 whiles Palm oil heated to 100 ˚C had the highest value of 19.57±0.165. There were no peroxides formed in Coconut and Palm oils at 28 ˚C as well as Palm oil at 100 ˚C. However, peroxides were highest in Coconut oil at 200˚C with value of 15.28±2.315. Saponification value of groundnut oil at 28 ˚C was the least at 89.52 ± 2.18 and 296.57±1.045 the highest in coconut oil at 200 ˚C. Heating however increased the unsaponifiable matter in all the vegetable oils used.Conclusion: The quality of the oils in terms of acid value, iodine vale, peroxide value and saponification value were retained after one heat treatment. This implies the quality of the oils are maintained during food processing.

Studies on the Acetone Extraction of Raw Rubber

1935 ◽  
Vol 8 (4) ◽  
pp. 604-612
Author(s):  
Hidemaro Endô
Keyword(s):  
Acid Value ◽  
Acetone Extract ◽  
Water Bath ◽  
Acetone Extraction ◽  
Saponification Value ◽  
Alcoholic Potash ◽  
Saponifiable Matter ◽  
Acetone Extracts ◽  
Hcl Solution

Abstract (1) For the determination of the saponification value of the acetone extract, 20 cc. 0.2 N alcoholic potash is added to the extract and the flask is heated on a water bath for 60 minutes. It is then titrated with 0.1 N HCl solution, using phenolphthalein as indicator. (2) When the saponification values of the acetone extracts of 8, 16, and 24 hours are compared, the saponification value of the 8 hour extract is seen to be high, while those of 16 and 24 hour extracts are low. This indicates (a) that the 8 hour extract contains a higher percentage of saponifiable matter than the 16 and 24 hour extracts; (b) the quantity of rubber hydrocarbon which is dissolved in the acetone extract increases with increasing time of extraction, and (c) the acid value of the acetone extract decreases during the period of extraction from 16 to 24 hours. (3) Regarding the saponification values (R) of the acetone extracts of 8, 16, and 24 hours, similar remarks may be made as in (2) above.

scholarly journals Pharmacognostic Screening of Elaeis guineensis ( Aracaceae) Jacq. Oil and its Effect as an Antidote on Cyanide Poisoning

2020 ◽  
Vol 10 (3-s) ◽  
pp. 1-5
Author(s):  
Felix N. Osuala ◽  
Uchenna E. Odoh ◽  
Grace O. Muoneme ◽  
Sylvester C. Ohadoma
Keyword(s):  
Acute Toxicity ◽  
Moisture Content ◽  
Elaeis Guineensis ◽  
Acid Value ◽  
Physicochemical Analysis ◽  
Phytochemical Analysis ◽  
Acute Toxicity Test ◽  
Cyanide Poisoning ◽  
Saponification Value ◽  
Oil Extract

Introduction: Elaeis guinenesis is a perennial monocot belonging to the family Arecaceae. It is the source of the oil commonly called African palm oil or macaw fat which in traditional medicine has many uses Aim: This study is focused on the pharmacognostic screening of oil of Elaeis guineensis, and its antidotal effect on cyanide poisoning. Method: The extracted oil was subjected to various screening technique in order to determine its quality, purity and chemical constituents. The oil was macroscopically examined; acute toxicity test of Elaeis guineensis oil was carried out on rats. The oil was subjected to heating to determine the moisture content. Phytochemical analysis was also carried out on the palm oil extract. The physicochemical analysis was carried to determine the acid value, saponification value, ester value, hydroxyl value and iodine value. The Ld50 for the pure cyanide was carried out on the rats using “Up and Down” method. The antidotal study of Elaeis guineensis oil was carried out on the rats. Result: Macroscopic evaluation showed, the oil was in fresh condition, smooth texture, bright red colour, characteristic taste, oily appearance and a characterictic smell. The Phytochemical analysis showed the presence of flavonoids, phenols, tannins, saponnins, alkaloids, steroids and terpenoids. The physicochemical analysis showed that the oil has an acid value of 31.2, Saponification value of 194.8, Ester value 163.54, Peroxide value of 18.0, Hydroxyl Percentage of 2.07% and Free Fatty Acid of 3.65. The moisture content was calculated to be 0.2%. For the acute toxicity test on the oil using Lorkes method no death was recorded. The LD50 of the cyanide carried out on the rats showed that the lethal dose of cyanide is 5 mg/kg. The antidotal effect of Elaeis guineensis oil showed the absence of death on the group given oil extract alone and the groups that were poisoned and given the oil (antidote) within 4 minutes. Deaths were recorded for the groups that were administered antidotes after 8 minutes. Conclusion: Elaeis guineensis oil has counteracting effect on cyanide poisoning if administered within four minutes of cyanide ingestion.  

Determination of phenolic acids in palm oil samples by HPLC-UV-AD using homemade flow cell

2018 ◽  
Vol 10 (37) ◽  
pp. 4535-4542 ◽  
Author(s):  
Rafaela Silva Lamarca ◽  
Renato Camargo Matos ◽  
Maria Auxiliadora Costa Matos
Keyword(s):  
Phenolic Acids ◽  
Vegetable Oils ◽  
Palm Oil ◽  
Flow Cell ◽  
Human Nutrition ◽  
Important Criterion ◽  
Nutrition And Health

The concentration of phenolic acids in vegetable oils is an important criterion for the assessment of the quality of oils with regard to their freshness, the maintenance of their properties, their storage and their influence on human nutrition and health.

scholarly journals A Study on Biochemical Properties and Effects of Different Vegetable Oils on Blood Indices in Wistar Rats

2019 ◽  
pp. 1-10
Author(s):  
Md. Tohidur Rahman ◽  
Meherunnahar . ◽  
Muhammad Ali ◽  
Shaikh Shahinur Rahman ◽  
A. Y. K. M. Masud Rana ◽  
...  
Keyword(s):  
Coconut Oil ◽  
Acid Value ◽  
Biochemical Properties ◽  
Normal Diet ◽  
Sesame Oil ◽  
Mustard Oil ◽  
Virgin Coconut Oil ◽  
Blood Indices ◽  
Saponification Value

Mustard oil is popular edible oil in Bangladesh. It contains about more than fifty percent erucic acid which is toxic to human beings. This study evaluated the determination of biochemical properties (acid value, iodine value, saponification value and unsaponifiable matter %) of mustard oil, virgin coconut and sesame oil and toxicity determination of these oils through blood indices targeting of these oil by mixing with normal diet as a dietary supplementation. This study found acid value of mustard, sesame and virgin coconut oil was 0.92, 0.312, 0.52 respectively. Iodine value of mustard, sesame and virgin coconut oil were 110.2, 105.2, and 11 respectively. Saponification value of wild mustard, sesame and virgin coconut oil was 171.1, 187.2 and 240   respectively and unsaponifiable matter % of mustard, sesame and virgin coconut oil was 1.19, 0.31 and 0.92 respectively. Also in vivo experiment  we divided wistar male rats were 4 groups such as normal diet 12 g/day/rat, mustard oil (MO) 0.6 g/day/rat, virgin coconut oil (VCO) 0.6g/day/rat and sesame oil (SO) 0.6 g/day/rat. In this study the vegetable oil causes the effect on average body weight gain, Food Efficiency Ratio (FER), and lipid profiles  [Total cholesterol (Tch), HDL- Cholesterol  LDL - Cholesterol, Triglyceride (TG)] and serum  enzymes [SGOT (AST), SGPT (ALT)] of different groups of rat also been estimated. The study found that mustard oil significantly (p<0.05) increase lipid profile and enzymes SGOT, SGPT level in blood serum which is an indication of heart and liver disorder. The study found that coconut and sesame oil consumption in rat significantly (p<0.05) decrease of these parameters.

scholarly journals Determination of acid, peroxide, and saponification value in patin fish oil by FTIR spectroscopy combined with chemometrics

Food Research ◽  
2020 ◽  
Vol 4 (5) ◽  
pp. 1758-1766
Author(s):  
A.R. Putri ◽  
A. Rohman ◽  
W. Setyaningsih ◽  
S. Riyanto
Keyword(s):  
Fish Oil ◽  
Ftir Spectroscopy ◽  
Principal Component Regression ◽  
Principal Component ◽  
Acid Value ◽  
Partial Least Square ◽  
Least Square ◽  
Coefficient Of Determination ◽  
Saponification Value

Simple, rapid, and reproducible methods for determining the acid value (AV), peroxide value (PV), and saponification value (SV) of patin fish oil (PFO) were developed using Fourier Transform Infrared (FTIR) spectroscopy combined with chemometrics of Principal Component Regression (PCR) and Partial Least Square (PLS). The relationship between actual values was determined using AOCS method and predicted value was determined with FTIR spectroscopy and chemometrics. From the validation work, the high coefficient of determination (R2 ) reached up to > 0.99. This study concluded that by means of FTIR spectra that combined with PCR and PLS technique can be used to determine AV, PV, and SV of PFO.

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