scholarly journals Experimental Study on the Effect of Combination of Thermodynamic Inhibitors’ and Kinetic Inhibitors’ Hydrate Inhibition

2021 ◽  
Vol 9 ◽  
Author(s):  
Yonghai Gao ◽  
Yanlong Wang ◽  
Guizhen Xin ◽  
Xiangdong Wang ◽  
Cheng Yue ◽  
...  
Keyword(s):  
Induction Time ◽  
Low Dose ◽  
Formation Rate ◽  
Hydrate Formation ◽  
Well Testing ◽  
Gas Well ◽  
Cooling Method ◽  
Mixed Use ◽  
Wellbore Temperature ◽  
Temperature And Pressure

In deepwater gas well testing, the high-pressure and low-temperature environment in the wellbore provides conditions for hydrate formation. When the thermodynamic inhibitor is used, it needs a large amount and is difficult to inject. Low-dose hydrate inhibitors such as kinetic inhibitors are rarely used in high supercooling and natural gas–dominated environments. The mixed use of thermodynamic inhibitors and kinetic inhibitors provides a new way. By simulating the wellbore temperature and pressure conditions during the deepwater gas well testing, the inhibiting effect of the mixtures of PVCap and methanol with various concentrations was experimentally tested by using rocking cells with a step-cooling method at 21MPa. The effect of PVCap and its mixture with methanol on hydrate plugging was evaluated by monitoring the movement of slider in the rocking cell. The results showed that 5 wt%, 16 wt%, and 20 wt% methanol mixed with 0.5 wt% PVCap could prolong the induction time, and the higher the methanol concentration, the longer the hydrate induction time. Among them, the best combination of 20wt% methanol and 0.5wt% PVCap can inhibit the hydrate for 379 min. The hydrate was formed but did not block the rocking cell, indicating that the combination of PVCap and methanol could not only prolong the hydrate formation time but also avoid the blockage after hydrate formation. The hydrate formation rate with various inhibitor concentrations was calculated; it may provide some guidance for making a shut-in plan for on-site wells.

Kinetic analysis of dual impellers on methane hydrate formation

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sotirios Nik Longinos ◽  
Mahmut Parlaktuna
Keyword(s):  
Power Consumption ◽  
Kinetic Analysis ◽  
Induction Time ◽  
Methane Hydrate ◽  
Formation Rate ◽  
Hydrate Formation ◽  
Mixed Flow ◽  
Pitched Blade Turbine ◽  
Decline Rate

Abstract This study investigates the effects of types of impellers and baffles on methane hydrate formation. Induction time, water conversion to hydrates (hydrate yield), hydrate formation rate and hydrate productivity are components that were estimated. The initial hydrate formation rate is generally higher with the use of Ruston turbine (RT) with higher values 28.93 × 10−8 mol/s in RT/RT with full baffle (FB) experiment, but the decline rate of hydrate formation was also high compared to up-pumping pitched blade turbine (PBTU). Power consumption is higher also in RT/RT and PBT/RT with higher value 392,000 W in PBT/RT with no baffle (NB) experiment compared to PBT/PBT and RT/PBT experiments respectively. Induction time values are higher in RT/RT experiments compared to PBT/PBT ones. Hydrate yield is always smaller when there is no baffle in all four groups of experiments while the higher values exist in experiments with full baffle. It should be noticed that PBT is the same with PBTU, since all experiments with mixed flow have upward trending.

Effects of Cyclodextrin Solutions on Methane Hydrate Formation

2007 ◽  
Author(s):  
Ryo Nozawa ◽  
Mohammad Ferdows ◽  
Kazuhiko Murakami ◽  
Masahiro Ota
Keyword(s):  
Raman Spectroscopy ◽  
Induction Time ◽  
Methane Hydrate ◽  
Methane Concentration ◽  
Formation Rate ◽  
Hydrate Formation ◽  
Formation Water ◽  
Advanced Method

In this paper, we suggest the advanced method of methane hydrate formation by cyclodextrin solutions. The structures of the methane hydrate were experimentally investigated by Raman spectroscopy. The induction time of the methane hydrate formation becomes by shorter 10–30 times and formation rate become by faster 2–4 times originated in the increased methane concentration of hydrate formation water by adding cyclodextrins. The results by the Raman spectroscopy indicate that the structure I methane hydrate is produced and methane molecules exist in both Large and Small cages.

scholarly journals Investigation and application of wellbore temperature and pressure field coupling with gas–liquid two-phase flowing

2021 ◽  
Author(s):  
Jie Zheng ◽  
Yihua Dou ◽  
Zhenzhen Li ◽  
Xin Yan ◽  
Yarong Zhang ◽  
...  
Keyword(s):  
Single Phase ◽  
Phase State ◽  
Pressure Field ◽  
Coupling Model ◽  
High Water ◽  
Two Phase ◽  
Gas Well ◽  
Single Phase State ◽  
Wellbore Temperature ◽  
Temperature And Pressure

AbstractWith the development of gas well exploitation, the calculation of wellbore with single-phase state affected by single factor cannot meet the actual needs of engineering. We need to consider the simulation calculation of complex wellbore environment under the coupling of multiphase and multiple factors, so as to better serve the petroleum industry. In view of the problem that the commonly used temperature and pressure model can only be used for single-phase state under complex well conditions, and the error is large. Combined with the wellbore heat transfer mechanism and the calculation method of pipe flow pressure drop gradient, this study analyzes the shortcomings of Ramey model and Hassan & Kabir model through transient analysis. Based on the equations of mass conservation, momentum conservation and energy conservation, and considering the interaction between fluid physical parameters and temperature and pressure, the wellbore pressure coupling model of water-bearing gas well is established, and the Newton Raphael iterative method is used for MATLAB programming. On this basis, the relationship between tubing diameter, gas production, gas–water ratio, and wellbore temperature field and pressure field in high water-bearing gas wells is discussed. The results show that the wellbore temperature pressure coupling model of high water-bearing gas well considering the coupling of gas–liquid two-phase flow wellbore temperature pressure field has higher accuracy than Ramey model and Hassan & Kabir model, and the minimum coefficients of variation of each model are 0.022, 0.037 and 0.042, respectively. Therefore, the model in this study is highly consistent with the field measured data. Therefore, the findings of this study are helpful to better calculate the wellbore temperature and pressure parameters under complex well conditions.

Study on the Optimization of Hydrate Management Strategies in Deepwater Gas Well Testing Operations

2019 ◽  
Vol 142 (3) ◽  
Author(s):  
Shangfei Song ◽  
Bohui Shi ◽  
Weichao Yu ◽  
Lin Ding ◽  
Yang Liu ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Management Strategies ◽  
Hydrate Formation ◽  
Oil And Gas Industry ◽  
Gas Production ◽  
Optimal Dosage ◽  
Well Testing ◽  
Delayed Effect ◽  
Gas Well ◽  
Risk Margin

Abstract Low temperature and high pressure conditions favor the formation of gas clathrate hydrates which is undesirable during oil and gas industries operation. The management of hydrate formation and plugging risk is essential for the flow assurance in the oil and gas production. This study aims to show how hydrate management in the deepwater gas well testing operations in the South China Sea can be optimized. To prevent the plugging of hydrate, three hydrate management strategies are investigated. The first method, injecting thermodynamic hydrate inhibitor (THI) is the most commonly used method to prevent hydrate formation. THI tracking is utilized to obtain the distribution of mono ethylene glycol (MEG) along the pipeline. The optimal dosage of MEG is calculated through further analysis. The second method, hydrate slurry flow technology is applied to the gas well. Pressure drop ratio (PDR) is defined to denote the hydrate blockage risk margin. The third method is the kinetic hydrate inhibitor (KHI) injection. The delayed effect of KHI on the hydrate formation induction time ensures that hydrates do not form in the pipe. This method is effective in reducing the injection amount of inhibitor. The problems of the three hydrate management strategies which should be paid attention to in industrial application are analyzed. This work promotes the understanding of hydrate management strategies and provides guidance for hydrate management optimization in oil and gas industry.

Formation Kinetics and Self-Preservation of CO2 Hydrates in the Presence of Carboxylated Multiwall Carbon Nanotubes

2021 ◽  
Author(s):  
Khalik Mohamad Sabil ◽  
Omar Nashed ◽  
Bhajan Lal ◽  
Khor Siak Foo
Keyword(s):  
Gas Hydrate ◽  
Induction Time ◽  
Completion Time ◽  
Formation Rate ◽  
Sodium Dodecyl ◽  
Hydrate Formation ◽  
Significant Finding ◽  
Formation Kinetic ◽  
Gas Hydrate Formation ◽  
The Impact

Abstract Nanofluids are known of having the capability to increase heat and mass transfer and their suitability to be used as kinetic gas hydrate promoters have been recently investigated. They have favorable properties such as high thermal conductivity, large surface area, recyclable, ecofriendly, and relatively cheap that are favorable for kinetic gas hydrate promoters. However, the nanomaterials face challenges related to their stability in the base fluid. Therefore, it is crucial to investigate the impact of surfactant free nanofluid on hydrate formation and dissociation kinetics. In this work, COOH-MWCNT suspended in water is used to study the effect of surfactant free nanofluid on CO2 hydrates formation kinetic and stability. Kinetic study on CO2 hydrates formation as well as self-preservation are conducted in a stirred tank reactor. The kinetic experiments are carried out at 2.7 MPa and 274.15 K. The induction time, initial gas consumption rate, half-completion time t50, semi completion time t95 are measured to evaluate the effect of COOH-MWCNT. Furthermore, the dissociation rate was calculated to assess the impact of COOH-MWCNT on self-preservation at 271.15 K and atmospheric pressure. The results are compared with that of sodium dodecyl sulphate (SDS). The study of CO2 hydrates formation kinetic shows that the induction time is not affected by COOH-MWCNT. The impact of nanofluid is more pronounced during the hydrate growth. The initial formation rate is the highest at 0.01 wt% of COOH-MWCNT whereas 0.01 and 0.03 wt% shows the same and shortest t50. However, t95 found to be decreased with increasing the concentration. The effect of COOH-MWCNT is attributed to the strong functional group. Self-preservation results shows CO2 hydrates are less stable in the presence of COOH-MWCNT. The result of this work may provide significant finding that can be used to developed kinetic gas hydrate promoter based on nanofluid that work better than SDS to eliminate gas hydrate formation in oil and gas pipeline.

Optimization of Hydrate Management in Deepwater Gas Well Testing Operations

2018 ◽  
Author(s):  
Shangfei Song ◽  
Bohui Shi ◽  
Weichao Yu ◽  
Wang Li ◽  
Jing Gong
Keyword(s):  
High Pressure ◽  
Low Temperature ◽  
Management Strategy ◽  
Oil And Gas ◽  
Management Strategies ◽  
Hydrate Formation ◽  
Optimal Dosage ◽  
Well Testing ◽  
Slurry Flow ◽  
Gas Well

Low temperature and high pressure conditions in deep water wells and sub-sea pipelines favour the formation of gas clathrate hydrates which is very undesirable during oil and gas industries operation. The management of hydrate formation and plugging risk is essential for the flow assurance in the oil and gas production. This study aims to show how the hydrate management in the deepwater gas well testing operations in the South China Sea can be optimized. As a result of the low temperature and the high pressure in the vertical 3860 meter-tubing, hydrate would form in the tubing during well testing operations. To prevent the formation or plugging of hydrate, three hydrate management strategies are investigated including thermodynamic inhibitor injection, hydrate slurry flow technology and thermodynamic inhibitor integrated with kinetic hydrate inhibitor. The first method, injecting considerable amount of thermodynamic inhibitor (Mono Ethylene Glycol, MEG) is also the most commonly used method to prevent hydrate formation. Thermodynamic hydrate inhibitor tracking is utilized to obtain the distribution of MEG along the pipeline. Optimal dosage of MEG is calculated through further analysis. The second method, hydrate slurry flow technology is applied to the gas well. Low dosage hydrate inhibitor of antiagglomerate is added into the flow system to prevent the aggregation of hydrate particles after hydrate formation. Pressure Drop Ratio (PDR) is defined to denote the hydrate blockage risk margin. The third method is a recently proposed hydrate risk management strategy which prevents the hydrate formation by addition of Poly-N-VinylCaprolactam (PVCap) as a kinetic hydrate inhibitor (KHI). The delayed effect of PVCap on the hydrate formation induction time ensures that hydrates do not form in the pipe. This method is effective in reducing the injection amount of inhibitor. The problems of the three hydrate management strategies which should be paid attention to in industrial application are analyzed. This work promotes the understanding of hydrate management strategy and provides guidance for hydrate management optimization in oil and gas industry.

scholarly journals Experimental Investigation of Effect on Hydrate Formation in Spray Reactor

2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Jianzhong Zhao ◽  
Yaqin Tian ◽  
Yangsheng Zhao ◽  
Wenping Cheng
Keyword(s):  
Storage Capacity ◽  
Pure Water ◽  
Formation Rate ◽  
Hydrate Formation ◽  
Gas Storage ◽  
Temperature And Pressure ◽  
Increase Production Cost ◽  
Lower Temperature ◽  
Gas Volume ◽  
Experimental Rig

The effects of reaction condition on hydrate formation were conducted in spray reactor. The temperature, pressure, and gas volume of reaction on hydrate formation were measured in pure water and SDS solutions at different temperature and pressure with a high-pressure experimental rig for hydrate formation. The experimental data and result reveal that additives could improve the hydrate formation rate and gas storage capacity. Temperature and pressure can restrict the hydrate formation. Lower temperature and higher pressure can promote hydrate formation, but they can increase production cost. So these factors should be considered synthetically. The investigation will promote the advance of gas storage technology in hydrates.

Real-Time Estimation and Management of Hydrate Plugging Risk During Deepwater Gas Well Testing

SPE Journal ◽  
2020 ◽  
Vol 25 (06) ◽  
pp. 3250-3264 ◽  
Author(s):  
Jianbo Zhang ◽  
Zhiyuan Wang ◽  
Wenguang Duan ◽  
Weiqi Fu ◽  
Baojiang Sun ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Real Time ◽  
Hydrate Formation ◽  
Dynamic Effect ◽  
Time Estimation ◽  
Gas Production ◽  
Well Testing ◽  
Gas Well ◽  
Wellhead Pressure ◽  
Real Time Estimation

Summary Hydrate formation and deposition are usually encountered during deepwater gas well testing, and if hydrates are not detected and managed in time, a plugging accident can easily occur. In this study, we demonstrate a method for estimating and managing the risk of hydrate plugging in real time during the testing process. The method includes the following steps: predicting the hydrate stability region, calculating the hydrate formation and deposition behaviors, analyzing the effect of the hydrate behaviors on variations in wellhead pressure, monitoring the variations in wellhead pressure and estimating the hydrate plugging risk in real time, and managing the risk in real time. An improved pressure-drop calculation model is established to calculate the pressure drop in annular flows with hydrate behaviors, and it considers the dynamic effect of hydrate behavior on fluid flow and surface roughness. The pressure drops calculated at different times agree well with experimental and field data. A case study is conducted to investigate the applicability of the proposed method, and results show that with the continued formation and deposition of hydrates, both the effective inner diameter of the tubing and the wellhead pressure decrease accordingly. When the wellhead pressure decreases to a critical safety value under a given gas production rate, a hydrate inhibitor must be injected into the tubing to reduce the severity of hydrate plugging. It is also necessary to conduct real-time monitoring of variations in wellhead pressure to guarantee that the risk of hydrate plugging is within a safe range. This method enables the real-time estimation and management of hydrate plugging during the testing process, and it can provide a basis for the safe and efficient testing of deepwater gas wells.

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