scholarly journals Use of Potabilized Water Sludge in the Production of Low-Energy Blended Calcium Sulfoaluminate Cements

2021 ◽  
Vol 11 (4) ◽  
pp. 1679
Author(s):  
Antonio Telesca ◽  
Neluta Ibris ◽  
Milena Marroccoli
Keyword(s):  
Co2 Emissions ◽  
Carbon Footprint ◽  
Energy Demand ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
X Ray Diffraction ◽  
Hydration Properties ◽  
Blended Cements ◽  
Calcium Sulfoaluminate ◽  
Pozzolanic Material

Ordinary Portland cement (OPC) manufacture determines about 8% of the global anthropogenic CO2 emissions. This has led to both the cement producers and the scientific community to develop new cementitious materials with a reduced carbon footprint. Calcium sulfoaluminate (CSA) cements are special hydraulic binders from non-Portland clinkers; they represent an important alternative to OPC due to their peculiar composition and significantly lower impact on the environment. CSA cements contain less limestone and require lower synthesis temperatures, which means a reduced kiln thermal energy demand and lower CO2 emissions. CSA cements can also be mixed with supplementary cementitious materials (SCMs) which further reduce the carbon footprint. This article was aimed at evaluating the possibility of using different amounts (20 and 35% by mass) of water potabilization sludges (WPSs) as SCM in CSA-blended cements. WPSs were treated thermally (TT) at 700° in order to obtain an industrial pozzolanic material. The hydration properties and the technical behavior of two different CSA-blended cements were investigated using differential thermal–thermogravimetric and X-ray diffraction analyses, mercury intrusion porosimetry, shrinkage/expansion and compressive strength measurements. The results showed that CSA binders containing 20% by mass of TTWPSs exhibited technological properties similar to those relating to plain CSA cement and were characterized by more pronounced eco-friendly features.

scholarly journals The Influence of Chemical Activators on the Hydration Behavior and Technical Properties of Calcium Sulfoaluminate Cements Blended with Ground Granulated Blast Furnace Slags

Buildings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 268
Author(s):  
Milena Marroccoli ◽  
Antonio Telesca
Keyword(s):  
Blast Furnace ◽  
Co2 Emissions ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
X Ray Diffraction ◽  
Cement Production ◽  
Blended Cements ◽  
Calcium Sulfoaluminate ◽  
Technical Performance ◽  
Technical Properties

The manufacture of Ordinary Portland cement (OPC) generates around 8% of the global CO2 emissions related to human activities. The last 20 years have seen considerable efforts in the research and development of methods to lower the carbon footprint associated with cement production. Specific focus has been on limiting the use of OPC and employing alternative binders, such as calcium sulfoaluminate (CSA) cements, namely special hydraulic binders obtained from non-Portland clinkers. CSA cements could be considered a valuable OPC alternative thanks to their distinctive composition and technical performance and the reduced environmental impact of their manufacturing process. To additionally reduce CO2 emissions, CSA cements can also be blended with supplementary cementitious materials. This paper investigates the influence of two separately added chemical activators (NaOH or Na2CO3) on the technical properties and hydration behavior of four CSA blended cements obtained by adding to a plain CSA cement two different ground granulated blast furnace slags. Differential thermal-thermogravimetric, X-ray diffraction and mercury intrusion porosimetry analyses were done, along with shrinkage/expansion and compressive strength measurements.

scholarly journals Assessing, Understanding and Unlocking Supplementary Cementitious Materials

2016 ◽  
Vol 1 ◽  
pp. 50 ◽  
Author(s):  
Ruben Snellings
Keyword(s):  
Co2 Emissions ◽  
Cementitious Materials ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
New Materials ◽  
Cement Production ◽  
Blended Cements ◽  
International Commitments ◽  
Roll Out

The partial replacement of Portland clinker by supplementary cementitious materials (SCM) is one of the most popular and effective measures to reduce both costs and CO2 emissions related to cement production. An estimated 800 Mt/y of blast furnace slags, fly ashes and other materials are currently being used as SCM, but still the cement industry accounts for 5-8% of global CO2 emissions. If no further actions are taken, by the year 2050 this share might even rise beyond 25%. There is thus a clear challenge as to how emissions will be kept at bay and sustainability targets set by international commitments and policy documents will be met.Part of the solution will be a further roll-out of blended cements in which SCMs constitute the main part of the binder to which activators such as Portland cement are added. Since supply concerns are being raised for conventional high-quality SCMs it is clear that new materials and beneficiation technologies will need to step in to achieve further progress. This paper presents opportunities and challenges for new SCMs and demonstrates how advances towards more powerful and reliable characterisation techniques help to better understand and exploit SCM reactivity.

scholarly journals Durability of Ternary Cements Based on New Supplementary Cementitious Materials from Industrial Waste

2021 ◽  
Vol 11 (13) ◽  
pp. 5977
Author(s):  
Isabel Fuencisla Sáez del Bosque ◽  
María Isabel Sánchez de Rojas ◽  
Gabriel Medina ◽  
Sara Barcala ◽  
César Medina
Keyword(s):  
Mercury Intrusion Porosimetry ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Reaction Products ◽  
X Ray Diffraction ◽  
Replacement Ratio ◽  
X Ray ◽  
Blended Cements ◽  
Optimal Replacement ◽  
Bearing Materials

Cement-based materials decay with exposure to aggressive agents, a development that raises infrastructure operation and maintenance costs substantially. This paper analyses the inclusion of ultrafine construction and demolition (UC&DW) and biomass-fuelled power plant (BA) waste as pozzolanic additions to cement in pursuit of more sustainable and eco-respectful binders and assesses the durability of the end materials when exposed to seawater, chlorides (0.5 M NaCl) or sulphates (0.3 M Na2SO4). The effect of adding silica fume (SF) at a replacement ratio of 5% was also analysed. Durability was determined using the methodology proposed by Koch and Steinegger, whilst microstructural changes were monitored with mercury intrusion porosimetry (MIP), X-ray diffraction (XRD) and scanning electron microscopy (SEM) for a fuller understanding of decay processes. According to the findings, the new blended cements containing 20%UC&DW + 10%BA or 20%UC&DW + 20%BA + 5%SF resist the attack by the aggressive media studied, with a 56-d corrosion index of over 0.7. The composition of the reaction products generated with the attack is essentially the same in OPC and the SCM-bearing materials. The results show that the optimal replacement ratio for SCM is 30%.

scholarly journals Sustainable low-carbon binders and concretes

2020 ◽  
Vol 166 ◽  
pp. 06007
Author(s):  
Myroslav Sanytsky ◽  
Tetiana Kropyvnytska ◽  
Stanislav Fic ◽  
Hanna Ivashchyshyn
Keyword(s):  
Activity Index ◽  
Chemical Properties ◽  
High Volume ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Cement Matrix ◽  
Low Carbon ◽  
Blended Cements ◽  
Physical And Chemical

Sustainable development depends on a consistency of interests, social, ecological and economic, and that the interests are evaluated in a balanced manner. In order to reduce CO2 emissions, the conception of decreasing clinker factor and increasing the role of supplementary cementitious materials (SCMs) in the cementitious materials has high economical and environmental efficiency. The performance of clinkerefficient blended cements with supplementary cementitious materials were examined. The influence of superfine zeolite with increased surface energy on the physical and chemical properties of low-carbon blended cements is shown. Increasing the dispersion of cementitious materials contributes to the growth of their strength activity index due to compaction of cement matrix and pozzolanic reactions in unclincker part. In consequence of the early structure formation and the directed formation of the microstructure of the cement matrix is solving the problem of obtaining clinker-efficient concretes. Shown that low-carbon blended cements with high volume of SCMs are suitable, in principle, for producing structural concretes.

Pulse Velocity Measurements in Fly Ash Blended Cementitious Systems Containing 43 Grade Cement

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
V. M. Sounthararajan ◽  
A. Sivakumar
Keyword(s):  
Fly Ash ◽  
Cost Savings ◽  
Ultrasonic Pulse Velocity ◽  
Cementitious Materials ◽  
Ultrasonic Pulse ◽  
Pozzolanic Reaction ◽  
Pulse Velocity ◽  
Supplementary Cementitious Materials ◽  
Pozzolanic Material ◽  
Cementitious Systems

Investigations on the different supplementary cementitious materials based on the hardening properties and the optimized dosage in cementitious systems find the right choice of pozzolanic material. It is essential to combine various additive/admixtures in concrete in proper proportions to maximize the benefits resulting in cost savings in construction. In the recent years, production technology and composition of hydraulic cements affect the setting and early age behavior of cementitious material. The addition of fly ash in cement is one viable technology to derive maximum benefits in terms of the economy and improved pozzolanic reaction. Ultrasonic pulse velocity testing is a feasible method for evaluating the hardening properties of cementitious materials. In this study, an attempt was made to derive the engineering basis for understanding the development of hardness during hydration of fly ash (FA) based cementitious systems. The tests conducted using pulse velocity technique proved to be an effective method for characterizing the early strength gain properties of different cementitious systems.

scholarly journals Pozzolanic Effect on the Hydration Heat of Cements Incorporating Fly Ash, Obsidian, and Slag Additives

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Ilker Ustabas ◽  
Sakir Erdogdu ◽  
Ihsan Omur ◽  
Erol Yilmaz
Keyword(s):  
Fly Ash ◽  
Cementitious Materials ◽  
Climate Impact ◽  
Hydration Heat ◽  
Replacement Rate ◽  
Blended Cements ◽  
Pozzolanic Material ◽  
Durable Products ◽  
Chloride Sulfate

Made up of an engineered mix of ordinary Portland cement (OPC) with artificial pozzolans such as trass, fly ash, and slag, the blended cements have been intensely employed within cementitious materials. The main reasons behind this intensive use can be clarified by enhanced workability/strength, the high resistance to chloride/sulfate, reduced permeability/alkali-silica reaction, and a drop in the heat generated by cement’s hydration. The use of cementitious blends within concrete not only offers durable products but also cuts climate impact by energy saving and falling CO2 emissions. This study presents pozzolanic effect on the hydration heat of cements incorporating fly ash, obsidian, and slag additives. The blended cements were manufactured by three different replacement ratios of 20%, 30%, and 50%. The change in the hydration heat of obsidian-, fly ash-, and slag-based cements was observed by several Turkish standards (TS EN 196-8 and TS EN 196-9). Mortars were used for determining the uniaxial strengths of obsidian-, fly ash-, and slag-based cements. The results show that cement’s hydration heat decreases as the rate of additives (e.g., obsidian) increases from 20% to 50%. The cement’s fineness greatly affects its hydration heat. Increasing the refinement of pozzolanic material to a certain level (30%) leads to an increase in the hydration temperature. After reaching this level, there is no clear relation between the fineness and the replacement rate of pozzolans. As a result, the findings of this work will provide a good understanding of artificial pozzolans on performance and quality of obsidian-, fly ash-, and slag-based cements.

scholarly journals Development of GHG Emissions Curves for Bio-Concretes Specification: Case Study for Bamboo, Rice Husk, and Wood Shavings Considering the Context of Different Countries

2022 ◽  
Author(s):  
Lucas Rosse Caldas ◽  
Carolina Goulart Bezerra ◽  
Francesco Pittau ◽  
Arthur Araujo ◽  
Mariana Franco ◽  
...  
Keyword(s):  
Life Cycle ◽  
Portland Cement ◽  
Rice Husk ◽  
Carbon Footprint ◽  
Ghg Emissions ◽  
Rotation Period ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Wood Shavings ◽  
Biogenic Carbon

Bio-concretes are receiving special attention in recent research as an alternative for climate change mitigation due to their low carbon footprints. Different bio-based materials can be used, e.g., wood shavings, bamboo, rice husk, and coconut. However, various methodological parameters can influence the carbon footprint of bio-based materials, especially bio-concretes, like biogenic carbon, amount of carbon in dry matter, rotation period of bio-aggregates, and type of cementitious materials. It is important to have easier ways of estimating the carbon footprint of bio-concretes, using parameters and data easily available. This research aims to evaluate the (1) carbon footprint of different mixtures of three bio-concretes (wood bio-concrete - WBC, bamboo bio-concrete - BBC and rice husk bio-concrete - RBC), and the (2) development of GHG emissions curves for bio-concretes specification based on easily available data (such as density, biomass content, and compressive strength). Based on experimental data, the carbon footprint was performed using the Life Cycle Assessment (LCA) methodology. In order to extend the findings of this study, the context of the following four countries was evaluated: Brazil, South Africa, India, and China. In addition, the replacement of Portland cement for Supplementary Cementitious Materials (SCMs) are evaluated hypothetically. The results show that the increase of biomass content in bio-concretes and the replacement of Portland cement by SCMs leads to a radical decrease in life cycle GHG emissions. The percentage of carbon in biomass is a critical factor for reducing the carbon footprint. The WBC was the biomass that performed better for this parameter. The presented GHG emissions curves can be a useful way to estimate the carbon footprint of bio-concretes and can be adapted to other kinds of bio-concretes and countries.

scholarly journals Portland Cements with High Content of Calcined Clay: Mechanical Strength Behaviour and Sulfate Durability

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4206 ◽  
Author(s):  
Carlos H. Aramburo ◽  
César Pedrajas ◽  
Rafael Talero
Keyword(s):  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Chemical Effect ◽  
Portland Cements ◽  
Calcined Clay ◽  
Blended Cements ◽  
Sulfate Resistance ◽  
Type Iv ◽  
Mechanical Strengths ◽  
Mineralogical Compositions

Calcined clay has become the supplementary cementitious materials with the greatest potential to reduce the clinker/cement. In this research, the mechanical strengths and sulphate resistance of blended cements with a high content of calcined clay as a pozzolanic addition were evaluated to demonstrate that these cements could be designed as CEM (cement) type IV/A-SR and IV/B-SR cements by the current European standard UNE-EN 197-1: 2011. The blended cements were prepared by two Portland cements (P1 and PY6) with different mineralogical compositions and a calcined clay. The level of replacement was greater than 40% by weight. The results obtained confirm the decrease in the mechanical strengths and the increase in the sulfate resistance of the two Portland cements when they are replaced by calcined clay at a level of replacement greater than 40%. These results are a consequence of the chemical effect from the pozzolanic activity of the calcined clay. Therefore, there is an important decrease in portlandite levels of paste liquid phase that causes the increase in sulfate resistance and the decrease of the mechanical strengths.

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