scholarly journals Investigation of the Effects of Multi-Wall and Single-Wall Carbon Nanotubes Concentration on the Properties of ABS Nanocomposites

2021 ◽  
Vol 7 (2) ◽  
pp. 33 ◽  
Author(s):  
Brenda Janett Alonso Gutierrez ◽  
Sithiprumnea Dul ◽  
Alessandro Pegoretti ◽  
Jaime Alvarez-Quintana ◽  
Luca Fambri
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Resistivity ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Single Wall Carbon Nanotubes ◽  
Flow Index ◽  
Melt Flow ◽  
Shore Hardness ◽  
Free Process ◽  
Butadiene Styrene

The effects of two types of carbon nanotubes, namely multiwall (MWCNT) and single-wall (SWCNT) carbon nanotube, on the thermal and mechanical properties of acrylonitrile-butadiene-styrene (ABS) nanocomposites, have been investigated. ABS filled-CNT nanocomposites with various filler loadings of 5–10 wt% were properly produced by a solvent-free process in blend compounding at 190 °C. Compression moulded plates and extruded filaments were obtained at 190 °C and 230 °C, respectively. Melt flow index (MFI), shore hardness, Vicat temperature, differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA) were performed to characterize and compared the different CNT nanocomposites. ABS/SWCNT composite filaments showed higher tensile properties (i.e., stiffness and strength), than ABS/MWCNT. The electrical resistivity of ABS/SWCNT and ABS/MWCNT filaments decreased to 0.19 Ω.cm and 0.65 Ω.cm for nanocomposites with 10 wt% of nanofillers; a power law was presented to describe the electrical resistivity of composites as a function of the CNTs content. A final comparative parameter regarding melt flow, stiffness and conductivity was also evaluated for understanding the combined effects of the nanofillers. SWCNT nanocomposites exhibited better overall cumulative results than MWCNT nanocomposites.

Investigation the mechanical, rheological, and morphological properties of acrylonitrile butadiene styrene blends with different recycling number content

2017 ◽  
Vol 232 (4) ◽  
pp. 449-458 ◽  
Author(s):  
Ibrahim Hamarat ◽  
Emel Kuram ◽  
Babur Ozcelik
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Morphological Properties ◽  
Flow Index ◽  
Melt Flow ◽  
Recycled Polymer ◽  
Recycled Material ◽  
Butadiene Styrene

In this study, acrylonitrile butadiene styrene polymer was exposed to 12 injection cycles to investigate the influence of recycling number on the mechanical, rheological, and morphological properties. Also, binary and ternary blends including different weight percentages and recycling number of virgin–recycled polymers were prepared. A slight decrement was found in the tensile strength values with recycling number. All blends including recycled polymer (binary or ternary) gave lower tensile strength values with respect to 100% virgin polymer. Strain at break value was decreased after twelve times recycling; however, no clear tendency was observed with the presence of different ratios of virgin polymer to recycled polymer. Impact strength of the polymer decreased with recycling number. There was relatively large drop in the third recycling, from 72 kJ/m2 to 38.5 kJ/m2; however, further recycling induced in a slower drop in the impact strength to 32.5 kJ/m2. All blends including recycled material gave lower impact strength values as compared to 100% virgin polymer. It was observed that the melt flow index values increased with the recycling number, a total of 26.53% after twelve times recycling. All blends containing recycled material showed higher melt flow index values as compared to 100% virgin polymer.

A Study of the Effect of Maleic Anhydride on the Synthesis, Morphology, and Properties of Acrylonitrile Butadiene Styrene Plastic

2018 ◽  
Vol 45 (6) ◽  
pp. 251-256 ◽  
Author(s):  
O.M. Trifonova ◽  
Yu.A. Panova ◽  
I.G. Akhmetov
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Maleic Anhydride ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Flow Index ◽  
Melt Flow ◽  
Gel Fraction ◽  
Butadiene Styrene

The results of investigating the synthesis of ABS plastic in the presence of maleic anhydride are set out. It was shown that increase in the modifier content in the range 0.5–1.75 wt% leads to a reduction in the melt flow index and gel-fraction swelling index and to an increase in the glass transition temperature of the polymer.

scholarly journals Melt Flow Index of Recycle ABS for Fused Deposition Modeling (FDM) Filament

2015 ◽  
Vol 773-774 ◽  
pp. 3-7 ◽  
Author(s):  
Nasuha Sa'ude ◽  
Khairu Kamarudin ◽  
Mustaffa Ibrahim ◽  
Mohd Halim Irwan Ibrahim
Keyword(s):  
Material Properties ◽  
Fused Deposition Modeling ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Flow Index ◽  
Melt Flow ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Higher Temperature ◽  
Butadiene Styrene

This paper presents the melt flow index (MFI) of acrylonitrile butadiene styrene (ABS) and recycle ABS filament wire for Fused Deposition Modeling (FDM) machine. In this study, the effect of MFI on recycle ABS material was investigated experimentally based on the melting temperature, density, screw speed and material properties. The MFI result on ABS recycle in wire filament was investigated using Melt Indexer Machine (MIM). Based on the result obtained, it was found that, ABS recycle was increase the density and MFI results. It can be observed that, the higher temperature was melt the recycle ABS material through the MIM and extruder machine.

scholarly journals Characterization of Polystyrene Wastes as Potential Extruded Feedstock Filament for 3D Printing

Recycling ◽  
2018 ◽  
Vol 3 (4) ◽  
pp. 57 ◽  
Author(s):  
Irina Turku ◽  
Sushil Kasala ◽  
Timo Kärki
Keyword(s):  
Fourier Transform ◽  
Glass Transition ◽  
Transition Temperature ◽  
3D Printing ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Flow Index ◽  
Recycled Material ◽  
Butadiene Styrene

The recyclability of polystyrene, acrylonitrile butadiene styrene and polyvinylchloride waste and their use as a source for 3D printing were studied. Filaments of about 3 mm in diameter were extruded successfully with a small-size extruder. The processed filaments were tested on a broad range of parameters-melt flow index, glass transition temperature, tensile properties and a pyrolysis scenario were obtained. The measured parameters were compared with parameters of virgin counterparts presented in the literature. In order to estimate the composition of the recycled material, Fourier Transform Infrared and elemental analysis of the samples was done.

scholarly journals A Study on Melt Flow Index on Copper-ABS for Fused Deposition Modeling (FDM) Feedstock

2015 ◽  
Vol 773-774 ◽  
pp. 8-12 ◽  
Author(s):  
Noor Mu'izzah Ahmad Isa ◽  
Nasuha Sa'ude ◽  
M. Ibrahim ◽  
Saiful Manar Hamid ◽  
Khairu Kamarudin
Keyword(s):  
Injection Molding ◽  
Fused Deposition Modeling ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Internal Force ◽  
Flow Index ◽  
Fused Deposition Modelling ◽  
Melt Flow ◽  
Volume Percentage ◽  
Fused Deposition

This paper presents of Polymer Matrix Composite (PMC) as feedstock used in Fused Deposition Modelling (FDM) machine. This study discussed on the development of a new PMC material by the injection molding machine. The material consist of copper powder filled in an acrylonitrile butadiene styrene (ABS), binder and surfactant material. The effect of metal filled in ABS and binder content was investigated experimentally by the Melt Flow Index (MFI) machine. Based on the result obtained, an increment of copper filled in ABS by volume percentage (vol. %) effected on melt flow index results. With highly filled copper in PMC composites increase the melt flow index results. It was concluded that, the propensity of the melt flow allow an internal force in PMC material through the injection molding and FDM machine.

scholarly journals Microstructure Evaluation and Thermal–Mechanical Properties of ABS Matrix Composite Filament Reinforced with Multi-Walled Carbon Nanotubes by a Single Screw Extruder for FDM 3D Printing

2021 ◽  
Vol 11 (19) ◽  
pp. 8798
Author(s):  
Thai-Hung Le ◽  
Van-Son Le ◽  
Quoc-Khanh Dang ◽  
Minh-Thuyet Nguyen ◽  
Trung-Kien Le ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Fused Deposition Modeling ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Tensile Tests ◽  
Flow Index ◽  
Fused Deposition ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Composite Filament

This paper reports the synthesis of a new printable ABS–MWCNT composite filament, for use in fused deposition modeling (FDM), using an extrusion technique. Acrylonitrile butadiene styrene (ABS) and multi-walled carbon nanotubes (MWCNTs) were the initial materials used for fabricating the filaments. The MWCNTs were dispersed in ABS resin, then extruded through a single-shaft extruder in filament form, with MWCNT contents of 0.5%, 1%, 1.5%, 2%, 3% or 4% by weight. After extrusion, the diameter of the filaments was about 1.75 mm, making them appropriate for FDM. The as-synthesized filaments were then used in FDM to print out samples, on which tensile tests and other analyses were carried out. The results demonstrate that the sample with 2% MWCNTs had the highest strength value, 44.57 MPa, comprising a 42% increase over that of the pure ABS sample. The morphology and dispersion of MWCNTs in the composite were observed by field emission scanning electron microscopy (FESEM), demonstrating the uniform distribution of MWCNTs in the ABS matrix. The thermal behavior results indicated no significant change in the ABS structure; however, the melt flow index of the filaments decreased with an increase in the MWCNT content.

Secondary recycled acrylonitrile–butadiene–styrene and graphene composite for 3D/4D applications: Rheological, thermal, magnetometric, and mechanical analyses

2020 ◽  
pp. 089270572092511 ◽  
Author(s):  
Vinay Kumar ◽  
Rupinder Singh ◽  
IPS Ahuja
Keyword(s):  
Acrylonitrile Butadiene Styrene ◽  
Melt Flow Index ◽  
Flow Index ◽  
Scanning Calorimetry ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
Microscopy Analysis ◽  
Vibration Sample Magnetometry ◽  
Porosity Analysis ◽  
Butadiene Styrene

This study reports investigation on nano-sized (5–10 nm) graphene (Gr)-reinforced, secondary (2°) recycled acrylonitrile–butadiene–styrene (ABS) as a smart composite material for 3D and 4D applications. Gr was blended (in different weight proportions) with 2°-recycled ABS granules mechanically for selection of composition/proportion after ascertaining rheological property (based upon melt flow index according to ASTM D 1238), thermal stability based upon differential scanning calorimetry, and magnetic property based upon vibration sample magnetometry. The selected compositions/proportions of ABS-Gr composite was further processed with a twin-screw extruder by varying screw temperature and torque. The results of the study suggest that as regards to mechanical properties (peak strength and Shore D hardness) are concerned, the best settings are 20 wt% Gr reinforcement in ABS at a screw temperature 210°C with torque of 0.4 Nm. The corresponding heat capacity and magnetization for the selected composition/proportion was observed as 0.77 J/g and 0.10 × 10−5 emu (+magnetization), 0.080 × 10−5 emu (−magnetization), respectively. The coercivity of the selected compositions ranges from 79.19 Oe to 1260.34 Oe (+coercivity) and 4.64 Oe to 639.50 Oe (−coercivity), whereas the retentivity of the investigated compositions ranges from 2.36 × 10−5 G to 5.44 × 10−4 G (+retentivity) and 4.31 × 10−5 G to 3.48 × 10−5 G (−retentivity). The results have been counter verified based upon optical photo micrographs, porosity analysis, scanning electron microscopy analysis, and energy-dispersive spectroscopy analysis.

Mechanical, electrical, and melt flow properties of polyurethane elastomer/surface-modified carbon nanotube composites

2016 ◽  
Vol 51 (14) ◽  
pp. 1987-1996 ◽  
Author(s):  
Umit Tayfun ◽  
Yasin Kanbur ◽  
Ufuk Abacı ◽  
Hasan Yüksel Güney ◽  
Erdal Bayramlı
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Melt Flow Index ◽  
Flow Index ◽  
Polyurethane Elastomer ◽  
Index Test ◽  
Melt Flow ◽  
Interfacial Interactions ◽  
Surface Modified ◽  
Modified Carbon Nanotubes

Carbon nanotube-reinforced polyurethane elastomer composites were prepared by melt-mixing. Nitric acid oxidation and silanization were applied to carbon nanotube surfaces to achieve better interfacial interactions with polyurethane elastomer. Tensile and hardness tests, differential scanning calorimetry, melt flow index test, dielectric measurements, and morphological studies of composites were reported. The best results were obtained for surface-modified carbon nanotubes containing composites with lower loading levels. Addition of carbon nanotubes leads to almost two-fold increase in strain and modulus compared to pristine polyurethane elastomer. Tensile strength of composites was also improved by inclusion of carbon nanotubes. However, strength values drop down with increasing carbon nanotube content. Shore hardness increased with the inclusion of modified carbon nanotube to polyurethane elastomer while pristine carbon nanotube caused remarkable decrease in hardness of polyurethane elastomer. Relatively higher melting points and slightly lower glass transition temperatures were observed for carbon nanotube-loaded composites compared to polyurethane elastomer because of plasticizing effect of carbon nanotube. Incorparation of carbon nanotube to polyurethane elastomer matrix caused reduction in melt flow index values due to formation of agglomarates, and n the contrary, surface modifications of carbon nanotube exhibited increase in melt flow index thanks to enhanced interfacial interactions between carbon nanotube and polyurethane elastomer. Significant increase in dielectric constant of composites was observed. Better dispersion of surface modified carbon nanotubes into polyurethane elastomer was also concluded from SEM micrographs of composites.

Study on the fluidity, mechanical and fracture behavior of ABS/TPU/CNT nanocomposites

2020 ◽  
pp. 089270572097869
Author(s):  
Farshad Heidari ◽  
Milad Aghalari ◽  
Ata Chalabi Tehran ◽  
Karim Shelesh-Nezhad
Keyword(s):  
Carbon Nanotubes ◽  
Fracture Behavior ◽  
Acrylonitrile Butadiene Styrene ◽  
Flow Index ◽  
Essential Work ◽  
Melt Mixing ◽  
Essential Work Of Fracture ◽  
Mechanical Performances ◽  
Work Of Fracture ◽  
Butadiene Styrene

Acrylonitrile butadiene styrene has relatively good mechanical performances, but its low melt fluidity limits the production of thin parts. In this research, acrylonitrile butadiene styrene/thermoplastic polyurethane (ABS/TPU) blends and ABS/TPU/CNT nanocomposites were prepared by employing melt-mixing process. The melt fluidity, mechanical and fracture behavior of different samples were evaluated. The morphology of fracture surfaces was studied by scanning electron microscopy. The addition of TPU into ABS substantially elevated the melt flow index, but noticeably weakened the notched impact toughness. The presence of carbon nanotubes in ABS/TPU blend promoted the mechanical performances and developed a rough fracture surface morphology. The notched impact resistance and essential work of fracture in nanocomposite containing 0.1 wt.% CNT showed about 95 and 50% increases respectively as compared to ABS/TPU (90/10) blend. In the presence of 0.3 wt.% CNT, the plane stress condition favorably dominated the toughness behavior, enhancing the non-essential work of fracture and crack propagation energy. The appropriate dispersion of carbon nanotubes and their adhesion to ABS/TPU polymer matrix were considered as the prominent factors affecting the fracture resistance of ABS/TPU/CNT nanocomposites.

scholarly journals Enhancement of mechanical, thermal and water uptake performance of TPU/jute fiber green composites via chemical treatments on fiber surface

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 133-143 ◽  
Author(s):  
Tuffaha Fathe Salem ◽  
Seha Tirkes ◽  
Alinda Oyku Akar ◽  
Umit Tayfun
Keyword(s):  
Water Absorption ◽  
Water Uptake ◽  
Mechanical Test ◽  
Fiber Surface ◽  
Melt Flow Index ◽  
Jute Fiber ◽  
Morphological Properties ◽  
Flow Index ◽  
Melt Flow ◽  
Treatment Type

AbstractChopped jute fiber (JF) surfaces were modified using alkaline, silane and eco-grade epoxy resin. Surface characteristics of jute fibers were confirmed by FTIR and EDX analyses. JF filled polyurethane elastomer (TPU) composites were prepared via extrusion process. The effect of surface modifications of JF on mechanical, thermo-mechanical, melt-flow, water uptake and morphological properties of TPU-based eco-composites were investigated by tensile and hardness tests, dynamic mechanical analysis (DMA), melt flow index (MFI) test, water absorption measurements and scanning electron microscopy (SEM) techniques, respectively. Mechanical test results showed that silane and epoxy treated JF additions led to increase in tensile strength, modulus and hardness of TPU. Glass transition temperature (Tg) of TPU rose up to higher values after JF inclusions regardless of treatment type. Si-JF filled TPU exhibited the lowest water absorption among composites. Surface treated JFs displayed homogeneous dispersion into TPU and their surface were covered by TPU according to SEM micro-photographs.

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