scholarly journals On the Support Effect and the Cr Promotion of Co Based Catalysts for the Acetic Acid Steam Reforming

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 133
Author(s):  
Marta Cortese ◽  
Concetta Ruocco ◽  
Vincenzo Palma ◽  
Pedro J. Megía ◽  
Alicia Carrero ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Mesoporous Silica ◽  
Steam Reforming ◽  
Supported Catalysts ◽  
Support Effect ◽  
The Other ◽  
Hexagonal Mesoporous Silica ◽  
Chromium Addition ◽  
Cr Addition ◽  
The Impact

This work focuses on the support effect of the performances of Co based catalysts for acetic acid steam reforming. SBA-15, a well ordered hexagonal mesoporous silica structure, and CeO2 have been selected as the supports, with the impact of chromium addition also being investigated. Better acetic acid steam reforming performances have been recorded for CeO2 compared to SBA-15 supported catalysts and, in particular, the 7Co/CeO2 catalyst showed the highest values of acetic acid conversions with enhanced H2 yields below 480 °C, in comparison to the other investigated catalytic formulations. In addition, more pronounced coke depositions and acetone concentrations have been obtained with CeO2 supported catalysts, due to the tendency of ceria to catalyse the ketonization reaction. Chromium addition to Co/SBA-15 catalysts led to an enhancement in the activity towards acetic acid steam reforming, while on CeO2 supported catalysts no improvement in the catalysts’ activity was observed. However, on both SBA-15 and CeO2 supported catalysts, Cr addition reduced the amount of coke deposited on the catalysts surface.

scholarly journals An Experimental Study of the Acetic Acid Steam Reforming Over Co-Based Catalysts

2020 ◽  
Author(s):  
Marta Cortese ◽  
Concetta Ruocco ◽  
Vincenzo Palma ◽  
Pedro Mejia ◽  
Alicia Carrero ◽  
...  
Keyword(s):  
Experimental Study ◽  
Acetic Acid ◽  
Mesoporous Silica ◽  
Steam Reforming ◽  
Supported Catalysts ◽  
Support Effect ◽  
The Other ◽  
Chromium Addition ◽  
Cr Addition ◽  
The Impact

This work focuses on the support effect on the performances of Co-based catalysts for the acetic acid steam reforming. SBA-15, a well ordered hexagonal mesoporous silica structure, and CeO2 have been selected as the supports, with the impact of chromium addition also being investigated. Better acetic acid steam reforming performances have been recorded for CeO2 compared to SBA-15 supported catalysts and, in particular, the 7Co/CeO2 catalyst showed the highest values of acetic acid conversions with enhanced H2 yields below 480°C, in comparison to the other investigated catalytic formulations. In addition, more pronounced coke depositions and acetone concentrations have been obtained with CeO2 supported catalysts, due to the tendency of ceria to catalyse the ketonization reaction. Chromium addition to Co/SBA-15 catalysts led to an enhancement in the activity towards acetic acid steam reforming, while on CeO2 supported catalysts no improvement in the catalysts activity was observed; however, on both SBA-15 and CeO2 supported catalysts, Cr addition reduced the amount of coke deposited on the catalysts surface.

Support effect on structure and performance of Co and Ni catalysts for steam reforming of acetic acid

2016 ◽  
Vol 514 ◽  
pp. 182-191 ◽  
Author(s):  
Saioa Goicoechea ◽  
Elka Kraleva ◽  
Sergey Sokolov ◽  
Matthias Schneider ◽  
Marga-Martina Pohl ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Steam Reforming ◽  
Support Effect ◽  
Ni Catalysts ◽  
And Performance

A comparative research on the catalytic activity of La2O3 and γ-Al2O3 supported catalysts for acetic acid steam reforming

2017 ◽  
Vol 42 (6) ◽  
pp. 3667-3675 ◽  
Author(s):  
Fan Zhang ◽  
Meijuan Wang ◽  
Lingjun Zhu ◽  
Shurong Wang ◽  
Jinsong Zhou ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Catalytic Activity ◽  
Steam Reforming ◽  
Comparative Research ◽  
Supported Catalysts

scholarly journals Co-pyrolysis–catalytic steam reforming of cellulose/lignin with polyethylene/polystyrene for the production of hydrogen

2020 ◽  
Vol 2 (3) ◽  
pp. 177-191
Author(s):  
Kaltume Akubo ◽  
Mohamad Anas Nahil ◽  
Paul T. Williams
Keyword(s):  
Thermal Degradation ◽  
Steam Reforming ◽  
Supported Catalysts ◽  
Hydrogen Yield ◽  
Syngas Production ◽  
Production Of Hydrogen ◽  
Catalyst Temperature ◽  
The Impact ◽  
Catalytic Steam Reforming ◽  
Mcm 41

Abstract Co-pyrolysis of biomass biopolymers (lignin and cellulose) with plastic wastes (polyethylene and polystyrene) coupled with downstream catalytic steam reforming of the pyrolysis gases for the production of a hydrogen-rich syngas is reported. The catalyst used was 10 wt.% nickel supported on MCM-41. The influence of the process parameters of temperature and the steam flow rate was examined to optimize hydrogen and syngas production. The cellulose/plastic mixtures produced higher hydrogen yields compared with the lignin/plastic mixtures. However, the impact of raising the catalytic steam reforming temperature from 750 to 850 °C was more marked for lignin addition. For example, the hydrogen yield for cellulose/polyethylene at a catalyst temperature of 750 °C was 50.3 mmol g−1 and increased to 60.0 mmol g−1 at a catalyst temperature of 850 °C. However, for the lignin/polyethylene mixture, the hydrogen yield increased from 25.0 to 50.0 mmol g−1 representing a twofold increase in hydrogen yield. The greater influence on hydrogen and yield for the lignin/plastic mixtures compared to the cellulose/plastic mixtures is suggested to be due to the overlapping thermal degradation profiles of lignin and the polyethylene and polystyrene. The input of steam to the catalyst reactor produced catalytic steam reforming conditions and a marked increase in hydrogen yield. The influence of increased steam input to the process was greater for the lignin/plastic mixtures compared to the cellulose/plastic mixtures, again linked to the overlapping thermal degradation profiles of the lignin and the plastics. A comparison of the Ni/MCM-41 catalyst with Ni/Al2O3 and Ni/Y-zeolite-supported catalysts showed that the Ni/Al2O3 catalyst gave higher yields of hydrogen and syngas. Graphic abstract

Steam Reforming of Acetic Acid over Co-Supported Catalysts: Coupling Ketonization for Greater Stability

2017 ◽  
Vol 5 (10) ◽  
pp. 9136-9149 ◽  
Author(s):  
Stephen D. Davidson ◽  
Kurt A. Spies ◽  
Donghai Mei ◽  
Libor Kovarik ◽  
Igor Kutnyakov ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Steam Reforming ◽  
Supported Catalysts

Modernism, Empiricism, and Rationalism

2016 ◽  
Vol 46 (1) ◽  
pp. 38-47
Author(s):  
Geoffrey Squires
Keyword(s):  
Twentieth Century ◽  
The Other ◽  
Modern Poetry ◽  
Philosophical Perspective ◽  
Irish Poetry ◽  
Dimensional Spectrum ◽  
Culture History ◽  
The World ◽  
The Impact ◽  
Rule Out

Modernism is usually defined historically as the composite movement at the beginning of the twentieth century which led to a radical break with what had gone before in literature and the other arts. Given the problems of the continuing use of the concept to cover subsequent writing, this essay proposes an alternative, philosophical perspective which explores the impact of rationalism (what we bring to the world) on the prevailing empiricism (what we take from the world) of modern poetry, which leads to a concern with consciousness rather than experience. This in turn involves a re-conceptualisation of the lyric or narrative I, of language itself as a phenomenon, and of other poetic themes such as nature, culture, history, and art. Against the background of the dominant empiricism of modern Irish poetry as presented in Crotty's anthology, the essay explores these ideas in terms of a small number of poets who may be considered modernist in various ways. This does not rule out modernist elements in some other poets and the initial distinction between a poetics of experience and one of consciousness is better seen as a multi-dimensional spectrum that requires further, more detailed analysis than is possible here.

HOME VISITS DURING THE FIRST MONTH OF DELIVERY FOR RECENTLY DELIVERED WOMEN IN UTTAR PRADESH, INDIA

2020 ◽  
Vol 6 (5) ◽  
pp. 1183-1189
Author(s):  
Dr. Tridibesh Tripathy ◽  
Dr. Umakant Prusty ◽  
Dr. Chintamani Nayak ◽  
Dr. Rakesh Dwivedi ◽  
Dr. Mohini Gautam
Keyword(s):  
Large Scale ◽  
National Level ◽  
Uttar Pradesh ◽  
Life Time ◽  
Structured Interview ◽  
The Other ◽  
Registration System ◽  
Action Group ◽  
Current Article ◽  
The Impact

The current article of Uttar Pradesh (UP) is about the ASHAs who are the daughters-in-law of a family that resides in the same community that they serve as the grassroots health worker since 2005 when the NRHM was introduced in the Empowered Action Group (EAG) states. UP is one such Empowered Action Group (EAG) state. The current study explores the actual responses of Recently Delivered Women (RDW) on their visits during the first month of their recent delivery. From the catchment area of each of the 250 ASHAs, two RDWs were selected who had a child in the age group of 3 to 6 months during the survey. The response profiles of the RDWs on the post- delivery first month visits are dwelled upon to evolve a picture representing the entire state of UP. The relevance of the study assumes significance as detailed data on the modalities of postnatal visits are available but not exclusively for the first month period of their recent delivery. The details of the post-delivery first month period related visits are not available even in large scale surveys like National Family Health Survey 4 done in 2015-16. The current study gives an insight in to these visits with a five-point approach i.e. type of personnel doing the visit, frequency of the visits, visits done in a particular week from among those four weeks separately for the three visits separately. The current study is basically regarding the summary of this Penta approach for the post- delivery one-month period.     The first month period after each delivery deals with 70% of the time of the postnatal period & the entire neonatal period. Therefore, it does impact the Maternal Mortality Rate & Ratio (MMR) & the Neonatal Mortality Rates (NMR) in India and especially in UP through the unsafe Maternal & Neonatal practices in the first month period after delivery. The current MM Rate of UP is 20.1 & MM Ratio is 216 whereas the MM ratio is 122 in India (SRS, 2019). The Sample Registration System (SRS) report also mentions that the Life Time Risk (LTR) of a woman in pregnancy is 0.7% which is the highest in the nation (SRS, 2019). This means it is very risky to give birth in UP in comparison to other regions in the country (SRS, 2019). This risk is at the peak in the first month period after each delivery. Similarly, the current NMR in India is 23 per 1000 livebirths (UNIGME,2018). As NMR data is not available separately for states, the national level data also hold good for the states and that’s how for the state of UP as well. These mortalities are the impact indicators and such indicators can be reduced through long drawn processes that includes effective and timely visits to RDWs especially in the first month period after delivery. This would help in making their post-natal & neonatal stage safe. This is the area of post-delivery first month visit profile detailing that the current article helps in popping out in relation to the recent delivery of the respondents.   A total of four districts of Uttar Pradesh were selected purposively for the study and the data collection was conducted in the villages of the respective districts with the help of a pre-tested structured interview schedule with both close-ended and open-ended questions.  The current article deals with five close ended questions with options, two for the type of personnel & frequency while the other three are for each of the three visits in the first month after the recent delivery of respondents. In addition, in-depth interviews were also conducted amongst the RDWs and a total 500 respondents had participated in the study.   Among the districts related to this article, the results showed that ASHA was the type of personnel who did the majority of visits in all the four districts. On the other hand, 25-40% of RDWs in all the 4 districts replied that they did not receive any visit within the first month of their recent delivery. Regarding frequency, most of the RDWs in all the 4 districts received 1-2 times visits by ASHAs.   Regarding the first visit, it was found that the ASHAs of Barabanki and Gonda visited less percentage of RDWs in the first week after delivery. Similarly, the second visit revealed that about 1.2% RDWs in Banda district could not recall about the visit. Further on the second visit, the RDWs responded that most of them in 3 districts except Gonda district did receive the second postnatal visit in 7-15 days after their recent delivery. Less than half of RDWs in Barabanki district & just more than half of RDWs in Gonda district received the third visit in 15-21 days period after delivery. For the same period, the majority of RDWs in the rest two districts responded that they had been entertained through a home visit.

Wacana Kolonial dalam Novel Max Havelaar: Sebuah Kajian Poskolonial

Metahumaniora ◽  
2017 ◽  
Vol 7 (3) ◽  
pp. 411
Author(s):  
Abu Bakar Ramadhan Muhamad
Keyword(s):  
Point Of View ◽  
The Other ◽  
The Novel ◽  
Colonial Discourse ◽  
The Impact ◽  
The Voice

AbstrakHegemoni kolonialisme dalam budaya poskolonial merupakan alasan penelitian inikemudian mengkaji wacana kolonial dalam novel Max Havellar (MH) khususnya dampakditimbulkannya. Dampak dimaksud adalah posisi keberpihakan pemikiran tersirat darikarya tersebut. Hasil pembahasan menunjukkan, secara temporal maupun permanen MHmenyuarakan ketidakadilan dalam kondisi-kondisi kolonial menyangkut penindasan sangpenjajah terhadap terjajah. Hanya saja, upaya mengatasnamakan atau mewakili suarakaum terjajah terbukti mengimplikasikan ciri ideologis statis kerangka kolonialisme(orientalisme); yakni cara pandang Eropasentris, di mana “Barat” sebagai self adalah superior,dan “Timur” sebagai other adalah inferior. Dalam konteks poskolonialisme, MH dengan sifatkritisnya yang berupaya “menyuarakan” nasib pribumi terjajah, justru menampilkan stigmapenguatan kolonialitas itu sendiri secara hegemonik. Artinya, “menyuarakan” nasib pribumidimaknai sebagai keberpihankan kolonial yang kontradiktif, di mana stigma penguatankolonialitas justru lebih terasa, ujung-ujungnya melanggengkan hegemoni kolonial. Tidakmembela yang terjajah, tetapi memperhalus cara kerja mesin kolonial.AbstractThe hegemony of colonialism in the culture of postcolonial society is the reason this studythen examines the colonial discourse in the novel Max Havellar (MH) in particular the impactit brings. The impact in question is the implied position of thought in the work. The resultsof the discussion show that, temporarily or permanently, MH voiced injustice in the colonialconditions regarding the oppression of the colonist against the colonized. However, the effort toname or represent the voice of the colonized has proven to imply a static ideological characterin the framework of colonialism (orientalism); ie Eropacentric point of view, in which “West” asself is superior, and “East” as the other is the inferior. In the context of postcolonialism, MH withits critical nature that seeks to “voice” the fate of the colonized natives, actually presents thestigma of strengthening coloniality itself hegemonicly. That is, “voicing” the fate of the pribumiis interpreted as a contradictory colonial flare, where the stigma of strengthening colonialityis more pronounced, which ultimately perpetuates the hegemony of colonialism. No longerdefending the colonized, but refining the workings of the colonial machinery.

Gifted Students' Motivation and its Impact on the Development of their Giftedness

2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Hussein SALEM MUBARAK BARABWD ◽  
Mohammad YUSOFF BIN MOHD NOR ◽  
Noriah Mohd Ishak
Keyword(s):  
Extrinsic Motivation ◽  
Gifted Students ◽  
Qualitative Approach ◽  
The Other ◽  
Phenomenological Method ◽  
Self Confidence ◽  
Verbal Praise ◽  
Intrinsic Motivations ◽  
The Impact ◽  
Intrinsic And Extrinsic Motivations

The aim of the current study is to examine the intrinsic and extrinsic motivations of the gifted students from Hadhramout Gifted Center HGC in Yemen, and to investigate the impact of these intrinsic and extrinsic motivations on their giftedness development. A qualitative approach was adopted; data has been collected through an open- ended questionnaire that was prepared by the researcher and distributed among a sample of gifted students who were chosen purposively from HGC. The interpretative phenomenological method has been used to analyze the data using, Atlas ti. The results indicate that the majority of the participants consider it interesting to explore new things, and experience curiosity and desire to achieve their goals as their intrinsic motivations. Whereas, the minority consider preference to serve the community, competition preference and self-confidence as their intrinsic motivations. On the other hand, half of the participants consider rewards as their extrinsic motivation, whereas 40 % of them consider exams scores, verbal praise, parents and environment as their extrinsic motivations. Regarding the impact of intrinsic and extrinsic motivations on the development of giftedness, the majority of the participants believe that intrinsic and extrinsic motivations affect positively the development of their giftedness development. Finally, based on the findings, some recommendations were provided. 

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