Transformation of 2-Butene into Propene on WO3/MCM-48: Metathesis and Isomerization of n-Butene
Keyword(s):
The metathesis of 2-butene (Trans and Cis) to propene was investigated over W-based catalysts. Thermodynamic calculations for metathesis and isomerization were carried out at various temperatures to test the reactions. The results showed that the WO3/MCM-48 catalyst had good catalytic activity. The metathesis activity depended on the acidity of the catalyst and the dispersity of the WO3 on the supports. High temperatures promoted the isomerization of 2-butene to 1-butene. According to thermodynamic analysis, however, this is adverse to the metathesis reaction, making it important to determine an appropriate reaction temperature.
2007 ◽
Vol 544-545
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pp. 23-26
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1978 ◽
Vol 36
(1)
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pp. 274-275
Keyword(s):
2013 ◽
Vol 457-458
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pp. 139-143
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2020 ◽
Vol 8
(3)
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pp. 1254-1264
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