scholarly journals Study of the Effect of Physicochemical Degradation and Contamination of Motor Oils on Their Lubricity

Coatings ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 60
Author(s):  
Marie Sejkorová ◽  
Ivana Hurtová ◽  
Petr Jilek ◽  
Martin Novák ◽  
Ondřej Voltr
Keyword(s):  
Combustion Engine ◽  
Degradation Products ◽  
Load Capacity ◽  
American Petroleum Institute ◽  
Chemical Degradation ◽  
Motor Oil ◽  
Zinc Dialkyldithiophosphate ◽  
Lubricating Film ◽  
Negative Effect ◽  
Motor Oils

Internal combustion engine lubrication is essential for unwanted energy and material losses. As part of the experimental work, the lubricity of both new and worn motor oils of Society of Automotive Engineers (SAE) 15W-40 and SAE 10W-40 with different American Petroleum Institute (API) performance classifications, which were taken from various motor trains during maintenance or oil change, was assessed. A total of sixteen lubricant samples were evaluated. Lubricity, i.e., the load capacity of the lubricating film, was evaluated on the basis of the Reichert test. Viscosity, as one of the most important parameters of lubricants, was evaluated by the Stabinger Viscometer. Chemical degradation of motor oils (oxidation, nitration, sulfation), contamination of oils with fuel, soot, water, and loss of antioxidant zinc dialkyldithiophosphate (ZDDP) were monitored by Fourier-transform infrared (FTIR) spectroscopy. Of the fresh motor oils, OMV 10W-40 API SL/CF motor oil had the best lubricity. URANIA LD 15W-40 API CI-4 and M7ADS V 15W-40 API CI-4 CH-4/SL oils showed similar lubricity. M7ADS III 15W-40 API CF-4/SG motor oil showed the highest wear of wear surface, i.e., the lowest lubricity, of the tested new motor oils. Correlation analysis of the experimental data confirmed that the fuel content penetrated the motor oils significantly negatively correlates with the viscosity (R = −0.87). The low water contamination in motor oil does not cause a significant negative effect on lubricity. A significant correlation between the oxidation, nitration, and sulfation products of chemical degradation of the tested oils was confirmed (R ≥ 0.90). These degradation products improve lubricity due to their polarity, i.e., they have caused better lubricity of worn oils compared to new motor oils. Even the depletion of the antioxidant ZDDP did not affect the reduction in lubricity and anti-abrasion properties of chemically degraded motor oils. The experimental results of testing of worn motor oils taken from motor trains showed that current motor oils have excellent lubricity, which they maintain throughout their life.

scholarly journals Measurement of flow and pressure characteristics of combustion engine oil filters

2021 ◽  
Vol 351 ◽  
pp. 01004
Author(s):  
Ľubomír Hujo ◽  
Matej Michalides ◽  
Jozef Nosian ◽  
Mirko Simikić
Keyword(s):  
Internal Combustion Engines ◽  
Combustion Engine ◽  
Engine Oil ◽  
Motor Vehicles ◽  
Combustion Engines ◽  
Motor Oil ◽  
Filtration Equipment ◽  
Motor Oils ◽  
The Given ◽  
Pressure Characteristics

For the purpose of measuring the flow and pressure characteristics of oil filters used in vehicles with internal combustion engines, a laboratory test equipment was used, which was designed at the Department of Transport and Handling of the Slovak University of Agriculture in Nitra. The target information from the given measurement is the obtained data on the change of flow and pressure, based on the type of oil filter used. The contribution of this paper is information that can be used in the future in the design of new filtration equipment, as well as the creation of a system for evaluating the technical life of motor oils, in order to extend the service intervals of motor oil, monitored set of motor vehicles.

Phase I Study of the Novel Epothilone Analog Ixabepilone (BMS-247550) in Patients With Advanced Solid Tumors and Lymphomas

2007 ◽  
Vol 25 (9) ◽  
pp. 1082-1088 ◽  
Author(s):  
Carol Aghajanian ◽  
Howard A. Burris ◽  
Suzanne Jones ◽  
David R. Spriggs ◽  
Marvin B. Cohen ◽  
...  
Keyword(s):  
Plasma Concentration ◽  
Solid Tumors ◽  
Dose Escalation ◽  
Mononuclear Cells ◽  
Degradation Products ◽  
Standard Dose ◽  
Chemical Degradation ◽  
Maximum Plasma ◽  
Advanced Solid Tumors ◽  
Phase Ii Studies

Purpose To establish the maximum-tolerated dose (MTD), dose-limiting toxicity (DLT), safety, pharmacokinetics, and pharmacodynamics of ixabepilone when administered as a 1-hour infusion every 3 weeks to patients with advanced solid tumors or relapsed/refractory non-Hodgkin's lymphoma. Dosing schedules of 40 mg/m2 and 50 mg/m2 over 3 hours were also evaluated. Patients and Methods Sixty-one patients were enrolled using an initial accelerated dose-escalation phase followed by a standard dose-escalation phase, with doses of ixabepilone ranging from 7.4 to 65 mg/m2. The pharmacokinetics of ixabepilone and two of its chemical degradation products were evaluated. Plasma pharmacodynamics were evaluated for both 1- and 3-hour infusions using an assay that measures the amount of endogenous tubulin in peripheral-blood mononuclear cells that exists in the polymerized versus the unpolymerized state. Response evaluation was performed every 6 weeks. Results The most common DLTs were neutropenia, stomatitis/pharyngitis, myalgia, and arthralgia. The MTD of ixabepilone as a 1-hour infusion every 3 weeks was established as 50 mg/m2. The maximum plasma concentration and area under the plasma concentration time curve appeared to increase less than proportionally to dose. Durable objective responses were seen in eight patients, including two complete responses. Five of the responders had experienced treatment failure with a taxane. Conclusion The recommended dose of ixabepilone for the initiation of phase II studies on the basis of these results is 50 mg/m2 over 1 hour every 3 weeks. The promising efficacy and tolerability results demonstrated by ixabepilone in this study warrant its continued development.

scholarly journals The optimization of internal combustion engine oil change periods

2019 ◽  
Vol 26 (01) ◽  
pp. 157-162
Author(s):  
Davaasuren G ◽  
Gantulga G
Keyword(s):  
Internal Combustion Engine ◽  
Combustion Engine ◽  
Internal Combustion ◽  
Operating Regime ◽  
Spare Parts ◽  
Operating Conditions ◽  
Engine Oil ◽  
Used Oil ◽  
Negative Effect

It is vitally important for vehicle users that are to study the operating regime that may negative effect to the operation of the engine, to reduce its effect, to maintain the engine's reliability in accordance with the specific operating conditions. Quality of lubrication is one of the main factors that are improving of reliability and operational efficiency for any machinery their spare parts. So this paper presents to optimize of oil change intervals and to determine of wear rating of spare parts by content of metal particles in the internal combustion engine used oil. Дотоод шаталтат хөдөлгүүрийн тос солих хугацааг оновчлох нь Хураангуй:  Машин ашиглагчдын хувьд тухайн хөдөлгүүрийн ажиллагаанд сөрөг нөлөө үзүүлэх  ашиглалтын горимыг судалж, түүний хор нөлөөг багасгах болон ашиглалтын өвөрмөц  нөхцөлд тохируулан хөдөлгүүрийн найдварт ажиллагааг ханган зөв, ашигтай ажиллуулах  чадвартай байх нь асар их ач холбогдолтой юм. Аливаа машин техник , тэдгээрийн агрегат,  зангилаа эд ангийн удаан эдлэхүй, найдвартай ажиллагааг хангах, ашиглалтын үр ашгийг  дээшлүүлэх гол хүчин зүйлүүдийн нэг нь тосолгооны чанар байдаг учраас дотоод шаталтат  хөдөлгүүрийн ашигласан тосон дахь металлын агууламжыг илрүүлж, эд ангийн элэгдлийн  явцыг тодорхойлон, тос солих хугацааг оновчлох асуудлыг судалгааны хүрээнд авч үзлээ.  Түлхүүр үг: Хөдөлгүүрийн ашигласан тосны шинжилгээ, металл хольц, тосны бохирдол,  тортог, элэгдлийн элементийн хязгаар 

Static Characteristics of Gas Foil Thrust Bearing Based on Gas Rarefaction Model

2015 ◽  
Author(s):  
Jiajia Yan ◽  
Guanghui Zhang ◽  
Zhansheng Liu ◽  
Fan Yang
Keyword(s):  
Film Thickness ◽  
Optimization Design ◽  
Reynolds Equation ◽  
Thrust Bearing ◽  
Rarefied Gas ◽  
Load Capacity ◽  
Structural Parameters ◽  
Lubricating Film ◽  
Lift Off ◽  
Foil Thrust Bearing

A modified Reynolds equation for bump type gas foil thrust bearing was established with consideration of the gas rarefaction coefficient. Under rarefied gas lubrication, the Knudsen number which was affected by the film thickness and pressure was introduced to the Reynolds equation. The coupled modified Reynolds and lubricating film thickness equations were solved using Newton-Raphson Iterative Method and Finite Difference Method. By calculating the load capacity for increasing rotor speeds, the lift-off speed under certain static load was obtained. Parametric studies for a series of structural parameters and assembled clearances were carried out for bearing optimization design. The results indicate that with gas rarefaction effect, the axial load capacity would be decreased, and the lift-off speed would be improved. The rarefied gas has a more remarkable impact under a lower rotating speed and a smaller foil compliance coefficient. When the assembled clearance of the thrust bearing rotor system lies in a small value, the lift-off speed increases dramatically as the assembled clearance decreases further. Therefore, the axial clearance should be controlled carefully in assembling the foil thrust bearing. It’s worth noting that the linear uniform bump foil stiffness model is not exact for large foil compliance ∼0.5, especially for lift-off speed analysis, due to ignoring the interaction between bumps and bending stiffness of the foil.

Identification of new aqueous chemical degradation products of isophosphoramide mustard

2001 ◽  
Vol 25 (3-4) ◽  
pp. 669-678 ◽  
Author(s):  
Stéphane Breil ◽  
Robert Martino ◽  
Véronique Gilard ◽  
Myriam Malet-Martino ◽  
Ulf Niemeyer
Keyword(s):  
Degradation Products ◽  
Chemical Degradation ◽  
Isophosphoramide Mustard

Experimental Validation of an Intelligent Hybrid Plain Bearing Active Control

2020 ◽  
Vol 143 (4) ◽  
Author(s):  
Clément Eberhardt ◽  
Robin Kurth ◽  
Christian Kraft ◽  
Hubert Schwarze ◽  
Thomas Päßler ◽  
...  
Keyword(s):  
Load Capacity ◽  
Hydrodynamic Pressure ◽  
Strong Increase ◽  
Plain Bearing ◽  
Press Hardening ◽  
Negative Effect ◽  
Clamping System ◽  
Smart Machine ◽  
Very High

Abstract The replacement of damaged journal bearings in forming machines eventuates in very high personal and material costs as well as long-term downtime. Moreover, new discontinuous forming processes (e.g., press hardening and pendulum operations) have a negative effect on the hydrodynamic pressure built up in the bearing and can lead to failure. Therefore, users and manufacturers of forming presses are looking for ways to improve the safety of this key component. In this paper, the concept of an intelligent hybrid plain bearing (IHPB) that combines hydrodynamic and hydrostatic characteristics, presented by Kurth et al., (2019, “Forming 4.0: Smart Machine Components Applied as a Hybrid Plain Bearing and a Tool Clamping System,” Proc. Manuf., 27, pp. 65–71), is detailed and validated on a test rig. The clearance state of the journal bearing is monitored through eddy current sensors and a controlled hydrostatic support is activated, when this state is evaluated as critical. The results show a strong increase in the load capacity and in the minimal lubrication gap of the IHPB within three series of tested experiments: stationary, nonstationary, and press-typical load cases.

Motor Oil Classification Using Color Histograms and Pattern Recognition Techniques

2018 ◽  
Vol 101 (6) ◽  
pp. 1967-1976 ◽  
Author(s):  
Shiva Ahmadi ◽  
Ahmad Mani-Varnosfaderani ◽  
Biuck Habibi
Keyword(s):  
Pattern Recognition ◽  
Discriminant Analysis ◽  
Classification Problem ◽  
Classification Model ◽  
Motor Oil ◽  
Pattern Recognition Techniques ◽  
Color Histograms ◽  
Different Types ◽  
Motor Oils

Abstract Motor oil classification is important for quality control and the identification of oil adulteration. In this work, we propose a simple, rapid, inexpensive and nondestructive approach based on image analysis and pattern recognition techniques for the classification of nine different types of motor oils according to their corresponding color histograms. For this, we applied color histogram in different color spaces such as red green blue (RGB), grayscale, and hue saturation intensity (HSI) in order to extract features that can help with the classification procedure. These color histograms and their combinations were used as input for model development and then were statistically evaluated by using linear discriminant analysis (LDA), quadratic discriminant analysis (QDA), and support vector machine (SVM) techniques. Here, two common solutions for solving a multiclass classification problem were applied: (1) transformation to binary classification problem using a one-against-all (OAA) approach and (2) extension from binary classifiers to a single globally optimized multilabel classification model. In the OAA strategy, LDA, QDA, and SVM reached up to 97% in terms of accuracy, sensitivity, and specificity for both the training and test sets. In extension from binary case, despite good performances by the SVM classification model, QDA and LDA provided better results up to 92% for RGB-grayscale-HSI color histograms and up to 93% for the HSI color map, respectively. In order to reduce the numbers of independent variables for modeling, a principle component analysis algorithm was used. Our results suggest that the proposed method is promising for the identification and classification of different types of motor oils.

scholarly journals A dynamic plant chamber system with downstream reaction chamber to study the effects of pollution on biogenic emissions

2013 ◽  
Vol 6 (5) ◽  
pp. 9005-9036
Author(s):  
J. Timkovsky ◽  
P. Gankema ◽  
R. Pierik ◽  
R. Holzinger
Keyword(s):  
Degradation Products ◽  
Proton Transfer Reaction ◽  
Reaction Chamber ◽  
Oxidation Products ◽  
Chemical Degradation ◽  
Biogenic Emissions ◽  
Dynamic Plant ◽  
Cryogenic Trapping ◽  
Plant Emissions ◽  
Set Up

Abstract. A system of two dynamic plant chambers and a downstream reaction chamber has been set up to investigate the emission of biogenic volatile organic compounds (BVOC) and possible effects from pollutants such as ozone. The system can be used to compare BVOC emissions from two sets of differently treated plants, or to study the photochemistry of real plant emissions under polluted conditions without exposing the plants to pollutants. The main analytical tool is a proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS) which allows online monitoring of biogenic emissions and chemical degradation products. The identification of BVOCs and their oxidation products is aided by cryogenic trapping and subsequent in situ gas chromatographic analysis. The data presented in the paper demonstrates the good performance of the setup.

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