scholarly journals Experimental Investigations of Behaviour of Biosurfactants in Brine Solutions Relevant to Hydrocarbon Reservoirs

2019 ◽  
Vol 3 (1) ◽  
pp. 24 ◽  
Author(s):  
Tinuola Udoh ◽  
Jan Vinogradov
Keyword(s):  
Surface Tension ◽  
Free Energy ◽  
Oil Recovery ◽  
High Salinity ◽  
Standard Free Energy ◽  
Experimental Investigations ◽  
Surface Excess ◽  
Hydrocarbon Reservoir ◽  
Air Interface ◽  
Gibbs Surface Excess

In this study, we investigated the behaviour of rhamnolipid and Greenzyme in brine solutions relevant to hydrocarbon reservoir. Prior to this work, several studies only reported the behaviour of the biosurfactants dissolved in sodium chloride solutions of varied salinity. The results of this study are relevant to the application of the biosurfactants in enhanced oil recovery, during which the compounds are injected into reservoir saturated with formation water, typically of high salinity and complex composition. Surface tension and conductivity methods were used to determine the critical micelle concentrations of the biosurfactants, Gibbs surface excess concentrations and standard free energy at water-air interface. The results show that rhamnolipid and Greenzyme could reduce the surface tension of water from 72.1 ± 0.2 mN/m to 34.7 ± 0.4 mN/m and 47.1 ± 0.1 mN/m respectively. They were also found to be stable in high salinity and high temperature with rhamnolipid being sensitive to brine salinity, composition and pH while Greenzyme showed tolerance for high salinity. Furthermore, the Gibbs standard free energy of micellisation shows that rhamnolipid and Greenzyme have the tendency to spontaneously form micelles with rhamnolipid showing more surface adsorption. However from maximal Gibbs surface excess concentration calculations, Greenzyme monomers tend to favour aggregation more than that of rhamnolipid.

scholarly journals Adsorption Properties of Hydrocarbon and Fluorocarbon Surfactants Ternary Mixture at the Water-Air Interface

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4313
Author(s):  
Bronisław Jańczuk ◽  
Katarzyna Szymczyk ◽  
Anna Zdziennicka
Keyword(s):  
Surface Tension ◽  
Water Surface ◽  
Standard Free Energy ◽  
Ternary Mixtures ◽  
Free Energy Of Adsorption ◽  
Interface Tension ◽  
Air Interface ◽  
Surface Excess Concentration ◽  
Tail Water ◽  
Triton X

Measurements were made of the surface tension of the aqueous solutions of p-(1,1,3,3-tetramethylbutyl) phenoxypoly(ethylene glycols) having 10 oxyethylene groups in the molecule (Triton X-100, TX100) and cetyltrimethylammonium bromide (CTAB) with Zonyl FSN-100 (FC6EO14, FC1) as well as with Zonyl FSO-100 (FC5EO10, FC2) ternary mixtures. The obtained results were compared to those provided by the Fainerman and Miller equation and to the values of the solution surface tension calculated, based on the contribution of a particular surfactant in the mixture to the reduction of water surface tension. The changes of the aqueous solution ternary surfactants mixture surface tension at the constant concentration of TX100 and CTAB mixture at which the water surface tension was reduced to 60 and 50 mN/m as a function of fluorocarbon surfactant concentration, were considered with regard to the composition of the mixed monolayer at the water-air interface. Next, this composition was applied for the calculation of the concentration of the particular surfactants in the monolayer using the Frumkin equation. On the other hand, the Gibbs surface excess concentration was determined only for the fluorocarbon surfactants. The tendency of the particular surfactants to adsorb at the water-air interface was discussed, based on the Gibbs standard free energy of adsorption which was determined using different methods. This energy was also deduced, based on the surfactant tail surface tension and tail-water interface tension.

scholarly journals Comparison between surface and volumetric properties of short-chain alcohols and some classical surfactants

2016 ◽  
Vol 71 (1) ◽  
pp. 1 ◽  
Author(s):  
Magdalena Bielawska ◽  
Anna Zdziennicka ◽  
Bronisław Jańczuk
Keyword(s):  
Free Energy ◽  
Aqueous Solutions ◽  
Chemical Potential ◽  
Standard Free Energy ◽  
Dynamic Surface Tension ◽  
Short Chain ◽  
Critical Aggregation Concentration ◽  
Free Energy Of Adsorption ◽  
Dynamic Surface ◽  
Air Interface

<p>Measurements of the dynamic surface tension of the aqueous solutions of methanol, ethanol, propanol, CTAB and SDDS at their given concentrations were made. From the obtained results and the literature data it was concluded that the adsorption of short-chain alcohols at the water-air interface is somewhat similar to that of classical surfactants. For that reason the relationship between the Gibbs standard free energy of adsorption of short-chain alcohols and classical surfactants at that interface was established. The correlation between the chemical potential of mixing of alcohols and surfactants was also analysed. This analysis concerned the critical aggregation concentration (CAC) of alcohols and the critical micelle concentration (CMC) of surfactants. The chemical potential of surfactant mixing was calculated from the literature CMC data for the homologous series of alkyl sulfates, alkyl sulfonates, alkyl ammonium chlorides, alkyl trimethylammonium bromides, and alkyl pyridinium bromides. The influence of the hydrophobic chain length of alcohol and surfactant molecules on the Gibbs standard free energy of their adsorption at the water-air interface and their chemical potential of mixing were considered. It appeared that there is a linear dependence between these thermodynamic functions and the number of carbon atoms increased by 1 in the hydrocarbon chains of these compounds. This confirms clearly our conclusion that the behaviour of short-chain alcohols and classical surfactants at the water-air interface and in the bulk phase of aqueous solutions is similar. </p>

scholarly journals Study of the influence of the binary mixtures of fluorocarbon surfactants on the surface tension of water

2017 ◽  
Vol 72 (1) ◽  
pp. 111
Author(s):  
Anna Taraba ◽  
Katarzyna Szymczyk
Keyword(s):  
Surface Tension ◽  
Free Energy ◽  
Surface Area ◽  
Binary Mixtures ◽  
Intermolecular Interactions ◽  
Adsorption Process ◽  
Interfacial Area ◽  
Model Parameter ◽  
Air Interface ◽  
Monolayer Adsorption

Influence of the binary mixtures of fluorocarbon surfactants Zonyl FSO-100  (FSO100) and Zonyl FSN-100 (FSN100) on the surface tension of the water was studied. The effectiveness of adsorption process of the surfactant at the water-air interface was calculated from the obtained values of the surface tension of studied mixtures. Also the maximum surface area per molecule of surfactant in the interfacial area  and the free energy at the water-air interface  were determined. Moreover, the existence of synergetizm or antagonism effect, which reduces the surface tension of the water was examined. On the basis of the Rosen's model parameter the values of intermolecular interactions in the mixed monolayer adsorption were calculated.

scholarly journals Surface - Active and Complexforming Copolymers of Sodium 2-acrylamido-2-methylpropanesulfonate with Ethyleneglycol Vinyl Ether

2015 ◽  
Vol 15 (4) ◽  
pp. 313
Author(s):  
Y.M. Shaikhutdinov ◽  
S.Kh. Khussain ◽  
N.Zh. Seitkaliyeva ◽  
A.Zh. Zhenissova ◽  
Z.G. Akkulova
Keyword(s):  
Surface Tension ◽  
Free Energy ◽  
Ethylene Glycol ◽  
Vinyl Ether ◽  
Surface Activity ◽  
Water Solution ◽  
Molar Fraction ◽  
Standard Free Energy ◽  
Water Soluble ◽  
Interpolymer Complex

<p>A new water-soluble polyelectrolyte - the copolymer of sodium 2-acrylamido-2-methylpropanesulfonate and ethylene glycol vinyl ether has been synthesized by free-radical copolymerization in aqueous medium. Synthesis of the linear structure water-soluble copolymer of sodium 2-acrylamido-2-methylpropanesulfonate (Na-AMPS) and ethylene glycol vinyl ether (EGVE) has been confirmed by IR spectroscopy method, potentiometric titration and viscometer. The concentration behavior of the reduced viscosity of copolymer solutions that is typical for polyelectrolytes has been revealed. The reactivity ratios for the copolymerization of the monomers estimated by the Mayo–Lewis method have indicated lower reactivity of ethylenglycol vinyl ether in comparison with sodium 2-acrylamido-2-methylpropanesulfonate. Also it was shown the decrease of reaction’s relative rate with an increase of molar fraction of EGVE in the initial mixture of monomers. Adsorption at the air-water solution interface was studied by measure of surface tension (σ) in order to determine the surface properties of new copolymers of ethyleneglycol vinyl ethers – sodium 2-acrylamido-2-methylpropanesulfonate. It was shown that copolymers of sodium 2-acrylamido-2-methylpropanesulfonate and ethylenglycol vinyl ether have higher surface activity compared to sodium 2-acrylamido-2-methylpropanesulfonate homopolymer. The isotherm of copolymer’s surface tension based on equilibrium value of σ was constructed together with the isotherm of surface tension water solution poly- Na-AMPS. Based on isotherms the surface activity on Rebinder (G<sub>Re</sub>) for poly- Na-AMPS and copolymer Na-AMPS-EGVE was determined. The values of polymer’s standard free energy of adsorption (Δ<sub>ads</sub>G<sup>0</sup><sub>298</sub>) were calculated in order to identify the causes and mechanism of change in surface activity and adsorption. Results show that the gain in standard free energy adsorption in the transition from homopolymer to copolymer Na-AMPS-EGVE is about 4 kJ/base-mole. Interpolymer reaction of the Na-AMS–EGVE copolymer with poly- <em>N,N</em>-dimethyl-<em>N,N</em>-diallylammonium chloride (PMAAC) has been studied. Higher surface activity of mixtures of copolymer and PMAAC than of individual polyelectrolytes was discovered. This effect testified to the formation of interpolymer complex of the Na-AMS–EGVE copolymer with polycations due to electrostatic interactions.</p>

scholarly journals Adsorption of Polycomplexes at Solution/Air Interface

2017 ◽  
Vol 4 (4) ◽  
pp. 259
Author(s):  
E.M. Shaikhutdinov ◽  
K.Zh. Abdiyev ◽  
M.B. Zhursumbayeva ◽  
S.Kh. Khussain
Keyword(s):  
Surface Tension ◽  
Relaxation Time ◽  
Complex Formation ◽  
Surface Activity ◽  
Kinetic Data ◽  
Hydrophobic Interactions ◽  
Standard Free Energy ◽  
Free Energy Of Adsorption ◽  
Air Interface ◽  
Potentiometric Measurements

<p>The effect of complex formation of polyacids (polyacrylic (PAAc) and polymethacrylic (PMAAc)) with polyacrylamide (PAA) on their surface properties at solution/air interface has been studied by surface tension, electric conductivity and potentiometric measurements at 293±0.2 K. The relaxation time and surface activity of polycomplexes were calculated from kinetic data on the surface tension. It was found that during complex formation the relaxation time of a surface layer has a maximum and the surface activity of macromolecules is increased. Also the standard free energy of adsorption for PAA and polyacid-PAA polycomplexes were calculated. They are equal DadsG°<sub>293</sub> = - 19.1±0.1 kJ/base-mol. for PAA, DadsG°<sub>293</sub> = -21.2±0.1 kJ/basemol. for PMAAc-PAA polycomplex and DadsG°<sub>293</sub> = -23.0±0.1 kJ/base-mol. for PAAc-PAA polycomplex (calculation per base-mole of PAA monomer link). It is shown that the surface activity and ability to decrease of the water surface tension is less for PMAAc-PAA than for PAAc-PAA. Such anomalous behaviour of PMAAc-PAA polycomplex probably is caused by an excessive strengthening of inner- and intermolecular hydrophobic interactions in macromolecules of PMAAc- PAA polycomplexes due to the presence of α-methyl groups in PMAAc macromolecules. Because of the rebuilding of macromolecule segments of complex by polarity at the interface is becoming a difficult one.</p>

Adsorption of Liquids and Swelling of Wood. Part VI. Saturated Amounts and Some Thermodynamic Values of Adsorption

Holzforschung ◽  
2002 ◽  
Vol 56 (1) ◽  
pp. 91-97
Author(s):  
Kei Morisato ◽  
Yutaka Ishimaru ◽  
Hiroyuki Urakami
Keyword(s):  
Free Energy ◽  
Standard Free Energy ◽  
Molecular Size ◽  
Free Energy Change ◽  
Energy Change ◽  
Multilayer Adsorption ◽  
Monolayer Adsorption ◽  
Wood Part ◽  
Cohesive Interaction

Summary To understand the swelling phenomenon of wood in liquids,the saturated amount of adsorption of liquids onto wood and the standard free energy changes of the adsorption were determined. The saturated amount of adsorption obtained by regression for several liquids decreased with increasing molecular size of the solvents. The mechanism of wood swelling is discussed systematically taking all the liquids examined in previous experiments into account. Since methanol molecules require more energy for release from cohesive interactions within bulk liquids in the adsorption onto pre-swollen wood,the values of free energy change of adsorption for methanol were lower than the values for acetone,although the relative swelling with methanol was higher. These results suggest that although the cohesive interaction within the bulk liquids reduces adsorptivity,the phenomenon of wood swelling is influenced not only by monolayer adsorption but also by multilayer adsorption. Therefore,the cohesive interaction within the bulk liquids reduces adsorptivity but enhances the condensation which strongly influences the swelling of wood.

Undersaturated Hydrocarbon Reservoir Waterflooding: A simulation Approach to Performance Assessment

2021 ◽  
Author(s):  
Adekunle Tirimisiyu Adeniyi ◽  
Miracle Imwonsa Osatemple ◽  
Abdulwahab Giwa
Keyword(s):  
Oil Recovery ◽  
Net Present Value ◽  
Oil Production ◽  
Base Case ◽  
Present Value ◽  
Sweep Efficiency ◽  
Recovery Method ◽  
Solution Approach ◽  
Hydrocarbon Reservoir

Abstract There are a good numbers of brown hydrocarbon reservoirs, with a substantial amount of bypassed oil. These reservoirs are said to be brown, because a huge chunk of its recoverable oil have been produced. Since a significant number of prominent oil fields are matured and the number of new discoveries is declining, it is imperative to assess performances of waterflooding in such reservoirs; taking an undersaturated reservoir as a case study. It should be recalled that Waterflooding is widely accepted and used as a means of secondary oil recovery method, sometimes after depletion of primary energy sources. The effects of permeability distribution on flood performances is of concerns in this study. The presence of high permeability streaks could lead to an early water breakthrough at the producers, thus reducing the sweep efficiency in the field. A solution approach adopted in this study was reserve water injection. A reverse approach because, a producing well is converted to water injector while water injector well is converted to oil producing well. This optimization method was applied to a waterflood process carried out on a reservoir field developed by a two - spot recovery design in the Niger Delta area of Nigeria that is being used as a case study. Simulation runs were carried out with a commercial reservoir oil simulator. The result showed an increase in oil production with a significant reduction in water-cut. The Net Present Value, NPV, of the project was re-evaluated with present oil production. The results of the waterflood optimization revealed that an increase in the net present value of up to 20% and an increase in cumulative production of up to 27% from the base case was achieved. The cost of produced water treatment for re-injection and rated higher water pump had little impact on the overall project economy. Therefore, it can conclude that changes in well status in wells status in an heterogenous hydrocarbon reservoir will increase oil production.

The Combined Flooding of Dispersed Particle Gel and Surfactant for Conformance Control and EOR: From Experiment to Pilot Test

2021 ◽  
Author(s):  
Xia Yin ◽  
Tianyi Zhao ◽  
Jie Yi
Keyword(s):  
Oil Recovery ◽  
Formation Energy ◽  
High Salinity ◽  
Surfactant Solution ◽  
Pilot Test ◽  
Control Performance ◽  
Core Flooding ◽  
Displacement Efficiency ◽  
Conformance Control ◽  
And Performance

Abstract The water channeling and excess water production led to the decreasing formation energy in the oilfield. Therefore, the combined flooding with dispersed particle gel (DPG) and surfactant was conducted for conformance control and enhanced oil recovery in a high temperature (100-110°C) high salinity (&gt;2.1×105mg/L) channel reservoir of block X in Tahe oilfield. This paper reports the experimental results and pilot test for the combined flooding in a well group of Block X. In the experiment part, the interfacial tension, emulsifying capacity of the surfactant and the particle size during aging of DPG were measured, then, the conformance control and enhanced oil recovery performance of the combined flooding was evaluated by core flooding experiment. In the pilot test, the geological backgrounds and developing history of the block was introduced. Then, an integrated study of EOR and conformance control performance in the block X are analyzed by real-time monitoring and performance after treatment. In addition, the well selection criteria and flooding optimization were clarified. In this combined flooding, DPG is applied as in-depth conformance control agent to increase the sweep efficiency, and surfactant solution slug following is used for improve the displacement efficiency. The long term stability of DPG for 15 days ensures the efficiency of in-depth conformance control and its size can increase from its original 0.543μm to 35.5μm after aging for 7 days in the 2.17×105mg/L reservoir water and at 110°C. In the optimization, it is found that 0.35% NAC-1+ 0.25% NAC-2 surfactant solution with interfacial tension 3.2×10-2mN/m can form a relatively stable emulsion easily with the dehydrated crude oil. In the double core flooding, the conformance control performance is confirmed by the diversion of fluid after combined flooding and EOR increases by 21.3%. After exploitation of Block X for 14 years, the fast decreasing formation energy due to lack of large bottom water and water fingering resulted in a decreasing production rate and increasing watercut. After combined flooding in Y well group with 1 injector and 3 producers, the average dynamic liquid level, daily production, and tracing agent breakthrough time increased, while the watercut and infectivity index decreased. The distribution rate of injected fluid and real-time monitoring also assured the conformance control performance. The oil production of this well group was increased by over 3000 tons. Upon this throughout study of combined flooding from experiment to case study, adjusting the heterogeneity by DPG combined with increasing displacement efficiency of surfactant enhanced the oil recovery synergistically in this high salinity high temperature reservoir. The criteria for the selection and performance of combined flooding also provides practical experiences and principles for combined flooding.

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