scholarly journals Time Dependent Lyotropic Chromonic Textures in Microfluidic Confinements

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 35 ◽  
Author(s):  
Anshul Sharma ◽  
Irvine Lian Hao Ong ◽  
Anupam Sengupta

Nematic and columnar phases of lyotropic chromonic liquid crystals (LCLCs) have been long studied for their fundamental and applied prospects in material science and medical diagnostics. LCLC phases represent different self-assembled states of disc-shaped molecules, held together by noncovalent interactions that lead to highly sensitive concentration and temperature dependent properties. Yet, microscale insights into confined LCLCs, specifically in the context of confinement geometry and surface properties, are lacking. Here, we report the emergence of time dependent textures in static disodium cromoglycate (DSCG) solutions, confined in PDMS-based microfluidic devices. We use a combination of soft lithography, surface characterization, and polarized optical imaging to generate and analyze the confinement-induced LCLC textures and demonstrate that over time, herringbone and spherulite textures emerge due to spontaneous nematic (N) to columnar M-phase transition, propagating from the LCLC-PDMS interface into the LCLC bulk. By varying the confinement geometry, anchoring conditions, and the initial DSCG concentration, we can systematically tune the temporal dynamics of the N- to M-phase transition and textural behavior of the confined LCLC. Overall, the time taken to change from nematic to the characteristic M-phase textures decreased as the confinement aspect ratio (width/depth) increased. For a given aspect ratio, the transition to the M-phase was generally faster in degenerate planar confinements, relative to the transition in homeotropic confinements. Since the static molecular states register the initial conditions for LC flows, the time dependent textures reported here suggest that the surface and confinement effects—even under static conditions—could be central in understanding the flow behavior of LCLCs and the associated transport properties of this versatile material.


1990 ◽  
Vol 216 ◽  
pp. 71-91 ◽  
Author(s):  
Bryan Travis ◽  
Peter Olson ◽  
Gerald Schubert

The stability of two-dimensional thermal convection in an infinite-Prandtl-number fluid layer with zero-stress boundaries is investigated using numerical calculations in three-dimensional rectangles. At low Rayleigh numbers (Ra < 20000) calculations of the stability of two-dimensional rolls to cross-roll disturbances are in agreement with the predictions of Bolton & Busse for a fluid with a large but finite Prandtl number. Within the range 2 × 104 < Ra [les ] 5 × 105, steady rolls with basic wavenumber α > 2.22 (aspect ratio < 1.41) are stable solutions. Two-dimensional rolls with basic wavenumber α < 1.96 (aspect ratio > 1.6) are time dependent for Ra > 4 × 104. For every case in which the initial condition was a time-dependent large-aspect-ratio roll, two-dimensional convection was found to be unstable to three-dimensional convection. Time-dependent rolls are replaced by either bimodal or knot convection in cases where the horizontal dimensions of the rectangular box are less than twice the depth. The bimodal planforms are steady states for Ra [les ] 105, but one case at Ra = 5 × 105 exhibits time dependence in the form of pulsating knots. Calculations at Ra = 105 in larger domains resulted in fully three-dimensional cellular planforms. A steady-state square planform was obtained in a 2.4 × 2.4 × 1 rectangular box. started from random initial conditions. Calculations in a 3 × 3 × 1 box produced steady hexagonal cells when started from random initial conditions, and a rectangular planform when started from a two-dimensional roll. An hexagonal planform started in a 3.5 × 3.5 × 1 box at Ra = 105 exhibited oscillatory time dependence, including boundary-layer instabilities and pulsating plumes. Thus, the stable planform in three-dimensional convection is sensitive to the size of the rectangular domain and the initial conditions. The sensitivity of heat transfer to planform variations is less than 10%.



Author(s):  
Basant K. Jha ◽  
Dauda Gambo

Abstract Background Navier-Stokes and continuity equations are utilized to simulate fully developed laminar Dean flow with an oscillating time-dependent pressure gradient. These equations are solved analytically with the appropriate boundary and initial conditions in terms of Laplace domain and inverted to time domain using a numerical inversion technique known as Riemann-Sum Approximation (RSA). The flow is assumed to be triggered by the applied circumferential pressure gradient (azimuthal pressure gradient) and the oscillating time-dependent pressure gradient. The influence of the various flow parameters on the flow formation are depicted graphically. Comparisons with previously established result has been made as a limit case when the frequency of the oscillation is taken as 0 (ω = 0). Results It was revealed that maintaining the frequency of oscillation, the velocity and skin frictions can be made increasing functions of time. An increasing frequency of the oscillating time-dependent pressure gradient and relatively a small amount of time is desirable for a decreasing velocity and skin frictions. The fluid vorticity decreases with further distance towards the outer cylinder as time passes. Conclusion Findings confirm that increasing the frequency of oscillation weakens the fluid velocity and the drag on both walls of the cylinders.



Author(s):  
Matthew A. Smith ◽  
Randall M. Mathison ◽  
Michael G. Dunn

Heat transfer distributions are presented for a stationary three passage serpentine internal cooling channel for a range of engine representative Reynolds numbers. The spacing between the sidewalls of the serpentine passage is fixed and the aspect ratio (AR) is adjusted to 1:1, 1:2, and 1:6 by changing the distance between the top and bottom walls. Data are presented for aspect ratios of 1:1 and 1:6 for smooth passage walls and for aspect ratios of 1:1, 1:2, and 1:6 for passages with two surfaces turbulated. For the turbulated cases, turbulators skewed 45° to the flow are installed on the top and bottom walls. The square turbulators are arranged in an offset parallel configuration with a fixed rib pitch-to-height ratio (P/e) of 10 and a rib height-to-hydraulic diameter ratio (e/Dh) range of 0.100 to 0.058 for AR 1:1 to 1:6, respectively. The experiments span a Reynolds number range of 4,000 to 130,000 based on the passage hydraulic diameter. While this experiment utilizes a basic layout similar to previous research, it is the first to run an aspect ratio as large as 1:6, and it also pushes the Reynolds number to higher values than were previously available for the 1:2 aspect ratio. The results demonstrate that while the normalized Nusselt number for the AR 1:2 configuration changes linearly with Reynolds number up to 130,000, there is a significant change in flow behavior between Re = 25,000 and Re = 50,000 for the aspect ratio 1:6 case. This suggests that while it may be possible to interpolate between points for different flow conditions, each geometric configuration must be investigated independently. The results show the highest heat transfer and the greatest heat transfer enhancement are obtained with the AR 1:6 configuration due to greater secondary flow development for both the smooth and turbulated cases. This enhancement was particularly notable for the AR 1:6 case for Reynolds numbers at or above 50,000.



2017 ◽  
Vol 23 (5) ◽  
pp. 415-425 ◽  
Author(s):  
M Dianat ◽  
M Taghizadeh ◽  
F Shahidi ◽  
SMA Razavi

In this study, the effect of barley malt extract at two brix levels (74 and 79 °Bx) and three ratios of malt extract/honey (65:35, 70:30 and 75:25) on the flow behavior properties of honey–malt spread at three temperature levels (35 ℃, 45 ℃ and 55 ℃) was investigated. Time-dependent behavior data of the spread samples were appropriately fitted to the Weltman, first-order stress decay with a zero stress value and first-order stress decay with a non-zero stress value models. Also, the Power-law, Herschel–Bulkley, Casson and Bingham models were used for curve fitting the time-independent behavior data. Regarding the R2 and root mean square error coefficients, the first-order stress decay with a non-zero stress value and Herschel–Bulkley models were selected as the suitable models to describe the flow behavior of samples. The results for time-dependent properties showed that spread samples exhibit a thixotropic behaviour, as the viscosity for all samples decreased with increase in shearing time at a constant shear rate of 50 s−1.



2008 ◽  
Vol 603 ◽  
pp. 63-100 ◽  
Author(s):  
G. SUBRAMANIAN ◽  
DONALD L. KOCH

A theoretical framework is developed to describe, in the limit of small but finite Re, the evolution of dilute clusters of sedimenting particles. Here, Re =aU/ν is the particle Reynolds number, where a is the radius of the spherical particle, U its settling velocity, and ν the kinematic viscosity of the suspending fluid. The theory assumes the disturbance velocity field at sufficiently large distances from a sedimenting particle, even at small Re, to possess the familiar source--sink character; that is, the momentum defect brought in via a narrow wake behind the particle is convected radially outwards in the remaining directions. It is then argued that for spherical clusters with sufficiently many particles, specifically with N much greater than O(R0U/ν), the initial evolution is strongly influenced by wake-mediated interactions; here, N is the total number of particles, and R0 is the initial cluster radius. As a result, the cluster first evolves into a nearly planar configuration with an asymptotically small aspect ratio of O(R0U/N ν), the plane of the cluster being perpendicular to the direction of gravity; subsequent expansion occurs with an unchanged aspect ratio. For relatively sparse clusters with N smaller than O(R0U/ν), the probability of wake interactions remains negligible, and the cluster expands while retaining its spherical shape. The long-time expansion in the former case, and that for all times in the latter case, is driven by disturbance velocity fields produced by the particles outside their wakes. The resulting interactions between particles are therefore mutually repulsive with forces that obey an inverse-square law. The analysis presented describes cluster evolution in this regime. A continuum representation is adopted with the clusters being characterized by a number density field (n(r, t)), and a corresponding induced velocity field (u (r, t)) arising on account of interactions. For both planar axisymmetric clusters and spherical clusters with radial symmetry, the evolution equation admits a similarity solution; either cluster expands self-similarly for long times. The number density profiles at different times are functions of a similarity variable η = (r/t1/3), r being the radial distance away from the cluster centre, and t the time. The radius of the expanding cluster is found to be of the form Rcl (t) = A (ν a)1/3N1/3t1/3, where the constant of proportionality, A, is determined from an analytical solution of the evolution equation; one finds A = 1.743 and 1.651 for planar and spherical clusters, respectively. The number density profile in a planar axisymmetric cluster is also obtained numerically as a solution of the initial value problem for a canonical (Gaussian) initial condition. The numerical results compare well with theoretical predictions, and demonstrate the asymptotic stability of the similarity solution in two dimensions for long times, at least for axisymmetric initial conditions.



2000 ◽  
Author(s):  
Bixia Li ◽  
Timothy L. Norman

Abstract In this study, rat femurs were used to test the diffusion and mechanical transport properties of a fluroscein stain tracer in microvessels of bone. Fluroscein was used as a tracer to visualize the fluid flow behavior using confocal microscopy. It was found that stain transport occurs due to diffusion under static conditions and due to mechanical loading. The transport increased with cyclic load level and frequency. Our results also show that stain transport at the canaliculi level occurs rapidly in rat bone.



2005 ◽  
Vol 16 (11) ◽  
pp. 1631-1670 ◽  
Author(s):  
MUKTISH ACHARYYA

The thermodynamical behaviors of ferromagnetic systems in equilibrium are well studied. However, the ferromagnetic systems far from equilibrium became an interesting field of research in last few decades. Recent exploration of ferromagnetic systems in the presence of a steady magnetic field are also studied by using standard tools of equilibrium statistical physics. The ferromagnet in the presence of time-dependent magnetic field, shows various interesting phenomena. An usual response of a ferromagnet in the presence of a sinusoidally oscillating magnetic field is the hysteresis. Apart from this hysteretic response, the nonequilibrium dynamic phase transition is also a very interesting phenomenon. In this chapter, the nonequilibrium dynamic phase transitions of the model ferromagnetic systems in presence of time-dependent magnetic field are discussed. For this kind of nonequilibrium phase transition, one cannot employ the standard techniques of equilibrium statistical mechanics. The recent developments in this direction are mainly based on numerical simulation (Monte Carlo). The Monte Carlo simulation of kinetic Ising model, in presence of sinusoidally oscillating (in time but uniform over space) magnetic field, is extensively performed to study the nonequilibrium dynamic phase transition. The temperature variations of dynamic order parameter, dynamic specific heat, dynamic relaxation time etc. near the transition point are discussed. The appearance and behaviors of a dynamic length scale and a dynamic time scale near the transition point are also discussed. All these studies indicate that this proposed dynamic transition is a nonequilibrium thermodynamic phase transition. The disorder (quenched) induced zero temperature (athermal) dynamic transition is studied in random field Ising ferromagnet. The dynamic transition in the Heisenberg ferromagnet is also studied. The nature of this transition in the Heisenberg ferromagnet depends on the anisotropy and the polarisation of the applied time varying magnetic field. The anisotropic Heisenberg ferromagnet in the presence of elliptically polarised magnetic field shows multiple dynamic transitions. This multiple dynamic transitions in anisotropic Heisenberg ferromagnet are discussed here. Recent experimental evidences of dynamic transitions are also discussed very briefly.



1964 ◽  
Vol 4 (01) ◽  
pp. 49-55 ◽  
Author(s):  
Pietro Raimondi ◽  
Michael A. Torcaso

Abstract The distribution of the oil phase in Berea sandstone resulting from increasing and decreasing the water saturation by imbibition was investigated Three types of distribution were recognized: trapped, normal and lagging. The amount of oil in each of these distributions was determined as a function of saturation by carrying out a miscible displacement in the oil phase under steady-state conditions of saturation. These conditions were maintained by flowing water and oil simultaneously in given ratios and by using a displacing solvent having essentially the same density and viscosity as the oil.A correlation shows the amount of trapped oil at any saturation to be directly proportional to the conventional residual oil saturation Sir The factor of proportionality is related to the fractional permeability to the water phase. Part of the oil which was not trapped was displaced in a piston- like manner (normal part) and part was eluted gradually (lagging part). The observed phenomena are more than of mere academic importance. Oil which is trapped may well provide the fuel essential for forward combustion and thus be beneficial. On the contrary, in tertiary recovery operations, it is this trapped oil which seems to make current techniques uneconomic. Introduction A typical oilfield may initially contain connate water and oil. After a period of primary production water often enters the field either from surrounding aquifers or from surface injection. During primary production evolution and establishment of a free gas saturation usually occurs. The effect and importance of this third phase is fully recognized. However, this investigation is limited to a two- phase system, one wetting phase (water) and one non-wetting phase (oil). The increase in water content of a water-wet system is termed imbibition. In a relative permeability-saturation diagram such as the one shown in Fig. 1, the initial conditions of the field would he represented by a point below a water saturation of about 35 per cent, i.e., where the imbibition and the drainage curves to the non-wetting phase nearly coincide. When water enters the field the relative permeability to oil decreases along the imbibition curve. At watered-out conditions the relative permeability to the oil becomes zero. At this point a considerable amount of oil, called residual oil, (about 35 per cent in Fig. 1) remains unrecovered. Any attempt to produce this oil will require that its saturation be increased. In Fig. 1 this would mean retracing the imbibition curve upwards. In addition, processes like alcohol and fire flooding, which can be employed at any stage of production, involve the complete displacement of connate water and an increase, or imbibition, of water saturation ahead of the displacing front. Thus, in several types of oil production it is the imbibition-relative permeability curve which rules the flow behavior. For this reason a knowledge of the distribution of the non-wetting phase, as obtained through imbibition, whether "coming down" or "going up" on the imbibition curve, is important. SPEJ P. 49^



Mechanika ◽  
2021 ◽  
Vol 27 (3) ◽  
pp. 201-208
Author(s):  
Mustafa FEKHAR ◽  
Rachid SACI ◽  
Renée GATIGNOL

Thermal buoyancy, induced by injection or by differential heating of a tiny rod is explored to control breakdown in the core of a helical flow driven by the lid rotation of a cylinder. Three main parameters are required to characterize numerically the flow behavior; namely, the rotational Reynolds number Re, the cavity aspect ratio and the Richardson number Ri. Warm injection/rod, Ri > 0, is shown to prevent on-axis flow stagnation while breakdown enhancement is evidenced when Ri < 0. Results revealed that a bubble vortex evolves into a ring type structure which may remain robust, as observed in prior related experiments or, in contrast, disappear over a given range of parameters (Λh, Re, Ri > 0). Besides, the emergence of such a toroidal mode was not found to occur under thermal stratification induced by a differentially heated rod. Moreover, three state diagrams were established which provide detailed flow characteristics under the distinct and combined effects of buoyancy strength, viscous effects and cavity aspect ratio.



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