scholarly journals Energy Use of Flux Salt Recovery Using Bipolar Membrane Electrodialysis for a CO2 Mineralisation Process

Entropy ◽  
2019 ◽  
Vol 21 (4) ◽  
pp. 395 ◽  
Author(s):  
Koivisto ◽  
Zevenhoven

Mineral carbonation routes have been extensively studied for almost two decades at Åbo Akademi University, focusing on the extraction of magnesium from magnesium silicates using ammonium sulfate (AS) and/or ammonium bisulfate (ABS) flux salt followed by carbonation. There is, however, a need for proper recovery and recirculation of chemicals involved. This study focused on the separation of AS, ABS and aqueous ammonia using different setups of bipolar membrane electrodialysis using both synthetic and rock-derived solutions. Bipolar membranes offer the possibility to split water, which in turn makes it possible to regenerate chemicals like acids and bases needed in mineral carbonation without excess gas formation. Tests were run in batch, continuous, and recirculating mode, and exergy (electricity) input during the tests was calculated. The results show that separation of ions was achieved, even if the solutions obtained were still too weak for use in the downstream process to control pH. Energy demand for separating 1 kg of NH4+ varied in the range 1.7, 3.4, 302 and 340 MJ/kg NH4+, depending on setup chosen. More work must hence be done in order to make the separation more efficient, such as narrowing the cell width.

2021 ◽  
Author(s):  
Éva Hülber-Beyer ◽  
Katalin Bélafi-Bakó ◽  
Nándor Nemestóthy

AbstractOrganic acids, e.g, citric acid, fumaric acid, lactic acid, malic acid, pyruvic acid and succinic acid, have important role in the food industry and are potential raw materials for the sustainable chemical industry. Their fermentative production based on renewable raw materials requires innovatively designed downstream processing to maintain low environmental impact and resource efficiency throughout the production process. The application of bipolar membranes offers clean and effective way to generate hydrogen ions required for free acid production from its salt. The water dissociation reaction inside the bipolar membrane triggered by electric field plays key role in providing hydrogen ion for the replacement of the cations in organic acid salts. Combined with monopolar ion-exchange membranes in a bipolar membrane electrodialysis process, material flow can be separated beside the product stream into additional reusable streams, thus minimizing the waste generation. This paper focuses on bipolar membrane electrodialysis applied for organic acid recovery from fermentation broth.


Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 575
Author(s):  
Alonso González ◽  
Mario Grágeda ◽  
Adrián Quispe ◽  
Svetlana Ushak ◽  
Philippe Sistat ◽  
...  

The objective of this work was to evaluate obtaining LiOH directly from brines with high LiCl concentrations using bipolar membrane electrodialysis by the analysis of Li+ ion transport phenomena. For this purpose, Neosepta BP and Fumasep FBM bipolar membranes were characterized by linear sweep voltammetry, and the Li+ transport number in cation-exchange membranes was determined. In addition, a laboratory-scale reactor was designed, constructed, and tested to develop experimental LiOH production tests. The selected LiCl concentration range, based on productive process concentrations for Salar de Atacama (Chile), was between 14 and 34 wt%. Concentration and current density effects on LiOH production, current efficiency, and specific electricity consumption were evaluated. The highest current efficiency obtained was 0.77 at initial concentrations of LiOH 0.5 wt% and LiCl 14 wt%. On the other hand, a concentrated LiOH solution (between 3.34 wt% and 4.35 wt%, with a solution purity between 96.0% and 95.4%, respectively) was obtained. The results of this work show the feasibility of LiOH production from concentrated brines by means of bipolar membrane electrodialysis, bringing the implementation of this technology closer to LiOH production on a larger scale. Moreover, being an electrochemical process, this could be driven by Solar PV, taking advantage of the high solar radiation conditions in the Atacama Desert in Chile.


2021 ◽  
Vol 11 (9) ◽  
pp. 3972
Author(s):  
Azin Velashjerdi Farahani ◽  
Juha Jokisalo ◽  
Natalia Korhonen ◽  
Kirsti Jylhä ◽  
Kimmo Ruosteenoja ◽  
...  

The global average air temperature is increasing as a manifestation of climate change and more intense and frequent heatwaves are expected to be associated with this rise worldwide, including northern Europe. Summertime indoor conditions in residential buildings and the health of occupants are influenced by climate change, particularly if no mechanical cooling is used. The energy use of buildings contributes to climate change through greenhouse gas emissions. It is, therefore, necessary to analyze the effects of climate change on the overheating risk and energy demand of residential buildings and to assess the efficiency of various measures to alleviate the overheating. In this study, simulations of dynamic energy and indoor conditions in a new and an old apartment building are performed using two climate scenarios for southern Finland, one for average and the other for extreme weather conditions in 2050. The evaluated measures against overheating included orientations, blinds, site shading, window properties, openable windows, the split cooling unit, and the ventilation cooling and ventilation boost. In both buildings, the overheating risk is high in the current and projected future average climate and, in particular, during exceptionally hot summers. The indoor conditions are occasionally even injurious for the health of occupants. The openable windows and ventilation cooling with ventilation boost were effective in improving the indoor conditions, during both current and future average and extreme weather conditions. However, the split cooling unit installed in the living room was the only studied solution able to completely prevent overheating in all the spaces with a fairly small amount of extra energy usage.


Desalination ◽  
2017 ◽  
Vol 424 ◽  
pp. 37-44 ◽  
Author(s):  
Samuel Bunani ◽  
Kazuharu Yoshizuka ◽  
Syouhei Nishihama ◽  
Müşerref Arda ◽  
Nalan Kabay

2014 ◽  
Vol 452 ◽  
pp. 54-61 ◽  
Author(s):  
Meng Wang ◽  
Kai-kai Wang ◽  
Yu-xiang Jia ◽  
Qing-chun Ren

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Stuti Haldar ◽  
Gautam Sharma

Purpose The purpose of this study is to investigate the impacts of urbanization on per capita energy consumption and emissions in India. Design/methodology/approach The present study analyses the effects of urbanization on energy consumption patterns by using the Stochastic Impacts by Regression on Population, Affluence and Technology in India. Time series data from the period of 1960 to 2015 has been considered for the analysis. Variables including Population, GDP per capita, Energy intensity, share of industry in GDP, share of Services in GDP, total energy use and urbanization from World Bank data sources have been used for investigating the relationship between urbanization, affluence and energy use. Findings Energy demand is positively related to affluence (economic growth). Further the results of the analysis also suggest that, as urbanization, GDP and population are bound to increase in the future, consequently resulting in increased carbon dioxide emissions caused by increased energy demand and consumption. Thus, reducing the energy intensity is key to energy security and lower carbon dioxide emissions for India. Research limitations/implications The study will have important policy implications for India’s energy sector transition toward non- conventional, clean energy sources in the wake of growing share of its population residing in urban spaces. Originality/value There are limited number of studies considering the impacts of population density on per capita energy use. So this study also contributes methodologically by establishing per capita energy use as a function of population density and technology (i.e. growth rates of industrial and service sector).


Energies ◽  
2018 ◽  
Vol 11 (7) ◽  
pp. 1869 ◽  
Author(s):  
Alexandre Lucas ◽  
Giuseppe Prettico ◽  
Marco Flammini ◽  
Evangelos Kotsakis ◽  
Gianluca Fulli ◽  
...  

Electric vehicle (EV) charging infrastructure rollout is well under way in several power systems, namely North America, Japan, Europe, and China. In order to support EV charging infrastructures design and operation, little attempt has been made to develop indicator-based methods characterising such networks across different regions. This study defines an assessment methodology, composed by eight indicators, allowing a comparison among EV public charging infrastructures. The proposed indicators capture the following: energy demand from EVs, energy use intensity, charger’s intensity distribution, the use time ratios, energy use ratios, the nearest neighbour distance between chargers and availability, the total service ratio, and the carbon intensity as an environmental impact indicator. We apply the methodology to a dataset from ElaadNL, a reference smart charging provider in The Netherlands, using open source geographic information system (GIS) and R software. The dataset reveals higher energy intensity in six urban areas and that 50% of energy supplied comes from 19.6% of chargers. Correlations of spatial density are strong and nearest neighbouring distances range from 1101 to 9462 m. Use time and energy use ratios are 11.21% and 3.56%. The average carbon intensity is 4.44 gCO2eq/MJ. Finally, the indicators are used to assess the impact of relevant public policies on the EV charging infrastructure use and roll-out.


Environments ◽  
2018 ◽  
Vol 5 (11) ◽  
pp. 119 ◽  
Author(s):  
Alessia Arteconi ◽  
Luca Del Zotto ◽  
Roberto Tascioni ◽  
Khamid Mahkamov ◽  
Chris Underwood ◽  
...  

In this paper, the smart management of buildings energy use by means of an innovative renewable micro-cogeneration system is investigated. The system consists of a concentrated linear Fresnel reflectors solar field coupled with a phase change material thermal energy storage tank and a 2 kWe/18 kWth organic Rankine cycle (ORC) system. The microsolar ORC was designed to supply both electricity and thermal energy demand to residential dwellings to reduce their primary energy use. In this analysis, the achievable energy and operational cost savings through the proposed plant with respect to traditional technologies (i.e., condensing boilers and electricity grid) were assessed by means of simulations. The influence of the climate and latitude of the installation was taken into account to assess the performance and the potential of such system across Europe and specifically in Spain, Italy, France, Germany, U.K., and Sweden. Results show that the proposed plant can satisfy about 80% of the overall energy demand of a 100 m2 dwelling in southern Europe, while the energy demand coverage drops to 34% in the worst scenario in northern Europe. The corresponding operational cost savings amount to 87% for a dwelling in the south and at 33% for one in the north.


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