scholarly journals Analysis of Entropy Production in Structured Chemical Reactors: Optimization for Catalytic Combustion of Air Pollutants

Entropy ◽  
2020 ◽  
Vol 22 (9) ◽  
pp. 1017 ◽  
Author(s):  
Mateusz Korpyś ◽  
Anna Gancarczyk ◽  
Marzena Iwaniszyn ◽  
Katarzyna Sindera ◽  
Przemysław J. Jodłowski ◽  
...  

Optimization of structured reactors is not without some difficulties due to highly random economic issues. In this study, an entropic approach to optimization is proposed. The model of entropy production in a structured catalytic reactor is introduced and discussed. Entropy production due to flow friction, heat and mass transfer and chemical reaction is derived and referred to the process yield. The entropic optimization criterion is applied for the case of catalytic combustion of methane. Several variants of catalytic supports are considered including wire gauzes, classic (long-channel) and short-channel monoliths, packed bed and solid foam. The proposed entropic criterion may indicate technically rational solutions of a reactor process that is as close as possible to the equilibrium, taking into account all the process phenomena such as heat and mass transfer, flow friction and chemical reaction.


2007 ◽  
Vol 12 (2) ◽  
pp. 157-180 ◽  
Author(s):  
O. Anwar Bég ◽  
R. Bhargava ◽  
S. Rawat ◽  
H. S. Takhar ◽  
Tasweer A. Bég

In the present paper we examine the steady double-diffusive free convective heat and mass transfer of a chemically-reacting micropolar fluid flowing through a Darcian porous regime adjacent to a vertical stretching plane. Viscous dissipation effects are included in the energy equation. Assuming incompressible, micro-isotropic fluid behaviour the transport equations are formulated in a two-dimensional coordinate system (x, y) using boundary-layer theory. The influence of the bulk porous medium retardation is modeled as a drag force term in the translational momentum equation. Transformations render the conservation equations into dimensionless form in terms of a single independent variable, η, transverse to the stretching surface. A simplified first order homogenous reaction model is also used to simulate chemical reaction in the flow. Using the finite element method solutions are generated for the angular velocity field, translational velocity field, temperature and species transfer fields. The effects of buoyancy, porous drag and chemical reaction rate are studied. Chemical reaction is shown to decelerate the flow and also micro-rotation values, in particular near the wall. Mass transfer is also decreased with increasing chemical reaction rate. Increasing Darcy number is shown to accelerate the flow. Applications of the study include cooling of electronic circuits, packed-bed chemical reactors and also the near field flows in radioactive waste geo-repositories.



2012 ◽  
Vol 3 (2) ◽  
pp. 101-105 ◽  
Author(s):  
C. K. Kirubhashankar C. K. Kirubhashankar ◽  
◽  
S.Ganesh S.Ganesh




2019 ◽  
Vol 50 (11) ◽  
pp. 1061-1080 ◽  
Author(s):  
Ambreen Afsar Khan ◽  
Syeda Rida Bukhari ◽  
Marin Marin ◽  
Rahmat Ellahi


Author(s):  
J. Buggaramulu ◽  
M. Venkatakrishna ◽  
Y. Harikrishna

The objective of this paper is to analyze an unsteady MHD free convective heat and mass transfer boundary flow past a semi-infinite vertical porous plate immersed in a porous medium with radiation and chemical reaction. The governing equations of the flow field are solved numerical a two term perturbation method. The effects of the various parameters on the velocity, temperature and concentration profiles are presented graphically and values of skin-frication coefficient, Nusselt number and Sherwood number for various values of physical parameters are presented through tables.





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