scholarly journals Ammonia Emissions in SI Engines Fueled with LPG

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 691
Author(s):  
Andrzej Żółtowski ◽  
Wojciech Gis

Ammonia is a toxic exhaust component emitted from internal combustion engines. Both pure ammonia and the products of its reaction with nitrogen and sulfur compounds, being the source of particulate matter (PM) emissions, are dangerous for human health and life. The aim of the article was to demonstrate that NH3 can be produced in exhaust gas after-treatment systems of spark-ignition (SI) engines used in light-duty vehicles. In some cases, NH3 occurs in high enough concentrations that can be harmful and dangerous. It would be reasonable to collect research data regarding this problem and consider the advisability of limiting these pollutant emissions in future regulations. The article presents the results of the spark-ignition engine testing on an engine test bench and discusses the impact of the air–fuel ratio regulation and some engine operating parameters on the concentration of NH3. It has been proven that in certain engine operating conditions and a combination of circumstances like the three-way catalytic reactor (TWC) temperature and periodic enrichment of the air–fuel mixture may lead to excessive NH3 emissions resulting from the NO conversion in the catalytic reactor. This is a clear disadvantage due to the lack of limitation of these pollutant emissions by the relevant type-approval regulations. This article should be a contribution to discussion among emissions researchers whether future emission regulations (e.g., Euro 7 or Euro VII) should include a provision to reduce NH3 emissions from all vehicles.

2021 ◽  
Vol 11 (13) ◽  
pp. 6035
Author(s):  
Luigi Teodosio ◽  
Luca Marchitto ◽  
Cinzia Tornatore ◽  
Fabio Bozza ◽  
Gerardo Valentino

Combustion stability, engine efficiency and emissions in a multi-cylinder spark-ignition internal combustion engines can be improved through the advanced control and optimization of individual cylinder operation. In this work, experimental and numerical analyses were carried out on a twin-cylinder turbocharged port fuel injection (PFI) spark-ignition engine to evaluate the influence of cylinder-by-cylinder variation on performance and pollutant emissions. In a first stage, experimental tests are performed on the engine at different speed/load points and exhaust gas recirculation (EGR) rates, covering operating conditions typical of Worldwide harmonized Light-duty vehicles Test Cycle (WLTC). Measurements highlighted relevant differences in combustion evolution between cylinders, mainly due to non-uniform effective in-cylinder air/fuel ratio. Experimental data are utilized to validate a one-dimensional (1D) engine model, enhanced with user-defined sub-models of turbulence, combustion, heat transfer and noxious emissions. The model shows a satisfactory accuracy in reproducing the combustion evolution in each cylinder and the temperature of exhaust gases at turbine inlet. The pollutant species (HC, CO and NOx) predicted by the model show a good agreement with the ones measured at engine exhaust. Furthermore, the impact of cylinder-by-cylinder variation on gaseous emissions is also satisfactorily reproduced. The novel contribution of present work mainly consists in the extended numerical/experimental analysis on the effects of cylinder-by-cylinder variation on performance and emissions of spark-ignition engines. The proposed numerical methodology represents a valuable tool to support the engine design and calibration, with the aim to improve both performance and emissions.


Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 4034
Author(s):  
Paolo Iodice ◽  
Massimo Cardone

Among the alternative fuels existing for spark-ignition engines, ethanol is considered worldwide as an important renewable fuel when mixed with pure gasoline because of its favorable physicochemical properties. An in-depth and updated investigation on the issue of CO and HC engine out emissions related to use of ethanol/gasoline fuels in spark-ignition engines is therefore necessary. Starting from our experimental studies on engine out emissions of a last generation spark-ignition engine fueled with ethanol/gasoline fuels, the aim of this new investigation is to offer a complete literature review on the present state of ethanol combustion in last generation spark-ignition engines under real working conditions to clarify the possible change in CO and HC emissions. In the first section of this paper, a comparison between physicochemical properties of ethanol and gasoline is examined to assess the practicability of using ethanol as an alternative fuel for spark-ignition engines and to investigate the effect on engine out emissions and combustion efficiency. In the next section, this article focuses on the impact of ethanol/gasoline fuels on CO and HC formation. Many studies related to combustion characteristics and exhaust emissions in spark-ignition engines fueled with ethanol/gasoline fuels are thus discussed in detail. Most of these experimental investigations conclude that the addition of ethanol with gasoline fuel mixtures can really decrease the CO and HC exhaust emissions of last generation spark-ignition engines in several operating conditions.


Author(s):  
Nicolas Iafrate ◽  
Anthony Robert ◽  
Jean-Baptiste Michel ◽  
Olivier Colin ◽  
Benedicte Cuenot ◽  
...  

Downsized spark ignition engines coupled with a direct injection strategy are more and more attractive for car manufacturers in order to reduce pollutant emissions and increase efficiency. However, the combustion process may be affected by local heterogeneities caused by the interaction between the spray and turbulence. The aim for car manufacturers of such engine strategy is to create, for mid-to-high speeds and mid-up-high loads, a mixture which is as homogeneous as possible. However, although injection occurs during the intake phase, which favors homogeneous mixing, local heterogeneities of the equivalence ratio are still observed at the ignition time. The analysis of the mixture preparation is difficult to perform experimentally because of limited optical accesses. In this context, numerical simulation, and in particular Large Eddy Simulation (LES) are complementary tools for the understanding and analysis of unsteady phenomena. The paper presents the LES study of the impact of direct injection on the mixture preparation and combustion in a spark ignition engine. Numerical simulations are validated by comparing LES results with experimental data previously obtained at IFPEN. Two main analyses are performed. The first one focuses on the fuel mixing and the second one concerns the effect of the liquid phase on the combustion process. To highlight these phenomena, simulations with and without liquid injection are performed and compared.


Author(s):  
Emiliano Pipitone ◽  
Salvatore Caltabellotta

Abstract In-cylinder expansion of internal combustion engines based on Diesel or Otto cycles cannot be completely brought down to ambient pressure, causing a 20% theoretical energy loss. Several systems have been implemented to recover and use this energy such as turbocharging, turbo-mechanical and turbo-electrical compounding, or the implementation of Miller Cycles. In all these cases however, the amount of energy recovered is limited allowing the engine to reach an overall efficiency incremental improvement between 4% and 9%. Implementing an adequately designed expander-generator unit could efficiently recover the unexpanded exhaust gas energy and improve efficiency. In this work, the application of the expander-generator unit to a hybrid propulsion vehicle is considered, where the onboard energy storage receives power produced by an expander-generator, which could hence be employed for vehicle propulsion through an electric drivetrain. Starting from these considerations, a simple but effective modelling approach is used to evaluate the energetic potential of a spark-ignition engine electrically supercharged and equipped with an exhaust gas expander connected to an electric generator. The overall efficiency was compared to a reference turbocharged engine within a hybrid vehicle architecture. It was found that, if adequately recovered, the unexpanded gas energy could reduce engine fuel consumption and related pollutant emissions by 4% to 12%, depending on overall power output.


Energies ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1566 ◽  
Author(s):  
S.D. Martinez-Boggio ◽  
S.S. Merola ◽  
P. Teixeira Lacava ◽  
A. Irimescu ◽  
P.L. Curto-Risso

To mitigate the increasing concentration of carbon dioxide in the atmosphere, energy production processes must change from fossil to renewable resources. Bioenergy utilization from agricultural residues can be a step towards achieving this goal. Syngas (fuel obtained from biomass gasification) has been proved to have the potential of replacing fossil fuels in stationary internal combustion engines (ICEs). The processes associated with switching from traditional fuels to alternatives have always led to intense research efforts in order to have a broad understanding of the behavior of the engine in all operating conditions. In particular, attention needs to be focused on fuels containing relatively high concentrations of hydrogen, due to its faster propagation speed with respect to traditional fossil energy sources. Therefore, a combustion study was performed in a research optical SI engine, for a comparison between a well-established fuel such as methane (the main component of natural gas) and syngas. The main goal of this work is to study the effect of inert gases in the fuel mixture and that of air dilution during lean fuelling. Thus, two pure syngas blends (mixtures of CO and H2) and their respective diluted mixtures (CO and H2 with 50vol% of inert gases, CO2 and N2) were tested in several air-fuel ratios (stoichiometric to lean burn conditions). Initially, the combustion process was studied in detail by traditional thermodynamic analysis and then optical diagnostics were applied thanks to the optical access through the piston crown. Specifically, images were taken in the UV-visible spectrum of the entire cycle to follow the propagation of the flame front. The results show that hydrogen promotes flame propagation and reduces its distortion, as well as resulting in flames evolving closer to the spark plug. All syngas blends show a stable combustion process, even in conditions of high air and fuel dilution. In the leanest case, real syngas mixtures present a decrease in terms of performance due to significant reduction in volumetric efficiency. However, this condition strongly decreases pollutant emissions, with nitrogen oxide (NOx) concentrations almost negligible.


Author(s):  
Xin Wang ◽  
Amir Khameneian ◽  
Paul Dice ◽  
Bo Chen ◽  
Mahdi Shahbakhti ◽  
...  

Abstract Combustion phasing, which can be defined as the crank angle of fifty percent mass fraction burned (CA50), is one of the most important parameters affecting engine efficiency, torque output, and emissions. In homogeneous spark-ignition (SI) engines, ignition timing control algorithms are typically map-based with several multipliers, which requires significant calibration efforts. This work presents a framework of model-based ignition timing prediction using a computationally efficient control-oriented combustion model for the purpose of real-time combustion phasing control. Burn duration from ignition timing to CA50 (ΔθIGN-CA50) on an individual cylinder cycle-by-cycle basis is predicted by the combustion model developed in this work. The model is based on the physics of turbulent flame propagation in SI engines and contains the most important control parameters, including ignition timing, variable valve timing, air-fuel ratio, and engine load mostly affected by combination of the throttle opening position and the previous three parameters. With 64 test points used for model calibration, the developed combustion model is shown to cover wide engine operating conditions, thereby significantly reducing the calibration effort. A Root Mean Square Error (RMSE) of 1.7 Crank Angle Degrees (CAD) and correlation coefficient (R2) of 0.95 illustrates the accuracy of the calibrated model. On-road vehicle testing data is used to evaluate the performance of the developed model-based burn duration and ignition timing algorithm. When comparing the model predicted burn duration and ignition timing with experimental data, 83% of the prediction error falls within ±3 CAD.


Author(s):  
Lorenzo Gasbarro ◽  
Jinlong Liu ◽  
Christopher Ulishney ◽  
Cosmin E. Dumitrescu ◽  
Luca Ambrogi ◽  
...  

Abstract Investigations using laboratory test benches are the most common way to find the technological solutions that will increase the efficiency of internal combustion engines and curtail their emissions. In addition, the collected experimental data are used by the CFD community to develop engine models that reduce the time-to-market. This paper describes the steps made to increase the reliability of engine experiments performed in a heavy-duty natural-gas spark-ignition engine test-cell such as the design of the control and data acquisition system based on Modbus TCP communication protocol. Specifically, new sensors and a new dynamometer controller were installed. The operation of the improved test bench was investigated at several operating conditions, with data obtained at both high- and low-sampling rates. The results indicated a stable test bench operation.


2019 ◽  
pp. 146808741985910 ◽  
Author(s):  
Guillermo Rubio-Gómez ◽  
Lis Corral-Gómez ◽  
David Rodriguez-Rosa ◽  
Fausto A Sánchez-Cruz ◽  
Simón Martínez-Martínez

In the last few years, increasing concern about the harmful effects of the use of fossil fuels in internal combustion engines has been observed. In addition, the limited availability of crude oil has driven the interest in alternative fuels, especially biofuels. In the context of spark ignition engines, bioalcohols are of great interest owing to their similarities and blend capacities with gasoline. Methanol and ethanol have been widely used, mainly due to their knocking resistance. Another alcohol of great interest is butanol, thanks to its potential of being produced as biofuel and its heat value closer to gasoline. In this study, a comparative study of gasoline–alcohol blend combustion, with up to 20% volume, with neat gasoline has been carried out. A single-cylinder, variable compression ratio, Cooperative Fuel Research-type spark ignition engine has been employed. The comparison is made in terms of fuel conversion efficiency and flame development angle. Relevant information related to the impact in the combustion process of the use of the three main alcohols used in blends with gasoline has been obtained.


2019 ◽  
Vol 179 (4) ◽  
pp. 86-92
Author(s):  
Mieczysław DZIUBIŃSKI ◽  
Ewa SIEMIONEK ◽  
Artur DROZD ◽  
Michał ŚCIRKA ◽  
Adam KISZCZAK ◽  
...  

The article discusses the impact of ignition system damage on the emission of toxic subcategories in a spark-ignition internal combustion engine. The aim of the work was to develop an analytical model of ignition system diagnostics, test performance and comparative analysis of the results of simulations and experiments. The model developed allows to analyse the basic parameters of the ignition system affecting the content of toxic substances in the exhaust. Experimental tests were carried out using the MAHA MGT5 exhaust gas analyser for four different combustion engines fueled with petrol at various operating conditions. During the tests, the content of toxic substances in the exhaust gas of a properly working engine and the engine working with damage to the ignition system were registered. The tests will be used to assess the impact of the damage of the spark-ignition engine on the emission of individual components of toxic fumes.


2020 ◽  
Vol 8 (6) ◽  
pp. 1027-1032

Turbulence is an important parameter to be considered for effective combustion inside a cylinder. Heat transfer inside the cylinder affects the combustion process. Insufficient turbulence leads to incomplete combustion, resulting in pollution. Effective flame propagation leads to higher combustion rates in SI engines which in turn requires enough turbulence. Effective combustion efficiency can be achieved through higher flame propagation velocities. In the present work an attempt has been made to enhance the turbulence inside the cylinder of a single cylinder spark ignition engine by injecting solid nanoparticles into the air fuel mixture.


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