scholarly journals Effect of Metal Additives in the Bed on the Performance Parameters of an Adsorption Chiller with Desalination Function

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7226
Author(s):  
Karol Sztekler ◽  
Wojciech Kalawa ◽  
Łukasz Mika ◽  
Marcin Sowa
Keyword(s):  
Silica Gel ◽  
Electricity Consumption ◽  
Sorption Kinetics ◽  
Coefficient Of Performance ◽  
Cooling Power ◽  
Adsorption Chiller ◽  
Cycle Times ◽  
Metal Additives ◽  
Low Performance ◽  
Kinetics Of

Adsorption chillers with desalination functionality, being devices characterised by very low electricity consumption, provide an alternative to conventional sources of cooling and water. The option of desalinating water means that the use of a single device enables obtaining two useful products. Adsorption chillers are not widely used at present. due to their low performance characteristics; these are, however, constantly being improved. This paper presents a verification of the possibility of increasing the cooling coefficient of performance (COP) and specific cooling power (SCP) of a laboratory adsorption chiller by optimising the length of cycle times and using a copper additive to silica gel with a mass fraction of 15% to increase heat transport in the bed. The choice of copper among other considered additives was determined by the conclusions from the research on the sorption kinetics of various mixtures, price and availability, and a high thermal conductivity. The device was operated in a two-bed mode aimed at producing cooling. The adsorbate was distilled water. The results were compared with those obtained under similar conditions when the beds were only filled with silica gel. As a result of the testing, it was found that the use of the copper additive with the sorbent increased both the COP and SCP. The tests were performed for different cycle times, of 100, 200, 300 and 600 s. With increasing cycle time COP also increased. In contrast, the specific cooling power increased only up to a certain point, whereafter its value decreased.

scholarly journals Effect of Additives on the Sorption Kinetics of a Silica Gel Bed in Adsorption Chiller

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1083
Author(s):  
Karol Sztekler ◽  
Wojciech Kalawa ◽  
Łukasz Mika ◽  
Agata Mlonka-Medrala ◽  
Marcin Sowa ◽  
...  
Keyword(s):  
Silica Gel ◽  
Adsorbed Water ◽  
Sorption Process ◽  
Sorption Kinetics ◽  
Experimental Results ◽  
Process Time ◽  
Vapor Sorption ◽  
Dynamic Vapor Sorption ◽  
Adsorption Chiller ◽  
Kinetics Of

The article presents experimental results of the metal-based and carbon nanotube additives influence on sorption kinetics of a silica-gel-based adsorption bed in an adsorption chiller. The purpose of the doping is to improve the efficiency of sorption processes within the bed by use of metallic and non-metallic additives characterized by higher thermal diffusivity than basic adsorption material. The higher the thermal conductivity of the bed, the faster the sorption processes take place, which directly translates into greater efficiency of the refrigerator. In this study, sorption kinetics of pure silica gel sorbent doped with a given amount of aluminum (Al) and copper (Cu) powders and carbon nanotubes (CNT) were analyzed. The tests were performed on DVS Dynamic Gravimetric Vapor Sorption System apparatus used for dynamic vapor sorption measurements. A decrease in the amount of adsorbed water was observed with an increase in the mass share of the additives in the performed studies. Experimental results show that, CNTs seems to be the most promising additive as the sorption process time was reduced with the smallest decrease in water uptake. Any significant reduction of adsorption time was noted in case of the Al addition. Whereas, in case of Cu doping, delamination of the mixture was observed.

scholarly journals Absorption and adsorption chillers applied to air conditioning systems

2010 ◽  
Vol 31 (2) ◽  
pp. 77-94 ◽  
Author(s):  
Agnieszka Kuczyńska ◽  
Władysław Szaflik
Keyword(s):  
Heat Source ◽  
Air Conditioning ◽  
Coefficient Of Performance ◽  
Cooling Power ◽  
Geothermal Heat ◽  
Pump System ◽  
Desorption Process ◽  
Heat Pump System ◽  
Adsorption Chiller ◽  
Air Conditioning Systems

Absorption and adsorption chillers applied to air conditioning systemsThis work presents an application possibility of sorption refrigerators driven by low temperature fluid for air conditioning of buildings. Thermodynamic models were formulated and absorption LiBr-water chiller with 10 kW cooling power as well as adsorption chiller with silica gel bed were investigated. Both of them are using water for desorption process with temperatureTdes= 80 °C. Coefficient of performance (COP) for both cooling cycles was analyzed in the same conditions of the driving heat source, cooling waterTc= 25 °C and temperature in evaporatorTevap= 5 °C. In this study, the computer software EES was used to investigate the performance of absorption heat pump system and its behaviour in configuration with geothermal heat source.

Performance Analysis of a Silica Gel-Water Adsorption Cooler: Impact of Nanofluids on Cooler Performance and Size

2015 ◽  
Author(s):  
I. P. Koronaki ◽  
M. T. Nitsas ◽  
E. G. Papoutsis ◽  
V. D. Papaefthimiou
Keyword(s):  
Heat Transfer ◽  
Silica Gel ◽  
Cooling Capacity ◽  
Heat Pumps ◽  
Coefficient Of Performance ◽  
Theoretical Research ◽  
Adsorption Chiller ◽  
Heat Transfer Fluids ◽  
Thermally Driven ◽  
Sorption Heat

Thermally driven chillers also known as sorption heat pumps have drawn considerable attention in recent years. They can be divided into two main categories: absorption (liquid-vapor) and adsorption (solid-vapor) systems. Even though adsorption cycles have relatively lower coefficient of performance compared to absorption cycles, however they prevail in terms of heat source, electric consumption for moving parts, crystallization etc. In order to overcome the drawback of low COP and specific cooling capacity, nanofluids, i.e. mixtures of nanometer size particles well-dispersed in a base fluid, can be used as heat transfer fluids as recent experimental and theoretical research has proved that nanofluids can exhibit a significant increase on heat transfer. In this study a two bed, single-stage adsorption chiller which utilizes the silica gel-water pair as adsorbent-refrigerant is simulated. The cooling capacity and the COP of the chiller are calculated for various cycle times. The usage of nanofluids as heat transfer fluids in the chiller evaporator and condenser and their effect on chiller performance and size is investigated. It is proved that the presence of nanofluids at different volume concentrations will enhance the cooling capacity and the COP of the adsorption chiller and therefore will lead to smaller, in terms of size, heat exchangers.

scholarly journals Desalination of Agricultural Wastewater by Solar Adsorption System: A Numerical Study

2021 ◽  
Vol 10 (4) ◽  
pp. 901-910
Author(s):  
Jehan F AlRubaiea ◽  
Farkad A Latteiff ◽  
Jasim M Mahdi ◽  
Mohammed A Atiya ◽  
Hasan Sh Majdi
Keyword(s):  
Silica Gel ◽  
Numerical Study ◽  
High Energy ◽  
Water Desalination ◽  
Hot Water ◽  
Coefficient Of Performance ◽  
Cooling Power ◽  
Adsorption System ◽  
Factors Affecting ◽  
Usage Cost

There are still areas around the world suffer from severe shortage of freshwater supplies. Desalination technologies are not widely used due to their high energy usage, cost, and environmental damaging effects. In this study, a mathematical model of single-bed adsorption desalination system using silica gel-water as working pair is developed and validated via earlier experiments. A very good match between the model predictions and the experimental results is recorded. The objective is to reveal the factors affecting the productivity of fresh water and cooling effect in the solar adsorption system. The proposed model is setup for solving within the commercially-available software (Engineering Equation Solver). It is implemented to solve the mass and heat balance equations for the adsorbent bed, condenser, and evaporator components. At a typical temperature of 89 °C and flow rate of 30 m3/sec for the hot water entering the bed, the following results are reported: (a) the specific daily water production of 1.89 m3 /ton of silica gel/ day, (b) coefficient of performance of 0.32, and (c) specific cooling power of 40.82 W/kg of silica gel. The concentration of salt (X) in the product (desalinated water) has been set with value of 0.5 gm/kg to be suitable for drinking and irrigation. The salt concentration in the evaporator is estimated to be 4.611 gm/kg during the overall adsorption process. The results from this study should be of wide interest for the field of solar water desalination and air-conditioning.

scholarly journals Numerical Simulation of Advanced Adsorption Refrigeration Chiller with Mass Recovery

1970 ◽  
Vol 3 (2) ◽  
pp. 59-67 ◽  
Author(s):  
MZI Khan ◽  
S Sultana ◽  
A Akisawa ◽  
T Kashiwagi
Keyword(s):  
Silica Gel ◽  
Operating Conditions ◽  
Cooling Power ◽  
Inlet Temperature ◽  
Low Grade ◽  
Outlet Temperature ◽  
Adsorption Chiller ◽  
Cycle Simulation ◽  
Chilled Water ◽  
Mass Recovery

This paper investigates the thermodynamic framework of a three-bed advanced adsorption chiller, where the mass recovery scheme has been utilized such that the performances of this chiller could be improved and a CFC-free-based sorption chiller driven by the low-grade waste heat or any renewable energy source can be developed for the next generation of refrigeration. Silica gel-water is chosen as adsorbent-refrigerant pair. The three-bed adsorption chiller comprises with three sorption elements (SEs), one evaporator and one condenser. The configuration of SE1 and SE2 are identical, but the configuration of SE3 is taken as half of SE1 or SE2. Mass recovery process occurs between SE3 with either SE1 or SE2 and no mass recovery between SE1 and SE2 occurs. The mathematical model shown herein is solved numerically. In the present numerical solution, the heat source temperature variation is taken from 50 to 90ºC along with coolant inlet temperature at 30ºC and the chilled water inlet temperature at 14ºC. A cycle simulation computer program is constructed to analyze the influence of operating conditions (hot and cooling water temperature) on COP (coefficient of performance), SCP (specific cooling power), η (chiller efficiency) and chilled water outlet temperature. Keywords: Adsorption; COP; SCP; Mass recovery; Silica gel-waterDOI: 10.3329/jname.v3i2.920 Journal of Naval Architecture and Marine Engineering 3(2006) 59-67 

Two-Stage Non-Regenerative Silica Gel-Water Adsorption Refrigeration Cycle

2000 ◽  
Author(s):  
B. B. Saha ◽  
K. C. A. Alam ◽  
A. Akisawa ◽  
T. Kashiwagi ◽  
K. C. Ng ◽  
...  
Keyword(s):  
Heat Pump ◽  
Silica Gel ◽  
Water Adsorption ◽  
Waste Heat ◽  
Cooling Capacity ◽  
Coefficient Of Performance ◽  
Adsorption Refrigeration ◽  
Two Stage ◽  
Adsorption Chiller ◽  
Adsorption Heat Pump

Abstract Over the past two decades there have been considerable efforts to use adsorption (solid/vapor) for cooling and heat pump applications, but intensified efforts were initiated only since the imposition of international restrictions on the production and use of CFCs (chlorofluorocarbons) and HCFCs (hydrochlorofluorocarbons). Closed-type, conventional adsorption refrigeration and heat pump systems have an increasing market share in Japan. In this paper, a two-stage non-regenerative, silica gel-water adsorption chiller design is outlined. Experimental measurements are performed on a prototype of a 3.5 kW rated cooling capacity adsorption heat pump in order to determine its performance under different operating temperatures (hot, cooling and chilled water). The chiller performance is analyzed in terms of cooling capacity and coefficient of performance (COP). The main innovative feature in the two-stage adsorption chiller is the ability to utilize low-temperature waste heat (∼55°C) as the driving source with a cooling source of 30°C. The technological difficulty inherent in operating a thermally activated cycle with such a small regenerating temperature lift (temperature difference between heat source and heat sink inlets) is overcome by use of a two-stage cycle.

scholarly journals Experimental and Theoretical Study of the Energy Flow of a Two Stages Four Generators Adsorption Chiller

2019 ◽  
Vol 14 (2) ◽  
pp. 129-136
Author(s):  
Faeza Mahdi Hadi
Keyword(s):  
Activated Carbon ◽  
Cold Water ◽  
Water Cycle ◽  
Electrical Power ◽  
Hot Water ◽  
Coefficient Of Performance ◽  
Cooling Power ◽  
Low Grade ◽  
Adsorption Chiller ◽  
Two Stages

This work is concerned with a two stages four beds adsorption chiller utilizing activated carbon-methanol adsorption pair that operates on six separated processes. The four beds that act as thermal compressors are powered by a low grade thermal energy in the form of hot water at a temperature range of 65 to 83 °C.  As well as, the water pumps and control cycle consume insignificant electrical power. This adsorption chiller consists of three water cycles. The first water cycle is the driven hot water cycle. The second cycle is the cold water cycle to cool the carbon, which adsorbs the methanol. Finally, the chilled water cycle that is used to overcome the building load. The theoretical results showed that average cycle cooling power is 2.15kW, while the experimental measurement revealed that the cooling capacity of the cycle is about 1.98 kW with a relative error of % 0.02. The generator and condensing temperatures are 83 and 30 °C, respectively. The coefficient of performance (COP) of that chiller was in the range of 0.37 to 0.49. The best operating point and the best working conditions were also investigated. The present chiller is superior more than the single stage, two beds adsorption chiller that works on the activated carbon methanol pair that needs a high ambient temperature.

Modeling a Novel Composite Adsorbent Based Adsorption Chiller Driven by Solar Energy

2013 ◽  
Author(s):  
C. Y. Tso ◽  
S. C. Fu ◽  
Christopher Y. H. Chao
Keyword(s):  
Coefficient Of Performance ◽  
Seasonal Effects ◽  
Cooling Power ◽  
Insulation Material ◽  
Composite Adsorbent ◽  
Adsorption Chiller ◽  
Flat Type ◽  
Collector Temperature ◽  
Typical Summer ◽  
Solar Powered

This paper aims to study the performance of a solar-powered adsorption chiller with a novel composite adsorbent material (silica activated carbon/CaCl2) operating during some typical months in Hong Kong. Modeling is established to investigate the cooling performance of this adsorption chiller driven by flat-type solar collectors with three different configurations of glaze: 1) single glazed cover; 2) double glazed cover and 3) transparent insulation material (TIM) cover. The simulation results show that the higher the solar collector temperature is, the better the coefficient of performance (COP) and the specific cooling power (SCP) of the adsorption chiller are. It is suggested to select a double glazed collector with a small value of the lumped capacitance for this adsorption chiller. Seasonal effects are discussed in which the solar COP achieves its highest value during autumn. However, the cooling capacities in spring, summer and autumn are similar. All in all, this newly developed composite material as adsorbent used in the adsorption chiller could achieve a mean solar COP of 0.36 and SCP of 94W/kg on a typical summer day of operation.

scholarly journals Simultaneous Optimization of Process Operational and Material Parameters for a 2-Bed Adsorption Refrigeration Process

2020 ◽  
Vol 4 (2) ◽  
pp. 31
Author(s):  
Marc Scherle ◽  
Ulrich Nieken
Keyword(s):  
Structural Material ◽  
Material Model ◽  
Heat Pumps ◽  
Simultaneous Optimization ◽  
Coefficient Of Performance ◽  
Cooling Power ◽  
Operational Parameters ◽  
Adsorption Refrigeration ◽  
Adsorption Chiller ◽  
Material Parameters

In process engineering, optimization is usually carried out without the simultaneous consideration of material and process. This issue is addressed in the following contribution. A model-based optimization is presented to improve the performance of adsorption heat pumps. Optimization is carried out in two steps. First, we optimize the operational parameters, the cycle time, and the thickness of the adsorbent for a given adsorption material. In a second step we use a material model to predict heat and mass transfer and adsorption capacity from structural material parameters. This allows us to vary the structural material parameters and calculate the optimal operational parameters for each adsorbent. The two-step optimization thus identifies optimal material properties together with corresponding optimal operational parameters. As constraints, a minimum specific cooling power (SCP) and the passive mass of heat transfer pipes are used. The coefficient of performance (COP) is taken as the objective function. We exemplarily demonstrate the approach for a two-bed adsorption chiller, carbide-derived carbon as the adsorbent, methanol as the sorptive and boron-nitrate as additive to improve heat conductivity. The approach can be easily extended to multi-bed installations and more sophisticated material models.

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