Synthesis and Investigations of Building Blocks with Dibenzo[b,f] Oxepine for Use in Photopharmacology
2021 ◽
Vol 22
(20)
◽
pp. 11033
Keyword(s):
The synthesis of photoswitchable azo-dibenzo[b,f]oxepine derivatives and microtubule inhibitors were described. Subsequently, we examined the reaction of methoxy derivative 3-nitrodibenzo[b,f]oxepine with different aldehydes and in the presence of BF3·OEt2 as a catalyst. Our study provided a very concise method for the construction of the azo-dibenzo[b,f]oxepine skeleton. The analysis of products was run using experimental and theoretical methods. Next, we evaluated the E/Z isomerization of azo-dibenzo[b,f]oxepine derivatives, which could be photochemically controlled using visible-wavelength light.
1993 ◽
Vol 169
(1)
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pp. 15-26
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2016 ◽
Vol 09
(04)
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pp. 1630006
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Keyword(s):
1978 ◽
Vol 82
(11)
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pp. 1288-1295
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Keyword(s):
1997 ◽
Vol 161
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pp. 23-47
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1988 ◽
Vol 46
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pp. 8-9
Keyword(s):
1993 ◽
Vol 51
◽
pp. 876-877
1984 ◽
Vol 105
(1)
◽
pp. 273-287
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2016 ◽
Vol 37
(3)
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pp. 181-193
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