scholarly journals Novel Hybrid Polymer Composites Based on Anthraquinone and Eco-Friendly Dyes with Potential for Use in Intelligent Packaging Materials

2021 ◽  
Vol 22 (22) ◽  
pp. 12524
Author(s):  
Anna Masek ◽  
Angelika Plota ◽  
Julia Chrzastowska ◽  
Małgorzata Piotrowska
Keyword(s):  
Polymer Composites ◽  
Color Change ◽  
Accelerated Aging ◽  
Degradation Process ◽  
Packaging Materials ◽  
Atmospheric Conditions ◽  
Hybrid Polymer ◽  
Intelligent Packaging ◽  
Ethylene Propylene ◽  
Anthraquinone Dyes

This study aimed to present the influence of bio-based and anthraquinone dyes and their combinations on the optical properties of ethylene-propylene (EPM) composites after thermo-oxidative and climatic aging. Therefore, the chosen polymer was filled with a natural, plant-origin flavonoid—quercetin, and with two commercial anthraquinone dyes (C.I. Solvent Yellow 163 and C.I. Solvent Red 207). The manufactured polymer composites were subjected to accelerated aging tests: weathering and thermo-oxidation, respectively. Examination of the materials’ properties indicated that the combination of synthetic and natural dyes can result in better resistance to oxidizing agents and higher thermal stability of ethylene-propylene products. Moreover, color change of quercetin-containing samples due to exposure to simulated atmospheric conditions could be a promising solution for use as aging indicators in intelligent packaging materials that will inform about the ongoing degradation process. Another interesting finding is that these samples exhibited good fungistatic activity against Candida albicans yeast and Aspergillus niger mold. Overall, this novel solution based on hybrid polymer composites containing natural and commercial dyes is a more environmentally friendly alternative to traditional materials used in the plastic packaging industry with better and more desirable properties.

Assessment of Color Stability of Treated Leathers with Silicone Oil and Polyethylene Glycol

2014 ◽  
Vol 1 (1) ◽  
pp. 24-34
Author(s):  
Alireza K. ◽  
Hossein Ahmadi ◽  
Mohsen Mohammadi
Keyword(s):  
Ascorbic Acid ◽  
Polyethylene Glycol ◽  
Treatment Process ◽  
Color Change ◽  
Silicone Oil ◽  
Accelerated Aging ◽  
Color Stability ◽  
Antioxidant Additive ◽  
Before And After ◽  
Aesthetic Values

Lubricants and leather dressings are the most common treatments of dry and water logged historical leathers. Color change has a great importance during the time and treatment process, due to visual and aesthetic values of historic leather relics. Polyethylene glycol (PEG) and silicone oil (SiO) are frequently used leather dressings in the conservation procedures. Therefore, color stability of treated leathers with PEG and SiO were investigated before and after heat accelerated aging. Moreover, application of ascorbic acid was evaluated as an antioxidant additive for PEG (PEG+AA).Color change after treatment and aging were studied by colorimetry technique in the CIE *L*a*b system. Results indicated to severe color alteration in PEG treated and aged leathers with or without ascorbic acid. Whereas, SiO treated samples showed better stability and minimum color shift after aging. Silicone oil was characterized as the best dressing for historical leathers with compared to PEG and PEG+AA, due to its high stability and aesthetical properties.

Hybrid polymer composite materials. Part 2. Preparation technology

2020 ◽  
pp. 8-13
Keyword(s):  
Composite Materials ◽  
Impact Toughness ◽  
Polymer Composites ◽  
The Other ◽  
Polymer Materials ◽  
Hybrid Polymer ◽  
Preparation Technology ◽  
Advantages And Disadvantages ◽  
Hybrid Polymer Composite ◽  
The One

The main methods (pressing and winding) of the processing of hybrid polymer composites to obtain items were examined. Advantages and disadvantages of the methods were noted. Good combinations of different-module fibers (carbon, glass, boron, organic) in hybrid polymer materials are described, which allow one to prepare materials with high compression strength on the one hand, and to increase fracture energy of samples and impact toughness on the other hand.

scholarly journals Tunable Crystalline Phases in UV-Curable PEG-Grafted Ladder-Structured Silsesquioxane/Polyimide Composites

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2295 ◽  
Author(s):  
Ryung Il Kim ◽  
Ju Ho Shin ◽  
Jong Suk Lee ◽  
Jung-Hyun Lee ◽  
Albert S. Lee ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Surface Properties ◽  
Weight Ratio ◽  
Hybrid Polymer ◽  
Water Contact ◽  
Uv Curable ◽  
Wide Range ◽  
Drastic Increase ◽  
Polyimide Composites ◽  
Crystalline Polyethylene

A series of UV-curable hybrid composite blends containing a carboxylic acid functionalized polyimidewith varying amounts of high molecular weight (~1 K) PEG-grafted ladder-structured polysilsesquioxanes copolymerized with methacryl groups were fabricated and their structural, thermal, mechanical, and surface properties characterized. At a composite weight ratio of polyimide above 50 wt.%, a stark shift from amorphous to crystalline polyethylene glycol (PEG) phases were observed, accompanied by a drastic increase in both surface moduli and brittleness index. Moreover, fabricated composites were shown to have a wide range water contact angle, 9.8°–73.8°, attesting to the tunable surface properties of these amphiphilic hybrid polymer composites. The enhanced mechanical properties, combined with the utility of tunable surface hydrophilicity allows for the possible use of these hybrid polymer composites to be utilized as photosensitive polyimide negative photoresists for a myriad of semiconductor patterning processes.

The effect of chemical treatment methods on the outdoor performance of waste textile fiber-reinforced polymer composites

2016 ◽  
Vol 51 (14) ◽  
pp. 2009-2021 ◽  
Author(s):  
Mustafa Bakkal ◽  
M Safa Bodur ◽  
H Ece Sonmez ◽  
B Can Ekim
Keyword(s):  
Polymer Composites ◽  
Water Uptake ◽  
Color Change ◽  
Fiber Reinforced Polymer ◽  
Silane Treatment ◽  
Textile Fiber ◽  
Fiber Reinforced ◽  
Chemical Treatments ◽  
Reinforced Polymer ◽  
Fiber Reinforced Polymer Composites

In this study, weathering effect on untreated textile fiber-reinforced polymer composites and the effect of different chemical treatments for better interfacial adhesion on the outdoor performance were investigated. Degradation of physical, mechanical, and chemical properties of textile fiber-reinforced polymer composites was evaluated through common chemical treatments such as maleated coupling, alkaline treatment, silane treatment, and alkali–silane treatment. Untreated and chemically treated textile fiber-reinforced polymer composites were subjected to water uptake and UV exposure up to 1000 h. Tensile and impact properties were mechanically examined, and the changes on the physical properties due to water uptake, swelling, and color change were investigated. In addition, Fourier transform infrared spectrum analysis was performed in order to evaluate the chemical changes after exposure.

Bulk and nano-mechanical behavior of silver and silver-CNT-reinforced hybrid polymer composites

2015 ◽  
Vol 37 (8) ◽  
pp. 2581-2587 ◽  
Author(s):  
Himel Chakraborty ◽  
Dipa Ray ◽  
Partha Protim Chattopadhyay
Keyword(s):  
Mechanical Behavior ◽  
Polymer Composites ◽  
Hybrid Polymer

Post-Fatigue Creep and Stress Relaxation Response of a Hybrid Polymer Composite

2017 ◽  
Author(s):  
Raghu V. Prakash ◽  
Monalisha Maharana
Keyword(s):  
Stress Relaxation ◽  
Polymer Composites ◽  
Polymer Composite ◽  
Fatigue Loading ◽  
Synthetic Fiber ◽  
Relaxation Response ◽  
Hybrid Polymer ◽  
Fatigue Cycling ◽  
Creep And Stress Relaxation ◽  
Hybrid Polymer Composite

Polymer composites have a characteristic, composition specific visco-elastic property which influences the damage progression during fatigue cycling. While some researchers have studied the time dependent constitutive response of polymer composites during the first cycle of fatigue loading, very few have experimentally investigated the dependence of visco-elastic response of built-up polymer composite materials at various stages of fatigue cycling [1]. Our earlier studies on fatigue response of polymer composites focused primarily on the stiffness degradation as a function of applied cycles of loading, which represents the gross response of the material [2]. While doing such an experiment, complimentary experimental techniques to measure the temperature evolution was attempted through the use of infrared thermal imaging technique, which gave some insight into the change in temperature response as a function of fatigue cycling. However, there was no systematic measurement of creep and stress relaxation response of the composite material as a function of induced fatigue damage. The present paper describes the results of creep and stress-relaxation obtained during uni-axial fatigue loading of a hybrid polymer composite material. For this purpose, a woven carbon fiber mat was chosen as the synthetic fiber and Flax fiber in the unidirectional form was chosen as the natural fiber that is laid between the two layers of woven carbon fiber mat. Epoxy LY 556 and hardener Araldite® was used for building up of composite laminate by hand-lay-up technique. Dog-bone shaped tensile specimens with a gage width of 13 mm and gage length of 57 mm were extracted from the 250 × 250 mm sq. plate laminate of 2.1 mm thickness using a numerical controlled milling machine. The specimens were tested at 35% of their median tensile strengths under fatigue at a positive stress ratio (Pmin/Pmax) of 0.1 in tension-tension loading. Prior to start of fatigue loading, the specimens were held in load control and the strain in the gage length was measured for understanding the creep response over 2500 seconds. For stress-relaxation characterization, the specimens were held in extensometer control over a period of 2500 sec. The creep and stress relaxation tests were carried out after periodic intervals of fatigue cycling. It was observed that in the case of un-impacted specimens, the creep rate is consistent with the stiffness variation, which in turn, is dependent on the number of fatigue cycles - till it showed signs of de-lamination. Thereafter it was governed by the woven synthetic fiber response. Similarly, the stress relaxation response was found to decrease with increasing fatigue cycles. In case of impacted specimens, the local deformation had a prominent role in terms of creep and stress relaxation response.

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